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    • 39. 发明授权
    • Nonaqueous electrolytic solution and nonaqueous electrolyte battery
    • 非水电解液和非水电解质电池
    • US08685562B2
    • 2014-04-01
    • US13397197
    • 2012-02-15
    • Minoru KotatoShinichi Kinoshita
    • Minoru KotatoShinichi Kinoshita
    • H01M6/14
    • H01M10/0567H01M10/052H01M10/0568Y02E60/122
    • A nonaqueous electrolytic solution that can provide a battery that is low in gas generation, has a large capacity, and is excellent in storage characteristics and cycle characteristics. The solution contains an electrolyte, a nonaqueous solvent dissolving the electrolyte, 0.001 vol % to 5 vol % of a compound represented by Formula (1), and further contains at least one compound selected from the group consisting of cyclic carbonate compounds having carbon-carbon unsaturated bonds, cyclic carbonate compounds having fluorine atoms, monofluorophosphates, and difluorophosphates. In Formula (1), R1 to R3 each independently represent an alkyl group having 1 to 12 carbon atoms, optionally substituted by a halogen atom; and n is an integer of 0 to 6.
    • 能够提供气体发生量低的电池的非水电解液具有大容量,并且具有优异的储存特性和循环特性。 溶液含有电解质,溶解电解质的非水溶剂,0.001体积%〜5体积%的式(1)表示的化合物,还含有至少一种选自具有碳 - 碳的环状碳酸酯化合物 不饱和键,具有氟原子的环状碳酸酯化合物,单氟磷酸盐和二氟磷酸盐。 式(1)中,R 1〜R 3各自独立地表示可以被卤素原子取代的碳原子数1〜12的烷基, n为0〜6的整数。