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    • 37. 发明专利
    • SEMICONDUCTOR MANUFACTURE AND DEVICE
    • JP2000216160A
    • 2000-08-04
    • JP1800399
    • 1999-01-27
    • HITACHI LTD
    • MIYAKE TATSUYAOTAKE ICHIROPETECK HARVOETAKEDA KENICHIHINODE KENJI
    • H01L21/3205H01L21/28H01L23/52
    • PROBLEM TO BE SOLVED: To enable fine strcutures of metal and metal oxide to be formed and to form a metal wiring without burying metal or etching a metal wiring directly, by a method wherein a metal oxide such as a copper oxide or the like is locally reduced by the use of a reducing gas beam of atomic hydrogen or the like. SOLUTION: A titanium nitride film 3 is formed on a silicon oxide substrate 2 in a vacuum so as to prevent copper from diffusing internally, and a copper oxide layer 4 is formed thereon. The copper oxide layer 4 is formed through two methods, one is that copper is evaporated and oxidized by oxygen and the other is that copper oxide is evaporated directly sputtering. A titanium nitride mask 5 is formed on the copper oxide layer 4 through a lithography method, and the titanium nitride mask 5 is irradiated with an atomic hydrogen beam 1 from above. At this point, the substrate 2 provided with the copper oxide layer 4 is kept at a temperature of 300 deg.C or so by heating. The atomic hydrogen beam 1 does not react on the mask 5 but reduces the copper oxide layer 4 reacting on it, by which a copper wiring 6 is formed.
    • 38. 发明专利
    • POLISHING METHOD
    • JPH11195628A
    • 1999-07-21
    • JP27693798
    • 1998-09-30
    • HITACHI LTD
    • KONDO SEIICHIHONMA YOSHIOSAKUMA NORIYUKITAKEDA KENICHIHINODE KENJI
    • B24B37/00C09K3/14H01L21/304
    • PROBLEM TO BE SOLVED: To suppress occurrence of dishing or erosion at the time of forming buried wiring, by mechanically rubbing the surface of a metallic film by using such an abrasive solution that contains abrasive grains at a low concentration of a specific wt.% or lower, and has a pH and an oxidation-reduction potential which fall within the corrosive region of the metallic film. SOLUTION: After a BPSG film (boron- and phosphorus-added silicon oxide film 24 and a silicon oxide film 23 are formed on a silicon substrate 25 on which an impurity-doped layer or insulating film is formed, a groove pattern for wiring is formed into the silicon oxide film 24 to a depth of 500 nm through a lithography process and a dry etching process. Then, after a TiN layer 22 is formed on the silicon oxide film 23 as an adhesive layer, a thin copper film 21 is continuously formed in a vacuum by the sputtering method. After the copper film 21 is formed, the surface of the film 21 is mechanically rubbed by using such an abrasive solution that contains abrasive grains at a low concentration of 0.2 which fall within the corrosive region of the film 21.
    • 39. 发明专利
    • POLISHING
    • JPH11135466A
    • 1999-05-21
    • JP29993797
    • 1997-10-31
    • HITACHI LTD
    • KONDO SEIICHIHONMA YOSHIOSAKUMA NORIYUKITAKEDA KENICHIHINODE KENJI
    • B24B37/00B24B37/04C09G1/02C09K3/14H01L21/02H01L21/304H01L21/321
    • PROBLEM TO BE SOLVED: To suppress generation of dishing and erosion when buried wiring is formed and to reduce the damage such as scratch, etc., by mechanically rubbing a metal film surface using a polishing solution containing no or low concentration of polishing abrasive grains, and having a pH and a oxidation reduction potential in the corrosion region of the metal film. SOLUTION: CPM is carried out by rotating a holder 12 supporting a wafer 14 via a backing pad 18 on a fixed panel 11 on which a polishing cloth 17 is applied. A retainer ring 13 is provided so that the wafer does not come off. A polishing solution is dropped on the polishing cloth from a first supply port 15 provided on the fixed panel to perform the CPM, and the supply of the polishing solution is stopped when the CPM is terminated, and pure water is supplied from a second supplying port 16 to perform rinse. Herein, a metal film surface is mechanically rubbed using a polishing solution, containing no polishing abrasive grains or low concentration of not more than 1 wt.% of polishing abrasive grains, and having a pH and an oxidation reduction potential in the corrosion region of the metal film.
    • 40. 发明专利
    • WIRING FORMATION METHOD AND MANUFACTURE OF SEMICONDUCTOR DEVICE
    • JPH1140526A
    • 1999-02-12
    • JP19619897
    • 1997-07-22
    • HITACHI LTD
    • KONDO SEIICHIHONMA YOSHIOSAKUMA NORIYUKITAKEDA KENICHIHINODE KENJI
    • H01L21/304
    • PROBLEM TO BE SOLVED: To perform chemical mechanical polishing at a high polishing speed, by forming a conductive film on a base body comprising a rough surface, removing the conductive film on the protruding part of the base body by chemical mechanical polishing, and making the conductive film contact a liquid containing an anti-corrosion material, for suppressing corrosion of a material forming wiring. SOLUTION: A silicon nitride film and a silicon oxide film are formed in order on a silicon substrate, and a wiring groove pattern is formed in a lithography process and a dry-etching process. Over it, a titanium nitride is film-formed as an adhesive layer, and a copper thin film is continuously film-formed in vacuum by a sputtering method. Then, an abrasive liquid is dropped from a first supply opening 15 onto an abrasive cloth, for chemical mechanical polishing. When the polishing ends, the first supply opening 15 is closed to stop supplying of the abrasive liquid, then an anti-corrosion liquid (water solution of anti- corrosion material or such non-aqueous liquid as alcohol) is supplied from a second supply opening 16 without delay while rotation of a level block 11 and a carrier 12 is kept, after that, flushing with pure water is performed.