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31. 发明专利

CA1021796A ANTISTATIC AGENTS 未知
公开(公告)号：CA1021796A
公开(公告)日：1977-11-29
申请号：CA169203
申请日：1973-04-19
申请人： BAYER AG
发明人： RADLMANN EDUARD , NISCHK GUENTHER
IPC分类号： C08J7/04 , C08K5/00 , C08K5/17 , C08K5/20 , C08K5/44 , C08L33/00 , C08L33/02 , C09K3/16 , D06M13/02 , D06M13/325 , D06M13/328 , D06M13/332 , D06M15/53 , D06M101/00 , D06M101/16

32. 发明专利

GB1262800A A PROCESS FOR THE PRODUCTION OF OXAMIDO-N-N'-BISALKYLCARBOXYLIC ACIDS 未知
公开(公告)号：GB1262800A
公开(公告)日：1972-02-09
申请号：GB4856070
申请日：1970-10-13
申请人： BAYER AG
发明人： RADLMANN EDUARD , NISCHK GUNTHER
IPC分类号： H01H13/70
摘要： 1,262,800. Oxamide bis-N-alkyl carboxylic acids. FARBENFABRIKEN BAYER A.G. 13 Oct., 1970 [16 Oct., 1969], No. 48560/70. Heading C2C. Compounds of the formula where R 1 is a C 2-30 alkylene radical, which may be unsaturated, are prepared by reacting H 2 NR 1 COOH with an ester ROCOCOOR, where each R is phenyl or C 1-10 alkyl, in a molar ratio of at least 2 : 1, either in the melt or in solution in an inert polar organic solvent, in an inert gas atmosphere, at 80-250‹ C.

33. 发明专利

CA862798A PROCESS FOR THE PRODUCTION OF NITROAMINODIARYL ETHERS 未知
公开(公告)号：CA862798A
公开(公告)日：1971-02-02
申请号：CA862798D
申请人： BAYER AG
发明人： SCHRAMM JURGEN , RADLMANN EDUARD , LESCH DIETER , LOHWASSER HERMANN , NISCHK GUNTHER

34. 发明专利

CA846289A POLYIMIDES 未知
公开(公告)号：CA846289A
公开(公告)日：1970-07-07
申请号：CA846289D
申请人： BAYER AG
发明人： RADLMANN EDUARD , BRADEN RUDOLF , NISCHK GUNTHER

35. 发明专利

GB1154816A Process for the production of High Melting Polyamides 未知
公开(公告)号：GB1154816A
公开(公告)日：1969-06-11
申请号：GB4158967
申请日：1967-09-12
申请人： BAYER AG
发明人： BODESHEIM FERDINAND , NISCHK GUENTHER , RADLMANN EDUARD , BLANKENSTEIN GUENTER , ROSENDAHL FRIEDRICH-KARL
IPC分类号： C08G69/32
摘要： 1,154,816. Soluble aromatic polyether-amides. FARBENFABRIKEN BAYER A.G. 12 Sept., 1967 [19 Sept., 1966], No. 41589/67. Heading C3R. Soluble aromatic polyamides comprising recurrent units where Ar, Ar 1 and Ar 2 are bivalent radicals free from substituents capable of reacting with the amide group and in which the NH and O are linked to Ar 2 in the m or p positions, may be prepared by reacting the appropriate diamine and acid dihalide at - 30 to 100 C. in polar organic solvents. Several suitable diamines and acid dihalides are specified. Preferred solvents are N-alkyl pyrrolidones and N,N 1 -dialkyl carboxylic acid amides. With other polar solvents, such as tetramethylene sulphone, acid acceptors, e.g. t-amines or LiOH, are necessary. The polymer may be precipitated with a water-alcohol mixture. In examples polymers are prepared from various combinations of the acid chlorides of isophthalic, terephthalic and 4,41-diphenylsulphone dicarboxylic acids and the following diamines: 4,4 1 - di(p - aminophenoxy) - diphenyl, - diphenyl propane, - diphenylsulphone and - diphenyl ether; 4,4 1 - di(2 - chloro - 4- aminophenoxy)diphenylpropane; 1,4 - di(2- chloro - 4 - aminophenoxy)benzene; and 3- chloro - or 3,3 1 - dichloro - 4,4 1 - di(p - aminophenoxy)diphenyl sulphone. The products are colourless polyamides having melting or decomposition points from 300 to above 360 C. and intrinsic viscosities between 0À91 and 1À62.

36. 发明专利

CA1085547A CROSSLINKED ACRYLONITRILE COPOLYMERS 未知
公开(公告)号：CA1085547A
公开(公告)日：1980-09-09
申请号：CA278753
申请日：1977-05-19
申请人： BAYER AG
发明人： RADLMANN EDUARD , REINEHR ULRICH , HOFFMANN PETER , ARLT DIETER , NISCHK GUENTHER
IPC分类号： C08F8/00 , C08F8/30 , D01F6/38 , D01F6/54 , C08F220/44 , C08G69/44
摘要： The invention relates to a process for the production of crosslinked fibres or filaments by spinning an acrylonitrile copolymer containing at least 20 mVal of carboxyl groups per kg of polymer together with a polyoxaxoline in a polar organic solvent and thereafter crosslinking at temperatures of from 120 to 190.degree.C. The invention also relates to crosslinked acrylonitrile fibres and filaments obtainable by this process.

