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31. 发明公开

EP2029696A1 MIXED PHASE, MULTISTAGE ALKYLAROMATICS PRODUCTION 有权转让
标题翻译：混色器，多级烷基芳烃生产
公开(公告)号：EP2029696A1
公开(公告)日：2009-03-04
申请号：EP07755093.7
申请日：2007-04-09
申请人： ExxonMobil Chemical Patents Inc. , Badger Licensing LLC
发明人： CLARK, Michael, C. , MAERZ, Brian
IPC分类号： C10G29/20 , C07C2/66 , C07C6/12
CPC分类号： C07C2/66 , C07C6/126 , C10G2400/30 , C07C15/085 , C07C15/02 , C07C15/073
摘要： A process is described for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene and one or more alkanes are introduced into said first alkylation reaction zone. The first alkylation reaction zone is operated under conditions of temperature and pressure effective to cause alkylation of the aromatic compound with the alkene in the presence of the alkylation catalyst, the temperature and pressure being such that the aromatic compound is partly in the vapor phase and partly in the liquid phase. An effluent comprising the alkylaromatic compound, unreacted alkylatable aromatic compound, any unreacted alkene and the alkane is withdrawn from the first alkylation reaction zone and then supplied to the second alkylation reaction zone without removal of the alkane. The operating conditions in each of said first and second reaction zones are such that the ratio of the volume of liquid to the volume of vapor in each zone is from about 0.1 to about 10.

32. 发明公开

EP2029511A1 ORGANIC COMPOUND CONVERSION PROCESS 无效
标题翻译：工艺转换的有机化合物
公开(公告)号：EP2029511A1
公开(公告)日：2009-03-04
申请号：EP06752400.9
申请日：2006-05-08
申请人： ExxonMobil Chemical Patents Inc.
发明人： CLARK, Michael, C. , XU, Teng , VINCENT, Matthew, J.
IPC分类号： C07C45/72 , C07C6/00 , C07C15/00 , C07C2/66 , C07C2/12 , C07C6/12 , C07C15/085 , C07C15/073 , C07C2/02
CPC分类号： C07C2/12 , C07C2/66 , Y02P20/52 , C07C15/02 , C07C15/073 , C07C15/085
摘要： The present invention provides a process for conversion of feedstock comprising organic compounds to desirable conversion product at organic compound conversion conditions in the presence of catalyst comprising an acidic, porous crystalline material and having a Proton Density Index of greater than 1.0, for example, from greater than 1.0 to about 2.0, e.g. from about 1.01 to about 1.85. The acidic, porous crystalline material of the catalyst may comprise a porous, crystalline material or molecular sieve having the structure of zeolite Beta, an MWW structure type material, e.g. MCM-22, MCM-36, MCM-49, MCM-56, or a mixture thereof.

33. 发明公开

EP1888715A2 PROCESS FOR REDUCING BROMINE INDEX OF HYDROCARBON FEEDSTOCKS 审中-公开
标题翻译：降低烃类原料溴指数的方法
公开(公告)号：EP1888715A2
公开(公告)日：2008-02-20
申请号：EP06750489.4
申请日：2006-04-18
申请人： ExxonMobil Chemical Patents Inc.
发明人： BROWN, Stephen, H. , MOHR, Gary, D. , CLARK, Michael, C. , LAWRENCE, Selma
IPC分类号： C10G53/02 , C10G53/08 , C10G29/16 , C10G25/00 , C10G25/03 , C10G69/12 , C10G67/06 , C10G67/14
CPC分类号： C10G29/16 , C10G25/003 , C10G25/03 , C10G53/02 , C10G53/08 , C10G67/06 , C10G67/14 , C10G69/12 , C10G2300/4018 , C10G2300/4056 , C10G2300/701
摘要： A process for reducing the Bromine Index of a hydrocarbon feedstock, the process comprising the step of contacting the hydrocarbon feedstock with a catalyst at conversion conditions, wherein the catalyst includes at least one molecular sieve and at least one clay, and wherein said catalyst is sufficient to reduce more than 50% of the Bromine Index of a hydrocarbon feedstock.
摘要翻译：一种降低烃原料的溴指数的方法，所述方法包括在转化条件下使所述烃原料与催化剂接触的步骤，其中所述催化剂包含至少一种分子筛和至少一种粘土，并且其中所述催化剂是足够的以减少烃原料的溴指数的50％以上。

34. 发明授权

EP2158302B1 IMPROVED LIQUID PHASE ALKYLATION PROCESS 有权
公开(公告)号：EP2158302B1
公开(公告)日：2019-07-10
申请号：EP08769618.3
申请日：2008-05-22
申请人： ExxonMobil Chemical Patents Inc.
发明人： CLARK, Michael, C. , LO, Frederick, Y. , ELIA, Christine, N. , VINCENT, Matthew, J.
IPC分类号： C10G29/20 , C07C2/58 , C07C2/66

