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31. 发明申请

US20110313213A1 PURIFICATION OF ALCOHOLS PRIOR TO THEIR USE IN THE PRESENCE OF AN ACID CATALYST 有权
标题翻译：在酸性催化剂存在下使用醇类物质的纯化
公开(公告)号：US20110313213A1
公开(公告)日：2011-12-22
申请号：US13131407
申请日：2009-11-27
申请人： Delphine Minoux , Walter Vermeiren , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Delphine Minoux , Walter Vermeiren , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C29/74
CPC分类号： C07C29/76 , C07C1/24 , C07C29/74 , C07C29/90 , C07C11/04 , C07C31/08
摘要： Process for the purification of an alcohol in the course of a process comprising: (1) providing a reaction zone (C) comprising an acid type catalyst; (2) providing a reaction zone (B) comprising an acid adsorbent material; (3) providing an alcohol stream comprising impurities; (4) introducing the alcohol stream of (3) into the reaction zone (B) and bringing said stream into contact with the acid adsorbent material at conditions effective to reduce the amount of impurities having an adverse effect on the acid type catalyst of the reaction zone (C); (5) recovering from step (4) an alcohol stream and introducing it into the reaction zone (C); (6) optionally introducing one or more reactants (R) into the reaction zone (C); (7) operating said reaction zone (C) at conditions effective to recover a valuable effluent.
摘要翻译：在包括以下步骤的过程中醇的纯化方法：（1）提供包含酸型催化剂的反应区（C）; （2）提供包含酸吸附材料的反应区（B）; （3）提供包含杂质的醇流; （4）将（3）的醇流引入反应区（B）中，并使所述物流与酸吸附剂材料接触，有效地减少对反应的酸型催化剂具有不利影响的杂质的量区（C）; （5）从步骤（4）中回收醇流并将其引入反应区（C）中; （6）任选地将一种或多种反应物（R）引入反应区（C）中; （7）在有效回收有价值流出物的条件下操作所述反应区（C）。

32. 发明申请

US20110124934A1 Process for Making Crystalline Metallosilicates 审中-公开
标题翻译：制备结晶金属硅酸盐的方法
公开(公告)号：US20110124934A1
公开(公告)日：2011-05-26
申请号：US12994570
申请日：2009-02-24
申请人： Metin Bulut , Pierre Jacobs , Delphine Minoux , Nikolai Nesterenko , Jean-Pierre Dath , Sander Van Donk
发明人： Metin Bulut , Pierre Jacobs , Delphine Minoux , Nikolai Nesterenko , Jean-Pierre Dath , Sander Van Donk
IPC分类号： C07C2/00 , C01B39/38
CPC分类号： C01B37/005 , B01J29/40 , B01J29/42 , B01J29/48 , C01B39/02 , C01B39/38 , C01P2002/72
摘要： The present invention provides a method for preparing a metallosilicate of MFI type, wherein organic templates, seeding techniques, using low aliphatic alcohols miscible with water or homogeneous starting solutions are not required.The present invention relates to a process for making a crystalline metallosilicate with high Si/Metal ratio comprising:a) providing an aqueous medium comprising OH− anions and a metal source, b) providing an aqueous medium comprising an inorganic water insoluble source of silicon, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to crystallize the desired metallosilicate, e) recovering the desired metallosilicate, wherein in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is
摘要翻译：本发明提供了一种制备MFI型金属硅酸盐的方法，其中不需要使用与水混合的低脂肪醇或均相起始溶液的有机模板，接种技术。本发明涉及一种制备具有高Si /金属比的结晶金属硅酸盐的方法，其包括：a）提供包含OH-阴离子和金属源的水性介质，b）提供包含无机水不溶性硅源的水性介质， c）任选地提供包含任选的二氧化硅有机源的非水液体培养基，d）在有效使结晶期望的金属硅酸盐的条件下混合培养基a），b）和任选的c），e）回收所需的金属硅酸盐，其中混合物a）+ b）+ c），在结晶之前，Si org / Si无机物的比例<0.3，有利地<0.2，优选为0，OH- / SiO 2的摩尔比为至少0.3，有利地为0.3至0.62，优选为0.31〜0.61，更优选为0.32〜0.61，非常优选为0.33〜0.6，基本上不存在模板。在另一个实施方案中，在回收所需的金属硅酸盐之前，插入步骤e），f）和g）步骤：e）将反应混合物a）+ b）+ c）冷却至约室温，f）将反应混合物的pH降低至少0.1，优选0.3至4，更优选0.5至3，g）使所得到的步骤f）的混合物在有效继续所需金属硅酸盐结晶的条件下进行。

