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31. 发明授权

US4607083A Long-term stability of the electrical conductivity of pyrrol polymers 失效
标题翻译：长期稳定的导电性的吡咯聚合物
公开(公告)号：US4607083A
公开(公告)日：1986-08-19
申请号：US684033
申请日：1984-12-20
申请人： Helmut Muenstedt , Herbert Naarmann
发明人： Helmut Muenstedt , Herbert Naarmann
IPC分类号： C08G61/00 , C08F8/00 , C08G61/10 , C08G61/12 , H01B1/12 , C08F283/00
CPC分类号： H01B1/128 , C08F8/00
摘要： The long-term stability of the electrical conductivity of pyrrole polymers is improved by a process in which the polymers are treated with an aqueous alkali metal hydroxide solution. Pyrrole polymers treated in this manner are used as electrical conductor elements or resistive films.
摘要翻译：通过其中聚合物用碱金属氢氧化物水溶液处理的方法改善了吡咯聚合物的电导率的长期稳定性。以这种方式处理的吡咯聚合物用作电导体元件或电阻膜。

32. 发明授权

US4585536A Ion exchange membranes consisting of pyrrole polymers 失效
标题翻译：由吡咯聚合物组成的离子交换膜
公开(公告)号：US4585536A
公开(公告)日：1986-04-29
申请号：US603241
申请日：1984-04-23
申请人： Hermann Puetter , Herbert Naarmann , Klaus Penzien
发明人： Hermann Puetter , Herbert Naarmann , Klaus Penzien
IPC分类号： H01M8/18 , B01D57/02 , B01D69/02 , B01J47/12 , C02F1/42 , C08J5/22 , C08L45/00 , C25B13/08 , G01N27/416 , H01M2/16 , H01M8/02 , H01M10/36
CPC分类号： B01D61/46 , B01D61/44 , B01D71/72 , C08J5/2256 , C25B13/08 , H01M10/36 , H01M2/1653 , C08J2379/06 , H01M2300/0005
摘要： Electrochemical processes for selectively separating ions in aqueous soltuion are carried out using apparatuses in which two or more different spaces are separated by means of ion exchange membranes, and the membrane material consists of electrochemically prepared pyrrole polymers. Such ion exchange membranes are used as proton and anion exchange membranes.
摘要翻译：使用其中两个或更多个不同空间通过离子交换膜分离的装置进行在水溶液中选择性分离离子的电化学方法，并且膜材料由电化学制备的吡咯聚合物组成。这种离子交换膜用作质子和阴离子交换膜。

33. 发明授权

US4567250A Preparation of finely divided electrically conductive pyrrole polymers 失效
标题翻译：精细分散的导电吡咯聚合物的制备
公开(公告)号：US4567250A
公开(公告)日：1986-01-28
申请号：US631947
申请日：1984-07-18
申请人： Herbert Naarmann , Walter Heckmann , Gernot Kohler , Petr Simak
发明人： Herbert Naarmann , Walter Heckmann , Gernot Kohler , Petr Simak
IPC分类号： C08G61/00 , C08G61/10 , C08G61/12 , C08G73/06 , H01B1/12 , C08G73/20 , C07D207/30
CPC分类号： H01B1/127 , C08G61/124 , C08G73/0611
摘要： Finely divided electrically conductive pyrrole polymers are prepared by a process in which the pyrroles, in solution and in the presence of a conductive salt, are treated with an oxygen-containing oxidizing agent. The finely divided conductive pyrrole polymers can be used for the production of moldings.
摘要翻译：细分导电的吡咯聚合物通过其中在溶液中和在导电盐存在下用含氧氧化剂处理吡咯的方法制备。精细分散的导电吡咯聚合物可用于生产模制品。

