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31. 发明申请

US20090030162A1 Polyether-Functional Siloxanes, Polyether Siloxane-Containing Compositions, Methods For The Production Thereof And Use Thereof 有权
标题翻译：聚醚官能硅氧烷，含聚醚硅氧烷的组合物，其生产方法及其用途
公开(公告)号：US20090030162A1
公开(公告)日：2009-01-29
申请号：US11576504
申请日：2004-11-05
申请人： Ekkehard Mueh , Peter Jenkner , Max Preisenberger , Burkhard Standke
发明人： Ekkehard Mueh , Peter Jenkner , Max Preisenberger , Burkhard Standke
IPC分类号： C08G77/46 , C08L83/12
CPC分类号： C08G77/46 , A61K8/893 , C08L83/12
摘要： The present invention provides a linear, cyclic or branched polyether-functional siloxane or a mixture of polyether-functional siloxanes of the general formula (I) R[—O(3-h)/2Si(R1)(OR)h]x[—O(3-i-j)/2Si(R2)(R3)i(OR)j]y, (II) in which groups R are identical or different and R is essentially H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, 2-methoxyethyl or 2-hydroxyethyl or, in the case of cyclic siloxanes, may be a silyl radical of the silyl units of the formula (I), groups R1 are identical or different and R1 is a terminally blocked polyether group of the formula (II), R4—O[—R5—O]n[(—R6)m]— (II) and groups R2 are identical or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having 1 to 18 carbon atoms or a mercaptoalkyl group or an alkenyl group having 2 to 8 carbon atoms or an alkenyl group having 2 to 8 carbon atoms or an aryl group having 6 to 12 carbon atoms or an aminoalkyl group or the general formula (III) H2N(CH2)d[(NH)e(CH2)f]g—(CH2)3— (III) The present invention further provides aqueous and/or alcoholic compositions which comprise a polyether siloxane according to formula (I), to methods for the production of said systems, and to the use thereof.
摘要翻译：本发明提供通式（I）R [-O（3-h）/ 2Si（R 1）（OR）h] x]的直链，环状或支链聚醚官能的硅氧烷或聚醚官能的硅氧烷的混合物， -O（3-ij）/ 2Si（R2）（R3）i（OR）j] y，（Ⅱ）其中基团R相同或不同，R基本上为H，甲基，乙基，正丙基，异丙基，正丁基，异丁基，叔丁基，2-甲氧基乙基或2-羟乙基，或在环状硅氧烷的情况下，可以是式（I）的甲硅烷基单元的甲硅烷基，基团R1相同或不同，R1 是式（II）的末端封闭的聚醚基团，R4-O [-R5-O] n [（ - R6）m] - （Ⅱ）和基团R2相同或不同，R2是直链，支链或环状，可以具有取代基的碳原子数1〜18的烷基或巯基烷基或碳原子数2〜8的烯基或碳原子数2〜8的烯基或碳原子数6〜12的芳基或氨基烷基，通式（III）H 2 N（CH 2）d [（NH）e（CH 3） 2）f] g-（CH 2）3 - （III）本发明进一步提供包含式（I）的聚醚硅氧烷，用于生产所述体系的方法和用途的水性和/或醇组合物其中。

32. 发明授权

US06297188B1 Magnesium ethoxide having a high coarse particle content, process for its preparation and its use 有权
标题翻译：粗颗粒含量高的乙醇镁，其制备方法及其用途
公开(公告)号：US06297188B1
公开(公告)日：2001-10-02
申请号：US09427926
申请日：1999-10-27
申请人： Reinhold Schork , Burkhard Standke , Hartwig Rauleder , Albert-Johannes Frings , Michael Horn , Peter Jenkner , Jaroslaw Monkiewicz
发明人： Reinhold Schork , Burkhard Standke , Hartwig Rauleder , Albert-Johannes Frings , Michael Horn , Peter Jenkner , Jaroslaw Monkiewicz
IPC分类号： B01J3100
CPC分类号： C07C31/30 , C07C29/70
摘要： Particulate magnesium ethoxide having a high coarse particle content can be obtained in a simple and economical manner by the present invention, which provides a process for preparing particulate magnesium ethoxide having a coarse grain content, and includes reacting metallic, optionally activated, magnesium with liquid ethanol under pressure at a temperature above 78° C. The present invention also relates to particulate magnesium ethoxide having a coarse grain content, which contains: 500 &mgr;m.
摘要翻译：通过本发明可以以简单和经济的方式获得具有高粗颗粒含量的颗粒状乙醇镁，其提供了制备具有粗颗粒含量的颗粒状乙醇镁的方法，并且包括使金属，任选活化的镁与液态乙醇在78℃以上的压力下，本发明还涉及具有粗颗粒含量的颗粒状的乙醇镁，其含有：<40重量％的筛选分数<=500μm和> = 60重量％筛选分数> 500 mum。