33. 发明申请

US20100076240A1 Production of Olefins 审中-公开
标题翻译：烯烃的生产
公开(公告)号：US20100076240A1
公开(公告)日：2010-03-25
申请号：US12374811
申请日：2007-07-13
申请人： Jean-Pierre Dath , Walter Vermeiren
发明人： Jean-Pierre Dath , Walter Vermeiren
IPC分类号： C07C4/06
CPC分类号： C10G11/05 , C10G2300/1037 , C10G2300/4018 , C10G2400/20
摘要： A process for converting a hydrocarbon feedstock to provide an effluent containing light olefins, the process comprising passing a hydrocarbon feedstock, the feedstock containing at least 25 wt % C5+ paraffins, through a reactor containing a crystalline silicate catalyst to produce an effluent including propylene.
摘要翻译：一种用于转化烃原料以提供含有轻质烯烃的流出物的方法，该方法包括使含烃原料（含有至少25wt％的C 5+链烷烃的原料）通过含有结晶硅酸盐催化剂的反应器，以产生包含丙烯的流出物。

34. 发明授权

US07375257B2 Process for cracking an olefin-rich hydrocarbon feedstock 失效
标题翻译：裂化烯烃富烃原料的方法
公开(公告)号：US07375257B2
公开(公告)日：2008-05-20
申请号：US10398603
申请日：2001-10-03
申请人： Jean-Pierre Dath , Walter Vermeiren
发明人： Jean-Pierre Dath , Walter Vermeiren
IPC分类号： C07C4/02 , C10G11/02
CPC分类号： C10G11/16 , C10G2400/20
摘要： A process for cracking an olefin containing hydrocarbon feedstock which is selective towards light olefins in the effluent, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a moving bed reactor containing a crystalline silicate catalyst selected from an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ration of from 150 to 800 which has been subjected to a steaming step, at an inlet temperature of from 500 to 600° C., at an olefin partial pressure of from 0.1 to 2 bars and the feedstock being passed over the catalyst at an LHSV of from 5 to 30 h−1 to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, intermittently removing a first fraction of the catalyst from the moving bed reactor, regenerating the first fraction of the catalyst in a regenerator and intermittently feeding into the moving bed reactor a second fraction of the catalyst which has been regenerated in the regenerator, the catalyst regeneration rate being controlled whereby the propylene purity is maintained constant at a value corresponding to the average value observed in a fixed bed reactor using the same feedstock, catalyst and cracking conditions, for example at least 94 wt. %.
摘要翻译：一种用于裂解对流出物中的轻质烯烃具有选择性的含烯烃的原料的方法，该方法包括使含有一种或多种烯烃的烃原料通过含有结晶硅酸盐催化剂的移动床反应器，该结晶硅酸盐催化剂选自MFI型结晶硅酸盐，入口温度为500-600℃的硅/铝原子比至少为180的硅/铝原子比为150〜800的MEL型结晶硅酸盐，其进行了蒸汽工序。，烯烃分压为0.1至2巴，原料以5至30小时-1的LHSV通过催化剂以产生具有较低分子量的烯烃含量的流出物比原料间歇地从移动床反应器中除去催化剂的第一部分，在再生器中再生催化剂的第一馏分并间歇地进料在移动床反应器中，在再生器中再生的催化剂的第二部分，控制催化剂再生速率，由此丙烯纯度保持恒定在与使用相同原料的固定床反应器中观察到的平均值的值，催化剂和裂化条件，例如至少94wt。％。

35. 发明申请

US20070114155A1 Hydrotreating and/or hydrocracking catalyst of hydrocarbons and preparation thereof 有权
标题翻译：烃的加氢处理和/或加氢裂化催化剂及其制备
公开(公告)号：US20070114155A1
公开(公告)日：2007-05-24
申请号：US10567564
申请日：2004-08-04
申请人： Thierry Cholley , Jean-Pierre Dath
发明人： Thierry Cholley , Jean-Pierre Dath
IPC分类号： C10G65/00
CPC分类号： B01J31/0254 , B01J23/85 , B01J23/88 , B01J23/882 , B01J37/0203 , B01J37/0236 , B01J37/20 , C10G45/08 , C10G47/12 , C10G2300/70
摘要： The invention relates to a hydroconversion catalyst, which comprises a refractory oxide support, at least one metal selected from group VIII and at least one metal selected from group VIB and which is characterized in that it has at least one organic compound containing at least one oxime group of formula (I)>C═NOR1, in which R1 is selected among hydrogen and alkyl, allyl, aryl, alkylene or cycloaliphatic groups, and combinations thereof, these groups being able to be substituted by at least one electron donor group.
摘要翻译：本发明涉及一种加氢转化催化剂，其包含难熔氧化物载体，至少一种选自VIII族的金属和至少一种选自VIB族的金属，其特征在于其具有至少一种含有至少一个肟的有机化合物式（I）的基团C-NOR 1其中R 1选自氢和烷基，烯丙基，芳基，亚烷基或脂环族基团及其组合，其中R 1，这些基团能够被至少一个电子给体基团取代。

