专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

31. 发明授权

US4797320A Composite plastic moldings and a process for their production 失效
标题翻译：复合塑料模制品及其生产工艺
公开(公告)号：US4797320A
公开(公告)日：1989-01-10
申请号：US140468
申请日：1988-01-04
申请人： Richard Kopp , Gerhard Grogler , Heinrich Hess , Hermann Schafer , Werner Rasshofer
发明人： Richard Kopp , Gerhard Grogler , Heinrich Hess , Hermann Schafer , Werner Rasshofer
IPC分类号： B29C39/12 , B29K75/00 , B29K105/04 , B29L31/58 , C08G18/70 , C08G18/80 , C08J9/04 , B29C67/20 , B32B3/26
CPC分类号： C08G18/8038 , C08G18/707 , C08G18/8058 , Y10T428/249981 , Y10T428/249988 , Y10T428/249991 , Y10T428/31554
摘要： A composite plastic molding made up of a plastic foam and having a polyurethane skin is made by heating a reactive one-component system to form a polyurethane skin and then joining the polyurethane skin to the plastic foam. The one-component system is composed of a finely divided polyisocyanate in which from 0.1 to 25 equivalent percent of the isocyanate groups have been deactivated, a polyamine and/or polyol having a molecular weight of from 400 to 8000 and optionally a chain extending agent, a catalyst and known auxiliaries and additives.
摘要翻译：通过加热反应性单组分体系以形成聚氨酯皮肤，然后将聚氨酯皮肤连接到塑料泡沫上，制成由塑料泡沫塑料和具有聚氨酯表皮的复合塑料模制品。单组分体系由细分多异氰酸酯组成，其中0.1至25当量异氰酸酯基团已失活，分子量为400至8000的多胺和/或多元醇和任选的扩链剂，催化剂和已知助剂和添加剂。

32. 发明授权

US4757105A Process for the production of finely divided polyisocyanates containing urea groups 失效
标题翻译：用于生产含尿素基团的细碎多异氰酸酯的方法
公开(公告)号：US4757105A
公开(公告)日：1988-07-12
申请号：US116108
申请日：1987-11-03
申请人： Richard Kopp , Gerhard Grogler , Heinrich Hess , Klaus Konig
发明人： Richard Kopp , Gerhard Grogler , Heinrich Hess , Klaus Konig
IPC分类号： C08G18/32 , C07C67/00 , C07C239/00 , C07C273/18 , C07C275/00 , C08G18/70 , C08G18/78 , C08L75/00
CPC分类号： C07C273/1827 , C08G18/703 , C08G18/7825
摘要： The present invention is directed to a process for the preparation of finely divided solid polyisocyanates containing urea groups by reacting organic polyisocyanates which are free from urea groups with water in an aqueous emulsion, characterized in that the reaction is carried out in the presence of an emulsion- and dispersion-stabilizing compound.
摘要翻译：本发明涉及通过在水性乳液中将不含尿素基团的有机多异氰酸酯与水反应制备含脲基团的细碎固体多异氰酸酯的方法，其特征在于反应在乳液存在下进行 - 和分散体稳定化合物。

33. 发明授权

US4732957A Polyurethane-based reactive mass and its use for the production of coatings 失效
标题翻译：聚氨酯类反应物质及其在涂料生产中的应用
公开(公告)号：US4732957A
公开(公告)日：1988-03-22
申请号：US839940
申请日：1986-03-17
申请人： Peter Schuster , Rudolf Punessen , Karl Nutzel , Richard Kopp , Werner Rasshofer
发明人： Peter Schuster , Rudolf Punessen , Karl Nutzel , Richard Kopp , Werner Rasshofer
IPC分类号： C08G18/00 , C08G18/72 , C08G18/78 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04 , C08G18/48
CPC分类号： C08G18/798 , C08G18/7831 , C08G18/7887 , C08G18/792 , C08G18/8032
摘要： A polyurethane-based reactive mass composed of(a) at least one organic compound in the molecular weight range of from 400 to 12000 containing isocyanate reactive groups and having a functionality from 2 to 8,(b) optionally an organic compound in the molecular weight range of from 62 to 399 containing isocyanate reactive groups and having a functionality from 2 to 8.(c) catalysts,(d) aliphatic isocyanate compounds and(e) optionally other auxiliary agents and additives known per se,characterized in that the aliphatic isocyanate compound used is one based on hexamethylene diisocyanate, hydrogenated diphenylmethane diisocyanate or isophorone diisocyanate containing isocyanurate and/or uretdione units and/or urethane and/or uretoneimine and/or oxadiazatrione groups is suitable for the production of lightfast coatings, including coatings in light colors, in particular for the formation of edgings round wooden panels without these panels having first to be dried down to the maximum dampness of 7% by weight.
摘要翻译：由（a）至少一种含有异氰酸酯反应性基团并且官能度为2至8的有机化合物，其分子量范围为400至12000，（b）任选的分子量有机化合物（c）催化剂，（d）脂族异氰酸酯化合物和（e）任选的其它助剂和本身已知的添加剂，其特征在于脂族异氰酸酯所使用的化合物是基于六亚甲基二异氰酸酯的化合物，含有异氰脲酸酯和/或脲二酮单元和/或氨基甲酸酯和/或脲酮亚胺和/或恶二唑二酮基团的氢化二苯基甲烷二异氰酸酯或异佛尔酮二异氰酸酯或异佛尔酮二异氰酸酯适用于生产包含浅色涂料的耐光涂层，特别是用于形成圆形木板的边缘，而这些面板首先被干燥到最大潮湿重量为7％。

