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    • 31. 发明专利
    • Biphenyl-substituted spirocyclic ketoenols
    • ZA200903746B
    • 2010-08-25
    • ZA200903746
    • 2009-05-29
    • BAYER CROPSCIENCE AG
    • BRETSCHNEIDER THOMASFISCHER REINERPONTZEN ROLFARNOLD CHRISTIANGOERGENS ULRICHMALSAM OLGARECKMANN UDOSANWALD ERICHLEHR STEFANDITTGEN JANFEUCHT DIETERHILLS MARTINROSINGER CHRIS
    • A01N20060101C07C20060101C07D20060101
    • Biphenyl substituted spirocyclic ketoenol derivatives (I), are new. Biphenyl substituted spirocyclic ketoenol derivatives of formula (I), are new. X : halo, (halo)alkyl or (halo)alkoxy; Z : optionally substituted fluorophenyl; W 1>, Y 1>H, halo, (halo)alkyl or (halo)alkoxy; CKE : pyrrolone derivative of formula (a) or furone derivative of formula (b); CAB 1>optionally saturated cyclic compound (optionally substituted and containing at least a heteroatom); G : H, E or a group of formula (-CO-R 1>), (-C(=L)-M-R 2>), (-SO 2-R 3>), (-P(=L)(R 4>)(R 5>)) or (-C(=L)-N(R 6>)(R 7>)); E : metal ion or ammonium ion; L, M : O or S; R 1>alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl (all optionally substituted with halo), cycloalkyl (interrupted through at least a heteroatom and optionally substituted with halo, alkyl or alkoxy), phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl; R 2>alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl (all optionally substituted with halo), cycloalkyl, phenyl or benzyl (all optionally substituted); R 3>-R 5>alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio (all optionally substituted with halo) or phenyl, benzyl, phenoxy or phenylthio (all optionally substituted); and either R 6>, R 7>alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl (all optionally substituted with halo), phenyl or benzyl (both optionally substituted) or H; or NR 6>R 7>a ring optionally interrupted by O or S. Independent claims are included for: (1) the preparation of (I); (2) an agent comprising active substance combination of (I) and at least a compound, which improves the compatibility of culture plant, e.g. 4-dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane, 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-one, 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine, 5-chloro-quinolin-8-oxy-acetic acid-(1-methyl-hexylester), 3-(2-chloro-benzyl)-1-(1-methyl-1-phenyl-ethyl)-urea, 2,4-dichloro-phenoxy acetic acid, piperidin-1-thiocarboxylic acid-S-1-methyl-1-phenylethylester, 2,2-di-chloro-N-(2-oxo-2-(2-propenylamino)-ethyl)-N-(2-propenyl)-acetamide, 2,2-dichloro-N,N-di-2-propenyl-acetamide, 4,6-dichloro-2-phenyl-pyrimidine, 1-(2,4-dichloro-phenyl)-5-trichlormethyl-1H-1,2,4-triazol-3-carboxylic acid-ethylester, 2-chloro-4-trifluoromethyl-thiazol-5-carboxylic acid-phenylmethylester and 3-dichloroacetyl-5-(2-furanyl)-2, 2-dimethyl-oxazolidine; (3) a composition comprising (I) and at least one salt compound of formula ((R 26>)(R 28>)D +>(R 29>)(R 27>)) n (R 30>) n -> (III); (4) a preparation of parasite combating agents and/or herbicides, comprising mixing (I) with diluting agent and/or surface active agent; (5) a method for increasing the effect of pesticide and/or herbicides containing (I), using ready-made agent (syringe broth) and (III); (6) N-acylamino acid ester compound of formula (II); (7) carboxylic acid ester compound of formula (III); (8) phenyl acetic acid derivative of formula (XVI) or (XIX); (9) acylamino acid compound of formula (XVII); (10) an aminonitrile derivative of formula ((A)(B 1>)-C-((NH) 2)(CN)) (XX); (11) a substituted phenyl-nitrile compound of formula (XXI); and (12) phenylacetic acid ester compound of formula (XXIII). D : N or phosphor; R 26>-R 29>1-8C alkyl, 1-8C alkylene (both optionally substituted with halo, NO 2 or CN) or H; n : 1-4; and R 30>inorganic or organic ion. [Image] [Image] [Image] [Image] ACTIVITY : Herbicide; Antiparasitic; Plant Protectant; Insecticide; Acaricide. MECHANISM OF ACTION : None given.