36. 发明申请

US20050222342A1 Polymer hydrogenation process 失效
标题翻译：聚合物加氢工艺
公开(公告)号：US20050222342A1
公开(公告)日：2005-10-06
申请号：US10484484
申请日：2002-07-16
申请人： Jean-Pierre Dath , Walter Vermeiren
发明人： Jean-Pierre Dath , Walter Vermeiren
IPC分类号： C08C19/02 , C08F8/04 , C08F36/00
CPC分类号： C08C19/02 , C08F8/04
摘要： A process for hydrogenating unsaturations in polymers, the process comprising contacting at least one polymer having unsaturations with a catalyst comprising at least one Group Ia, Ib, IIb, VIb, VIIb or VIII metal on a support of an alkaline earth metal silicate having a surface area of at least 30 m2/g at a temperature of from 50 to 250° C. and a pressure of from 5 to 150 bar.
摘要翻译：一种用于氢化聚合物中的不饱和度的方法，该方法包括使具有不饱和度的至少一种聚合物与包含至少一种Ia，Ib，IIb，VIb，VIIb或VIII族金属的催化剂接触在具有表面的碱土金属硅酸盐的载体上在50至250℃的温度和5至150巴的压力下至少30m 2 / g的面积。

37. 发明授权

US06448198B1 Acid catalyst with a sulfated zirconia base and its uses 失效
标题翻译：具有硫酸化氧化锆基体的酸催化剂及其用途
公开(公告)号：US06448198B1
公开(公告)日：2002-09-10
申请号：US09613585
申请日：2000-07-10
申请人： Georges Szabo , Pedro Nascimento , Alain Milan , Sebastien Decker , Joeri Denayer , Jean-Pierre Dath
发明人： Georges Szabo , Pedro Nascimento , Alain Milan , Sebastien Decker , Joeri Denayer , Jean-Pierre Dath
IPC分类号： B01J27053
CPC分类号： B01J21/066 , B01J27/053 , B01J37/0009
摘要： The invention relates to an acid catalyst containing a substantial quantity of supported or mass sulfated zirconia and at least one hydrogenating transition metal. This catalyst is characterized by the fact that the sulfated zirconia is in crystallized form and that it shows a specific surface area greater than or equal to 135 m2/g, a pore volume greater than or equal to 0.16 cm3/g and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m). The invention also relates to methods of making this catalyst and to the uses of this catalyst in hydrocarbon transformation chemical reactions requiring the use of an acid type catalyst, such as for example, isomerization, alkylation, oligomerization reactions or even light hydrocarbon dehydration reactions, and also heavier hydrocarbon hydrocracking and hydroisomerization reactions. In a preferred embodiment of the method of the present invention, a hydrated zirconia gel is washed with a soluble polar organic solvent (other than water). In accordance with the method including this washing step, a solid acid catalyst containing pure mass sulfated zirconia in a crystallized form has a surface area greater than or equal to 150 m2/g, a pore volume greater than or equal to 0.2 cm3/g, and more preferably greater than or equal to 0.25 cm3/g, and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m) and preferably greater than or equal to 30 Angstroms (30×10−10 m).
摘要翻译：本发明涉及含有大量负载或大量硫酸化氧化锆和至少一种氢化过渡金属的酸催化剂。该催化剂的特征在于硫酸化氧化锆是结晶形式，并且其表现出大于或等于135m 2 / g的比表面积，大于或等于0.16cm 3 / g的孔体积和平均孔径大于或等于20埃（20x10-10米）。本发明还涉及制备该催化剂的方法以及该催化剂在需要使用酸型催化剂的烃转化化学反应中的用途，例如异构化，烷基化，低聚反应或甚至轻质烃脱水反应，以及还有较重的烃加氢裂化和加氢异构化反应。在本发明方法的优选实施方案中，用可溶性极性有机溶剂（水除外）洗涤水合氧化锆凝胶。根据包括该洗涤步骤的方法，含有结晶形式的纯质量硫酸化氧化锆的固体酸催化剂具有大于或等于150m 2 / g的表面积，大于或等于0.2cm 3 / g的孔体积，更优选大于或等于0.25cm 3 / g，平均孔径大于或等于20埃（20×10 -10 m），优选大于或等于30埃（30×10 -10 m）。

