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31. 发明授权

US06586635B2 Process for the preparation of unsaturated ketones 失效
公开(公告)号：US06586635B2
公开(公告)日：2003-07-01
申请号：US10132195
申请日：2002-04-26
申请人： Nongyuan Shi , Bernd Drapal , Steffen Krill , Markus Julino , Klaus Huthmacher
发明人： Nongyuan Shi , Bernd Drapal , Steffen Krill , Markus Julino , Klaus Huthmacher
IPC分类号： C07C4571
CPC分类号： C07C45/513 , C07C45/62 , C07C49/203 , C07C49/04
摘要： A process for the preparation of &bgr;,&ggr;,&dgr;-unsaturated ketones and/or &agr;,&bgr;,&ggr;,&dgr;-unsaturated ketones by the reaction of an unsaturated alcohol with an enol ether or mixture of enol ethers, with formation of ketals as a by-product, at temperatures of from 50° C. to 200° C., in the presence of an acid catalyst, whereby one or all of the reagents is/are heated to the reaction temperature of from 50° C. to 200° C. before the acid catalyst is added.

32. 发明授权

US06350897B2 Process for preparing trimethylhydroquinone diacetate and trimethylhydroquinone 失效
标题翻译：制备三甲基对苯二酚二乙酸酯和三甲基氢醌的方法
公开(公告)号：US06350897B2
公开(公告)日：2002-02-26
申请号：US09825361
申请日：2001-04-04
申请人： Steffen Krill , Klaus Huthmacher
发明人： Steffen Krill , Klaus Huthmacher
IPC分类号： C07C6900
CPC分类号： C07C37/07 , C07C37/0555 , C07C67/00 , C07C69/017 , C07C69/16 , C07C39/08
摘要： A process for preparing trimethylhydroquinone diacetate, with subsequent hydrolysis to give trimethylhydroquinone, the process including reacting 2,2,6-trimethylcyclohexane-1,4-dione under oxidative conditions, in the presence of a sulfonating agent and a strong acid, and in the presence of an acylating agent.
摘要翻译：一种制备三甲基对苯二酚二乙酸酯的方法，随后水解得到三甲基氢醌，该方法包括在氧化条件下，在磺化剂和强酸存在下使2,2,6-三甲基环己烷-1,4-二酮反应，酰化剂的存在。

33. 发明授权

US06310259B1 Method for producing 6,10 and 6,9-dimethyl-5,10-undecadienyl-2-ones 失效
标题翻译：制备6,10和6,9-二甲基-5,10-十一二烯基-2-酮的方法
公开(公告)号：US06310259B1
公开(公告)日：2001-10-30
申请号：US09446734
申请日：2000-03-23
申请人： Wilhelm Keim , Armin Kraus , Rainer Hahn , Klaus Huthmacher
发明人： Wilhelm Keim , Armin Kraus , Rainer Hahn , Klaus Huthmacher
IPC分类号： C07C4500
CPC分类号： C07C45/676 , C07C49/203 , C07C67/347 , C07C69/738
摘要： The present application refers to a process for preparing 6,10- and 6,9-dimethyl-5,10-undecadienyl-2-ones by telomerizing isoprene with alkyl acetoacetates in the presence of a catalyst system containing a transition metal compound catalyst and a phosphorus- or arsenic-containing compound cocatalyst, wherein the process is performed in the presence of a protic additive of the general formula in which: R1, R2, R3 represent an alkyl group with 1 to 9 carbon atoms, branched or unbranched, a cycloalkyl group with 6 to 8 carbon atoms, an aryl group, in particular phenyl, or an arylalkyl group, X(−) represents an inorganic or organic anion, y is 1 or 2, and the &bgr;-ketoester so obtained is saponified and decarboxylated in a manner known per se.
摘要翻译：本申请是指通过在含有过渡金属化合物催化剂的催化剂体系存在下将异戊二烯与乙酰乙酸烷基酯聚合来制备6,10-和6,9-二甲基-5,10-十一二烯基-2-酮的方法，含磷或砷的化合物助催化剂，其中该方法在一般形式的质子添加剂存在下进行：其中R1，R2，R3代表具有1至9个碳原子的烷基，支链或非支链，环烷基具有6至8个碳原子，芳基，特别是苯基或芳基烷基，X（ - ）表示无机或有机阴离子，y为1或2，所得到的β-酮酯被皂化并脱羧本身已知的方式。

34. 发明授权

US06229018B1 Process for the preparation of nicotinic acid 失效
标题翻译：制备烟酸的方法
公开(公告)号：US06229018B1
公开(公告)日：2001-05-08
申请号：US09386951
申请日：1999-08-31
申请人： Dieter Heinz , Wolfgang Hölderich , Steffen Krill , Wolfgang Böck , Klaus Huthmacher
发明人： Dieter Heinz , Wolfgang Hölderich , Steffen Krill , Wolfgang Böck , Klaus Huthmacher
IPC分类号： C07D213803
CPC分类号： C07D213/803 , C07D213/80
摘要： A process for the preparation of nicotinic acid by the direct oxidation of &bgr;-picoline in the gas phase, wherein water and &bgr;-picoline are fed separately to the catalyst bed and the catalyst is based on a titanium dioxide support which has been prepared by the sulfate method and has a high specific surface area and a vanadium oxide content of from 5 to 50 %.
摘要翻译：通过在气相中直接氧化β-甲基吡啶来制备烟酸的方法，其中将水和β-甲基吡啶分别加入到催化剂床中，催化剂基于二氧化钛载体，其由硫酸盐法，比表面积高，氧化钒含量5〜50％。

