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31. 发明申请

WO2008042037A1 PROPYLENE COPOLYMERS FOR ADHESIVE APPLICATIONS 审中-公开
标题翻译：用于粘合剂应用的丙烯共聚物
公开(公告)号：WO2008042037A1
公开(公告)日：2008-04-10
申请号：PCT/US2007/017174
申请日：2007-08-01
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , BRANT, Patrick , HENNING, David, Aaron , JOHNSRUD, David, R. , SIMS, Charles, L.
发明人： JIANG, Peijun , BRANT, Patrick , HENNING, David, Aaron , JOHNSRUD, David, R. , SIMS, Charles, L.
IPC分类号： C08L23/14 , C09J123/14 , C08F10/06
CPC分类号： C08F210/06 , C08F10/06 , C08L23/142 , C08L2666/06 , C09J123/142 , C08F2/001 , C08F210/14 , C08F2500/17 , C08F2500/09 , C08F2500/20 , C08F2500/11 , C08F2500/21
摘要： Disclosed herein is an in-reactor produced multi-component copolymer comprises a semi- crystalline component having a crystallinity of 20% or more, and an amorphous component having a crystallinity of 5% or less. The copolymer comprises at least 80 wt% of units derived from propylene and from about 1 to about 20 wt% of units derived from at least one C 6 to C 12 alpha-olefin. The copolymer has a viscosity at 19O°C of at least 530 mPa sec and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer exhibits a good balance of adhesive properties and mechanical strength.
摘要翻译：本文公开了一种反应器内生产的多组分共聚物，其包含结晶度为20％以上的半结晶组分和结晶度为5％以下的无定形组分。共聚物包含至少80重量％的衍生自丙烯的单元和约1至约20重量％的衍生自至少一个C 6至C 12 - 烯烃。共聚物在190℃下的粘度至少为530mPa·s，熔融热在约10至约70J / g之间。含有共聚物的粘合剂显示良好的粘合性能和机械强度的平衡。

32. 发明申请

WO2006025949A3 POLYMER PRODUCTION AT SUPERCRITICAL CONDITIONS 审中-公开
公开(公告)号：WO2006025949A3
公开(公告)日：2006-03-09
申请号：PCT/US2005/024240
申请日：2005-07-08
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BRANT, Patrick , RIX, Francis, C. , KISS, Gabor , REYNOLDS, Robert, P.
发明人： BRANT, Patrick , RIX, Francis, C. , KISS, Gabor , REYNOLDS, Robert, P.
IPC分类号： G07F17/00
摘要： This invention relates to a process to polymerize olefins comprising contacting, in a polymerization system, olefins having three or more carbon atoms with a catalyst compound, activator, optionally comonomer, and optionally diluent or solvent, at a temperature above the cloud point temperature of the polymerization system and a pressure no lower than lOMPa below the cloud point pressure of the polymerization system, where the polymerization system comprises any comonomer present, any diluent or solvent present, the polymer product, where the olefins having three or more carbon atoms are present at 40 weight % or more, wherein the catalyst compound is a bridged metallocene based on indenyl groups.

33. 发明申请

WO2012134722A2 DIBLOCK COPOLYMERS PREPARED BY CROSS METATHESIS 审中-公开
标题翻译：由交叉METASESIS制备的二嵌段共聚物
公开(公告)号：WO2012134722A2
公开(公告)日：2012-10-04
申请号：PCT/US2012/027691
申请日：2012-03-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGADORN, John, R. , RUFF, Charles, J. , GANESH, Renuka, N. , BRANT, Patrick
发明人： HAGADORN, John, R. , RUFF, Charles, J. , GANESH, Renuka, N. , BRANT, Patrick
IPC分类号： C08F10/00 , C08F297/08 , C08F4/64 , C08L23/02 , C08L53/00
CPC分类号： C08G61/08 , C08F297/083 , C08G61/04 , C08G2261/418 , C08L53/00 , C08L65/00
摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-C(R 11 )(R 12 )-C(R 13 )=C(R 14 )-C(R 15 )(R 16 )-PO*, or isomers thereof, wherein R 11 , R 12 , R 13 , R 14 , R 15 , and R 16 , are each independently a substituted or unsubstituted C 1 through C 4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C 20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13 C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio "Z" = 0.1 to 10 where Z is the Mn (as determined by 13 C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1 H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.
摘要翻译：本发明涉及一种组合物，其包含由下式表示的多嵌段聚烯烃：PO-C（R11）（R12）-C（R13）= C（R14）-C（R15）（R16）-PO * 其中R11，R12，R13，R14，R15和R16各自独立地为取代或未取代的C1至C4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9至4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13 C NMR所示的内部不饱和度在约128至约132ppm之间的峰; 2）Mn比“Z”= 0.1〜10，其中Z为Mn（通过13 C NMR测定）除以Mn（根据使用聚苯乙烯标准品的凝胶渗透色谱法测定）; 和3）任选地，通过1 H NMR光谱确定的每1000个碳的0.3（J）和0.75（J）内部不饱和度，其中J是成为PO和PO的乙烯基封端的聚烯烃的混合物的每1000个碳的反应性数 *，在它们通过烯烃复分解催化剂偶合之前。

