会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 31. 发明申请
    • PROCESS FOR OBTAINING 2-HYDROXY-4-METHYL THIOBUTYRIC ACID (MHA), MHA AND ITS USE
    • 一种获得2-羟基-4-甲硫基丁(MHA),MHA及其用途
    • WO1996001809A1
    • 1996-01-25
    • PCT/EP1995002515
    • 1995-06-28
    • DEGUSSA AKTIENGESELLSCHAFTHASSEBERG, Hans-AlbrechtHUTHMACHER, KlausTANNER, HerbertHÄFNER, VolkerHEINZEL, Harald
    • DEGUSSA AKTIENGESELLSCHAFT
    • C07C319/28
    • C07C319/28A23K20/105C07C319/20Y10S426/807C07C323/60
    • It is known to isolate MHA from a reaction mixture obtained by the addition of hydrocyanic acid (HCN) to methyl mercaptopropionic aldehyde (MMP) and the hydrolysis of the methyl mercapto propionic aldehyde cyanohydrine (MMP-CH) obtained thereby with sulphuric acid, in which the reaction mixture is brought into contact with a substantially non-water-miscible organic solvent, in order to form an extraction solution having the solvent and MHA transferred from the reaction mixture, and the MHA is obtained as an extract from this extraction solution by concentration. The simplest and most economical process of the invention concerning the processing of the reaction product which facilitates the production of a highly concentrated product with an extremely low dimer, oligomer and by-product content, is characterised in that the concentration is conducted in such a way that the remaining extract contains less than 4 wt % and preferably less than 2 wt % of water. Animal feed supplement, mixtures for supplementing animal feed, e.g. with methionine or ammonium-MHA.
    • 已知的是,从反应混合物中,这是通过加入氢氰酸(HCN)与甲硫基丙醛(MMP)和由此得到的甲硫基丙醛氰醇(MMP-CH)用硫酸水解而获得的,其特征在于,具有基本上在反应混合物中分离MHA 水不混溶的有机溶剂被带入在液/液萃取体系接触以形成提取液,其包括溶剂,从反应混合物中定罪MHA,并且MHA回收作为通过蒸发从该提取溶液的提取物。 的关于后处理,将反应产物作为本发明,其允许生产高度浓缩的产物,二聚体,低聚物的含量极低和副产物,其特征在于,所述蒸发,是使余下的提取物是小于4的简单和廉价的方法的 重量%的水,优选小于2重量%的水具有。 动物饲料补充物,用于Tierfuttermittelsupplementierung混合物,例如 蛋氨酸或铵MHA。
    • 32. 发明申请
    • PROCESS FOR PRODUCING AMMONIUM-2-HYDROXY-4-(METHYLTHIO)-BUTYRATE, MIXTURES CONTAINING THE SAME IN LIQUID FORM AND THEIR USE
    • 用于生产铵2-羟基-4-(甲硫基)丁酸酯和含氟化合物为液体形式,及其用途
    • WO1996001808A1
    • 1996-01-25
    • PCT/EP1995002600
    • 1995-07-05
    • DEGUSSA AKTIENGESELLSCHAFTSUCHSLAND, HelmutKOHL, Heinz
    • DEGUSSA AKTIENGESELLSCHAFT
    • C07C319/20
    • C07C319/28A23K20/105C07C319/20Y10S426/807C07C323/60
    • Process for producing ammonium-2-hydroxy-4-(methylthio)-butyrate, mixtures containing the same in liquid form and their use. Processes are known for producing ammonium-2-hydroxy-4-methylthio-n-butyrate (MHHAS) by treating 2-hydroxy-4-methylthio-butyric acid (MHA) with ammonia or by isolating MHA, which also contains dimers and higher oligomers, from a reaction mixture obtained by adding hydrogen cyanide (HCN) to methylmercaptopropionic aldehyde (MMP) and by hydrolysing in mineral acid conditions the thus obtained methylmercaptopropionic aldehyde cyanhydrine (MMP-CH). In order to produce ammonium-2-hydroxy-4-methylthio-n-butyrate and mixtures containing the same with a remarkable fluidity and a very low oligomer proportion by a process based on exclusively "liquid" steps, the reaction mixture is treated with a water-immiscible or partially water-miscible inert solvent, until a first organic extract and a first aqueous raffinate are obtained, and the first organic extract is decomposed into a second organic extract and a second aqueous raffinate by treating it with ammonia and phase separation. Re-extraction of MHA as MHAAS is carried out in the second aqueous raffinate, causing salt formation, and MHAAS is isolated from the second aqueous raffinate. This compound is useful as feedstuff supplement and as methionine substitute.
