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    • 31. 发明申请
    • CURABLE SILICONE RUBBER COMPOSITION
    • 可固化硅橡胶组合物
    • WO2010087525A1
    • 2010-08-05
    • PCT/JP2010/051663
    • 2010-01-29
    • DOW CORNING TORAY CO., LTD.YOSHIDA, HiroakiISHIGAMI, NozomiHASEGAWA, ChiichiroYOSHITAKE, Makoto
    • YOSHIDA, HiroakiISHIGAMI, NozomiHASEGAWA, ChiichiroYOSHITAKE, Makoto
    • C08L83/04C09D183/04
    • C08L83/04C08G77/12C08G77/20C09D183/04Y10T428/31663C08L83/00
    • A curable silicone rubber composition characteristically comprising (A) an alkenyl-containing organopolysiloxane comprising (A-1) a dialkylpolysiloxane that has an average of at least two alkenyl groups in each molecule and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO?4/2#191 unit, Rソ1??2#191Rソ2?SiO?1/2#191 unit, and Rソ1??3#191SiO?1/2#191 unit wherein Rソ1? is C1-10 alkyl and Rソ2? is alkenyl and that contains the alkenyl group in the range from more than 2.5 mass% to not more than 5.0 mass%; (B) an organopolysiloxane that contains the silicon-bonded hydrogen atom; and (C) a hydrosilylation reaction catalyst in a catalytic quantity and provides a cured silicone material that has a hardness is not more than 75 and the elongation is at least 35%. Also, a composite in which the cured silicone material provided by the thermosetting of the curable silicone rubber composition is integrated into a single article with a substrate.
    • 一种可固化的硅橡胶组合物,其特征在于包含(A)含有烯基的有机聚硅氧烷,其包含(A-1)在每个分子中平均具有至少两个烯基的二烷基聚硅氧烷和(A-2)含烯基的树脂形式 包含SiO 4/2#191单元的有机聚硅氧烷,R 1 1 2 2#191R 2 2 SiO 1/2#191单元和R 1 1〜3#191SiO 1/2#191单元,其中 R'1? 是C 1-10烷基和R 2 是烯基并且含有在大于2.5质量%至不大于5.0质量%范围内的烯基; (B)含有硅键合氢原子的有机聚硅氧烷; 和(C)催化剂的氢化硅烷化反应催化剂,并提供硬度不大于75且伸长率至少为35%的固化的硅氧烷材料。 另外,其中通过可固化硅橡胶组合物的热固化提供的固化的硅氧烷材料与基材整合成单个制品的复合材料。
    • 32. 发明申请
    • CURABLE SILICONE COMPOSITION
    • 可固化硅胶组合物
    • WO2009017251A1
    • 2009-02-05
    • PCT/JP2008/064080
    • 2008-07-30
    • DOW CORNING TORAY CO., LTD.HASEGAWA, ChiichiroYOSHITAKE, MakotoAKITOMO, Hiroshi
    • HASEGAWA, ChiichiroYOSHITAKE, MakotoAKITOMO, Hiroshi
    • C08L83/04C09D183/04C08L83/05C08L83/07C09D183/05C09D183/07
    • C08L83/04C08G77/12C08G77/20C09D183/04C08L83/00
    • A curable silicone composition comprising: an alkenyl-containing organopolysiloxane (A) that contains: a dialkylpolysiloxane (A-1) having on average at least 2 alkenyl groups in one molecule having a 25°C viscosity in the range of 5,000 to 35,000 mPa.s, and a alkenyl-containing organopolysiloxane resin (A-2) consisting of SiO 4/2 units, R 1 2 R 2 SiO 1/2 units, and R 1 3 SiO 1/2 units (where R 1 designates alkyl groups with 1 to 10 carbon atoms, and R 2 designates alkenyl groups) with the content of alkenyl groups ranging from 3.5 to 5.0 mass %, and with the ratio of the sum of the mole numbers of the R 1 2 R 2 SiO 1/2 units and R 1 3 SiO 1/2 units to 1 mole of the SiO 4/2 units in the range from 0.5 to 1.4; an organopolysiloxane (B), wherein silicon-bonded hydrogen atoms are in an amount of at least 0.7 mass %; and a hydrosilylation catalyst (C). The composition is capable of forming a flex-resistant highly transparent cured silicone product with non-tacky surface.
    • 一种可固化的有机硅组合物,其包含:含有烯基的有机聚硅氧烷(A),其含有:在一分子中平均具有至少2个烯基的二烷基聚硅氧烷(A-1),其粘度在5,000至35,000mPa的范围内。 和由SiO 4/2单元组成的含链烯基的有机聚硅氧烷树脂(A-2),R1 2R2SiO1 / 2单元和R1 3SiO1 / 2单元(其中R1表示具有1-10个碳原子的烷基,R2表示 链烯基的含量范围为3.5〜5.0质量%,R1R2SiO1 / 2单元和R1 3SiO1 / 2单元的摩尔数与1摩尔SiO 4/2单元的摩尔比之和 在0.5至1.4的范围内; 有机聚硅氧烷(B),其中与硅键合的氢原子的量为至少0.7质量%; 和氢化硅烷化催化剂(C)。 该组合物能够形成具有非粘性表面的耐挠曲高透明固化硅氧烷产品。
    • 35. 发明申请
    • REACTIVE SILICONE COMPOSITION, REACTIVE THERMOPLASTIC ARTICLE, CURED PRODUCT, AND OPTICAL SEMICONDUCTOR DEVICE
    • 反应性硅酮组合物,反应性热塑性制品,固化产品和光学半导体器件
    • WO2014002918A1
    • 2014-01-03
    • PCT/JP2013/067163
    • 2013-06-18
    • DOW CORNING TORAY CO., LTD.
