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31. 发明授权

US4128620A Production of phosphine 失效
标题翻译：生产磷化氢
公开(公告)号：US4128620A
公开(公告)日：1978-12-05
申请号：US830160
申请日：1977-09-02
申请人： Jurgen Stenzel , Gero Heymer
发明人： Jurgen Stenzel , Gero Heymer
IPC分类号： C01B25/06 , C01B25/37 , C01B25/00
CPC分类号： C01B25/37 , C01B25/06
摘要： Production of phosphine. The phosphine is produced by reducing, in a first step, anhydrous zinc phosphate to zinc phosphide by treatment with carbon at a temperature higher than 1000.degree. C, and, in a second step, reacting the zinc phosphide formed in the first step with phosphoric acid. The resulting gaseous phosphine is collected, and the resulting zinc phosphate, which is obtained as a difficultly soluble precipitate, is dried, dehydrated and recycled to the first step.
摘要翻译：生产磷化氢。通过在高于1000℃的温度下用碳处理将第一步中的无水磷酸锌还原为磷化锌，并且在第二步骤中，使第一步中形成的磷化锌与磷酸。收集所得的气态膦，将得到的作为难溶性沉淀物得到的磷酸锌干燥，脱水并再循环至第一步。

32. 发明授权

US4073810A Production of organophosphines 失效
标题翻译：生产有机膦
公开(公告)号：US4073810A
公开(公告)日：1978-02-14
申请号：US549172
申请日：1975-02-12
申请人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
发明人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
IPC分类号： B01J21/00 , C07B61/00 , C07F9/50 , C07F9/53 , C07F9/54
CPC分类号： C07F9/5086 , C07F9/54
摘要： Production of organophosphines of the general formula R.sub.n PH.sub.3-n, in which R stands for identical or different, substituted or unsubstituted alkyl, cycloalkyl or aralkyl groups having from 1 to 18 carbon atoms, preferably from 1 to 4 carbon atoms, more preferably from 1 to 2 carbon atoms, and n stands for a whole number within the range 1 and 3. The compounds are more particularly produced by continuously reacting hydrocarbon halides of the general formula RX, in which R has the meaning given hereinabove and X stands for halogen, especially for chlorine or bromine, with hydrogen phosphide, and primary or secondary organophosphines at temperatures within the range 100.degree. and 600.degree. C. and under pressures of up to 20 atmospheres in contact with a catalyst being placed in a reactor. Gaseous matter issuing from the reactor is cooled and the resulting organophosphonium halides (R.sub.n PH.sub.4-n)X are hydrolyzed in conventional manner to the corresponding organophosphines.
摘要翻译：制备通式RnPH3-n的有机膦，其中R代表相同或不同的取代或未取代的具有1至18个碳原子，优选1至4个碳原子的烷基，环烷基或芳烷基，更优选1至 2个碳原子，n表示1和3范围内的整数。化合物更特别地通过连续反应通式RX的卤代烃，其中R具有上文给出的含义，X代表卤素，特别是对于氯或溴，与磷化氢以及初级或次级有机膦在100℃和600℃的温度范围内以及在与置于反应器中的催化剂接触的情况下在高达20个大气压的压力下进行。将从反应器排出的气态物质冷却，并将所得的有机鏻卤化物（RnPH4-n）X以常规方式水解成相应的有机膦。

33. 发明授权

US4042324A Process for inhibiting the corrosions and deposition of boiler scale in water-conveying systems 失效
标题翻译：防止锅炉水垢在水输送系统中的腐蚀和沉积的过程
公开(公告)号：US4042324A
公开(公告)日：1977-08-16
申请号：US654885
申请日：1976-02-03
申请人： Theodor Auel , Hannsjorg Ulrich , Horst-Dieter Wasel-Nielen , Gero Heymer
发明人： Theodor Auel , Hannsjorg Ulrich , Horst-Dieter Wasel-Nielen , Gero Heymer
IPC分类号： C02F5/14 , C07F9/38 , C23F11/167 , C02B5/06 , C23F11/16
CPC分类号： C23F11/1676 , C02F5/14 , C07F9/3808 , C23F11/167
摘要： Corrosion and deposition of boiler scale in water-conveying systems are inhibited. To this end the water is admixed with at least one carboxy-alkane compound of phosphorus of the general formula: ##STR1## in which each of the substituents R.sup.1, R.sup.2, R.sup.3, and R.sup.4 stands for hydrogen or an alkyl group having from 1 to 4 carbon atoms, R.sup.5 stands for hydrogen, an OH-group or an alkyl group having from 1 to 3 carbon atoms, and n stands for 0 or 1, or with at least one water-soluble salt thereof.
摘要翻译：锅炉秤在输水系统中的腐蚀和沉积受到抑制。为此，将水与至少一种以下通式的磷的羧基烷烃化合物混合：其中每个取代基R 1，R 2，R 3和R 4代表氢或具有1至 4个碳原子，R5代表氢，OH-基团或具有1至3个碳原子的烷基，n代表0或1，或其至少一种水溶性盐。

