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31. 发明授权

US06750309B1 Methacrylated polyurethane copolymers with silicone segments containing alkoxysilyl groups 失效
标题翻译：具有含有烷氧基甲硅烷基的硅氧烷链段的甲基丙烯酸聚氨酯共聚物
公开(公告)号：US06750309B1
公开(公告)日：2004-06-15
申请号：US10150628
申请日：2002-05-17
申请人： Hsien-Kun Chu , Steven T. Nakos
发明人： Hsien-Kun Chu , Steven T. Nakos
IPC分类号： C08G77458
CPC分类号： C08J3/243 , C08G18/10 , C08G18/672 , C08G77/458 , C09J175/16 , C08G18/289 , C08G18/61
摘要： The present invention relates to the preparation of a new class of materials, namely, an acrylate terminated or end-capped urethane/urea copolymer containing silicone soft segments capable of dual cure via unsaturated groups and dialkoxyl silanol groups. This new class of material is a reaction product of a partially methacrylated end-capped urethane polymer containing hard segment blocks and an amino alkylene dialkoxy end-capped siloxane block polymer, containing soft-segments. The aminoalkylene dialkoxysilane end-capped siloxane segment of this copolymer can include siloxane diol segments of various molecular weights (e.g., 1,000 to 20,000) end-capped with various alkylaminoalkylene trimethoxy silanes. This copolymer is therefore capable of dual cure via these functional groups.
摘要翻译：本发明涉及新类材料的制备，即含有可通过不饱和基团和二烷氧基硅烷醇基团双重固化的硅氧烷软链段的丙烯酸酯封端或封端的氨基甲酸酯/尿素共聚物。这种新型材料是含有硬链段和部分甲基丙烯酸酯封端的聚氨酯聚合物与含有软链段的氨基亚烷基二烷氧基封端硅氧烷嵌段聚合物的反应产物。该共聚物的氨基亚烷基二烷氧基硅烷封端的硅氧烷链段可以包括用各种烷基氨基亚烷基三甲氧基硅烷封端的各种分子量（例如1,000至20,000）的硅氧烷二醇链段。因此，该共聚物能够通过这些官能团双重固化。

32. 发明授权

US5853520A Preapplied silicone threadlocker and sealant 失效
标题翻译：预涂硅胶螺纹锁和密封剂
公开(公告)号：US5853520A
公开(公告)日：1998-12-29
申请号：US788724
申请日：1997-01-23
申请人： Richard D. Rich , Eerik Maandi , Paula M. Gontarz , Hsien-Kun Chu
发明人： Richard D. Rich , Eerik Maandi , Paula M. Gontarz , Hsien-Kun Chu
IPC分类号： C08K9/10 , C09J4/00 , C09J4/02 , C09J5/00 , C09J183/06 , C09J183/07 , F16B39/00
CPC分类号： C09J4/00 , C08K9/10 , C09J183/06
摘要： A curable composition, having utility for threadlocking engageable members of a threaded mechanical fastener, comprising: a reactive silicone (meth)acrylate emulsified in an aqueous medium, optionally further comprising a polymerizable non-silicone (meth)acrylate monomer or oligomer; and a microencapsulated peroxy initiator which is initiatingly effective for cure of the reactive silicone (meth)acrylate. The curable composition may be usefully employed for adhesively bonding engageable structural parts, by applying the aqueous emulsion of the reactive silicone (meth)acrylate, containing a microencapsulated peroxy initiator, to at least a portion of an engagement surface of a matable part which is matably engageable with a complimentary engagement structure, to yield an emulsion-coated engagement surface, drying the emulsion-coated engagement surface to form a dried coating thereon; and thereafter engaging the surface having the dried coating thereon, with the complimentary engagement structure, to release the microencapsulated peroxy initiator and bond the matable part and complimentary engagement structure.
摘要翻译：一种可固化组合物，其用于螺纹机械紧固件的可接合构件的螺纹锁定，包括：在水性介质中乳化的反应性硅氧烷（甲基）丙烯酸酯，任选地还包含可聚合的非硅氧烷（甲基）丙烯酸酯单体或低聚物; 和对于反应性硅氧烷（甲基）丙烯酸酯的固化起始有效的微胶囊化过氧化引发剂。可固化组合物可用于粘合可接合的结构部件，通过将含有微胶囊化过氧化物引发剂的反应性硅氧烷（甲基）丙烯酸酯的水性乳液施用于可配合的可配配部分的接合表面的至少一部分可接合互补的接合结构，以产生乳液涂覆的接合表面，干燥乳液涂覆的接合表面以在其上形成干燥的涂层; 然后将其上具有干燥涂层的表面与互补的接合结构接合，以释放微胶囊化的过氧化物引发剂并结合可配合部分和互补的接合结构。