34. 发明授权

US4547270A Electrochemical polymerization of pyrroles, an anode for carrying this out, and products obtained by this procedure 失效
标题翻译：吡咯的电化学聚合，用于进行该反应的阳极，以及通过该方法获得的产物
公开(公告)号：US4547270A
公开(公告)日：1985-10-15
申请号：US633282
申请日：1984-07-23
申请人： Herbert Naarmann
发明人： Herbert Naarmann
IPC分类号： C25B3/10 , C08G61/12 , C08G73/06 , C25B11/03 , D06M10/10 , D06M13/02 , D06M13/322 , D06M13/35 , D06M13/352 , D06M15/00 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/16 , H01B1/12 , C25B3/02
CPC分类号： C25B11/03 , C08G61/124 , C08G73/0611 , D06M10/10 , H01B1/127
摘要： Pyrroles or mixtures of pyrroles with comonomers are polymerized electrochemically by anodic oxidation of the monomers in solution or dispersion in an electrolyte solvent, in the presence of a conductive salt, with deposition of the pyrrole polymer at the sheet-like anode, by a process in which the anode used consists of an electrically non-conductive sheet-like element which can be impregnated with the electrolyte solution and one or more electrically conducting support and contact strips which connects electrically to a current supply for the anode.The special anode for the electrochemical polymerization of pyrroles, and the products obtainable by the process.
摘要翻译：吡咯或共聚单体的混合物通过在导电盐存在下溶液或分散体中的单体在电解质溶剂中的阳离子氧化，通过在片状阳极上沉积吡咯聚合物，通过在所使用的阳极包括可以浸渍电解质溶液的非导电片状元件和一个电连接到用于阳极的电流源的导电支撑和接触条。用于吡咯的电化学聚合的特殊阳极，以及通过该方法获得的产物。

35. 发明授权

US4518535A Preparation of electrically conductive systems from substituted phenalenes, and the products obtained 失效
标题翻译：由取代的非对映体制备导电体系，得到的产物
公开(公告)号：US4518535A
公开(公告)日：1985-05-21
申请号：US491717
申请日：1983-05-05
申请人： Herbert Naarmann , Volker Muench , Gernot Kohler , Petr Simak
发明人： Herbert Naarmann , Volker Muench , Gernot Kohler , Petr Simak
IPC分类号： C09K3/16 , C07F1/00 , C07F11/00 , C07F13/00 , C07F15/00 , C08G79/00 , C08K5/00 , H01B1/12 , H01L51/30 , C07F1/08 , C07F1/10 , C07F15/02
CPC分类号： H01B1/121 , C08G79/00 , C08K5/0075 , C08K5/0091 , H01L51/0051 , H01L51/0052 , H01L51/0077 , Y02E10/549
摘要： Air-stable, electrically conductive systems having conductivities greater than 1.times.10.sup.-3 .OMEGA..sup.-1 cm.sup.-1 are prepared by reacting a metal cation of an element of sub-group VII, VIII or I of the periodic table with a 1,9-substituted phenalene of the general formula (I) ##STR1## where X is O, NH, S, Se or Te and Y is OH, NH.sub.2 or SH, to give a metal chelate, and oxidizing this metal chelate by means of an organic electron acceptor. The electrically conductive systems can be used in the electrical industry for the production of solar cells and for converting and fixing radiation, for producing electric and magnetic switches and electrochemical stores, and for the antistatic treatment of plastics.
摘要翻译：通过使元素周期表第Ⅶ族，Ⅷ族或第Ⅵ族元素的金属阳离子与1,9-取代的非那苯甲醛反应，制备电导率大于1×10-3欧姆 - 1cm -1的空气稳定的导电体系的通式（I）其中X是O，NH，S，Se或Te，Y是OH，NH 2或SH，得到金属螯合物，并通过有机物氧化该金属螯合物电子受体。导电系统可用于电气工业中用于生产太阳能电池和用于转换和固定辐射，用于生产电磁开关和电化学存储器以及用于塑料的抗静电处理。