34. 发明授权

US4906445A Continuous process for complete removal or organic impurities from and complete decolorization of prepurified wet-process phosphoric acid 失效
标题翻译：用于完全去除或有机杂质的连续方法和完全脱湿的湿法磷酸完全脱色
公开(公告)号：US4906445A
公开(公告)日：1990-03-06
申请号：US311640
申请日：1989-02-16
申请人： Gunther Schimmel , Gerhard Bettermann , Gero Heymer , Friedrich Kolkmann
发明人： Gunther Schimmel , Gerhard Bettermann , Gero Heymer , Friedrich Kolkmann
IPC分类号： C01B25/234 , C01B25/235 , C01B25/46
CPC分类号： C01B25/461 , C01B25/235
摘要： A continuous process is indicated for complete removal of organic impurities from and complete decolorization of pre-purified wet-process phosphoric acid which has been purified by an extractive method using an organic solvent, freed from residual hydrofluoric acid by steam stripping and treated with hydrogen peroxide at elevated temperature, which comprises mixing the pre-purified wet-process phosphoric acid and the hydrogen peroxide in a mixing zone at a temperature of from 100.degree. to 200.degree. C., preferably 140.degree. to 160.degree. C., and allowing them to react at this temperature for a further 1 to 4 hours, cooling to from 85.degree. to 90.degree. C. the pre-purified wet-process phosphoric acid treated in this way and pumping it at this temperature with exclusion of air firstly through an activated charcoal bed which has been prepared on the basis of peat and has been steam-activated and has a BET surface area of from 800 to 1000 m.sup.2 /g, and subsequently through a silicon carbide and/or graphite bed while maintaining a pumping rate of less than 0.5 m.sup.3 /h of wet-process phosphoric acid per m.sup.3 of activated charcoal bed.
摘要翻译：指示完全除去有机杂质并完全脱色预纯化的湿法磷酸的连续方法，其通过萃取方法使用有机溶剂纯化，通过汽提除去残留的氢氟酸并用过氧化氢处理在高温下，其包括在预先纯化的湿法磷酸和过氧化氢的混合区中在100至200℃，优选140至160℃的温度下混合，并使它们在该温度下再反应1至4小时，冷却至85℃至90℃，预纯化的湿法磷酸以此方式处理并在该温度下泵送，首先通过活性炭排除空气基于泥炭制备并已蒸汽活化并具有800至1000m2 / g的BET表面积的床，随后通过碳化硅和/或石墨b 同时保持每立方米活性炭床的湿法磷酸的泵送速率小于0.5m 3 / h。

35. 发明授权

US4600565A Process for making manganese (II) salt solutions containing ammonium salt 失效
标题翻译：制备含有铵盐的锰（II）盐溶液的方法
公开(公告)号：US4600565A
公开(公告)日：1986-07-15
申请号：US708299
申请日：1985-03-05
申请人： Klaus Lehr , Bernhard Hofmann , Gero Heymer
发明人： Klaus Lehr , Bernhard Hofmann , Gero Heymer
IPC分类号： C01G45/00 , C22B47/00
CPC分类号： C01G45/00 , C22B47/00
摘要： Manganese(II)salt solutions containing ammonium salt are made by subjecting a manganese-containing compound to processing treatment with an ammonium salt solution. A boiling temperature of 57.degree.-68.degree. C. is established in the suspension to be subjected to the processing treatment, by application of a vacuum. The ammonium salt solution used contains 0.5-2.5 mol/l diammonium sulfate or 1.0-5.0 mol/l ammonium nitrate.
摘要翻译：含有铵盐的锰（II）盐溶液通过使含锰化合物用铵盐溶液进行处理来制备。通过施加真空在待处理处理的悬浮液中建立沸点为57-68℃的温度。使用的铵盐溶液含有0.5-2.5mol / l硫酸二铵或1.0-5.0mol / l硝酸铵。