33. 发明授权

US6084116A Process for preparing acetoxysilanes 失效
标题翻译：制备乙酰氧基硅烷的方法
公开(公告)号：US6084116A
公开(公告)日：2000-07-04
申请号：US374843
申请日：1999-08-16
申请人： Michael Horn , Albert-Johannes Frings , Peter Jenkner , Jaroslaw Monkiewicz , Burkhard Standke , Bertram Trautvetter
发明人： Michael Horn , Albert-Johannes Frings , Peter Jenkner , Jaroslaw Monkiewicz , Burkhard Standke , Bertram Trautvetter
IPC分类号： B01J31/02 , C07B61/00 , C07F7/04 , C07F7/18 , C07F7/08
CPC分类号： C07F7/1896
摘要： Acetoxysilanes are prepared by a process comprising:(i) reacting at least one chlorosilane with acetic acid in a medium containing acetyl chloride and a catalyst, and removing the hydrogen chloride which is formed during the reaction;(ii) reacting the reaction mixture from step (i) with acetic anhydride; and(iii) separating and obtaining the product acetoxysilane.
摘要翻译：通过以下方法制备毒素溶液：（i）在含有乙酰氯和催化剂的介质中使至少一种氯硅烷与乙酸反应，并除去反应期间形成的氯化氢; （ii）使来自步骤（i）的反应混合物与乙酸酐反应; 和（iii）分离并获得产物乙酰氧基硅烷。

34. 发明申请

US20080003448A1 Stable Solutions of N-Substituted Aminopolysiloxanes, Their Preparation and Use 有权
标题翻译： N-取代氨基聚硅氧烷的稳定溶液及其制备与应用
公开(公告)号：US20080003448A1
公开(公告)日：2008-01-03
申请号：US11569363
申请日：2005-05-12
申请人： Burkhard Standke , Peter Jenkner
发明人： Burkhard Standke , Peter Jenkner
IPC分类号： C07F7/21 , C08G77/26 , C09D183/00 , C09D4/00
CPC分类号： C08J3/095 , C07F7/21 , C08J2383/08 , Y10T428/12569 , Y10T428/31612 , Y10T428/31663
摘要： Stable, low-chloride solutions of hydrosalts of organic acids with cationic N substituted aminopolysiloxanes of the formula (I) in which groups R independently of each other are each benzyl or vinylbenzyl, groups Y are identical or different and Y is an alkoxy or hydroxyl group or 01/2, A is an organic carboxylic acid and 0≦a
摘要翻译：其中基团R各自独立地为苄基或乙烯基苄基的式（I）的阳离子N取代的氨基聚硅氧烷的有机酸稳定的低氯化物溶液是相同或不同的，Y是烷氧基或羟基或0 <1/2，A是有机羧酸，0 <= a <2,0 <= b <= c1 = 0.125,0.125 <=（a + b）≤3 和x> = 2，其基本上以低级醇中的T结构单元的形式存在。通过与NaOH或醇钠或与有机羧酸A的钠盐反应，从阳离子N-取代的氨基聚硅氧烷的相应的盐酸盐进行制备，析出和除去NaCl。这些溶液用作有机和无机表面之间的粘合促进剂，与有机聚合物与无机填料，玻璃纤维或金属颗粒的增强有关，或与无机表面与有机聚合物的涂层有关，其中氨基聚硅氧烷涂层厚度为达到800nm。

35. 发明授权

US06491838B1 Triamino- and fluoroalkyl-functional organosiloxanes 有权
标题翻译：三氨基和氟烷基官能的有机硅氧烷
公开(公告)号：US06491838B1
公开(公告)日：2002-12-10
申请号：US09712224
申请日：2000-11-15
申请人： Burkhard Standke , Michael Horn , Peter Jenkner , Jaroslaw Monkiewicz
发明人： Burkhard Standke , Michael Horn , Peter Jenkner , Jaroslaw Monkiewicz
IPC分类号： C14C900
CPC分类号： C04B41/009 , C01P2004/64 , C02F1/00 , C04B41/4961 , C07F7/12 , C08G77/24 , C08G77/26 , C08L83/08 , C09C3/12 , C09D183/08 , C23C2222/20 , C04B14/043
摘要： An organosiloxane which has at least one triamino group of formula I: [NHx(CH2)aNHy(CH2)bNHz]— (I) which is bonded to at least one silicon atom via at least one N-bonded alkylene group having 1 to 4 C atoms, a and b are identical or different and are each an integer ranging from 1 to 6, x is 0 or 1 or 2, y is 0 or 1, z is 0 or 1 or 2, with the proviso that (x+y+z)≦4, and at least one Si—C-bonded fluoroalkyl group of formula II: F3C(CF2)r(CH2)s— (II) wherein r is 0 or an integer ranging from 1 to 18 and s is 0 or 2.
摘要翻译：具有至少一个式I的三氨基的有机硅氧烷：其通过至少一个具有1-4个C原子的N-键合的亚烷基与至少一个硅原子键合，a和b相同或不同，并且各自为整数范围从1到6，x是0或1或2，y是0或1，z是0或1或2，条件是（x + y + z）<= 4，并且至少一个Si-C- 式II的键合氟代烷基：其中r为0或1至18的整数，s为0或2。

