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    • 34. 发明专利
    • Blocked polyisocyanates
    • AU2003204743C1
    • 2008-04-24
    • AU2003204743
    • 2003-06-17
    • BAYER AG
    • PETZOLDT JOACHIMMAZANEK JANGURTLER CHRISTOPHMULLER HEINO
    • C08G18/80C08G18/70C09D175/04
    • Post-crosslinkable polyurethane-polyurea dispersion comprises polyisocyanate, polymeric polyol having average molar weight of 400- 6000, optionally mono- or polyalcohol or mono- or polyamine having average molar weight of up to 400, at least one blocking agent, and at least one compound chosen from compounds having at least one ionic or potentially ionic group and nonionically hydrophilicizing compounds. Post-crosslinkable polyurethane-polyurea dispersion comprises polyisocyanate, polymeric polyol having average molar weight of 400-6000, optionally mono- or polyalcohol or mono- or polyamine having average molar weight of up to 400, at least one blocking agent, and at least one compound chosen from compounds having at least one ionic or potentially ionic group and nonionically hydrophilicizing compounds. At least 20 wt.% of the blocking agent comprises aralkylamine. Independent claims are included for the following: (1) method for producing one of paints and coating compositions, sizes and glass fiber sizes; (2) coating compositions, sizes and glass fiber sizes, comprising the post-crosslinkable polyurethane-polyurea dispersion; (3) substrate coated with coating composition; and (4) glass fibers sized with size comprising the dispersion.
    • 35. 发明专利
    • Blocked polyisocyanates
    • AU2003204743B2
    • 2007-08-09
    • AU2003204743
    • 2003-06-17
    • BAYER AG
    • PETZOLDT JOACHIMMAZANEK JANGURTLER CHRISTOPHMULLER HEINO
    • C08G18/80C08G18/70C09D175/04
    • Post-crosslinkable polyurethane-polyurea dispersion comprises polyisocyanate, polymeric polyol having average molar weight of 400- 6000, optionally mono- or polyalcohol or mono- or polyamine having average molar weight of up to 400, at least one blocking agent, and at least one compound chosen from compounds having at least one ionic or potentially ionic group and nonionically hydrophilicizing compounds. Post-crosslinkable polyurethane-polyurea dispersion comprises polyisocyanate, polymeric polyol having average molar weight of 400-6000, optionally mono- or polyalcohol or mono- or polyamine having average molar weight of up to 400, at least one blocking agent, and at least one compound chosen from compounds having at least one ionic or potentially ionic group and nonionically hydrophilicizing compounds. At least 20 wt.% of the blocking agent comprises aralkylamine. Independent claims are included for the following: (1) method for producing one of paints and coating compositions, sizes and glass fiber sizes; (2) coating compositions, sizes and glass fiber sizes, comprising the post-crosslinkable polyurethane-polyurea dispersion; (3) substrate coated with coating composition; and (4) glass fibers sized with size comprising the dispersion.
    • 37. 发明专利
    • Blocked polyisocyanates
    • HK1062293A1
    • 2004-10-29
    • HK04105240
    • 2004-07-16
    • BAYER AG
    • GURTLER CHRISTOPHMAZANEK JANPETZOLDT JOACHIMKLIMMASCH THOMASMULLER HEINO
    • C07C20060101C08G18/80C09D11/00C09D175/04C09J175/04
    • Post-crosslinkable polyurethane-polyurea dispersion comprises polyisocyanate, polymeric polyol having average molar weight of 400- 6000, optionally mono- or polyalcohol or mono- or polyamine having average molar weight of up to 400, at least one blocking agent, and at least one compound chosen from compounds having at least one ionic or potentially ionic group and nonionically hydrophilicizing compounds. Post-crosslinkable polyurethane-polyurea dispersion comprises polyisocyanate, polymeric polyol having average molar weight of 400-6000, optionally mono- or polyalcohol or mono- or polyamine having average molar weight of up to 400, at least one blocking agent, and at least one compound chosen from compounds having at least one ionic or potentially ionic group and nonionically hydrophilicizing compounds. At least 20 wt.% of the blocking agent comprises aralkylamine. Independent claims are included for the following: (1) method for producing one of paints and coating compositions, sizes and glass fiber sizes; (2) coating compositions, sizes and glass fiber sizes, comprising the post-crosslinkable polyurethane-polyurea dispersion; (3) substrate coated with coating composition; and (4) glass fibers sized with size comprising the dispersion.
    • 38. 发明专利
    • BR0211092A
    • 2004-06-15
    • BR0211092
    • 2002-07-01
    • BAYER AG
    • KOENIG EBERHARDMAZANEK JANMUELLER HEINOPETZOLDT JOACHIM
    • C08G18/32C08G18/40C08G18/79C08G18/80C09D5/00C09D5/46C09D175/00C09D175/04C08G18/34
    • Polyisocyanate blocked with diisopropylamine is stable on storage in the aqueous phase and does not undergo constant carbon dioxide emission as occurs, for example, with malonic acid diethyl ester or 1,2,4-triazole blocked polyisocyanate. An aqueous and/or water dilutible blocked polyisocyanate crosslinking agent comprises (equivalent %): (a) polyisocyanate component (100); (b) diisopropylamine (50-80); (c) monohydroxy and/or dihydroxycarboxylic acid as hydrophilizing agent (15-40); and (d) a difunctional HO and/or NH2 group carrying chain lengthening agent (0-15), Where the quantity ratio of the reaction partner is selected so that the equivalent ratio of NCO groups of component (a) to the reactive groups of components (c) and (d) is 1:0.8 to 1:1.2 respectively, and containing additives and adjuvants. An Independent claim is included for preparation of the crosslinking agent from component (a) by reaction of 30 wt. % water-miscible solvent in a first reaction stage at 80 deg C with a hydrophilizing monohydroxycarboxylic acid, with cooling to 50 deg C, and blocking of the residual NCO groups by addition of diisopropylamine