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31. 发明授权

US5330886A Color photographic recording material 失效
标题翻译：彩色摄影材料
公开(公告)号：US5330886A
公开(公告)日：1994-07-19
申请号：US009952
申请日：1993-01-27
申请人： Gunter Helling , Gunter Renner
发明人： Gunter Helling , Gunter Renner
IPC分类号： G03C1/043 , G03C1/053 , G03C7/20 , G03C7/38 , G03C7/396 , G03C1/76
CPC分类号： G03C7/396
摘要： A color photographic recording material having a support, at least one light-sensitive silver halide emulsion layer containing a pyrazoloazole magenta coupler, at least one other layer which is arranged closer to the source of light and at least one other layer arranged further away from the source of light than the silver halide emulsion layer containing the pyrazoloazole magenta coupler, these other layers containing gelatine and a randomly or alternatingly structured copolymer of vinyl alcohol and an unsaturated carboxylic acid or a graft polymer of vinyl acetate on polyalkylene oxide followed by saponification of the acetate groups is distinguished by improved stability to light of the magenta dye obtained after processing.
摘要翻译：一种具有载体的彩色照相记录材料，至少一种含有吡唑并噻唑品红色偶合剂的感光卤化银乳剂层，至少一层布置得更靠近光源的另外一层，以及至少另外一层布置成远离光源比含有吡唑并噻唑品红色成色剂的卤化银乳剂层，这些其它层含有明胶和乙烯醇和不饱和羧酸的无规或交替结构的共聚物或乙酸乙烯酯在聚环氧烷上的接枝聚合物，然后皂化乙酸酯基的特征在于加工后获得的品红色染料的光稳定性提高。

32. 发明授权

US5292610A Microcapsules and their use 失效
标题翻译：微胶囊及其用途
公开(公告)号：US5292610A
公开(公告)日：1994-03-08
申请号：US846812
申请日：1992-03-06
申请人： Gunter Helling , Michael Muller , Wolfgang Podszun
发明人： Gunter Helling , Michael Muller , Wolfgang Podszun
IPC分类号： G03F7/00 , G03F7/027 , G03C1/72
CPC分类号： G03F7/002 , G03F7/027 , Y10S430/163
摘要： Microcapsules containing at least one leuco dye, at least one photopolymerisation initiator and at least one photopolymerisable monomer corresponding to the following formulaA[--NHCO--X--L.sub.1 --(OCO--CR.sub.1 =CH.sub.2).sub.1 ].sub.mwhereinA stands for a 3- to 6-valent organic group having the following meanings:a) a saturated hydrocarbon group having 5 to 25 carbon atoms orb) ##STR1## or c) ##STR2## wherein A.sub.1, A.sub.2, R.sub.3, R.sub.4, o and p have the meanings indicated in the description,X denotes O or NR.sub.2,L.sub.1 denotes a divalent or trivalent aliphatic hydrocarbon group whose carbon chain may be interrupted by 1 to 3 oxygen atoms,R.sub.1 denotes hydrogen or methyl,R.sub.2 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl,l denotes 1 or 2 andm denotes a number from 3 to 6,are distinguished by improved sensitivity.
摘要翻译：含有至少一种无色染料，至少一种光聚合引发剂和至少一种对应于下列通式A（-NHCO-X-L1-（OCO-CR 1 = CH 2）1）m）的可光聚合单体的微胶囊，其中A代表3- 具有以下含义的6价有机基团：a）具有5至25个碳原子的饱和烃基或b）（*化学结构*）或c）（*化学结构*）其中A1，A2，R3，R4， o和p具有说明书中所示的含义，X表示O或NR 2，L 1表示碳链可被1至3个氧原子间隔的二价或三价脂族烃基，R 1表示氢或甲基，R 2表示氢或C 1 -C 1-4 - 烷基，l表示1或2，m表示3至6的数，通过改进的灵敏度来区分。

