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    • 31. 发明专利
    • DK133008C
    • 1976-08-09
    • DK317172
    • 1972-06-23
    • BAYER AG
    • COLLN RHAMMANN IUNTERSTENHOFER G
    • C07D487/04C07F9/6561C07F9/65A01N9/36
    • 1391354 Pesticidal phosphorus-containing pyrazolo-pyrimidine derivatives BAYER AG 23 June 1972 [24 June 1971] 29518/72 Addition to 1049960 Headings C2P and C2C The invention comprises particular compounds falling within the general formula where R 1 is methyl, isopropoxy, methoxy or ethoxy, R 2 is methyl, ethyl, phenyl, methoxy, ethoxy, dimethylamino or isopropylamino, R 3 is hydrogen, chlorine or bromine, X is oxygen or sulphur and Hal is halogen which may be prepared by reacting a compound of Formula II R 1 R 2 -P(X)-Hal where Hal is halogen with a compound of Formula III in the presence of an acid acceptor or in the form of an alkali metal, alkaline earth metal or ammonium salt. The starting materials of Formula III in which R 3 is hydrogen may be prepared by reacting 3-aminopyrazolone with 1,1,3,3-tetramethoxypropane and concentrated HC1, and this material may be halogenated to give the compounds of Formula III in which R 3 is halogen. The compounds of the invention have insecticidal and acaricidal properties and may be used as the active ingredients in conventional pesticidal compositions.