34. 发明授权

US4720545A Process for the preparation of complexes of one mol of dimerized or low-oligodimerized 4,4'-diisocyanatodiphenylmethane and two to three mol of 4,4'-diisocyanatodiphenylmethane, corresponding complexes, and their use for polyurethane production 失效
标题翻译：制备一摩尔二聚或低二聚体4,4'-二异氰酸二苯基甲烷和2至3摩尔4,4'-二异氰酸二苯基甲烷，相应络合物及其用于聚氨酯生产的配合物的方法
公开(公告)号：US4720545A
公开(公告)日：1988-01-19
申请号：US829056
申请日：1986-02-13
申请人： Gerhard Grogler , Richard Kopp , Heinrich Hess
发明人： Gerhard Grogler , Richard Kopp , Heinrich Hess
IPC分类号： C08G18/00 , C07D229/00 , C08G18/72 , C08G18/76 , C08G18/79 , C07D403/14
CPC分类号： C07D229/00 , C08G18/798
摘要： The present invention relates to a process for the dimerization of 4,4'-diisocyanatodiphenylmethane from emulsion in apolar solvents with the formation of complexes and to the complexes obtainable for the first time by this process. The complexes consist of one mol of low molecular weight 4,4'-diisocyanato-diphenylmethane-uretdione or its low oligomers corresponding to the idealized formula (I) ##STR1## (n=0 to 0.5, where n is the average degree of oligomerization of the dimer) and 2 to 3 mol of 4,4'-diisocyanatodiphenylmethane (MDI) ##STR2## In the process according to the invention, 4,4'-diisocyanatodiphenylmethane (II) in the molten form is emulsified in apolar solvents. Dimerization is started in the presence of conventional dimerization catalysts at temperatures above the melting point of MDI, preferably up to an upper temperature limit of 50.degree. to 60.degree. C. The temperature is then lowered to
摘要翻译：本发明涉及一种在非极性溶剂中形成络合物的乳液中的4,4'-二异氰酸二苯基甲烷二聚作用的方法以及通过该方法首次获得的络合物。络合物由1mol低分子量的4,4'-二异氰酸酯基 - 二苯基甲烷脲二酮或其对应于理想化的式（I）的低聚物组成。（I）（n = 0至0.5，其中n 是二聚体的平均低聚度）和2〜3mol的4,4'-二异氰酸根合二苯基甲烷（MDI）。（II）在本发明的方法中，4,4'-二异氰酸根合二苯基甲烷熔融形式在非极性溶剂中乳化。在常规二聚催化剂存在下，在高于MDI熔点的温度下，优选开始二聚，最好达到50-60℃的上限温度。然后将温度降至<40℃。如果需要，二聚可以当异氰酸酯含量达到22.4％至26.9％时停止。然后将产物在低温下，优选0℃至25℃下处理。所得的络合物作为新物质被要求。还要求使用该复合物生产聚氨酯。

