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    • 33. 发明授权
    • Self-assembly of water-soluble nanocrystals
    • 水溶性纳米晶体的自组装
    • US08092595B1
    • 2012-01-10
    • US12038037
    • 2008-02-27
    • Hongyou FanC. Jeffrey BrinkerGabriel P. Lopez
    • Hongyou FanC. Jeffrey BrinkerGabriel P. Lopez
    • C30B7/04
    • C30B7/14C30B29/68
    • A method for forming an ordered array of nanocrystals where a hydrophobic precursor solution with a hydrophobic core material in an organic solvent is added to a solution of a surfactant in water, followed by removal of a least a portion of the organic solvent to form a micellar solution of nanocrystals. A precursor co-assembling material, generally water-soluble, that can co-assemble with individual micelles formed in the micellar solution of nanocrystals can be added to this micellar solution under specified reaction conditions (for example, pH conditions) to form an ordered-array mesophase material. For example, basic conditions are used to precipitate an ordered nanocrystal/silica array material in bulk form and acidic conditions are used to form an ordered nanocrystal/silica array material as a thin film.
    • 一种用于形成纳米晶体的有序阵列的方法,其中在有机溶剂中具有疏水性核心材料的疏水性前体溶液加入到表面活性剂在水中的溶液中,然后除去至少一部分有机溶剂以形成胶束 纳米晶体的溶液。 可以在规定的反应条件(例如,pH条件)下,将能够与形成在纳米晶体的胶束溶液中的单个胶束共同组装的通常为水溶性的前体共组装材料加入到该胶束溶液中, 阵列中间相材料。 例如,使用基本条件来沉淀有序的纳米晶体/二氧化硅阵列材料的体积形式,并且酸性条件用于形成有序的纳米晶体/二氧化硅阵列材料作为薄膜。