36. 发明授权

US5646325A Process for the preparation of 3-acryloyloxypropylalkoxysilanes 失效
标题翻译： 3-丙烯酰氧基丙基烷氧基硅烷的制备方法
公开(公告)号：US5646325A
公开(公告)日：1997-07-08
申请号：US533313
申请日：1995-09-25
申请人： Jaroslaw Monkiewicz , Albert Frings , Michael Horn , Peter Jenkner , Hans-Joachim Koetzsch , Frank Kropfgans , Claus-Dietrich Seiler , Hans-Guenther Srebny , Burkhard Standke
发明人： Jaroslaw Monkiewicz , Albert Frings , Michael Horn , Peter Jenkner , Hans-Joachim Koetzsch , Frank Kropfgans , Claus-Dietrich Seiler , Hans-Guenther Srebny , Burkhard Standke
IPC分类号： B01J31/12 , C07B61/00 , C07F7/18 , C07F7/08
CPC分类号： C07F7/1876
摘要： 3-Acryloyloxypropylalkoxysilanes of formula I:CH.sub.2 .dbd.C(R)C(O)O(CH.sub.2).sub.3 Si(R.sup.1).sub.a (OR.sup.2).sub.3-a (I)are prepared by reacting a hydridosilane of formula II:HSi(R.sup.1).sub.a (OR.sup.2).sub.3-a (II)with an allyl ester of formula III:CH.sub.2 .dbd.C(R)C(O)OCH.sub.2 CH.dbd.CH.sub.2 (III),where R is a hydrogen atom or a methyl group, R.sup.1 and R.sup.2 are each C.sub.1 to C.sub.6 alkyl groups or phenyl groups, and a is 0, 1 or 2, in the presence of a platinum catalyst.
摘要翻译：通式I的氢化硅烷：HSi（R1）a（I）通过使式II的氢化硅烷反应来制备式I的3-丙烯酰氧基丙基烷氧基硅烷：CH 2 = C（R）C（O）O（CH 2）3 Si （OR 2）3-a（II）与式III的烯丙基酯：CH 2 = C（R）C（O）OCH 2 CH = CH 2（III），其中R是氢原子或甲基， C1-C6烷基或苯基，a是0,1或2，在铂催化剂的存在下。

37. 发明授权

US08147918B2 Water-dilutable sol-gel composition 有权
标题翻译：水可稀释溶胶 - 凝胶组合物
公开(公告)号：US08147918B2
公开(公告)日：2012-04-03
申请号：US12159785
申请日：2006-12-06
申请人： Burkhard Standke , Christian Wassmer , Peter Jenkner
发明人： Burkhard Standke , Christian Wassmer , Peter Jenkner
IPC分类号： B05D1/00 , B05D3/00
CPC分类号： C09D4/00 , C09D5/08 , C09D183/14 , C23C2222/20 , Y10T428/31663 , C08G77/04
摘要： The present invention provides a sol-gel composition which is dilutable with water in any proportion and is based on the reaction of at least the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having a solids content of >1% by weight, (iii) an organic acid as hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, starting from a mass ratio of the solids mass of component (ii) to component (i) 0.75, a process for preparing it and its use, in particular as a sol-gel composition for corrosion control coatings, a corresponding corrosion control coat or primer coat, and articles equipped with such a coating.
摘要翻译：本发明提供一种溶胶 - 凝胶组合物，其可以以任何比例用水稀释，并且基于至少以下组分的反应：（i）缩水甘油氧基丙基烷氧基硅烷，（ii）固体含量> 1的水性硅溶胶（iii）作为水解催化剂的有机酸，和（iv）锆酸正丙酯，钛酸丁酯或乙酰丙酮钛作为交联剂，从组分（ii）与组分（i）的固体质量的质量比开始， 0.75，其制备方法及其用途，特别是作为腐蚀控制涂料的溶胶 - 凝胶组合物，相应的腐蚀控制涂层或底漆涂层以及配备有这种涂层的制品。

