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31. 发明授权

US06747124B2 Process for working up emulsion polymers 失效
标题翻译：加工乳液聚合物的方法
公开(公告)号：US06747124B2
公开(公告)日：2004-06-08
申请号：US10017302
申请日：2001-12-14
申请人： Herbert Eichenauer , Stefan Moss
发明人： Herbert Eichenauer , Stefan Moss
IPC分类号： C08J303
CPC分类号： C08C1/15 , C08F6/22 , Y10S528/934 , Y10S528/936
摘要： A process for working up polymer components prepared by emulsion polymerization is disclosed. The process is characterized in that coagulation of the aqueous polymer latex present after emulsion polymerization is performed using a combination of A) an aqueous solution of at least one salt selected from the group consisting of sodium chloride, calcium chloride, magnesium chloride, aluminum chloride, sodium sulfate, magnesium sulfate and aluminum sulfate, B) an aqueous solution of at least one salt of an acid selected from the group consisting of hypophosphorous acid (H3PO2), phosphorous acid (H3PO3 or HPO2) and ascorbic acid and optionally C) an aqueous dilute acid selected from the group consisting of sulfuric acid, phosphoric acid and acetic acid.
摘要翻译：公开了通过乳液聚合制备聚合物组分的方法。该方法的特征在于，乳液聚合之后存在的聚合物胶乳的凝结是使用以下组合进行的：A）至少一种选自氯化钠，氯化钙，氯化镁，氯化铝，硫酸钠，硫酸镁和硫酸铝，B）至少一种选自次磷酸（H3PO2），亚磷酸（H 3 PO 3或HPO 2）和抗坏血酸的酸的盐的水溶液和任选的C）水性选自硫酸，磷酸和乙酸的稀酸。

32. 发明授权

US06620883B2 Process for the preparation of graft rubber latexes having a reduced residual monomer content 有权
公开(公告)号：US06620883B2
公开(公告)日：2003-09-16
申请号：US09965702
申请日：2001-09-26
申请人： Hans-Erich Gasche , Herbert Eichenauer , Pierre Vanhoorne , Ulrich Jansen , Eckhard Wenz , Stefan Moss
发明人： Hans-Erich Gasche , Herbert Eichenauer , Pierre Vanhoorne , Ulrich Jansen , Eckhard Wenz , Stefan Moss
IPC分类号： C08L5104
CPC分类号： C08L51/04 , C08F279/04 , C08L55/02 , C08L2666/02
摘要： The invention relates to a process for the preparation of graft rubber polymers of the ABS type by emulsion polymerization according to the so-called fed batch process, in which latexes having markedly reduced residual monomer contents are obtained, and to compositions containing the mentioned graft rubber polymers. The polymers so obtained have no negative effects at all on other properties

33. 发明授权

US06384133B1 ABS-moulding compounds with an improved combination of properties 失效
标题翻译： ABS成型化合物具有改进的性能组合
公开(公告)号：US06384133B1
公开(公告)日：2002-05-07
申请号：US09831853
申请日：2001-05-15
申请人： Herbert Eichenauer
发明人： Herbert Eichenauer
IPC分类号： C08L5502
CPC分类号： C08L55/02 , C08L2666/14 , C08L2666/04
摘要： A thermoplastic molding composition having improved mechanical properties is disclosed. The ABS composition that comprise a graft rubber polymer obtained by emulsion polymerization in the presence of specifically defined butadiene polymer latices and a rubber-free copolymer is suitable for making molded articles.
摘要翻译：公开了具有改进的机械性能的热塑性模塑组合物。在具体限定的丁二烯聚合物胶乳和无橡胶共聚物的存在下，通过乳液聚合获得的包含接枝橡胶聚合物的ABS组合物适于制备模制品。