34. 发明申请

WO2012134715A2 BRANCHED VINYL TERMINATED POLYMERS AND METHODS FOR PRODUCTION THEREOF 审中-公开
标题翻译：分支乙烯终止聚合物及其生产方法
公开(公告)号：WO2012134715A2
公开(公告)日：2012-10-04
申请号：PCT/US2012/027675
申请日：2012-03-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , BRANT, Patrick
发明人： JIANG, Peijun , BRANT, Patrick
IPC分类号： C08F10/06 , C08F4/16 , C07F17/00 , C07F7/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F10/06 , C08F210/06 , C08F210/16 , C08F2500/09 , C08F2500/20 , C08F210/08 , C08F110/06 , C08F4/65927
摘要： This invention relates to a process for polymerization, comprising (i) contacting, at a temperature greater than 35°C, one or more monomers comprising ethylene and/or propylene, with a catalyst system comprising a metallocene catalyst compound and an activator, (ii) converting at least 50 mol% of the monomer to polyolefin; and (iii) obtaining a branched polyolefin having greater than 50% allyl chain ends, relative to total unsaturated chain ends. The invention also relates to the branched polyolefins and functionalized branched polyolefins.
摘要翻译：本发明涉及聚合方法，其包括（i）在大于35℃的温度下使一种或多种包含乙烯和/或丙烯的单体与包含茂金属催化剂化合物和活化剂的催化剂体系接触（ii））将至少50摩尔％的单体转化成聚烯烃; 和（iii）获得相对于总不饱和链末端具有大于50％烯丙基链端的支链聚烯烃。本发明还涉及支链聚烯烃和官能化支化聚烯烃。

35. 发明申请

WO2010147802A3 MICROPOROUS MEMBRANES, METHODS FOR MAKING THESE MEMBRANES, AND THE USE OF THESE MEMBRANES AS BATTERY SEPARATOR FILMS 审中-公开
公开(公告)号：WO2010147802A3
公开(公告)日：2010-12-23
申请号：PCT/US2010/037769
申请日：2010-06-08
申请人： TORAY TONEN SPECIALTY SEPARATOR GODO KAISHA , ISHIHARA, Takeshi , MIYAOKA, Satoshi , KONO, Koichi , BRANT, Patrick , EXXONMOBIL CHEMICAL PATENTS INC.
发明人： ISHIHARA, Takeshi , MIYAOKA, Satoshi , KONO, Koichi , BRANT, Patrick
IPC分类号： B01D69/00 , B01D67/00 , B01D71/00 , H01M2/16
摘要： The invention relates to microporous membranes having high meltdown temperature, high air permeability, and high puncture strength. The invention also relates to the production of such membranes and the use of such membranes as battery separator film.