35. 发明授权

US6150563A Aliphatic alkanals with improved storage stability and method of improving the storage stability 有权
标题翻译：具有改善储存稳定性的脂肪族链烷烃和提高储存稳定性的方法
公开(公告)号：US6150563A
公开(公告)日：2000-11-21
申请号：US134562
申请日：1998-08-14
申请人： Hans Joachim Hasselbach , Klaus Huthmacher , Katja Kelm , Horst Weigel
发明人： Hans Joachim Hasselbach , Klaus Huthmacher , Katja Kelm , Horst Weigel
IPC分类号： C07C45/86 , C07C47/02 , C07C319/26 , C07C323/22 , C07C47/00
CPC分类号： C07C323/22 , C07C45/86
摘要： Aliphatic alkanals with a water content of greater than 300 ppm which are stable in storage, and a method of improving the storage stability of these aliphatic alkanals, especially of substituted, sulfur-containing alkanals. The formation of oligomers, polymers and condensation products from elimination reactions and oxidation and the subsequent reactions of the products formed results in undesired impurities that are largely prevented by the addition of an organic acid that forms metal complexes and, optionally, alkanolamines or trialkanolamines.
摘要翻译：水分大于300ppm的脂肪族链烷烃，其储存稳定，以及提高这些脂肪族链烷烃，特别是取代的含硫链烷烃的储存稳定性的方法。由消除反应和氧化形成的低聚物，聚合物和缩合产物以及所形成的产物的后续反应导致不期望的杂质，其通过加入形成金属络合物的有机酸和任选的烷醇胺或三链烷醇胺而大大地被防止。

36. 发明授权

US6103924A Process for the preparation of 2,3,5-trimethylhydroquinone diesters 失效
标题翻译：制备2,3,5-三甲基氢醌二酯的方法
公开(公告)号：US6103924A
公开(公告)日：2000-08-15
申请号：US295359
申请日：1999-04-21
申请人： Nongyuan Shi , Mario Scholz , Steffen Hasenzahl , Horst Weigel , Bernd Drapal , Ralph McIntosh , Hans J. Hasselbach , Klaus Huthmacher
发明人： Nongyuan Shi , Mario Scholz , Steffen Hasenzahl , Horst Weigel , Bernd Drapal , Ralph McIntosh , Hans J. Hasselbach , Klaus Huthmacher
IPC分类号： C07C37/01 , C07C37/07 , C07C39/08 , C07C67/00 , C07C67/29 , C07C67/293 , C07C69/16 , C07C67/48
CPC分类号： C07C37/0555 , C07C67/00
摘要： Preparation of 2,3,5-trimethylhydroquinone diesters by rearrangement of 2,6,6-trimethylcyclohex-2-ene-1,4-dione (4-oxo-isophorone, ketoisophorone) in the presence of a solid, acid catalyst and an acylating agent, for example carboxylic acid anhydrides or carboxylic acid halides. The 2,3,5-trimethylhydroquinone diester may then optionally be saponified to the free 2,3,5-trimethylhydroquinone, which is a valuable building block in the synthesis of vitamin E.
摘要翻译：通过在固体酸催化剂存在下重新配置2,6,6-三甲基环己-2-烯-1,4-二酮（4-氧代 - 异佛尔酮，酮异佛尔酮），制备2,3,5-三甲基氢醌二酯酰化剂，例如羧酸酐或羧酸酰卤。然后可以将2,3,5-三甲基氢醌二酯任选地皂化成游离的2,3,5-三甲基氢醌，其是维生素E合成中的有价值的结构单元。

37. 发明授权

US06008409A Method for obtaining 2-hydroxy-4-methylthiobutyric acid (MHA) which is stable in storage 失效
标题翻译：获得储存稳定的2-羟基-4-甲硫基丁酸（MHA）的方法
公开(公告)号：US06008409A
公开(公告)日：1999-12-28
申请号：US999000
申请日：1997-12-29
申请人： Hans-Albrechl Hasseberg , Hans-Joachim Hasselbach , Klaus Huthmacher , Volker Hafner , Harald Heinzel , Axel Ronneburg
发明人： Hans-Albrechl Hasseberg , Hans-Joachim Hasselbach , Klaus Huthmacher , Volker Hafner , Harald Heinzel , Axel Ronneburg
IPC分类号： C07C319/20 , A23K20/105 , C07C319/26 , C07C319/28 , C07C323/52 , C07C315/00
CPC分类号： C07C319/28 , A23K20/105 , C07C319/26
摘要： A method for obtaining 2-hydroxy-4-methylthiobutyric acid (methionine-hydroxy analog, MHA) in primarily free form which is stable in storage by distilling a product solution containing MHA and by producing MHA product mixtures with improved storage stability from such a distillate. The distillate can be produced directly starting from MHA raw products from any MHA production process, which can optionally also contain solvent or water. The starting material may also be a commercial MHA product.
摘要翻译：获得主要游离形式的2-羟基-4-甲硫基丁酸（甲硫氨酸 - 羟基类似物，MHA）的方法，其通过蒸馏含有MHA的产物溶液并通过生产具有改善的储存稳定性的这种馏出物的MHA产物混合物而在储存中稳定。馏出物可以从任何MHA生产过程的MHA原始产品直接生产，其可任选地还含有溶剂或水。起始材料也可以是商业MHA产品。