35. 发明授权

US4667008A Process for the production of solid polyisocyanates of retarded reactivity, polymer-coated, finely divided polyisocyanates and their use 失效
公开(公告)号：US4667008A
公开(公告)日：1987-05-19
申请号：US732039
申请日：1985-05-08
申请人： Gerhard Grogler , Richard Kopp , Heinrich Hess
发明人： Gerhard Grogler , Richard Kopp , Heinrich Hess
IPC分类号： C08G18/00 , C08G18/70 , C08G18/72 , C08L75/04 , C09D175/00 , C09D175/04 , C14C11/00 , D06N3/14 , C08G18/32 , C08G18/48
CPC分类号： C08G18/8019 , C07C263/18 , C08G18/3206 , C08G18/3234 , C08G18/4825 , C08G18/5024 , C08G18/703 , C08G18/725 , C08G18/755 , C08G18/7621 , C08G18/7831 , C08G18/8038 , Y10T428/2991
摘要： This invention relates to the production of polymer-coated, finely divided polyisocyanates by mixing(A) solid, finely divided polyisocyanates (preferably dimeric diisocyanates or urea diisocyanates) with(B) polyisocyanates differing in composition from those mentioned under (A) (preferably (cyclo) aliphatic polyisocyanates, such as biuretized diisocyanates or trimers or NCO-prepolymers),in quantities of from 0.05 to 50 parts by weight, and preferably in quantities of from 0.2 to 25 parts by weight, of (B) per 100 parts by weight of (A). The solid polyisocyanate particles surface-modified by covering with polyisocyanates (B) and then reacted with(D) isocyanate-reactive compounds containing reactive hydrogen atoms or with compounds free from active hydrogen atoms which form polymers with isocyanates in sub-equivalent to substantially equivalent quantities (preferably 0.5 to 1.0 equivalent per NCO-equivalent), in the presence of(C) inert, weakly polar organic solvents, (for example aliphatic hydrocarbons or relatively long chain dialkyl ethers), plasticizers, polyols or aromatic polyamines.A polymer coating is formed by the reaction of (B) and (D) around the solid polyisocyanate cores (A).The present invention also relates to the polyisocyanate particles covered with polyisocyanates (B) on the surface of the solid polyisocyanates (A) and, in particular, to the foreign-polymer coated, finely particulate polyisocyanates of retarded reactivity obtained by reaction with (D).The present invention also relates to the use of the polyisocyanate-covered and, more particularly, polymer-coated polyisocyanates, optionally in suspension in polyols and/or plasticizers, for the production of polyurethanes, more particularly in one-component polyurethane reactive systems having a long shelf life and a high thickening point.

36. 发明授权

US4581388A Process for the production of urethane-modified polyisocyanate using an oxyalkylated bisphenol 失效
标题翻译：使用烷氧基化双酚制备氨基甲酸酯改性的多异氰酸酯的方法
公开(公告)号：US4581388A
公开(公告)日：1986-04-08
申请号：US689112
申请日：1985-01-07
申请人： Werner Rasshofer , Richard Kopp , Reiner Paul , Klaus Seel , Otto Ganster
发明人： Werner Rasshofer , Richard Kopp , Reiner Paul , Klaus Seel , Otto Ganster
IPC分类号： C08G18/00 , C08G18/10 , C08G18/32 , C08G18/48 , C08G18/78 , C08G18/80 , C08G18/14
CPC分类号： C08G18/8019 , C08G18/10 , C08G18/4879 , C08G2120/00
摘要： Urethane-modified polyisocyanates having an NCO-content of from 5 to 45 wt. % are made by reacting an organic polyisocyanate or mixture of polyisocyanates having an NCO-content of from 30 to 50 wt. % with an organic polyhydroxyl compound or mixtures of polyhydroxyl compounds. The organic polyhydroxyl compound must include at least 10 hydroxyl equivalent percent of an alkoxylation product of a bisphenol corresponding to a specified formula containing two alcoholic hydroxyl groups and having an OH number of from 112 to 389. The reactants are employed in quantities such that the NCO:OH equivalent ratio is from 2:1 to 50:1. The urethane-modified polyisocyanates of the present invention are particularly useful in the production of polyurethanes by the isocyanate polyaddition process.
摘要翻译： NCO含量为5〜45重量％的聚氨酯改性多异氰酸酯通过使NCO含量为30〜50重量％的有机多异氰酸酯或多异氰酸酯的混合物反应，％的有机多羟基化合物或多羟基化合物的混合物。有机多羟基化合物必须包含至少10个羟基当量百分比的双酚的烷氧基化产物，该双酚对应于含有两个醇羟基并具有112至389的OH数的规定式。反应物的用量使得NCO ：OH当量比为2：1至50：1。本发明的氨基甲酸酯改性的多异氰酸酯特别可用于通过异氰酸酯加聚工艺生产聚氨酯。