36. 发明申请

WO2008109212A1 POLYMER PRODUCTION UNDER SUPERSOLUTION CONDITIONS 审中-公开
标题翻译：聚合物生产在超声条件下
公开(公告)号：WO2008109212A1
公开(公告)日：2008-09-12
申请号：PCT/US2008/052749
申请日：2008-02-01
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , EXXONMOBIL RESEARCH & ENGINEERING COMPANY , BRANT, Patrick , KISS, Gabor , FRIEDERSDORF, Chris, B. , LATTNER, James, R. , CASTY, Gary, L.
发明人： BRANT, Patrick , KISS, Gabor , FRIEDERSDORF, Chris, B. , LATTNER, James, R. , CASTY, Gary, L.
IPC分类号： C08F10/06 , C08F2/06 , C08F4/659
CPC分类号： C08F10/06 , C08F110/06 , C08F210/06 , C08F4/64144 , C08F2/06 , C08F2500/03 , C08F2500/20 , C08F210/08 , C08F210/16
摘要： This invention relates to a process to polymerize olefins comprising contacting propylene, at a temperature of 65° C to 150° C and a pressure of 1.72 to 34.5 MPa, with: 1) a catalyst system comprising one or more activators and one or more nonmetallocene metal-centered, heteroaryl ligand catalyst compounds, where the metal is chosen from the Group 4, 5, 6, the lanthanide series, or the actinide series of the Periodic Table of the Elements, 2) optionally one or more comonomers selected from ethylene and C4 to C 12 olefins, 3) diluent or solvent, and 4) optionally scavenger, wherein: a) the olefin monomers and any comonomers are present in the polymerization system at 30 wt% or more, b) the propylene is present in the feed at 80 wt% or more, c) the polymerization occurs at a temperature above the so lid- fluid phase transition temperature of the polymerization system and a pressure greater than 1 MPa below the cloud point pressure of the polymerization system, and d) the polymerization occurs: (1) at a temperature below the critical temperature of the polymerization system, or (preferably and) (2) at a pressure below the critical pressure of the polymerization system.
摘要翻译：本发明涉及聚合烯烃的方法，包括在65℃至150℃的温度和1.72至34.5MPa的压力下使丙烯接触，其中：1）包含一种或多种活化剂和一种或多种非茂金属的催化剂体系金属中心的杂芳基配体催化剂化合物，其中金属选自第4,5,6族，镧系元素或元素周期表的锕系，2）任选地一种或多种选自乙烯和 C4至C12烯烃，3）稀释剂或溶剂，和4）任选的清除剂，其中：a）烯烃单体和任何共聚单体在聚合体系中以30重量％或更多存在，b）丙烯存在于进料在80重量％以上的情况下，c）聚合发生在高于聚合体系的盖 - 流体相转变温度的温度和低于聚合体系的浊点压力1MPa以上的压力下，d）聚合发生：（1）在低于聚合体系的临界温度的温度下，或（优选和）（2）在低于聚合体系的临界压力的压力下。

37. 发明申请

WO2007061525A1 SYNDIOTACTIC PROPYLENE ELASTOMERS 审中-公开
标题翻译： SYNDIOTACTIC丙烯弹性体
公开(公告)号：WO2007061525A1
公开(公告)日：2007-05-31
申请号：PCT/US2006/040077
申请日：2006-10-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BRANT, Patrick
发明人： BRANT, Patrick
IPC分类号： C08F10/00
CPC分类号： C08F110/06 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F2500/17 , C08F2500/11 , C08F2500/20 , C08F2500/15
摘要： Disclosed herein is an elastomeric composition comprising propylene, the composition further comprising a peak melting point temperature below about 110°C, a tensile set of 40% or less, and greater than or equal to about 60% [r] dyads, based on the total number of dyads present in the composition. A process to produce an elastomeric composition is also disclosed.
摘要翻译：本文公开了包含丙烯的弹性体组合物，所述组合物还包含峰值熔点温度低于约110℃，拉伸组合为40％或更小，以及大于或等于约60％组合物中存在的二聚体总数。还公开了一种生产弹性体组合物的方法。

