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    • 38. 发明授权
    • VERFAHREN ZUR HERSTELLUNG VON ALKOXYCARBONYLAMINO-TRIAZINEN
    • EP1575927B1
    • 2010-08-04
    • EP03813126.4
    • 2003-12-16
    • BASF SE
    • SCHNEIDER, JörgSCHERR, GünterSCHUPP, HansEICHFELDER, AndreasROBERT, AlainREIF, Martin
    • C07D251/70
    • C07D251/54C07D251/70
    • Disclosed is a method for producing alkoxycarbonylamino triazines of formula (I) by reacting diaminotriazines or triaminotriazines with cyclic carbonic acid esters and optional subordinate quantities of acyclic carbonic acid esters in the presence of an alcohol and an alkaline alkanol or alkaline-earth alkanol as a base. In said formula, Y1 represents hydrogen, C1-C4 alkyl, phenyl that is optionally substituted by C1-C4 alkyl, C1-C4 alkoxy, or halogen, or a radical of formula NR5R6 while R1, R2, R3, R4, R5, and R6 independently represent hydrogen or a radical of formula COOX or X, wherein X represents C1-C13 alkyl, the carbon skeleton of which can be interrupted by 1 or 2 oxygen atoms having the function of ether and/or substituted by hydroxy, or C3-C6 alkenyl provided that at least one of the radicals R1 to R4 in formula (I) represents COOX, or at least one of the radicals R1 to R6 in said formula represents COOX if Y1 represents NR5R6.
    • 公开了一种通过使二氨基三嗪或三氨基三嗪与环状碳酸酯和任选的次要量的无环碳酸酯在醇和碱性链烷醇或碱土金属链烷醇作为碱存在下反应来制备式(I)的烷氧基​​羰基氨基三嗪的方法 。 在所述式中,Y1表示氢,C1-C4烷基,任选被C1-C4烷基,C1-C4烷氧基或卤素取代的苯基或式NR5R6基团,而R1,R2,R3,R4,R5和 R6独立地代表氢或式COOX或X的基团,其中X代表C1-C13烷基,其碳骨架可被1或2个具有醚官能团和/或被羟基取代的氧原子间隔,或C3- C6烯基,条件是式(I)中的基团R1至R4中的至少一个代表COOX,或者如果Y1代表NR5R6,则所述式中基团R1至R6中的至少一个代表COOX。