36. 发明授权

US4488986A Preparation of electrically conductive polyarylene compounds having electron-attracting side groups 失效
标题翻译：具有吸电子基团的导电聚亚芳基化合物的制备
公开(公告)号：US4488986A
公开(公告)日：1984-12-18
申请号：US519507
申请日：1983-08-02
申请人： Herbert Naarmann , Petr Simak , Gernot Kohler
发明人： Herbert Naarmann , Petr Simak , Gernot Kohler
IPC分类号： C08L65/00 , C07C57/42 , C08F8/30 , C08F8/42 , C08F38/00 , C08G16/00 , C08G61/00 , C08L101/00 , H01B1/12 , H01M4/60 , H01B1/06
CPC分类号： C07C255/00 , C07C57/42 , C08L101/00 , H01B1/128 , H01M4/60 , C08L2201/04
摘要： Electrically conductive polymeric systems having electrical conductivities greater than 10.sup.-4 S/cm are prepared by a method wherein a polyarylene compound which contains one or more chain members of the formula ##STR1## where n is greater than 1, preferably from 5 to 50, R is a nitrile, acid amide, carboxyl or ester group, R.sup.1 and R.sup.2 are each hydrogen or a nitrile, acid amide, carboxyl or ester group, with the proviso that in each case one of the radicals R.sup.1 and R.sup.2 is hydrogen and the other is a nitrile, acid amide, carboxyl or ester group, and Y is an aromatic radical, preferably phenylene, is doped, in the absence of moisture and oxygen, with from 0.03 to 0.9 mole percent of an electron-attracting or electron-donating complexing agent. The resulting electrically conductive polymeric systems are useful in the electrical industry for the production of solar cells, for converting and fixing electromagnetic radiation and for the production of electrical and magnetic switches and electrical storage devices, and can be used for the antistatic treatment of plastics.
摘要翻译：电导率大于10 -4 S / cm的导电聚合体系通过一种方法制备，其中含有一个或多个下式的链成员的聚亚芳基化合物，其中n大于1，优选为5至50， R是腈，酰胺，羧基或酯基，R 1和R 2各自为氢或腈，酰胺，羧基或酯基，条件是在每种情况下，基团R 1和R 2中的一个为氢，另一个为氢是腈，酰胺，羧基或酯基，并且Y是芳族基团，优选亚苯基，在没有水分和氧的情况下掺杂有0.03-0.9摩尔％的吸电子或给电子络合物代理商所得到的导电聚合物体系可用于电气工业中用于生产太阳能电池，用于转换和固定电磁辐射以及生产电磁开关和电存储装置，并可用于塑料的抗静电处理。

37. 发明授权

US4418187A Preparation of electrically conductive polymers 失效
标题翻译：导电聚合物的制备
公开(公告)号：US4418187A
公开(公告)日：1983-11-29
申请号：US254258
申请日：1981-04-15
申请人： Volker Muench , Herbert Naarmann , Klaus Penzien
发明人： Volker Muench , Herbert Naarmann , Klaus Penzien
IPC分类号： C08F4/06 , C08F38/00 , H01L51/30 , C08F112/32 , C08F126/00 , C08F126/06 , C08F126/12
CPC分类号： H01L51/004 , C08F38/00 , H01L51/0042 , Y02E10/549
摘要： A process for the preparation of electrically conductive polymers by polymerizing acenaphthylene, N-vinyl-heterocyclics, eg. N-vinylcarbazole or N-vinylpyridine, or N,N-divinylaniline at from -80.degree. to +100.degree. C. in the presence of a cationtic catalyst, wherein from 1 to 50 percent by weight of an oxidizing Lewis acid, preferably FeCl.sub.3, FeBr.sub.3, SbCl.sub.5, SbF.sub.5, AsF.sub.5 or CF.sub.3 -SO.sub.3 H, or a combination of AlCl.sub.3 or TiCl.sub.4 with the said compounds or with CrO.sub.3 or OsO.sub.4 is used as the catalyst. In a preferred embodiment of the process, thin films of the monomers to be polymerized, applied to glass or to a polymeric base, preferably to a plastic film, are treated with gaseous SbCl.sub.5, SbF.sub.5 or AsF.sub.5. The conductive polymers obtained can be used in the electrical industry for the production of solar cells, for the conversion and fixing of radiation and for the production of electrical and magnetic switches, as well as for the antistatic treatment of plastics.
摘要翻译：通过聚合苊烯，N-乙烯基 - 杂环化合物制备导电聚合物的方法， N-乙烯基咔唑或N-乙烯基吡啶或N，N-二乙烯基苯胺，在-80℃至+ 100℃下，在阳离子催化剂存在下，其中1至50重量％的氧化路易斯酸，优选FeCl 3， FeBr 3，SbCl 5，SbF 5，AsF 5或CF 3 SO 3 H，或AlCl 3或TiCl 4与所述化合物或与CrO 3或OsO 4的组合用作催化剂。在该方法的优选实施方案中，将待聚合的单体的薄膜施加到玻璃上或聚合物基体上，优选用塑料膜，用气态SbCl 5，SbF 5或AsF 5处理。所得到的导电聚合物可用于电气工业中用于生产太阳能电池，用于辐射的转换和固定以及电气和磁性开关的生产以及用于塑料的抗静电处理。