36. 发明授权

US4530769A Process for separating carbon black from an aqueous suspension 失效
标题翻译：从水性悬浮液中分离炭黑的方法
公开(公告)号：US4530769A
公开(公告)日：1985-07-23
申请号：US479965
申请日：1983-03-29
申请人： Manfred Wolter , Friedrich-Wilhelm Dorn , Gero Heymer , Hans-Werner Stephan
发明人： Manfred Wolter , Friedrich-Wilhelm Dorn , Gero Heymer , Hans-Werner Stephan
IPC分类号： B01D25/12 , C09C1/48 , C10G31/09 , B01D29/10
CPC分类号： C09C1/487 , C01P2006/12
摘要： The disclosure relates to a process for the discontinuous separation of a solid consisting predominantly of carbon black from its aqueous suspension by filtration. To this end, the disclosure provides for use to be made of a tube pressure filter which is operated under a final pressure of 30 to 100 bars.
摘要翻译：本公开涉及通过过滤从其水悬浮液中主要由炭黑组成的固体的不连续分离的方法。为此，本公开提供了用于在30至100巴的最终压力下操作的管式压力过滤器的使用。

37. 发明授权

US4525333A Process for separating gallium and indium from aqueous solutions 失效
标题翻译：从水溶液中分离镓和铟的工艺
公开(公告)号：US4525333A
公开(公告)日：1985-06-25
申请号：US531156
申请日：1983-09-09
申请人： Gunther Schimmel , Gero Heymer , Werner Krause , Werner Pieper
发明人： Gunther Schimmel , Gero Heymer , Werner Krause , Werner Pieper
IPC分类号： C22B58/00 , C01G15/00 , C22B3/38
CPC分类号： C01G15/003 , C22B3/0067 , C22B3/0087 , Y02P10/234
摘要： The disclosure relates to a process for separating gallium and indium from an aqueous solution by subjecting this latter to liquid/liquid extraction with the use of certain classes of organylphosphonic acid esters and separating the resulting liquid phases from one another.
摘要翻译：本公开涉及通过使用后者使用某些种类的有机膦酸酯并将所得液相彼此分离来从水溶液中分离镓和铟的方法。

38. 发明授权

US4466948A Process for removing heavy metal ions and arsenic from wet-processed phosphoric acid 失效
标题翻译：从湿法处理的磷酸中去除重金属离子和砷的工艺
公开(公告)号：US4466948A
公开(公告)日：1984-08-21
申请号：US508272
申请日：1983-06-24
申请人： Gunther Schimmel , Reinhard Gradl , Gero Heymer
发明人： Gunther Schimmel , Reinhard Gradl , Gero Heymer
IPC分类号： C01B25/237 , C01B25/238 , C01G1/00 , C01G3/00 , C01G11/00 , C01G13/00 , C01G21/00 , C01G28/00 , C22B3/38 , C01B25/16 , B01D11/00 , B03C1/00 , C01G17/00
CPC分类号： C01G3/003 , C01B25/238 , C01G11/003 , C01G13/003 , C01G21/003 , C01G28/001 , C22B3/007 , C22B3/24 , Y02P10/234
摘要： The disclosure relates to a process for removing heavy metal ions and arsenic from wet-processed phosphoric acid, wherein the crude wet-processed phosphoric acid is treated at temperatures between 10.degree. and 100.degree. C. initially with a diorganyldithiosphosphoric acid ester and then with an adsorbent, and the phoshoric acid so purified is separated from the ester and adsorbent. More particularly, the wet-processed phosphoric acid is treated with the diorganyldithiophosphoric acid ester at temperatures higher than 50.degree. C. and with the adsorbent at temperatures lower than 50.degree. C.
摘要翻译：本公开涉及从湿法处理的磷酸中除去重金属离子和砷的方法，其中粗制湿法处理的磷酸最初用二有机基二硫代磷酸酯在10℃至100℃的温度下处理，然后用吸附剂，如此纯化的磷酸与酯和吸附剂分离。更具体地说，湿法处理的磷酸在二氧化二硫代磷酸酯的温度高于50℃下处理，吸附剂在低于50℃的温度下处理。