35. 发明授权

EP2134815B1 IMPROVED ALKYLAROMATIC PRODUCTION PROCESS 有权
标题翻译：改进用于生产烷基芳烃
公开(公告)号：EP2134815B1
公开(公告)日：2013-05-01
申请号：EP08713997.8
申请日：2008-01-25
申请人： Exxonmobil Chemical Patents Inc. A Corporation Of The State Of Delaware
发明人： CLARK, Michael, C. , ELIA, Christine, N. , LO, Frederick, Y. , VINCENT, Matthew, J.
IPC分类号： C10G50/00 , C07C2/66
CPC分类号： C10G50/00 , C07C2/66 , C10G2300/1088 , C10G2300/1092 , C10G2300/1096 , C10G2300/70 , C10G2400/30 , Y02P20/52 , C07C15/073 , C07C15/085

36. 发明授权

EP1542947B8 ALKYLAROMATICS PRODUCTION 有权
标题翻译：烷基酚生产
公开(公告)号：EP1542947B8
公开(公告)日：2010-05-19
申请号：EP03754437.6
申请日：2003-09-04
申请人： ExxonMobil Chemical Patents Inc. , Washington Group International, Inc.
发明人： CLARK, Michael, C. , SMITH, Charles, M. , CIMINI, Ronald, J. , MAERZ, Brian
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C6/126 , C07C15/073
摘要： A process is described for producing an alkylaromatic compound by reacting an alkylatable aromatic compound with a feed comprising an alkene and an alkane in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones each containing an alkylation catalyst. At least the first alkylation reaction zone is operated under conditions of temperature and pressure effective to cause alkylation of the aromatic compound with the alkene in the presence of the alkylation catalyst, the temperature and pressure being such that the aromatic compound is partly in the vapor phase and partly in the liquid phase. An effluent comprising the alkylaromatic compound, unreacted alkylatable aromatic compound, any unreacted alkene and the alkane is withdrawn from the first alkylation reaction zone and at least part of the alkane is removed from the effluent to produce an alkane-depleted effluent. The alkane depleted effluent is then supplied to the second alkylation reaction zone.
摘要翻译：描述了一种通过使可烷基化芳族化合物与包含烯烃和烷烃的进料在多级反应体系中反应来制备烷基芳族化合物的方法，所述多级反应体系包含至少第一和第二串联连接的各自含有烷基化催化剂的烷基化反应区。至少第一烷基化反应区在有效引起芳族化合物与烯烃在烷基化催化剂存在下烷基化的温度和压力条件下操作，温度和压力使得芳族化合物部分为气相部分处于液相。包含烷基芳族化合物，未反应的可烷基化芳族化合物，任何未反应的烯烃和烷烃的流出物从第一烷基化反应区中排出，并且至少部分烷烃从流出物中除去以产生贫烷烃流出物。然后将贫去链烷烃的流出物供应到第二烷基化反应区。

37. 发明公开

EP2113018A1 LIQUID PHASE ALKYLATION WITH MULTIPLE CATALYSTS 有权转让
标题翻译：烷基化液相中与多种催化剂的应用
公开(公告)号：EP2113018A1
公开(公告)日：2009-11-04
申请号：EP08713466.4
申请日：2008-01-03
申请人： ExxonMobil Chemical Patents Inc. , Stone & Webster, Inc.
发明人： CLARK, Michael, C. , NANDA, Vijay , CHI, Chung-Ming , BHANDAKAR, Maruti , MAERZ, Brian , VINCENT, Matthew, J.
IPC分类号： C10G29/20 , C07C2/66 , C07C6/12
CPC分类号： C10G29/205 , C07C2/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C10G2300/1092 , C10G2300/1096 , C10G2400/30 , Y02P20/52 , C07C15/073 , C07C15/02 , C07C15/085
摘要： A process is disclosed for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones, each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into the first alkylation reaction zone. The first and second alkylation reaction zones are operated under conditions of temperature and pressure effective to cause alkylation of the aromatic compound with the alkene in the presence of the alkylation catalyst, the temperature and pressure being such that the aromatic compound is at least partly in the liquid phase. The alkylation catalyst in the first alkylation reaction zone, which may be a reactor guard bed, has more acid sites per unit volume of catalyst than the alkylation catalyst in the second reaction zone.