33. 发明授权

US06451870B1 Dual curing silicone compositions 有权
标题翻译：双重固化硅酮组合物
公开(公告)号：US06451870B1
公开(公告)日：2002-09-17
申请号：US09719172
申请日：2000-12-14
申请人： Alfred A. DeCato , Hsien-Kun Chu
发明人： Alfred A. DeCato , Hsien-Kun Chu
IPC分类号： C08G7720
CPC分类号： C08J3/243 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/28 , C08J2383/04 , C08L83/04 , C08L83/06 , C09D183/04 , C09D183/06 , C08L83/00 , C08L2666/28
摘要： The present invention relates to dual curing silicone compositions which are capable of cross-linking when subjected to ultraviolet (“UV”) or visible (“VIS”) light and/or by a moisture condensation method. When cured, these compositions have excellent adhesion to a variety of substrates. These are particularly useful in potting and coating applications.
摘要翻译：本发明涉及当经受紫外线（“UV”）或可见光（“VIS”）光和/或通过湿气凝结法时能够交联的双重固化硅氧烷组合物。固化时，这些组合物对各种基材具有优异的粘合性。这些在灌封和涂布应用中特别有用。

34. 发明授权

US4962076A Silicone sealants having reduced color 失效
标题翻译：有机硅密封胶颜色降低
公开(公告)号：US4962076A
公开(公告)日：1990-10-09
申请号：US418074
申请日：1989-10-06
申请人： Hsien-Kun Chu , Russell P. Kamis , Jerome M. Klosowski , Loren D. Lower
发明人： Hsien-Kun Chu , Russell P. Kamis , Jerome M. Klosowski , Loren D. Lower
IPC分类号： C08K5/37 , C08K5/54 , C09K3/10
CPC分类号： C09K3/1018 , C08K5/37 , C08K5/5406
摘要： A chelated titanium catalyst can be improved by the addition of an additive selected from the group consisting of organomercaptan of the formula RSH, where R is a hydrocarbon radical containing from 3 to 12 carbon atoms, and mercapto containing silane of the formula HSR'SiX.sub.3, where R' is a divalent hydrocarbon having from 1 to 8 carbon atoms and X is alkoxy radical having 1 to 6 carbon atoms. The improved composition has a reduced tendency to develop color upon storage. The improved composition is particularly useful in a silicone composition comprising a hydroxyl endblocked polydiorganosiloxane and an alkoxysilane or mixture of alkoxysilanes, or in a silicone composition comprising an alkoxy endblocked polydiorganosiloxane.
摘要翻译：通过添加选自式RSH的有机巯基，其中R是含有3至12个碳原子的烃基，以及式HSR'SiX 3的巯基硅烷，可以改善螯合钛催化剂，其中R'是具有1至8个碳原子的二价烃，X是具有1至6个碳原子的烷氧基。改进的组合物在储存时具有降低发色的倾向。改进的组合物在包含羟基封端的聚二有机硅氧烷和烷氧基硅烷或烷氧基硅烷的混合物的有机硅组合物中或在包含烷氧基封端的聚二有机硅氧烷的有机硅组合物中特别有用。

35. 发明授权

US07691959B1 Moisture curable silicone hot melt 失效
标题翻译：防潮硅胶热熔胶
公开(公告)号：US07691959B1
公开(公告)日：2010-04-06
申请号：US11926883
申请日：2007-10-29
申请人： Thomas Fay-Oy Lim , David Dworak , Jessica Fedorchick , Hsien-Kun Chu
发明人： Thomas Fay-Oy Lim , David Dworak , Jessica Fedorchick , Hsien-Kun Chu
IPC分类号： C08G77/04
CPC分类号： C09J183/14 , C08G18/3893 , C08G18/61 , C08G18/6523 , C08G18/755 , C08G2170/20 , C09J183/10
摘要： The present invention generally relates to a moisture curable composition in the form of a hot melt. The inventive compositions contain hydrolyzable silyl groups connected to a polymer which is capable of crosslinking when exposed to moisture.
摘要翻译：本发明一般涉及热熔胶形式的湿气固化组合物。本发明的组合物含有与聚合物连接的可水解的甲硅烷基，该聚合物当暴露于水分时能够交联。

36. 发明授权

US07368519B2 Fast moisture curing and UV-moisture dual curing compositions 有权
标题翻译：快速湿润固化和UV-水分双重固化组合物
公开(公告)号：US07368519B2
公开(公告)日：2008-05-06
申请号：US10524542
申请日：2003-10-15
申请人： Hsien-Kun Chu
发明人： Hsien-Kun Chu
IPC分类号： C08G77/20 , C08L83/04
CPC分类号： C08G77/38 , C08G77/12 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/24 , C08K5/541 , C08K5/5425 , C08K5/544 , C08L83/04 , C08L101/10 , C08L2666/44
摘要： The invention provides fast moisture and photo/moisture curing silicone compositions and methods for the preparation thereof. More particularly, the compositions provided are prepared from silanol and silane cappers; the cappers have an α-carbon bonded to the silicon atom allowing for a favorable hypervalent silicon transition state when reacting the silane and silanol. This favorable transition state enables both a fast endcapping reaction and contributes to the fast moisture curing properties of the inventive compositions.
摘要翻译：本发明提供了快速水分和光/湿固化硅氧烷组合物及其制备方法。更具体地，所提供的组合物由硅烷醇和硅烷封盖剂制备; 封盖具有与硅原子键合的α-碳，当使硅烷和硅烷醇反应时允许有利的超价硅过渡态。这种有利的过渡状态能够实现快速封端反应并有助于本发明组合物的快速湿固化性能。

