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    • 33. 发明授权
    • VERFAHREN ZUR HERSTELLUNG VON POLYURETHAN-HARTSCHAUMSTOFFEN
    • EP2066717B2
    • 2013-11-20
    • EP07803299.2
    • 2007-09-06
    • BASF SE
    • EMGE, AndreasFREIDANK, DanielSEIFERT, Holger
    • C08G18/40C08G18/48C08G18/63C08G18/81
    • C08G18/632C08G18/4072C08G18/482C08G18/4829C08G18/635C08G18/8108C08G2101/0025C08G2101/005
    • The invention relates to a process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein at least one graft polyol b1) which can be prepared by in-situ polymerization of olefinically unsaturated monomers in a polyether alcohol b1i), where the polyether alcohol b1i) has a functionality of from 2 to 4 and a hydroxyl number in the range from 100 to 250 mg KOH/g, its polyether chain comprises propylene oxide and up to 20% by weight, based on the polyether alcohol b1i), of ethylene oxide, and acrylonitrile and styrene in a weight ratio of acrylonitrile:styrene of from >1:1 to 4:1 are used as olefinically unsaturated monomers, is used as compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b), and the reaction is carried out in the presence of at least one compound b1ii) which has at least one olefinic double bond and is miscible with the polyether alcohol b1i).
    • 本发明涉及一种通过a)多异氰酸酯与b)具有至少两个对异氰酸酯基团呈反应性的氢原子的化合物在c)发泡剂存在下反应生产硬质聚氨酯泡沫体的方法,其中至少一种接枝多元醇b1) 可以通过烯属不饱和单体在聚醚醇b1i)中原位聚合而制备,其中聚醚醇b1i)具有2至4的官能度和100至250mg KOH / g的羟基值,其 聚醚链包含环氧丙烷和基于聚醚醇b1i)至多20重量%的环氧乙烷,并且丙烯腈和苯乙烯以> 1:1至4:1的丙烯腈:苯乙烯的重量比用作 烯属不饱和单体用作具有至少两个对异氰酸酯基团b)具有反应性的氢原子的化合物,并且该反应在至少一种具有至少一种烯烃的化合物b1ii)存在下进行 ic双键并且与聚醚醇b1i)混溶。