38. 发明公开

EP1866267A1 ALKYLAROMATICS PRODUCTION USING DILUTE ALKENE 有权转让
标题翻译：用稀ALKEN MANUFACTURING烷基芳族化合物
公开(公告)号：EP1866267A1
公开(公告)日：2007-12-19
申请号：EP06736556.9
申请日：2006-03-01
申请人： ExxonMobil Chemical Patents Inc. , Badger Licensing LLC
发明人： CLARK, Michael, C. , MAERZ, Brian
IPC分类号： C07C2/66
CPC分类号： G01N21/643 , A61B5/0833 , C07C2/64 , C07C2/66 , C07C6/12 , C07C6/126 , C07C15/073 , C07C15/02 , C07C15/085
摘要： Process for producing an alkylated aromatic product in a reactor by reacting an alkylatable aromatic compound feedstock with another feedstock comprising alkene component and alkane component in a reaction zone containing an alkylation catalyst. The reaction zone is operated in predominantly liquid phase without inter-zone alkane removal. The polyalkylated aromatic compounds can be separated as feed stream for transalkylation reaction in a transalkylation reaction zone.

39. 发明申请

WO2010024958A3 METHOD OF ISOLATING LINEAR BUTENES FROM A MIXED HYDROCARBON FEED INCLUDING AN ISOBUTENE OLIGOMERISATION STEP 审中-公开
公开(公告)号：WO2010024958A3
公开(公告)日：2010-03-04
申请号：PCT/US2009/046111
申请日：2009-06-03
申请人： EXXONMOBIL CHEMICAL PATENT INC. , PHILLION, Katherine, S. , BRIGNAC, Garland, B. , CLARK, Michael, C. , MOLONEY, Glenn, J. , NORRIS, Donald, J. , UMANSKY, Benjamin, S.
发明人： PHILLION, Katherine, S. , BRIGNAC, Garland, B. , CLARK, Michael, C. , MOLONEY, Glenn, J. , NORRIS, Donald, J. , UMANSKY, Benjamin, S.
IPC分类号： C07C2/04
摘要： Described is an apparatus for, and a method of, recovering linear butenes from a mixed feed comprising providing a first mixed feed comprising linear butenes and isobutene; contacting the first mixed feed with an oligomerization catalyst such as an MWW family zeolite in a first oligomerization reactor to produce a second mixed feed comprising the linear butenes, C 8 olefins and higher oligomers, and a reduced amount of isobutene relative to the first mixed feed; and separating the second mixed feed to produce a first effluent of first purified linear butenes, and a second effluent of C 8 olefins and higher oligomers. The oligomerization reactor may be a converted isobutene-to-methyl-t-butylether reactor.

40. 发明申请

WO2010104581A2 PROCESS FOR MAKING HIGH OCTANE GASOLINE WITH REDUCED BENZENE CONTENT BY BENZENE ALKYLATION AT HIGH BENZENE CONVERSION 审中-公开
标题翻译：通过苯甲醛在高浓度苯甲醛转化中制备具有降低苯并呋喃含量的高辛烷值的方法
公开(公告)号：WO2010104581A2
公开(公告)日：2010-09-16
申请号：PCT/US2010/000731
申请日：2010-03-11
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , CLARK, Michael, C. , UMANSKY, Benjamin, S. , NYE, Elizabeth, A. , REICHENSPERGER, Mark, J. , LEWIS, William, C.
发明人： CLARK, Michael, C. , UMANSKY, Benjamin, S. , NYE, Elizabeth, A. , REICHENSPERGER, Mark, J. , LEWIS, William, C.
IPC分类号： C10G35/06
CPC分类号： C10G35/065 , B01J29/7038 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G2300/1092 , C10G2300/1096 , C10G2300/301 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , Y02P20/52 , C07C15/085
摘要： A process for the alkylation of a benzene-containing refinery stream such as reformate with light refinery olefins which is capable of achieving high benzene conversion levels operates in a fixed bed of an MWW zeolite catalyst, preferably MCM- 22, in single pass mode in the liquid phase at a relatively low to moderate temperatures with pressure maintained at a value adequate to ensure subcritical operation. High levels of benzene conversion with conversions of at least 90% and higher, e.g. 92% or 95% or even higher are achievable. A high octane product is produced, comprising mono-, di- and tri-alkylbenzenes with lesser levels of the tetra-substituted products. By operating with staged olefin injection, the end point of the alkylation product can be maintained at a low value while, at the same time, achieving high levels of benzene and olefin conversion.
摘要翻译：使用能够实现高苯转化水平的轻炼油烯烃的含苯精炼料流如重整油的烷基化方法在MWW沸石催化剂（优选MCM-22）的固定床中以单程模式在液相在相对低至中等温度下，压力保持在足以确保亚临界操作的值。高转化率的苯转化率至少为90％以上，例如。可达到92％或95％甚至更高。产生高辛烷值的产物，其包含具有较少含量的四取代产物的单烷基苯，二烷基苯和三烷基苯。通过使用分段烯烃注入操作，烷基化产物的终点可以保持在低值，同时实现高水平的苯和烯烃转化。

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