37. 发明授权

US4569982A Process for the production of polyurea-elastomers and corresponding elastomers having an idealized segment structure 失效
标题翻译：制备具有理想化段段结构的聚脲弹性体和相应的弹性体的方法
公开(公告)号：US4569982A
公开(公告)日：1986-02-11
申请号：US694572
申请日：1985-01-24
申请人： Gerhard Grogler , Heinrich Hess , Richard Kopp , Werner Rasshofer
发明人： Gerhard Grogler , Heinrich Hess , Richard Kopp , Werner Rasshofer
IPC分类号： C08G18/00 , C08G18/10 , C08G18/46 , C08G18/50 , C08G18/64 , C08G18/65 , C08G18/70 , C08G18/72 , C08G18/79 , C08G18/32
CPC分类号： C08G18/707 , C08G18/10 , C08G18/4615 , C08G18/4623 , C08G18/5024 , C08G18/5027 , C08G18/5048 , C08G18/6529
摘要： According to the present invention, relatively high molecular weight aliphatic and/or aromatic polyamines having molecular weights of from 400 to 8,000 (preferably from 600 to 4,000) are mixed with substantially equivalent quantities of low molecular weight, solid, finely-divided diisocyanates having a melting point of >40.degree. C., (preferably >80.degree. C.), such as phenylene diisocyanate, naphth lene-1,5-diisocyanate, dimeric toluylene-2,4-diisocyanate or the urea diisocyanate of toluylene-2,4-diisocyanate. This mixture, having a pot life of at least several minutes, is subsequently heated to a relatively high temperature, such as from 80.degree. to 200.degree. C.The products obtained have excellent elastic properties over a broad temperature range. They have an exceptionally flat modulus of elasticity curve (G') in the torsional vibration test. The hard and soft segments are markedly segregated and are thus not substantially disturbed by reciprocal interaction causing "softening".
摘要翻译：根据本发明，分子量为400至8,000（优选600至4,000）的相对高分子量的脂族和/或芳族多胺与基本上等量的低分子量固体，细分二异氰酸酯混合，其具有熔点> 40℃（优选> 80℃），如亚苯基二异氰酸酯，萘-1,5-二异氰酸酯，二聚甲苯-2,4-二异氰酸酯或甲苯-2,4 二异氰酸酯。随后将具有至少几分钟的适用期的混合物加热到相对较高的温度，例如80℃至200℃。所得产物在宽的温度范围内具有优异的弹性。在扭转振动试验中，它们具有非常平坦的弹性模量曲线（G'）。硬段和软段显着分离，因此基本上不会受到引起“软化”的相互作用的相互干扰。

38. 发明授权

US4546165A Process for the production of stabilized polyisocyanates of retarded reactivity and their use in the production of polyurethanes 失效
标题翻译：用于生产延迟反应性稳定的多异氰酸酯及其在生产聚氨酯中的用途的方法
公开(公告)号：US4546165A
公开(公告)日：1985-10-08
申请号：US694566
申请日：1985-01-24
申请人： Gerhard Grogler , Heinrich Hess , Richard Kopp
发明人： Gerhard Grogler , Heinrich Hess , Richard Kopp
IPC分类号： C08G18/00 , C07C265/00 , C08G18/08 , C08G18/70 , C08G18/72 , C08G18/80 , C08G18/18
CPC分类号： C08G18/6648 , C08G18/089 , C08G18/10 , C08G18/5045 , C08G18/6685 , C08G18/705 , C08G18/7825 , C08G18/798 , C08G18/80
摘要： The present invention relates to a process for the production of solid polyisocyanates of retarded reactivity stabilized by surface modification by reacting solid, finely divided polyisocyanates, and particularly dimeric tolylene diisocyanate, dimeric diphenylmethane diisocyanate and 3,3'-diisocyanato-4,4'-dimethyl-N,N'-diphenyl urea, with acyclic, mono- or bicyclic compounds having an amidine or guanidine structure and which do not contain any hydrogen atoms reactive to isocyanates at room temperature in a quantity of from 0.1 to 25 equivalent percent of "amidine" or "guanidine" per isocyanate equivalent. The reaction may be carried out directly in a liquid medium selected from the group consisting of active hydrogen compounds, plasticizers, water, and solvents to form a suspension of polyadduct-coated, stabilized polyisocyanates in the liquid medium.
摘要翻译：本发明涉及通过使固体，细分散的多异氰酸酯，特别是二聚甲苯二异氰酸酯，二聚二苯基甲烷二异氰酸酯和3,3'-二异氰酸根合-4,4'-二异氰酸酯二异氰酸酯反应，通过表面改性而稳定的延迟反应性固体聚异氰酸酯的制备方法，二甲基-N，N'-二苯基脲，其具有脒或胍结构的无环，单或双环化合物，并且在室温下不含任何与异氰酸酯反应的氢原子，其量为0.1至25当量的“ 脒“或”胍“。反应可以直接在选自活性氢化合物，增塑剂，水和溶剂的液体介质中进行，以在液体介质中形成多加成膜包被的稳定化多异氰酸酯的悬浮液。