    • YAMAZAKI, RyosukeYAMAZAKI, HarunaYOSHITAKE, Makoto
    • C08L83/04C08K3/22C08K3/36H01L33/56
    • C08K7/18C08G77/12C08G77/20C08G77/80C08K3/22C08K3/36C08K7/14C08K2003/2241C08L83/04H01L33/486H01L33/60H01L2924/0002H01L2933/0033H01L2924/00
    • The present invention relates to a reactive silicone composition comprising: (A) an alkenyl group-containing organopolysiloxane represented by the average unit formula; (B) an alkenyl group-containing organopolysiloxane represented by the general formula; (C) a silicon atom-bonded hydrogen atom-containing organopolysiloxane represented by the general formula; (D) a hydrosilylation reaction catalyst; (E) a white pigment; and (F) non-spherical silica, spherical silica or glass fibers, a reactive thermoplastic article obtained by the composition to reaction under specified conditions, a cured product obtained by heating the article, and an optical semiconductor device having the cured product. The reactive silicone composition is a solid at an ordinary temperature and gives a reactive thermoplastic article that is fluidized at elevated temperatures. The reactive thermoplastic article is once fluidized upon heating and then gives a cured product. The cured product exhibits little reduction in mechanical strength or discoloration caused by heat or light and has high light reflectance. And the optical semiconductor device exhibits high luminous efficiency and causes little thermal degradation or photodegradation of a light reflection material.
    • 本发明涉及一种反应性硅氧烷组合物,其包含:(A)由平均单元式表示的含烯基的有机聚硅氧烷; (B)由通式表示的含烯基的有机聚硅氧烷; (C)由通式表示的与硅原子键合的含氢原子的有机聚硅氧烷; (D)氢化硅烷化反应催化剂; (E)白色颜料; 和(F)非球形二氧化硅,球形二氧化硅或玻璃纤维,通过组合物在特定条件下反应获得的反应性热塑性制品,通过加热制品获得的固化产物和具有固化产物的光学半导体装置。 反应性硅氧烷组合物在常温下为固体,得到在升高的温度下流化的活性热塑性制品。 反应性热塑性制品在加热后一度流化,然后得到固化产物。 固化产物的机械强度或由热或光引起的变色几乎不降低并且具有高的光反射率。 并且光学半导体器件表现出高的发光效率,并且导致光反射材料的热降解或光降解很少。
    • 40. 发明申请
    • CURABLE SILICONE COMPOSITION THAT PROVIDES A HIGHLY TRANSPARENT CURED SILICONE MATERIAL
    • 提供高度透明的固化硅材料的可固化硅胶组合物
    • WO2010087523A1
    • 2010-08-05
    • PCT/JP2010/051661
    • 2010-01-29
    • DOW CORNING TORAY CO., LTD.HASEGAWA, ChiichiroYOSHITAKE, MakotoAKITOMO, Hiroshi
    • HASEGAWA, ChiichiroYOSHITAKE, MakotoAKITOMO, Hiroshi
    • C08L83/04C09D183/04
    • C08L83/04C08G77/12C08G77/20C09D183/04C08L83/00C08K5/56
    • A curable silicone composition characteristically comprises (A) (A-1) a dialkylpolysiloxane that has at least two alkenyl groups in each molecule and a viscosity of at least 1,000 mPa•s to not more than 50,000 mPa•s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO 4/2 unit, R 1 R 2 SiO 1/2 unit, and R 1 3 SiO 1/2 unit wherein R 1 is alkyl and R 2 is alkenyl and that contains the alkenyl group in the range from at least 0.5 mass% to less than 3.5 mass%; (B) an organopolysiloxane that has at least three silicon-bonded hydrogen atoms; and (C) a hydrosilylation reaction catalyst and provides a highly transparent cured silicone material that characteristically has a hardness is in the range from at least 30 to not more than 80, the parallel light transmittance at 25 °C is at least 90%, and the parallel light transmittance at 200 °C is a value that is at least 99% of the parallel light transmittance at 25 °C.
    • 可固化的有机硅组合物特征在于包含(A)(A-1)在每个分子中具有至少两个烯基的二烷基聚硅氧烷和至少1,000mPa·s至50,000mPa·s以下的粘度和(A-2) 包含SiO 4/2单元,R1R2SiO1 / 2单元和R1 3SiO1 / 2单元的含烯基的树脂形式的有机聚硅氧烷,其中R1是烷基,R2是链烯基并且含有至少0.5质量% %至小于3.5质量%; (B)具有至少三个与硅键合的氢原子的有机聚硅氧烷; 和(C)氢化硅烷化反应催化剂,并且提供特征在于硬度在至少30至不大于80的范围内的高度透明的固化的硅氧烷材料,25℃下的平行透光率为至少90%,以及 在200℃下的平行透光率是在25℃下的平行光透射率的至少99%的值。