37. 发明专利

CA1023895A PROCESS FOR THE PREPARATION OF POLYCAPROLACTAM WHICH CAN BE DYED WITH CATIONIC DYES 未知
公开(公告)号：CA1023895A
公开(公告)日：1978-01-03
申请号：CA194462
申请日：1974-03-08
申请人： BAYER AG
发明人： RADLMANN EDUARD , SCHRAMM JUERGEN , NISCHK GUENTHER
IPC分类号： C08G69/00 , C08G69/16 , C08G69/42
摘要： 1422498 Polycaprolactam of modified dyability BAYER AG 5 March 1974 [10 March 1973] 9783/74 Heading C3R A modified homogeneous polycaprolactam containing repeating units and -[-CORCO-NH(CH 2 ) 6 NH-]- is made by (A) condensing #1 sulphonate diester in aqueous solution with excess H 2 N(CH 2 ) 6 NH 2 , (B) adding caprolactam and, in an amount at least equivalent to the excess of H 2 N(CH 2 ) 6 NH 2 , a dicarboxylic acid R(COOH) 2 and (C) removing water and condensing to give the polycaprolactam; where M is an alkali metal, R is C 4-12 alkylene, and R 1 is C 1-10 alkyl. M may be, e.g. Na or Li. In step (A), the molar ratio diester/ H 2 N(CH 2 ) 6 NH 2 may be from 2 to 4. The excess of R(COOH) 2 may be up to 25 % moles, based on the excess of H 2 N(CH 2 ) 6 NH 2 . Step (A) and the condensation in (C) may be performed in an inert atmosphere. In step (C), the water may be removed at 100-140‹ C., and the condensation performed at 100-300‹ C. and at 0À001 Torr to 20 atmos-gauge pressure. The modified polycaprolactam may be added, e.g. in amount of up to 20% wt., to a polycaprolactam composition. The modified polycaprolactam or the composition may be granulated and then used to form filaments, fibres, yarns, or foils which are resistant to acid dyes and can be dyed with basic dyes. The basic dyes may be, e.g.

38. 发明专利

CA1002062A ACRYLONITRILE POLYMERS WITH ANTI-STATIC PROPERTIES 未知
公开(公告)号：CA1002062A
公开(公告)日：1976-12-21
申请号：CA168547
申请日：1973-04-12
申请人： BAYER AG
发明人： RADLMANN EDUARD , NISCHK GUENTHER
IPC分类号： C08L33/00 , C08G65/04 , C08G65/26 , C08G65/334 , C08K5/42 , C08L33/02 , C08L33/18 , D01F1/10 , D01F6/54
摘要： The invention relates to acrylonitrile polymers or copolymers containing as an anti-static agent from 1 to 20 percent by weight based on the mixture as a whole of polyalkylene oxide derivatives with terminal sulphonate groups attached through alkylphenyl ether groups.

39. 发明专利

GB1216109A PROCESS FOR THE PRODUCTION OF NITROAMINODIARYL ETHERS 未知
公开(公告)号：GB1216109A
公开(公告)日：1970-12-16
申请号：GB1361568
申请日：1968-03-21
申请人： BAYER AG
发明人： SCHRAMM JURGEN , RADLMANN EDUARD , LOHWASSER HERMANN , NISCHK GUNTHER , LESCH DIETER
IPC分类号： C07C20060101
摘要： 1,216,109. Nitroaminodiaryl ethers. FARBENFABRIKEN BAYER A.G. 21 March, 1968 [27 April, 1967; 14 July, 1967], No. 13615/68. Heading C2C. Nitroaminodiaryl ethers are prepared by reacting an amino phenol of general formula in which An 1 is an aromatic radical, R is an alkyl or alkoxy radical or halogen and x is 0 or an integer from 1 to 6, with a nitrohalobenzene of general formula in which An 2 is a phenylene radical, Hal is a halogen atom o- or pto a nitro group, R 1 is alkyl or alkoxy or halogen in o-position to the halogen already present, y is 1 or 2 and z is 0-3 or 0-2 if R 1 represents halogen, in the presence of the stoichiometric amount of the phenolate, an alcoholate or a hydroxide of an alkali metal in a polar solvent at 20‹-150‹ C. Examples are given of the preparation of 4 - (41 - nitrophenoxy)aniline; 3 - (4 1 - nitrophenoxy)- aniline; 4 - (2 1 - nitrophenoxy)aniline; 4 - (4 1 - nitrophenoxy) - 2 - chloro - aniline; 7 - (4 1 nitrophenoxy) - 2 - naphthylamine; and 4 - (21- chloro-4 1 -nitrophenoxy)-aniline.

40. 发明专利

CA847978A HIGH MOLECULAR WEIGHT AROMATIC POLYAMIDES 未知
公开(公告)号：CA847978A
公开(公告)日：1970-07-28
申请号：CA847978D
申请人： BAYER AG
发明人： NISCHK GUNTHER , RADLMANN EDUARD , REESE ECKART

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