39. 发明授权

US4418159A Process for the production of polyurethanes and a storable intermediate product for carrying out this process 失效
标题翻译：用于生产聚氨酯的方法和用于实施该方法的可储存的中间产物
公开(公告)号：US4418159A
公开(公告)日：1983-11-29
申请号：US433198
申请日：1982-10-07
申请人： Werner Rasshofer , Richard Kopp , Reiner Paul
发明人： Werner Rasshofer , Richard Kopp , Reiner Paul
IPC分类号： C08G18/00 , C08G18/22 , C08G18/24 , C08G18/14
CPC分类号： C08G18/242
摘要： Optionally-foamed polyurethanes are produced by reacting polyisocyanates with organic compounds containing at least two isocyanate-reactive hydrogen atoms and having a molecular weight in the range from 400 to 10,000, in the presence of activators corresponding to the general formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may be the same or different and represent C.sub.1 -C.sub.20 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.6 -C.sub.14 -aryl or C.sub.7 -C.sub.30 -alkaryl,X.sup.1 and X.sup.2 may be the same or different and represent halogen or a radical of the formula --OR.sup.5, --SR.sup.6 or ##STR2## with the proviso that X.sup.1 and X.sup.2 cannot both represent a halogen atom,R.sup.5, R.sup.6 and R.sup.7 may be the same or different and represent a C.sub.1 -C.sub.20 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.6 -C.sub.14 -aryl or C.sub.7 -C.sub.30 -alkaryl and 1.ltoreq.x.ltoreq.4,and, optionally, in the presence of co-catalysts, blowing agents, chain-extending agents having a molecular weight of from 32 to 400 and other known auxiliaries and additives.
摘要翻译：任选发泡的聚氨酯通过使多异氰酸酯与含有至少两个异氰酸酯反应性氢原子并且分子量为400至10,000的有机化合物在对应于通式的活化剂的存在下反应来制备，其中R1， R 2，R 3和R 4可以相同或不同，表示C 1 -C 20烷基，C 5 -C 7 - 环烷基，C 6 -C 14 - 芳基或C 7 -C 30 - 烷芳基，X 1和X 2可以相同或不同，表示卤素或式 - OR5，-SR6或的基团，条件是X1和X2不能都表示卤素原子，R5，R6和R7可以相同或不同，表示C1-C20烷基，C5- C7-环烷基，C6-C14 - 芳基或C7-C30-烷芳基和1个x = 4，以及任选地，在助催化剂，发泡剂，扩链剂的存在下，分子量为从32到400和其他已知的助剂和添加剂。

40. 发明授权

US4377644A Mixed anhydrides of isocyanates and carboxylic acids, mixtures thereof with carboxylic acids, and the use thereof as blowing agents for the production of cellular plastics 失效
标题翻译：异氰酸酯和羧酸的混合酸酐，其与羧酸的混合物及其作为泡沫塑料生产发泡剂的用途
公开(公告)号：US4377644A
公开(公告)日：1983-03-22
申请号：US312034
申请日：1981-10-16
申请人： Richard Kopp , Gerhard Grogler , Max Mann
发明人： Richard Kopp , Gerhard Grogler , Max Mann
IPC分类号： C08J9/08 , C08G18/14
CPC分类号： C08J9/08
摘要： This invention relates to solid reaction products of aliphatic, cycloaliphatic or araliphatic mono- and/or polyisocyanates and organic, weakly acid mono- and/or polycarboxylic acids for the production of cellular plastics articles and particularly polyurethane foams. The products of the present invention may also be in the form of mixtures with carboxylic acids. The products are suitable for the production of cellular or porous plastics articles, but are preferably used in the preparation of cellular thermoplastic polyurethanes and semi-rigid and particularly rigid polyurethane integral skin foams having a compact outer skin formed by foaming the reaction mixture in closed molds.
摘要翻译：本发明涉及脂肪族，脂环族或芳脂族单 - 和/或多异氰酸酯和有机，弱酸单 - 和/或多元羧酸的固体反应产物，用于生产细胞塑料制品，特别是聚氨酯泡沫。本发明的产品也可以是与羧酸的混合物的形式。该产品适用于生产细胞或多孔塑料制品，但优选用于制备细胞热塑性聚氨酯和半刚性和特别硬的聚氨酯整体皮肤泡沫，其具有通过将闭合模具中的反应混合物发泡而形成的致密外皮。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式