34. 发明授权

US5274031A Polymer alloys of high ageing resistance 失效
标题翻译：耐老化的聚合物合金
公开(公告)号：US5274031A
公开(公告)日：1993-12-28
申请号：US435057
申请日：1989-11-13
申请人： Herbert Eichenauer , Alfred Pischtschan , Christian Lindner
发明人： Herbert Eichenauer , Alfred Pischtschan , Christian Lindner
IPC分类号： C08L51/00 , C08L51/04 , C08L51/06 , C08L51/08
CPC分类号： C08L51/04 , C08L51/085
摘要： Molding compounds ofA) 5 to 95 parts by weight of a graft product of resin-forming monomers on a particulate silicone rubber having a total rubber content of from 30 to 90% by weight andB) 95 to 5 parts by weight of resin-forming monomers on a particulate EPDM rubber having a total rubber content of 10 to 50% by weight andC) 10 to 200 parts by weight (based on 100 parts by weight A+B) of a graft product of resin-forming monomers on a particulate acrylate rubber having a total rubber content of from 30 to 80% by weight.
摘要翻译： A）成型化合物A）5至95重量份的树脂形成单体的接枝产物在总橡胶含量为30至90重量％的颗粒状硅橡胶上，B）95至5重量份树脂 - 在总橡胶含量为10至50重量％的颗粒状EPDM橡胶上形成单体，C）10至200重量份（基于100重量份A + B）的树脂形成单体的接枝产物总橡胶含量为30至80重量％的颗粒状丙烯酸酯橡胶。

35. 发明授权

US5066717A Thermoplastic moulding compounds based on aromatic polycarbonates and vinyl polymers with improved thermostability 失效
标题翻译：基于具有改进的热稳定性的芳族聚碳酸酯和乙烯基聚合物的热塑性模塑化合物
公开(公告)号：US5066717A
公开(公告)日：1991-11-19
申请号：US511680
申请日：1990-04-20
申请人： Herbert Eichenauer , Dieter Wittmann , Adolf Schmidt , Karl-Heinz Ott
发明人： Herbert Eichenauer , Dieter Wittmann , Adolf Schmidt , Karl-Heinz Ott
IPC分类号： C08L25/00 , B01F17/36 , C08F2/24 , C08F2/26 , C08L51/00 , C08L69/00
CPC分类号： C08L69/00
摘要： This invention relates to thermostable thermoplastic moulding compounds consisting of a thermoplastic aromatic polycarbonate resin, a graft polymer and optionally a thermoplastic vinyl polymer wherein the graft or vinyl polymer is emulsion polymerized with an emulsifier which is the reaction product of 2 mols of certain carboxylic anhydrides and 1 mole of certain diols.
摘要翻译：本发明涉及由热塑性芳族聚碳酸酯树脂，接枝聚合物和任选的热塑性乙烯基聚合物组成的耐热性热塑性模塑料，其中接枝或乙烯基聚合物与乳化剂乳液聚合，乳化剂是2摩尔某些羧酸酐的反应产物和 1摩尔某些二醇。

36. 发明授权

US4859731A Polymeric dihydroxy compounds and their use as stabilizers for polymers 失效
标题翻译：聚合二羟基化合物及其作为聚合物稳定剂的用途
公开(公告)号：US4859731A
公开(公告)日：1989-08-22
申请号：US223541
申请日：1988-07-25
申请人： Herbert Eichenauer , Hartwig Hocker , Thomas Heitz
发明人： Herbert Eichenauer , Hartwig Hocker , Thomas Heitz
IPC分类号： C08F8/00
CPC分类号： C08F8/00
摘要： Polymer dihydroxy compounds corresponding to the following formula ##STR1## in whichR.sup.1, R.sup.2, R.sup.3 =H or C.sub.1 -C.sub.4 alkyl,R.sup.4 =H or C.sub.1 -C.sub.4 alkyl,R.sup.5 =--C.sub.6 H.sub.5, --C.sub.6 H.sub.4 CH.sub.3, --CH.dbd.CH.sub.2, or --CO.sub.2 R.sup.7,R.sup.6 =C.sub.1 -C.sub.4 alkyl, aryl, or H,R.sup.7 =C.sub.1 -C.sub.4 alkyl,m=0 or 1,n=5 to 100,q=0 or 1,a process for their production and their use in thermoplastic molding compositions.
摘要翻译：对应于下式的化合物二羟基化合物，其中R1，R2，R3 = H或C1-C4烷基，R4 = H或C1-C4烷基，R5 = -C6H5，-C6H4CH3，-CH = CH2或 - CO 2 R 7，R 6 = C 1 -C 4烷基，芳基或H，R 7 = C 1 -C 4烷基，m = 0或1，n = 5〜100，q = 0或1，其制备方法及其在热塑性成型组合物。