33. 发明授权

US4865960A Polymeric magneta coupler and a colour photographic recording material containing this polymeric magenta coupler 失效
标题翻译：聚合磁性耦合器和含有该聚合物品红色耦合器的彩色照相记录材料
公开(公告)号：US4865960A
公开(公告)日：1989-09-12
申请号：US21782
申请日：1987-03-04
申请人： Gunter Helling , Erich Wolff
发明人： Gunter Helling , Erich Wolff
IPC分类号： G03C7/38 , G03C7/327
CPC分类号： G03C7/3275
摘要： Magenta images of increased color density D.sub.max can be obtained by using polymeric couplers containing polymerized units of a polymerizable pyrazoloazole coupler of formula I and polymerized units of a polymerizable monomer S which contains at least one acid group and is unsoluble in water at pH .ltoreq.6 and soluble in water at pH .gtoreq.10. ##STR1## In formula I R.sup.1 denotes H, alkyl, aralkyl or aryl,X denotes H or a group which is releasable by coupling, andZ.sub.a, and Z.sub.b and Z.sub.c denote a substituted or unsubstituted methine group,.dbd.N-- or --NH--, and either the linkage in Z.sub.a --Z.sub.b or the linkage in Z.sub.b --Z.sub.c is a double bond and the other linkage is a single bond,and at least R.sup.1 or X or a substituent on a methine group denoted by Z.sub.a, Z.sub.b or Z.sub.c contains an ethylenically unsaturated, polymerizable group.
摘要翻译：可以通过使用含有式I的可聚合吡唑并唑成色剂的聚合单元的聚合物成色剂和含有至少一个酸基的可聚合单体S的聚合单元并且在pH < 6，溶于水，pH> = 10。在式Ⅰ中，R1表示H，烷基，芳烷基或芳基，X表示H或可通过偶联而可释放的基团，Za和Zb和Zc表示取代或未取代的次甲基，= N-或-NH - ，并且Za-Zb中的键合或Zb-Zc中的连接是双键，另一个键是单键，并且至少R1或X或由Za，Zb或Zc表示的次甲基上的取代基含有烯属不饱和的可聚合基团。

34. 发明授权

US4714671A Color photographic recording material containing a polymeric gelatine plasticizer 失效
标题翻译：含有聚合物明胶增塑剂的彩色照相记录材料
公开(公告)号：US4714671A
公开(公告)日：1987-12-22
申请号：US855701
申请日：1986-04-25
申请人： Gunter Helling , Wolfgang Himmelmann
发明人： Gunter Helling , Wolfgang Himmelmann
IPC分类号： G03C1/04 , G03C1/053 , G03C1/31 , G03C7/396 , G03C7/26
CPC分类号： G03C1/31 , G03C7/396
摘要： Polymer latices in which the dispersed particles consist of a soft core and a hard shell are suitable plasticizers for gelatine in photographic recording materials.
摘要翻译：其中分散的颗粒由软核和硬壳组成的聚合物胶乳是用于照相记录材料中明胶的合适的增塑剂。

35. 发明授权

US4388403A Process for the preparation of dispersions of hydrophobic substances in water 失效
标题翻译：疏水性物质分散在水中的方法
公开(公告)号：US4388403A
公开(公告)日：1983-06-14
申请号：US305201
申请日：1981-09-24
申请人： Gunter Helling , Helmut Reiff , Wolfgang Himmelmann , Gunter Renner
发明人： Gunter Helling , Helmut Reiff , Wolfgang Himmelmann , Gunter Renner
IPC分类号： C08L101/00 , C08L67/00 , C08L77/00 , G03C1/005 , G03C1/04 , G03C1/06 , G03C7/388 , G03C1/40
CPC分类号： G03C1/005 , G03C1/04 , G03C7/3882
摘要： Dispersions of hydrophobic substances in water are prepared by dissolving the hydrophobic substance together with an ionomeric polyaddition or condensation product in an organic, water-miscible solvent or a mixture of such a solvent with water, diluting the solution with water and removing the organic solvent. The dispersions are excellently suitable for the preparation of photographic recording materials.
摘要翻译：疏水性物质在水中的分散体是通过将疏水性物质与离聚物加聚或缩合产物一起溶解在有机，水混溶性溶剂或这种溶剂与水的混合物中，将水稀释并除去有机溶剂来制备的。分散体非常适合于制备照相记录材料。

