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    • 32. 发明授权
    • Homogeneous polymer blend and articles therefrom
    • 均相聚合物共混物及其制品
    • US07619038B2
    • 2009-11-17
    • US11299022
    • 2005-12-09
    • Aspy K. MehtaChia ChengSudhin DattaWen LiChon Y. LinSrivatsan S. Iyer
    • Aspy K. MehtaChia ChengSudhin DattaWen LiChon Y. LinSrivatsan S. Iyer
    • C08L23/10C08L23/14
    • C08L23/10C08L23/142C08L2205/02C08L2205/025C08L2314/06C08L2666/06
    • This invention relates to homogeneous blends of: 1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight % alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170° C. and a melt flow rate of 200 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having: a) 10 to 50 percent crystallinity or less; b) a melt flow rate of 200 dg/min or less; c) a DSC melting point (second melt Tm) of 130° C. or less; d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt % comonomer content with a difference of no greater than 20 wt % relative to the average wt % comonomer content of the copolymer; e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, for use in films, fibers, non-wovens, molded articles and the like.
    • 本发明涉及以下均质共混物:1)60至99重量%的一种或多种半结晶聚合物(基于半结晶和半无定形聚合物的重量),每种半结晶聚合物包含丙烯和 0至5重量%的α-烯烃共聚单体(基于聚合物的重量),所述半结晶聚合物各自具有100-170℃的熔点和200dg / min以下的熔体流动速率; 和2)1至40重量%的一种或多种半无定形聚合物(基于半结晶和半无定形聚合物的重量),每种包含丙烯的半无定形聚合物和5至12重量%的一种 或更多的C 2和C 4至C 10α-烯烃共聚单体,所述半无定形聚合物各自具有:a)10至50%的结晶度或更低; b)200dg / min或更低的熔体流动速率; c)130℃或更低的DSC熔点(第二熔体Tm); d)通过在己烷中的热分馏测定的分子间组成分布,使得85重量%或更多的聚合物作为一个或两个相邻的可溶性级分分离,在紧邻的前面或后续级分中余量的聚合物分离; 并且其中这些级分中的每一种都具有相对于共聚物的平均重量%共聚单体含量的不大于20重量%的重量%共聚单体含量; e)Mw / Mn为1.5至4,f)通过13 C NMR测量的三个丙烯单元的三单元组立构规整度为75%或更大,用于膜,纤维,无纺布,模制品等。