    • 34. 发明专利
    • CETOENOLES ESPIROCICLICOS SUSTITUIDOS CON BIFENILO
    • CO6170404A2
    • 2010-06-18
    • CO09047994
    • 2009-05-12
    • BAYER CROPSCIENCE AG
    • BRETSCHNEIDER THOMASFISCHER REINERPONTZEN ROLFARNOLD CHRISTIANGORGENS ULRICHMALSAM OLGARECKMANN UDOSANWALD ERICHLEHR STEFANDITTGEN JANFEUCHT DIETERHILLS MARTINROSINGER CHRIS
    • A01N43/08A01N43/36C07D209/54C07D307/94C07D309/28C07D491/107
    • 1.- Compuestos de fórmula (I)en la que X representa halógeno, alquilo, alcoxi, halogenoalquilo o halogenoalcoxi, Z representa fluorofenilo dado el caso sustituido una o varias veces, W y Y representan, independientemente entre sí, hidrógeno, halógeno, alquilo, alcoxi, halogenoalquilo o halogenoalcoxi,CKE representa uno de los grupos en los que A y B, conjuntamente con el átomo de carbono al que están unidos, representan un ciclo saturado o insaturado, sin sustituir o sustituido que dado el caso contiene al menos un heteroátomo, G representa hidrógeno (a) o representa uno de los grupos en los que E representa un ión metálico o un ión amonio, L representa oxigeno o azufre, M representa oxigeno o azufre, R1 representa alquilo, alquenilo, alcoxialquilo, alquiltioalquilo, polialcoxialquilo respectivamente dado el caso sustituido con halógeno o cicloalquilo dado el caso sustituido con halógeno, alquilo o alcoxi, que puede estar interrumpido por al menos un heteroátomo, fenilo, fenilalquilo, hetarilo, fenoxialquilo o hetariloxialquilo respectivamente dado el caso sustituido, R2 representa respectivamente alquilo, alquenilo, alcoxialquilo, polialcoxialquilo dado el caso sustituido con halógeno o representa respectivamente cicloalquilo, fenilo o bencilo dado el caso sustituido, R3, R4 y R5 representan, independientemente entre sí, alquilo, alcoxi, alquilamino, dialquilamino, alquiltio, alqueniltio, cicloalquiltio respectivamente dado el caso sustituido con halógeno o representan fenilo, bencilo, fenoxi o feniltio respectivamente dado el caso sustituido y R6 y R7 representan, independientemente entre sí, hidrógeno, alquilo, cicloalquilo, alquenilo, alcoxi, alcoxialquilo respectivamente dado el caso sustituido con halógeno, representan fenilo dado el caso sustituido, representan bencilo dado el caso sustituido o representan, conjuntamente con el átomo de N al que están unidos, un anillo dado el caso interrumpido por oxígeno o azufre.