    • 过程由处理2-羟基-4-甲硫基 - 丁酸(MHA)与氨,和方法已知用于铵2-羟基-4-甲硫基正丁酸(MHAAS)的制备,其中MHA,二聚体 和高级低聚物的步骤包括,从(MMP)通过加入氢氰酸(HCN)的甲硫基丙醛,以得到的反应混合物,得到由此获得的甲硫基丙醛氰醇(MMP-CH)的无机酸水解分离。 因为根据本发明的不或仅部分混溶的溶剂,反应混合物被处理以获得一个第一有机萃取液,并用一种​​惰性的水的第一水提余,在第二有机萃取所述第一有机萃取液和相分离下的第二通过用氨处理 水性萃余液被分割,所述盐的形成,MHA的反萃取发生作为MHAAS到第二水提余,以及从所述第二水提余的MHAAS是隔离的,所以能够在一个仅基于“液体”的方法步骤过程中,铵-2-羟基 -4-甲硫基 - 正丁酸盐和包含具有优异的流动性和非常低的低聚物含量提供的混合物。 动物饲料添加剂,蛋氨酸替代品。
    • 38. 发明申请
    • ACTIVATORS FOR PEROXO COMPOUNDS AND AGENTS CONTAINING THEM
    • 活化剂的过氧化合物和试剂含
    • WO1996030482A1
    • 1996-10-03
    • PCT/EP1996000599
    • 1996-02-13
    • DEGUSSA AKTIENGESELLSCHAFT
    • DEGUSSA AKTIENGESELLSCHAFTDEL GROSSO, MichaelDORFER, AstridOFFERMANNS, Heribert
    • C11D03/39
    • C11D3/3907C11D3/391
    • The invention relates to novel highly effective activators based on phenolic and enolic O-acyl compounds for peroxo compounds, activator compositions and washing, bleaching, cleaning and disinfecting agents containing these activators. The activator effect of phenolic O-alkanoyl compounds is greatly reduced if the chain of the alkanoyl group contains more than 9 to 10 C atoms. The phenolic and enolic activators of the invention contain the undecenoyl radical or an alkadienoyl group with 5 to 17 C atoms as the O-acyl group. The activator 4-undec-10-enoyl oxybenzole sulphonic acid or a water-soluble salt thereof is substantially more effective than the corresponding activator with an undecanoyl group. Activator mixtures of an activator of the invention and one based on an O-acyl or N-acyl compound exhibit synergistic effectiveness.
    • 本发明涉及新的高效活化剂酚醛烯醇和过氧化合物的O-酰基化合物,含有它们的活化剂的洗涤剂,漂白剂,清洁剂和消毒剂组合物的基础上。 活化剂作用的酚类O形Alkanoylverbindungen急剧减小为含有超过9至10个碳原子的链烷酰基的链长。 该新型酚醛烯醇和活化剂存在O形酰基Undecenoylrest或碳原子数5〜17 Alkadienoylgruppe。 活化剂4-十一碳-10-烯酰基oxybenzolsulfonsäure或其水溶性盐是相当比具有Undecanoylgruppe相应活化剂更有效。 根据本发明和基于一个O-酰基或N-酰基化合物表现出了协同作用的活化剂活化剂的Aktivatormischungen。