37. 发明授权

US4771109A Graft polymers on rubber polymers with a block-like structure 失效
标题翻译：具有块状结构的橡胶聚合物上的接枝聚合物
公开(公告)号：US4771109A
公开(公告)日：1988-09-13
申请号：US17729
申请日：1987-02-24
申请人： Herbert Eichenauer , Christian Lindner , Karl-Heinz Ott
发明人： Herbert Eichenauer , Christian Lindner , Karl-Heinz Ott
IPC分类号： C08F285/00 , C08F287/00 , C08L51/08
CPC分类号： C08F287/00
摘要： Graft polymers of vinyl monomers or vinyl monomer mixtures on block copolymers of recurring structural units from the polysiloxane series and recurring structural units from the series comprising homo- and copolymers of conjugated dienes as grafting bases.
摘要翻译：乙烯基单体或乙烯基单体混合物的接枝聚合物与来自聚硅氧烷系列的重复结构单元的嵌段共聚物和包含共轭二烯作为接枝基的均聚物和共聚物的重复结构单元的接枝聚合物。

38. 发明授权

US4699967A Polysiloxane block copolymers 失效
标题翻译：聚硅氧烷嵌段共聚物
公开(公告)号：US4699967A
公开(公告)日：1987-10-13
申请号：US820067
申请日：1986-01-21
申请人： Herbert Eichenauer , Christian Lindner , Karl-Heinz Ott , Peter Orth , Hartwig Hocker
发明人： Herbert Eichenauer , Christian Lindner , Karl-Heinz Ott , Peter Orth , Hartwig Hocker
IPC分类号： C08G77/00 , C08G63/68 , C08G77/42 , C08G77/445 , C08G77/46 , C08G81/00 , C08G77/04
CPC分类号： C08G77/445 , C08G77/46
摘要： Block copolymers of recurring structural units of the series of polysiloxanes and recurring structural units of the series of aliphatic polyesters, polyethers or polyetheresters with rubber properties, the polymeric block-forming polymers in each case producing rubber-type products with glass transition temperatures below practical temperatures of use and a process for the production thereof.
摘要翻译：一系列聚硅氧烷的重复结构单元和具有橡胶性能的脂族聚酯，聚醚或聚醚酯系列的重复结构单元的嵌段共聚物，每种情况下的聚合物嵌段形成聚合物生产玻璃化转变温度低于实际温度的橡胶类产品的用途及其生产方法。

39. 发明授权

US07358290B2 Polycarbonate molding compositions with improved hydrolysis resistance 有权
标题翻译：具有改善耐水解性的聚碳酸酯模塑组合物
公开(公告)号：US07358290B2
公开(公告)日：2008-04-15
申请号：US11342739
申请日：2006-01-30
申请人： Eckhard Wenz , Thomas Eckel , Olaf Meincke , Holger Warth , Herbert Eichenauer
发明人： Eckhard Wenz , Thomas Eckel , Olaf Meincke , Holger Warth , Herbert Eichenauer
IPC分类号： C08K3/26 , C08L69/00
CPC分类号： C08L69/005 , C08F279/02 , C08F279/04 , C08K3/26 , C08K3/32 , C08K5/0008 , C08L27/18 , C08L51/04 , C08L55/02 , C08L69/00 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： A thermoplastic molding composition is disclosed. The composition that contains at least one member selected from the group consisting of aromatic polycarbonate and polyester carbonate, a rubber-modified vinyl (co)polymer, and calcium carbonate having average particle diameter of less than 100 nm is particularly suitable for making articles resistant to hydrolysis.
摘要翻译：公开了一种热塑性模塑组合物。含有选自芳族聚碳酸酯和聚酯碳酸酯，橡胶改性的乙烯基（共）聚合物，平均粒径小于100nm的碳酸钙中的至少一种的组合物特别适用于制造耐受水解。

40. 发明申请

US20070135549A1 ABS moulding materials containing special metal compounds 审中-公开
标题翻译： ABS成型材料含有特殊的金属化合物
公开(公告)号：US20070135549A1
公开(公告)日：2007-06-14
申请号：US11633798
申请日：2006-12-05
申请人： Herbert Eichenauer
发明人： Herbert Eichenauer
IPC分类号： C08K3/10
CPC分类号： C08L51/04 , C08K3/22 , C08L55/02 , C08L67/02 , C08L69/00 , G01N2021/6439 , C08L2666/14 , C08L2666/24 , C08L2666/02
摘要： ABS moulding materials containing an addition of at least one compound of the lanthanides, process for the preparation of the moulding materials and a method for identifying ABS moulding materials.
摘要翻译：含有至少一种镧系化合物的ABS成型材料，用于制备成型材料的方法以及用于识别ABS成型材料的方法。

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