    • 40. 发明专利
    • Biphenyl-substituted spirocyclic ketoenols
    • AU2007327961A1
    • 2008-06-12
    • AU2007327961
    • 2007-11-22
    • BAYER CROPSCIENCE AG
    • RECKMANN UDOHILLS MARTINARNOLD CHRISTIANPONTZEN ROLFDITTGEN JANGORGENS ULRICHFEUCHT DIETERROSINGER CHRISLEHR STEFANSANWALD ERICHBRETSCHNEIDER THOMASMALSAM OLGAFISCHER REINER
    • C07D209/54A01N43/08A01N43/36A01N43/38C07C57/58C07C69/65C07C69/74C07D307/94C07D309/28C07D317/72C07D319/08C07D491/107C07D491/113C07D493/10C07D495/10
    • Biphenyl substituted spirocyclic ketoenol derivatives (I), are new. Biphenyl substituted spirocyclic ketoenol derivatives of formula (I), are new. X : halo, (halo)alkyl or (halo)alkoxy; Z : optionally substituted fluorophenyl; W 1>, Y 1>H, halo, (halo)alkyl or (halo)alkoxy; CKE : pyrrolone derivative of formula (a) or furone derivative of formula (b); CAB 1>optionally saturated cyclic compound (optionally substituted and containing at least a heteroatom); G : H, E or a group of formula (-CO-R 1>), (-C(=L)-M-R 2>), (-SO 2-R 3>), (-P(=L)(R 4>)(R 5>)) or (-C(=L)-N(R 6>)(R 7>)); E : metal ion or ammonium ion; L, M : O or S; R 1>alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl (all optionally substituted with halo), cycloalkyl (interrupted through at least a heteroatom and optionally substituted with halo, alkyl or alkoxy), phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl; R 2>alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl (all optionally substituted with halo), cycloalkyl, phenyl or benzyl (all optionally substituted); R 3>-R 5>alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio (all optionally substituted with halo) or phenyl, benzyl, phenoxy or phenylthio (all optionally substituted); and either R 6>, R 7>alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl (all optionally substituted with halo), phenyl or benzyl (both optionally substituted) or H; or NR 6>R 7>a ring optionally interrupted by O or S. Independent claims are included for: (1) the preparation of (I); (2) an agent comprising active substance combination of (I) and at least a compound, which improves the compatibility of culture plant, e.g. 4-dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane, 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-one, 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine, 5-chloro-quinolin-8-oxy-acetic acid-(1-methyl-hexylester), 3-(2-chloro-benzyl)-1-(1-methyl-1-phenyl-ethyl)-urea, 2,4-dichloro-phenoxy acetic acid, piperidin-1-thiocarboxylic acid-S-1-methyl-1-phenylethylester, 2,2-di-chloro-N-(2-oxo-2-(2-propenylamino)-ethyl)-N-(2-propenyl)-acetamide, 2,2-dichloro-N,N-di-2-propenyl-acetamide, 4,6-dichloro-2-phenyl-pyrimidine, 1-(2,4-dichloro-phenyl)-5-trichlormethyl-1H-1,2,4-triazol-3-carboxylic acid-ethylester, 2-chloro-4-trifluoromethyl-thiazol-5-carboxylic acid-phenylmethylester and 3-dichloroacetyl-5-(2-furanyl)-2, 2-dimethyl-oxazolidine; (3) a composition comprising (I) and at least one salt compound of formula ((R 26>)(R 28>)D +>(R 29>)(R 27>)) n (R 30>) n -> (III); (4) a preparation of parasite combating agents and/or herbicides, comprising mixing (I) with diluting agent and/or surface active agent; (5) a method for increasing the effect of pesticide and/or herbicides containing (I), using ready-made agent (syringe broth) and (III); (6) N-acylamino acid ester compound of formula (II); (7) carboxylic acid ester compound of formula (III); (8) phenyl acetic acid derivative of formula (XVI) or (XIX); (9) acylamino acid compound of formula (XVII); (10) an aminonitrile derivative of formula ((A)(B 1>)-C-((NH) 2)(CN)) (XX); (11) a substituted phenyl-nitrile compound of formula (XXI); and (12) phenylacetic acid ester compound of formula (XXIII). D : N or phosphor; R 26>-R 29>1-8C alkyl, 1-8C alkylene (both optionally substituted with halo, NO 2 or CN) or H; n : 1-4; and R 30>inorganic or organic ion. [Image] [Image] [Image] [Image] ACTIVITY : Herbicide; Antiparasitic; Plant Protectant; Insecticide; Acaricide. MECHANISM OF ACTION : None given.