38. 发明授权

US06388161B1 Production of olefins 失效
标题翻译：生产烯烃
公开(公告)号：US06388161B1
公开(公告)日：2002-05-14
申请号：US09594282
申请日：2000-06-15
申请人： Jean-Pierre Dath , Walter Vermeiren
发明人： Jean-Pierre Dath , Walter Vermeiren
IPC分类号： C10G4702
CPC分类号： C10G11/00 , C10G2400/20 , C10G2400/22
摘要： A process for cracking an olefin-rich hydrocarbon feedstock which is selective towards propylene in the effluent, the process comprising contacting a hydrocarbon feedstock containing one or more olefinic components of C4 or greater with a crystalline silicate catalyst to produce an effluent having a second composition of one or more olefinic components of C3 or greater, the feedstock and the effluent having substantially the same olefin content by weight therein characterized in that ethylene is added to the feedstock before the feedstock contacts the catalyst.
摘要翻译：一种用于裂解在流出物中对丙烯有选择性的富烯烃的原料的方法，该方法包括将含有一种或多种C4或更多烯烃组分的烃原料与结晶硅酸盐催化剂接触以产生具有第二组成的流出物 C3或更高的一种或多种烯烃组分，所述原料和流出物具有基本上相同的烯烃含量，其特征在于在原料接触催化剂之前将乙烯加入到原料中。

39. 发明授权

US06294500B1 Production of polyethylene having a bimodal molecular weight distribution 失效
标题翻译：生产具有双峰分子量分布的聚乙烯
公开(公告)号：US06294500B1
公开(公告)日：2001-09-25
申请号：US09432187
申请日：1999-11-02
申请人： Guy Debras , Jean-Pierre Dath
发明人： Guy Debras , Jean-Pierre Dath
IPC分类号： B01J2326
CPC分类号： C08F10/02 , C08F210/16 , Y02P20/52 , C08F4/24 , C08F4/025 , C08F210/14 , C08F2500/12 , C08F2500/05 , C08F2500/07
摘要： A process for producing high density polyethylene, the process comprising polymerising ethylene, or copolymerising ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms, in the presence of a catalyst system comprising first and second chromium-based catalysts, the first chromium-based catalyst having been reduced and reoxidised and the second chromium-based catalysts having been activated, fluoridised before or during the activation step, and reduced, the first and second chromium-based catalysts having a pore volume difference of at least 0.8 cc/g. There is further provided a catalyst system for the production of high density polyethylene by polymerising ethylene or copolymerising ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms, the catalyst system comprising first and second chromium-based catalysts, the first chromium-based catalyst having been reduced and reoxidised and the second chromium-based catalyst been activated, fluoridised before or after the activation step, and reduced, and the first and second chromium-based catalysts having a pore volume difference of at least 0.8 cc/g. There is further provided the use of the catalyst system for increasing the biomodality of the molecular weight distribution of a high density polyethylene.
摘要翻译：一种生产高密度聚乙烯的方法，该方法包括在包含第一和第二铬基催化剂的催化剂体系存在下聚合乙烯或共聚乙烯和含有3-10个碳原子的α-烯烃共聚单体，第一种铬的催化剂已经被还原和再氧化，并且第二铬基催化剂已经在活化步骤之前或期间被活化，氟化，并且还原了具有至少0.8cc / g的孔体积差的第一和第二种铬基催化剂。还提供了一种用于通过聚合乙烯或共聚乙烯和包含3至10个碳原子的α-烯烃共聚单体生产高密度聚乙烯的催化剂体系，所述催化剂体系包含第一和第二铬基催化剂，第一铬 - 已经还原和再氧化并且第二铬基催化剂在活化步骤之前或之后被活化，氟化，还原，并且第一和第二铬基催化剂的孔体积差异至少为0.8cc / g。还提供了催化剂体系用于增加高密度聚乙烯的分子量分布的生物学性质的用途。

40. 发明授权

US10464053B2 Method for making a catalyst comprising a phosphorous modified zeolite and use of said zeolite 有权
公开(公告)号：US10464053B2
公开(公告)日：2019-11-05
申请号：US14236750
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
IPC分类号： B01J29/06 , B01J29/85 , B01J29/40 , B01J37/02 , B01J29/70 , B01J29/65 , B01J37/10 , B01J37/28 , C07C1/20 , C07C1/24 , C07C2/66 , C07C2/86 , C07C4/06 , C10G29/20 , C10G29/22 , C10G3/00 , B01J37/00 , C07C1/22 , C07C2/08
摘要： A method to make a phosphorus modified zeolite can include providing a zeolite having at least one ten member ring, making an ion-exchange, steaming the zeolite, and introducing phosphorus on the zeolite. The zeolite can be mixed with one or more binders and shaping additives, and then shaped. A metal can be introduced, and the catalyst can be washed, calcined, and steamed in an equilibration step. The steaming can be at performed at a steam severity (X) of at least about 2. The steaming can be performed at a temperature above 625° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatics by alcohols with olefins and/or alcohols.

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