38. 发明申请

WO2005105941A1 BLEND FUNCTIONALIZED POLYOLEFIN ADHESIVE 审中-公开
标题翻译：混合功能性聚烯烃胶粘剂
公开(公告)号：WO2005105941A1
公开(公告)日：2005-11-10
申请号：PCT/US2005/012597
申请日：2005-04-13
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , SIMS, Charles, L. , BRANT, Patrick , JIANG, Peijun , ABHARI, Ramin
发明人： SIMS, Charles, L. , BRANT, Patrick , JIANG, Peijun , ABHARI, Ramin
IPC分类号： C09J123/10
CPC分类号： C08F255/00 , C08F8/00 , C08F255/02 , C08F2800/20 , C08L51/06 , C08L2205/02 , C08L2666/02 , C08L2666/04 , C08L2666/06 , C09J123/10 , C09J151/06 , C08F210/06
摘要： Disclosed herein is an adhesive composition comprising a blend functionalized with a functional group, wherein the blend comprises a C3 to C40 olefin polymer and an additive, the C3 to C40 olefin polymer comprising at least 50 mol% of one or more C3 to C40 olefins, and where the C3 to C40 olefin polymer has: a Dot T-Peel of 1 Newton or more on Kraft paper; an Mw of 10,000 to 100,000; and a branching index (g’) of 0.98 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 60,000, or a branching index (g’) of 0.95 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 100,000. A process of producing the adhesive composition, as well as methods of utilizing the adhesive composition are also disclosed.
摘要翻译：本文公开了一种粘合剂组合物，其包含用官能团官能化的共混物，其中所述共混物包含C 3至C 40烯烃聚合物和添加剂，所述C 3至C 40烯烃聚合物包含至少50摩尔％的一种或多种C 3至C 40烯烃，并且其中C 3至C 40烯烃聚合物具有：在牛皮纸上具有1牛顿或更多的点T-Peel; 10,000至100,000的Mw; 当聚合物的Mw为10,000〜60,000，或在聚合物的Mz下测定的支化指数（g'）为0.95以下时，在聚合物的Mz下测定的支化指数（g'）为0.98以下，聚合物的Mw为10,000至100,000。还公开了制备粘合剂组合物的方法以及利用粘合剂组合物的方法。

39. 发明申请

WO2010147799A3 MULTI-LAYER MICROPOROUS FILM 审中-公开
公开(公告)号：WO2010147799A3
公开(公告)日：2010-12-23
申请号：PCT/US2010/037758
申请日：2010-06-08
申请人： TORAY TONEN SPECIALTY SEPARATOR GODO KAISHA , ISHIHARA, Takeshi , MIYAOKA, Satoshi , KONO, Koichi , BRANT, Patrick , EXXONMOBIL CHEMICAL PATENTS INC.
发明人： ISHIHARA, Takeshi , MIYAOKA, Satoshi , KONO, Koichi , BRANT, Patrick
IPC分类号： B32B27/08 , B32B5/18 , C08J5/18 , H01M2/14
摘要： Embodiments of the invention relate to microporous membranes that include first and second layers. The first layer includes ≤ 20.0 wt.% polymethylpentene and the second layer includes a compatibilizer. The invention also relates to methods for making such membranes and the use of such membranes as battery separator film.

40. 发明申请

WO2008079565A8 POLYMER PRODUCTION AT SUPERCRITICAL CONDITIONS 审中-公开
公开(公告)号：WO2008079565A8
公开(公告)日：2008-07-03
申请号：PCT/US2007/085348
申请日：2007-11-21
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , CASTY, Gary, L. , COOK, Raymond, A. , KISS, Gabor , BRANT, Patrick
发明人： CASTY, Gary, L. , COOK, Raymond, A. , KISS, Gabor , BRANT, Patrick
IPC分类号： C08F10/06 , C08F2/06 , C08F4/62
摘要： This invention relates to a process to polymerize olefins comprising contacting, at a temperature of 600C or more and a pressure of at least 15 MPa, one or more olefin monomers having three or more carbon atoms, with: 1) a catalyst system comprising one or more activators and one or more nonmetallocene metal-centered, heteroaryl ligand catalyst compounds, where the metal is chosen from the Group 4, 5, 6, the lanthanide series, or the actinide series of the Periodic Table of the Elements, 2) optionally one or more comonomers, 3) optionally diluent or solvent, and 40 optionally solvent, wherein: a) the olefin monomers and any comonomers are present in the polymerization system at 40 weight % or more, b) the monomer having three or more carbon atoms is present at 80 wt% or more based upon the weight of all monomers and comonomers present in the feed, c) the polymerization occurs at a temperature above the solid- fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, in the event the solid-fluid phase transition temperature of the polymerization system cannot be determined then the polymerization occurs at a temperature above the fluid fluid phase transition temperature.

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