36. 发明授权

US4379838A Photosensitive photographic recording material comprising a dyed layer 失效
标题翻译：包含染色层的感光照相记录材料
公开(公告)号：US4379838A
公开(公告)日：1983-04-12
申请号：US308521
申请日：1981-10-05
申请人： Gunter Helling , Hans hlschlager , Wolfgang Himmelmann , Manfred Beck
发明人： Gunter Helling , Hans hlschlager , Wolfgang Himmelmann , Manfred Beck
IPC分类号： C08F8/00 , C08F8/14 , C08F8/44 , C08F20/00 , C08F20/34 , C08F30/00 , C08F30/02 , G03C1/835 , G03C8/56 , G03C1/84
CPC分类号： G03C1/835 , C08F8/44 , Y10S430/142
摘要： Addition polymers containing at least 10 mole % of recurring structural units of formula I are useful mordants for acid dyes which preferably contain at least two sulfo groups. The polymers can be used together with the dyes in dyed layers of photographic recording materials, such as in antihalo or filter layers. ##STR1## in which Q represents N or P;R.sup.1, R.sup.2, R.sup.3 represent alkyl or carbocyclic radicals or two of R.sup.1, R.sup.2 and R.sup.3 complete a 5- or 6-membered heterocyclic ring,R.sup.4 represents H or alkyl,X.sup..crclbar. represents an anion.
摘要翻译：含有至少10摩尔％的式I的重复结构单元的加成聚合物是优选含有至少两个磺基的酸性染料的有用的媒染剂。聚合物可以与照相记录材料的染色层中的染料一起使用，例如在抗卤素或过滤层中。其中Q表示N或P; R 1，R 2，R 3表示烷基或碳环基，或者R 1，R 2和R 3中的两个完成5-或6-元杂环，R 4表示H或烷基，X（ - ）表示阴离子。

37. 发明授权

US4294920A Photographic silver halide emulsion 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US4294920A
公开(公告)日：1981-10-13
申请号：US212890
申请日：1980-12-04
申请人： Gunter Helling , Wilhelm Saleck , Peter Bergthaller
发明人： Gunter Helling , Wilhelm Saleck , Peter Bergthaller
IPC分类号： G03C1/10 , C09D4/00 , G03C1/005 , G03C1/053 , G03C1/02 , G03C1/72
CPC分类号： G03C1/053 , C09D4/00
摘要： A polymer of at least one compound A with at least one compound B, in which A and B correspond to the following formulae ##STR1##B: H--S.sub.n --Q.sup.1 --W).sub.m Q.sup.2 --S--H is useful in light sensitive photographic materials comprising at least one silver halide emulsion layer.
摘要翻译：至少一种化合物A与至少一种化合物B的聚合物，其中A和B对应于下式B：H-Sn-Q1-W）m Q2-SH可用于光敏照相材料，其包含至少一个卤化银乳剂层。

38. 发明授权

US4138260A Photographic film unit with crosslinked neutralization layer 失效
标题翻译：具有交联中和层的摄影胶片单元
公开(公告)号：US4138260A
公开(公告)日：1979-02-06
申请号：US851310
申请日：1977-11-14
申请人： Werner Krafft , Gunter Helling
发明人： Werner Krafft , Gunter Helling
IPC分类号： G03C7/00 , G03C8/04 , G03C8/52 , G03C8/54 , G03C1/40 , G03C5/54
CPC分类号： G03C8/52
摘要： The neutralization layer (acid polymer layer) in a photographic film unit for the production of colored transfer images contains a crosslinked acrylic or methacrylic acid copolymer having at least 30 mol % of copolymerized acrylic acid or methacrylic acid and the crosslinking has been brought about by copolymerizing said acid monomers or the corresponding esters together with a crosslinking agent having at least two copolymerizable carbon-carbon double bands.
摘要翻译：用于生产彩色转印图像的照相胶片单元中的中和层（酸性聚合物层）含有具有至少30mol％的共聚丙烯酸或甲基丙烯酸的交联的丙烯酸或甲基丙烯酸共聚物，并且通过共聚所述酸单体或相应的酯与具有至少两个可共聚碳 - 碳双键的交联剂一起。