38. 发明授权

US4360644A Preparation of electrically conductive polyaromatics 失效
标题翻译：导电多芳族化合物的制备
公开(公告)号：US4360644A
公开(公告)日：1982-11-23
申请号：US221731
申请日：1980-12-31
申请人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
发明人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
IPC分类号： C08K5/00 , C07C27/00 , C07C39/12 , C07C67/00 , C08K5/13 , C08L65/00 , C08L65/02 , C09K3/16 , H01B1/12 , H01L51/30 , H01L51/42 , C08G61/10 , C08L3/00
CPC分类号： H01B1/128 , C08L65/00 , C08L65/02 , C09K3/16 , H01L51/0035 , C08G2261/312 , H01L51/0052 , H01L51/42 , Y02E10/549
摘要： A process for the preparation of electrically conductive polyaromatics having conductivities greater than 10.sup.-2 S/cm, wherein from 0.5 to 15% by weight of an oxidizing Lewis acid, e.g. antimony pentafluoride or arsenic pentafluoride, or their NO.sup.+ - or NO.sub.2.sup.+ -salts, or a nitroaromatic, e.g. trinitrophenol or trinitrobenzenesulfonic acid, and/or a fluorine derivative, e.g. CF.sub.3 --COOH, or an acid, e.g. sulfuric acid, nitric acid or perchloric acid, is added to a polyaromatic, in the absence of moisture.
摘要翻译：一种制备电导率大于10-2S / cm的导电多芳族化合物的方法，其中按重量计0.5至15％的氧化性路易斯酸，例如，五氟化锑或五氟化砷，或它们的NO +或NO 2 +盐，或硝基芳族化合物。三硝基苯酚或三硝基苯磺酸，和/或氟衍生物。 CF 3 -COOH，或酸，例如。在没有水分的情况下，将硫酸，硝酸或高氯酸加入到多芳族化合物中。

39. 发明授权

US4344869A Preparation of electrically conductive hetero-poly-phenylenes 失效
标题翻译：导电异聚亚苯基的制备
公开(公告)号：US4344869A
公开(公告)日：1982-08-17
申请号：US237635
申请日：1981-02-24
申请人： Gerd Blinne , Herbert Naarmann , Klaus Penzien
发明人： Gerd Blinne , Herbert Naarmann , Klaus Penzien
IPC分类号： C08L71/00 , C08L81/00 , C08L85/00 , C09K3/16 , H01B1/12 , H01L51/30 , H01B1/00
CPC分类号： H01L51/0036 , C08L71/00 , C08L81/00 , C08L85/00 , C09K3/16 , H01B1/128 , H01L51/0035 , Y02E10/549
摘要： A process for the preparation of electrically conductive hetero-polyphenylenes, having conductivities greater than 10.sup.-2 S/cm, wherein from 0.5 to 35 percent by weight of a strong Lewis acid having a pk.sub.a of from -10 to +4, preferably AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ AsF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sub.2.sup.+BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid or 2,4,6-trinitrobenzoic acid, is added to a hetero-polyphenylene in the absence of moisture and of oxygen.
摘要翻译：具有导电性大于10-2S / cm的导电异聚亚苯基的制备方法，其中0.5至35重量％的pka为-10至+4的强路易斯酸，优选AsF5，SbF5 ，UF6，HClO4，NO + SbF6-，NO2 + SbF6-，NO + AsF6-，NO + PF6-，NO2 + PF6-，NO + BF4-，NO2 + BF4-，NO + ClO4-，（CF3）将2,4,6-三硝基苯酚，2,4,6-三硝基苯磺酸或2,4,6-三硝基苯甲酸加入到不存在水分和氧气的异亚苯基中。

40. 发明授权

US4301272A Addition polymers of dimorpholone compounds and diamines 失效
标题翻译：二吗啉酮化合物和二胺的加成聚合物
公开(公告)号：US4301272A
公开(公告)日：1981-11-17
申请号：US126289
申请日：1980-03-03
申请人： Hans-Juergen Degen , Herbert Naarmann
发明人： Hans-Juergen Degen , Herbert Naarmann
IPC分类号： C08G69/02 , C08G69/00
CPC分类号： C08G69/02
摘要： Novel addition polymers of dimorpholone compounds and diamines, which contain structural units of the general formula ##STR1## where X and Y may be various conventional organic radicals, are obtained by reacting dimorpholone compounds with diamines. The polymers may be used for modifying plastics, and for textile or paper finishing.
摘要翻译：通过使二吗啉酮化合物与二胺反应，获得含有通式为“IMAGE”的结构单元的二缩水甘油化合物和二胺的新型加成聚合物，其中X和Y可以是各种常规的有机基团。聚合物可用于改性塑料，以及纺织品或纸张整理。

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