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    • 33. 发明公开
    • A CARBON PRECURSOR COMPOSITION
    • CARBONVORLÄUFERZUSAMMENSETZUNG
    • EP2861653A1
    • 2015-04-22
    • EP13726956.9
    • 2013-05-17
    • Dow Global Technologies LLC
    • LAKROUT, HamedMARKS, Maurice, J.VALETTE, Ludovic
    • C08J3/00C04B35/524C04B35/83C08L63/00
    • C04B35/524C04B35/83C04B2235/48C08G59/40C08G59/68C08G59/687C08J3/00
    • A liquid carbon precursor composition including (a) at least one aromatic epoxy resin; and (b)(i) at least one aromatic co-reactive curing agent or (b)(ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; wherein the liquid composition prior to adding optional components and curing, has a neat viscosity of less than 10,000 mPa-s, at 25 °C; and wherein the liquid precursor composition has a neat viscosity of less than 10,000 mPa-s at 25 °C prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid precursor composition being cured has a carbon yield of at least 35 weight percent as measured in the absence of optional components; a cured liquid carbon precursor composition; a carbonized material made from the above liquid carbon precursor composition; and processes for producing the above compositions.
    • 一种液体碳前体组合物,其包含(a)至少一种芳族环氧树脂; 和(b)(i)至少一种芳族共反应性固化剂或(b)(ii)至少一种催化固化剂,或(b)(iii)其混合物; 其中所述液体组合物在加入任选组分和固化之前,在25℃下具有小于10,000mPa·s的纯粘度; 并且其中所述液体前体组合物在25℃下具有小于10,000mPa·s的洁净粘度,然后在加入任选的组分之前,在固化之前和在碳化之前; 并且其中固化的液体前体组合物具有至少35重量%的碳收率,在不存在任选组分的情况下测量; 固化液体碳前体组合物; 由上述液体碳前体组合物制成的碳化材料; 以及制备上述组合物的方法。
    • 34. 发明公开
    • VITREOUS CARBON COMPOSITION
    • GLASKOHLENSTOFFZUSAMMENSETZUNG
    • EP2861532A1
    • 2015-04-22
    • EP13726955.1
    • 2013-05-17
    • Dow Global Technologies LLC
    • LAKROUT, HamedMARKS, Maurice, J.VALETTE, Ludovic
    • C01B31/02C04B35/524
    • C01B31/02C01B32/05C04B35/524C04B35/6269C04B35/63452C04B2235/602C04B2235/6022C04B2235/6025C04B2235/6027C04B2235/6562C04B2235/658C04B2235/662C08G59/687
    • A process for preparing a vitreous carbon including the steps of: (I) providing a curable low viscosity liquid carbon precursor formulation comprising (a) at least one aromatic epoxy resin; and (b)(i) at least one aromatic co-reactive curing agent, (b)(ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; wherein the liquid precursor composition has a neat viscosity of less than 10,000 mPa-s at 25 °C prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid precursor composition being cured has a carbon yield of at least 35 weight percent as measured in the absence of optional components; (II) curing the liquid formulation from step (I) to form a cured product wherein the cured product has a carbon yield of at least 35 weight percent as measured in the absence of optional components; (III) carbonizing the cured product from step (II) to form a carbonized composition; and (IV) purifying the carbonized product from step (III) to form a vitreous carbon composition; and a vitreous carbon prepared by the above process.
    • 一种制备玻璃碳的方法,包括以下步骤:(I)提供可固化的低粘度液体碳前体制剂,其包含(a)至少一种芳族环氧树脂; 和(b)(i)至少一种芳族共反应性固化剂,(b)(ii)至少一种催化固化剂,或(b)(iii)它们的混合物; 其中所述液体前体组合物在25℃下具有小于10,000mPa·s的净粘度,然后在固化之前和在碳化之前添加任选组分。 并且其中固化的液体前体组合物具有至少35重量%的碳收率,在不存在任选组分的情况下测量; (II)固化来自步骤(I)的液体制剂以形成固化产物,其中固化产物的碳收率为至少35重量%,在不存在任选组分的情况下测量; (III)将来自步骤(II)的固化产物碳化以形成碳化组合物; 和(IV)从步骤(III)中纯化碳化产物以形成玻璃碳组合物; 和通过上述方法制备的玻璃碳。
    • 38. 发明公开
    • A CONDUCTIVE CARBONIZED LAYERED ARTICLE
    • LEITFÄHIGERKARBONISIERTER SCHICHTARTIKEL
    • EP2861652A1
    • 2015-04-22
    • EP13726954.4
    • 2013-05-17
    • Dow Global Technologies LLC
    • LAKROUT, HamedMARKS, Maurice, J.VALETTE, Ludovic
    • C08J3/00C04B35/524C04B35/83C08L63/00
    • C09D5/24B82Y10/00C03C17/22C03C2217/28C04B35/524C04B35/6269C04B35/63452C04B2235/9653C08J3/00C08L63/00H01B1/04H01B1/24H01L51/0045H01L51/442Y10T428/265
    • A process for preparing a conductive carbonized layered article including the steps of: (I) providing a liquid carbon precursor formulation comprising (a) at least one aromatic epoxy resin; and (b)(i) at least one aromatic co-reactive curing agent, (b) (ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; wherein the liquid precursor composition has a neat viscosity of less than 10,000 mPa-s at 25° C. prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid precursor composition being cured has a carbon yield of at least 35 weight percent disregarding the weight of the substrate and any optional components present in the composition; (II) applying the liquid formulation of step (I) as a thin coating layer onto at least a portion of the surface of a substrate; (III) curing the liquid formulation of step (II) to form a cured product, wherein the cured product has a carbon yield of at least 35 weight percent disregarding the weight of the substrate and any optional components present in the composition; and (IV) carbonizing the cured product of step (III) to form a conductive carbonized layered article; and a conductive carbonized layered article such as a carbon optical transparent electrode (COTE) prepared by the above process.
    • 一种制备导电碳化层状制品的方法,包括以下步骤:(I)提供液体碳前体制剂,其包含(a)至少一种芳族环氧树脂; 和(b)(i)至少一种芳族共反应性固化剂,(b)(ii)至少一种催化固化剂,或(b)(iii)它们的混合物; 其中所述液体前体组合物在25℃下具有小于10,000mPa·s的纯粘度,在加入任选组分之前,在固化之前和在碳化之前; 并且其中固化的液体前体组合物具有至少35重量%的碳收率,而不考虑基材的重量和组合物中存在的任何任选组分; (II)将作为薄涂层的步骤(I)的液体制剂施用到基材表面的至少一部分上; (III)固化步骤(II)的液体制剂以形成固化产物,其中固化产物具有至少35重量%的碳收率,而不考虑基质的重量和组合物中存在的任何任选组分; 和(IV)将步骤(III)的固化产物碳化以形成导电性碳化层压制品; 以及通过上述方法制备的碳光透明电极(COTE)等导电性炭化层叠体。