38. 发明授权

US5817854A Process for the preparation of organocarbonoyloxysilanes 失效
标题翻译：制备有机碳酰氧基硅烷的方法
公开(公告)号：US5817854A
公开(公告)日：1998-10-06
申请号：US978025
申请日：1997-11-25
申请人： Michael Horn , Albert-Johannes Frings , Peter Jenkner , Jaroslaw Monkiewicz , Claus-Dietrich Seiler , Burkhard Standke , Bertram Trautvetter
发明人： Michael Horn , Albert-Johannes Frings , Peter Jenkner , Jaroslaw Monkiewicz , Claus-Dietrich Seiler , Burkhard Standke , Bertram Trautvetter
IPC分类号： B01J31/02 , C07B61/00 , C07F7/18 , C07F7/08
CPC分类号： C07F7/1896
摘要： Organocarbonoyloxysilanes are prepared by reacting an organochlorosilane with a carboxylic acid in a first step which liberates HCl, removing the HCl which is formed, reacting the reaction mixture from the first step with a carboxylic acid anhydride in a second reaction step, the first and/or second reaction steps being conducted in the presence of a catalyst, and isolating the resulting organocarbonoyloxysilane product from the reaction mixture.
摘要翻译：有机氯硅烷与羧酸反应制备，第一步是释放HCl，除去形成的HCl，使第一步的反应混合物与羧酸酐在第二反应步骤中反应，第一和/或在催化剂存在下进行第二反应步骤，并从反应混合物中分离得到的有机碳硅烷氧基硅烷产物。

39. 发明申请

US20090022898A1 WATER-DILUTABLE SOL-GEL COMPOSITION 有权
标题翻译：水可溶性凝胶组合物
公开(公告)号：US20090022898A1
公开(公告)日：2009-01-22
申请号：US12159785
申请日：2006-12-06
申请人： Burkhard Standke , Christian Wassmer , Peter Jenkner
发明人： Burkhard Standke , Christian Wassmer , Peter Jenkner
IPC分类号： C09D5/00 , C09D4/00
CPC分类号： C09D4/00 , C09D5/08 , C09D183/14 , C23C2222/20 , Y10T428/31663 , C08G77/04
摘要： The present invention provides a sol-gel composition which is dilutable with water in any proportion and is based on the reaction of at least the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having a solids content of >1% by weight, (iii) an organic acid as hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, starting from a mass ratio of the solids mass of component (ii) to component (i) 0.75, a process for preparing it and its use, in particular as a sol-gel composition for corrosion control coatings, a corresponding corrosion control coat or primer coat, and articles equipped with such a coating.
摘要翻译：本发明提供一种溶胶 - 凝胶组合物，其可以以任何比例用水稀释，并且基于至少以下组分的反应：（i）缩水甘油氧基丙基烷氧基硅烷，（ii）固体含量> 1的水性硅溶胶（iii）作为水解催化剂的有机酸，和（iv）锆酸正丙酯，钛酸丁酯或乙酰丙酮钛作为交联剂，从组分（ii）与组分（i）的固体质量的质量比开始， 0.75，其制备方法及其用途，特别是作为腐蚀控制涂料的溶胶 - 凝胶组合物，相应的腐蚀控制涂层或底漆涂层以及配备有这种涂层的制品。

40. 发明授权

US06255516B1 Process for preparing fluoroalkyl-containing organosilicon compounds, and their use 有权
标题翻译：制备含氟烷基的有机硅化合物的方法及其应用
公开(公告)号：US06255516B1
公开(公告)日：2001-07-03
申请号：US09207988
申请日：1998-12-09
申请人： Peter Jenkner , Albert-Johannes Frings , Michael Horn , Jaroslaw Monkiewicz , Burkhard Standke
发明人： Peter Jenkner , Albert-Johannes Frings , Michael Horn , Jaroslaw Monkiewicz , Burkhard Standke
IPC分类号： C07F708
CPC分类号： D06M13/517 , C03C17/30 , C04B41/4933 , C07F7/14 , C07F7/1876 , C08G77/385 , C23C30/00 , D06M15/657
摘要： Fluoroalkyl organosilicon compounds are prepared by reacting fluoroolefins with organosilicon compounds that contain at least one H-Si group, in the presence of a Pt(0) complex catalyst. Further, fluoroalkylalkoxy organosilicon compounds are prepared by esterifying fluoroalkyl organosilicon compounds. The process proceeds uniformly under mild conditions with high yields and selectivities.
摘要翻译：氟烷基有机硅化合物是通过氟代烯烃与含有至少一个H-Si基团的有机硅化合物在Pt（0）配位催化剂的存在下反应来制备的。此外，通过酯化氟烷基有机硅化合物制备氟代烷基烷氧基有机硅化合物。该方法在高产率和选择性的温和条件下均匀地进行。

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