39. 发明授权

US4399114A Process for the dearsenification of polyphosphoric acid 失效
标题翻译：多磷酸脱砷方法
公开(公告)号：US4399114A
公开(公告)日：1983-08-16
申请号：US402941
申请日：1982-07-29
申请人： Alexander Maurer , Gero Heymer , Markus Erpenbach
发明人： Alexander Maurer , Gero Heymer , Markus Erpenbach
IPC分类号： C01B25/24 , C01B25/16
CPC分类号： C01B25/24
摘要： The disclosure relates to a process for the continuous dearsenification of polyphosphoric acid with the aid of hydrogen sulfide in a gas admission zone. To this end, the disclosure provides for the acid to be dearsenified in a gas admission zone subdivided so as to comprise at least two separate liquid matter-receiving zones, each zone being separated from the other by means of a separate gas zone; for the liquid in each of the liquid matter-receiving zones to be maintained at a level 0.1 up to 10 cm high, without admission of gas; for hydrogen sulfide which remained unreacted in the individual liquid matter-receiving zones to be collected in the respective gas zone and for it to be finely redispersed in the liquid matter-receiving zone directly upstream of the respective gas zone by allowing the hydrogen sulfide to flow through a plurality of openings into the acid, the latter being delivered from the respective liquid-matter-receiving zone into the next downstream liquid-matter-receiving zone, and introduced thereinto directly below the liquid matter level therein; for precipitated arsenic sulfide to be separated from the acid coming from the lower end of the gas admission zone, and for the filtrate obtained to be freed from gaseous hydrogen sulfide in excess.
摘要翻译：本公开涉及在气体入口区借助硫化氢连续脱砷多磷酸的方法。为此，本公开内容提供了在气体进入区域中进行脱砷的酸，其被细分为包括至少两个分离的液体物质接收区域，每个区域通过单独的气体区域与另一个区域分离; 使每个液体物质接收区域中的液体保持在0.1至10厘米高的水平，而不允许气体; 对于在各个液体物质接收区中保持未反应的硫化氢，其被收集在各个气体区中，并且通过允许硫化氢流动直接在各个气体区的上游被精细地再分散在液体物质接收区中通过多个开口进入酸，后者从相应的液体接收区输送到下一个下游液体接收区，并直接在其中引入液体物质的下方; 使沉淀的硫化砷与气体入口区的下端的酸分离，得到的过滤得到的无水硫化氢的滤液。

40. 发明授权

US4394358A Production of granular alkali metal diphosphates or triphosphates 失效
标题翻译：生产颗粒状碱金属二磷酸盐或三磷酸盐
公开(公告)号：US4394358A
公开(公告)日：1983-07-19
申请号：US303100
申请日：1981-09-17
申请人： Alexander Maurer , Renate Adrian , Herbert Panter , Gero Heymer , Dieter Nolker
发明人： Alexander Maurer , Renate Adrian , Herbert Panter , Gero Heymer , Dieter Nolker
IPC分类号： C01B25/41 , C01B25/42 , C11D3/06 , C01B25/30
CPC分类号： C01B25/418 , C01B25/425 , C11D3/062
摘要： The invention relates to a process for making granulated, partially or completely hydrated alkali metal diphosphates or triphosphates. To this end, the invention provides for alkali metal diphosphates or triphosphates which consist to an extent of at least 20% of particles with a size of less than 0.045 mm and are hydrated to an extent of less than 90%, based on the phosphates' theoretical content of water of hydration, to be intensively mixed and granulated in the presence of water and an ammonium polyphosphate, this latter being used in a proportion of about 0.5 to 50 weight %, based on the quantity of water used.
摘要翻译：本发明涉及制备颗粒状，部分或完全水合的碱金属二磷酸盐或三磷酸盐的方法。为此，本发明提供碱金属二磷酸盐或三磷酸盐，其碱度至少为20％，其尺寸小于0.045mm，并且基于磷酸盐的水合物水合至小于90％的程度，在水和多磷酸铵的存在下，水合的水的理论含量将被浓缩混合和造粒，后者基于所用的水量以约0.5至50重量％的比例使用。

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