39. 发明授权

US5935773A Colour photographic silver halide material 失效
标题翻译：彩色照相卤化银材料
公开(公告)号：US5935773A
公开(公告)日：1999-08-10
申请号：US639970
申请日：1996-04-29
申请人： Jorg Hagemann , Gunter Helling
发明人： Jorg Hagemann , Gunter Helling
IPC分类号： G03C7/392 , G03C1/46
CPC分类号： G03C7/39268 , G03C7/39208 , G03C7/39296
摘要： A colour photographic silver halide material with a support, at last one silver halide emulsion layer containing at least one yellow coupler and at least one silver halide emulsion layer containing a cyan coupler applied thereon, in which material the silver halide emulsion layer, of which there is at least one, containing at least one yellow coupler and/or the silver halide emulsion layer, of which there is at least one, containing at least one cyan coupler contains a compound of the formula (I) ##STR1## in which R.sub.1, R.sub.2, R.sub.3 mean alkyl, alkenyl or acyl andn means 6, 7 or 8,is distinguished by improved stability of the image dyes produced by processing.
摘要翻译：具有载体的彩色照相卤化银材料，最后含有至少一种黄色成色剂的卤化银乳剂层和至少一种含有青色成色剂的卤化银乳剂层，其中存在卤化银乳剂层，其中存在卤化银乳剂层至少一个，含有至少一个黄色成色剂和/或卤化银乳剂层，其中至少有一个含有至少一个含有式（I）的化合物的青色成色剂，其中R1，R2，R3 平均烷基，烯基或酰基，n表示6,7或8，其特征在于通过加工产生的图像染料的改进的稳定性。

40. 发明授权

US5731138A Color photographic material 失效
标题翻译：彩色照相材料
公开(公告)号：US5731138A
公开(公告)日：1998-03-24
申请号：US592692
申请日：1996-01-26
申请人： Gunter Helling , Beate Weber , Markus Geiger
发明人： Gunter Helling , Beate Weber , Markus Geiger
IPC分类号： G03C7/00 , G03C7/30 , G03C7/38 , G03C7/388 , G03C7/392 , G03C7/396 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号： G03C7/39296 , G03C7/3008 , G03C7/3825 , G03C7/3882 , G03C7/396
摘要： A color photographic material which contains in at least one layer a stabilizer of the formula (I) ##STR1## in which R.sub.1 means H, alkyl, aryl or acyl; R.sub.2 means --OR.sub.1, --COOH, alkyl, aryl, dialkylamino, acylamino, sulphonamido, acyl or sulphonyl; R.sub.3, R.sub.4, R.sub.5 and R.sub.6 independently of one another mean H, halogen or a residue as R.sub.2 or two adjacent residues --OR.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 may together complete a 5- to 8-membered ring, and a polymer insoluble in water as pH 5 and soluble at pH 11 with an acid value of 30 to 300 and a Tg of.ltoreq.40.degree. C. of the formula (II) ##STR2## in which R.sub.7 mutually independently mean hydrogen, C.sub.1 -C.sub.4 alkyl or CH.sub.2 --COOH, R.sub.8 means alkyl, aryl or aralkyl a means 80 to 95 mol. % and b means 5 to 20 mol. %, is distinguished by improved stability of the image dyes.
摘要翻译：一种彩色照相材料，其在至少一层中含有式（I）r酰基的稳定剂; R2表示-OR1，-COOH，烷基，芳基，二烷基氨基，酰氨基，磺酰氨基，酰基或磺酰基; R 3，R 4，R 5和R 6彼此独立地表示H，卤素或作为R 2或两个相邻残基-OR 1，R 2，R 3，R 4，R 5和R 6的残基可以一起完成5-至8-元环，不溶于水的聚合物，其pH值为5，在pH值为11，酸值为30至300，Tg为40℃，式（Ⅱ）其中R7相互独立地表示氢，C 1 -C 4烷基或CH 2 -COOH，R 8表示烷基，芳基或芳烷基，是指80至95摩尔。％和b表示5〜20mol。％，通过改善图像染料的稳定性来区分。

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