37. 发明授权

US06828355B1 Resin-reinforced UV, moisture and UV/moisture dual curable silicone compositions 有权
标题翻译：树脂增强的UV，水分和UV /水分双固化硅酮组合物
公开(公告)号：US06828355B1
公开(公告)日：2004-12-07
申请号：US10031361
申请日：2002-01-18
申请人： Hsien-Kun Chu
发明人： Hsien-Kun Chu
IPC分类号： C08F248
CPC分类号： C08L83/06 , C08G77/14 , C08G77/18 , C08G77/20 , C08G77/70 , C08K5/0025 , C08L83/00 , C08L83/04 , C09D183/06 , C09J183/04 , C08L2666/28
摘要： This invention relates to resin-reinforced silicone compositions curable upon exposure to radiation in the electromagnetic spectrum, which compositions when cured demonstrate improved elastomeric properties, such as tensile strength, modulus and elongation. The inventive resin-reinforced silicone compositions may alternatively be rendered curable by exposure to moisture. In addition, the inventive composition may be rendered curable by exposure to radiation in the electromagnetic spectrum, and exposure to moisture. The inventive silicone compositions are particularly well suited for use in electronic conformal coating and potting applications, as well as in automotive gasketing applications, pressure sensitive adhesive applications and the like.
摘要翻译：本发明涉及在电磁光谱中暴露于辐射时可固化的树脂增强硅氧烷组合物，当固化时该组合物显示出改进的弹性体性质，例如拉伸强度，模量和伸长率。本发明的树脂增强硅酮组合物可以替代地通过暴露于水分而可固化。此外，本发明的组合物可以通过暴露于电磁光谱中的辐射并暴露于水分而变得可固化。本发明的有机硅组合物特别适用于电子保形涂布和灌封应用，以及汽车垫片应用，压敏粘合剂应用等。

38. 发明授权

US06391993B1 High temperature, controlled strength anaerobic compositions curable under ambient environmental conditions 有权
标题翻译：高温，可控强度的厌氧组合物可在环境条件下固化
公开(公告)号：US06391993B1
公开(公告)日：2002-05-21
申请号：US09446492
申请日：2000-02-01
申请人： Shabbir Attarwala , Gina M. Mazzella , Hsien-Kun Chu , Dzu D. Luong , Lester D. Bennington , Mark M. Konarski , Eerik Maandi , Richard D. Rich , Natalie R. Li , Frederick F. Newberth, III , Susan L. Levandoski
发明人： Shabbir Attarwala , Gina M. Mazzella , Hsien-Kun Chu , Dzu D. Luong , Lester D. Bennington , Mark M. Konarski , Eerik Maandi , Richard D. Rich , Natalie R. Li , Frederick F. Newberth, III , Susan L. Levandoski
IPC分类号： C08F2606
CPC分类号： C09J4/00 , C08F290/148 , C08G77/20 , C09J4/06 , C08F222/1006
摘要： The present invention provides anaerobic adhesive compositions, reaction products of which demonstrate controlled-strength at ambient temperature conditions and enhanced resistance to thermal degradation at elevated temperature conditions. The compositions are (meth)acrylate- and/or polyorganosiloxane-based and may include one or more of a variety of other components, such as certain coreactants, a maleimide component, a diluent component reactive at elevated temperature conditions, mono- or poly-hydroxyalkane components, and other components.
摘要翻译：本发明提供厌氧粘合剂组合物，其反应产物在环境温度条件下表现出控制强度，并且在升高的温度条件下具有增强的耐热降解性。组合物是（甲基）丙烯酸酯和/或聚有机硅氧烷，并且可以包括多种其它组分中的一种或多种，例如某些共反应物，马来酰亚胺组分，在高温条件下反应的稀释剂组分，单 - 或多 - 羟基烷烃组分和其他组分。

39. 发明授权

US4956435A Neutral cure silicone sealants 失效
标题翻译：中性固化硅酮密封胶
公开(公告)号：US4956435A
公开(公告)日：1990-09-11
申请号：US327209
申请日：1989-03-22
申请人： Hsien-Kun Chu , Russell P. Kamis , Jerome M. Klosowski , Loren D. Lower
发明人： Hsien-Kun Chu , Russell P. Kamis , Jerome M. Klosowski , Loren D. Lower
IPC分类号： C08K5/05 , C08K5/33 , C08K5/5465 , C08L83/04 , C08L83/07 , C09K3/10
CPC分类号： C09K3/1018 , C08K5/33 , C08K5/5465 , Y10S528/901
摘要： A faster curing neutral curing composition is obtained by the additive of an oxime compound to a composition comprising a trialkoxysilethylene endblocked polydiorganosiloxane, alkoxysilane crosslinker, and titanium catalyst.

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