38. 发明授权

US08372780B2 Catalysts containing tungstate for the synthesis of alkyl mercaptan and method for the production thereof 有权
标题翻译：含有用于合成烷基硫醇的钨酸盐的催化剂及其制备方法
公开(公告)号：US08372780B2
公开(公告)日：2013-02-12
申请号：US12796079
申请日：2010-06-08
申请人： Hubert Redlingshofer , Christoph Weckbecker , Klaus Huthmacher
发明人： Hubert Redlingshofer , Christoph Weckbecker , Klaus Huthmacher
IPC分类号： B01J23/00 , C01G41/02
CPC分类号： B01J23/30 , B01J21/04 , B01J37/0201 , C07C319/08 , C07C321/04
摘要： The invention relates to a catalyst containing alkali tungstate for the synthesis of alkylmercaptanes from alkanols and hydrogen sulphide, in addition to a method for the production of said catalyst, wherein the molar ratio of alkali to tungsten is
摘要翻译：本发明涉及一种含有用于从链烷醇和硫化氢合成烷基硫醇的碱金属钨酸盐的催化剂，除了制备所述催化剂的方法之外，其中碱与钨的摩尔比为<2:1。

39. 发明授权

US08008227B2 Mixed oxide catalysts for the catalytic gas-phase oxidation of olefins and processes for producing them 有权
标题翻译：用于烯烃催化气相氧化的混合氧化物催化剂及其制备方法
公开(公告)号：US08008227B2
公开(公告)日：2011-08-30
申请号：US12091116
申请日：2006-09-15
申请人： Achim Fischer , Werner Burkhardt , Christoph Weckbecker , Klaus Huthmacher , Frank Wilz
发明人： Achim Fischer , Werner Burkhardt , Christoph Weckbecker , Klaus Huthmacher , Frank Wilz
IPC分类号： B01J25/00
CPC分类号： C07C45/36 , B01J23/002 , B01J23/8876 , B01J37/0045 , B01J37/0221 , B01J37/0223 , B01J37/03 , B01J2523/00 , C07C45/35 , C07C51/252 , C07C51/265 , C07C47/22 , C07C47/54 , C07C57/04 , C07C63/06 , B01J2523/13 , B01J2523/3737 , B01J2523/51 , B01J2523/54 , B01J2523/68 , B01J2523/72 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/31 , B01J2523/41
摘要： The invention relates to mixed oxide catalysts for the catalytic gas-phase oxidation of olefins and methylated aromatics, processes for producing the catalysts and the reaction with air or oxygen in the presence of inert gases in various ratios at elevated temperatures and pressure to form aldehydes and carboxylic acids.
摘要翻译：本发明涉及用于烯烃和甲基化芳族化合物的催化气相氧化的混合氧化物催化剂，用于生产催化剂的方法和在惰性气体存在下在高温和高压下以各种比例与空气或氧气反应以形成醛和羧酸。

40. 发明授权

US07994366B2 Process for continuously preparing methyl mercaptan from carbon- and hydrogen-containing compounds 有权
标题翻译：从含碳和氢的化合物连续制备甲硫醇的方法
公开(公告)号：US07994366B2
公开(公告)日：2011-08-09
申请号：US12126322
申请日：2008-05-23
申请人： Jan-Olaf Barth , Hubert Redlingshoefer , Caspar-Heinrich Finkeldei , Christoph Weckbecker , Klaus Huthmacher
发明人： Jan-Olaf Barth , Hubert Redlingshoefer , Caspar-Heinrich Finkeldei , Christoph Weckbecker , Klaus Huthmacher
IPC分类号： C07C321/00
CPC分类号： C07C319/02 , B01J21/063 , B01J23/28 , B01J23/34 , B01J23/36 , B01J37/0205 , Y02P20/127 , C07C321/04
摘要： Provided is a process for continuously preparing methyl mercaptan by reacting a reactant mixture comprising solid, liquid and/or gaseous carbon- and/or hydrogen-containing compounds with air or oxygen, and/or water and sulfur.
摘要翻译：本发明提供一种通过使含有固体，液体和/或气态的含碳和/或含氢化合物的反应物混合物与空气或氧气和/或水和硫反应来连续制备甲硫醇的方法。

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