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31. 发明授权

US09550706B2 Method for oligomerising alkenes using the ITQ-39 zeolite 有权
标题翻译：使用ITQ-39沸石使烯烃低聚的方法
公开(公告)号：US09550706B2
公开(公告)日：2017-01-24
申请号：US14599544
申请日：2015-01-19
申请人： Avelino Corma Canós , Cristina Martínez Sánchez
发明人： Avelino Corma Canós , Cristina Martínez Sánchez
IPC分类号： C07C2/12 , C07C2/06 , C07C2/02 , C10G50/00 , C01B39/02 , C01B39/48 , B01J37/28 , B01J29/72 , B01J29/70 , C10L1/08 , B01J35/00
CPC分类号： C07C2/12 , B01J29/70 , B01J29/72 , B01J35/002 , B01J37/28 , B01J2229/123 , B01J2229/186 , B01J2229/34 , B01J2229/37 , B01J2229/40 , B01J2229/42 , C01B39/026 , C01B39/48 , C07C2529/70 , C10G50/00 , C10L1/08 , C10L2270/026 , Y02P20/52 , C07C11/02
摘要： The invention relates to a heterogeneous method for oligomerising alkenes in order to produce hydricarbons within a diesel fraction in the present of a catalyst based on the ITQ-39 zeolite. The oligomerisation method described in the present invention includes at least: a. feeding a catalyst containing at least the ITQ-39 zeolitic material into the reactor; b. supplying the reactor with a stream that includes at least one olefinic compound; and c. enabling the catalyst containing at least the ITQ-39 material and the organic compound to remain in contact during the time required for the reaction to take place.
摘要翻译：本发明涉及用于低聚烯烃的非均相方法，以便在基于ITQ-39沸石的催化剂存在下在柴油馏分内产生氢化碳。本发明描述的低聚方法至少包括：a。将至少含有ITQ-39沸石材料的催化剂加入到反应器中; b。向所述反应器供应包含至少一种烯属化合物的物流; 和c。使得至少含有ITQ-39材料和有机化合物的催化剂在反应发生所需的时间内保持接触。

32. 发明申请

US20150110711A1 PROCESS FOR THE DIRECT SYNTHESIS OF CU-SAPO-34 有权
标题翻译： CU-SAPO-34的直接合成方法
公开(公告)号：US20150110711A1
公开(公告)日：2015-04-23
申请号：US14395872
申请日：2012-04-27
申请人： Raquel Martínez Franco , Manuel Moliner Marin , Avelino Corma Canós , Arkady Kustov , Joakim Reimer Thøgersen
发明人： Raquel Martínez Franco , Manuel Moliner Marin , Avelino Corma Canós , Arkady Kustov , Joakim Reimer Thøgersen
IPC分类号： B01J29/85 , B01D53/86 , B01J37/08 , C01B39/54
CPC分类号： B01J29/85 , B01D53/8628 , B01D2255/50 , B01D2257/404 , B01J37/08 , B01J2229/183 , C01B37/08 , C01B39/54
摘要： Process for the direct synthesis of Cu-SAPO-34 comprising at least the following steps: preparation of a mixture containing water, at least one silicon source, at least one Al source, at least one P source, at least one Cu source, at least one OSDA1 (where OSDA1 is any polyamine), and at least one OSDA2 (where OSDA2 is any organic molecule capable of directing the synthesis of the SAPO-34); and where the final synthesis mixture has the next molar composition: a Si:0.5 Al:b P:c Cu:d OSDA1:e OSDA2:f H20 wherein a is in the range from 0.01 to 0.3; wherein b is in the range from 0.2 to 0.49; wherein c is in the range from 0.001 to 0.6; wherein d is in the range from 0.001 to 0.6; wherein e is in the range from 0.001 to 2; wherein f is in the range from 1 to 200; hydrothermal treatment of the mixture at 80-200° C. until formation of the crystalline material, and recovery of the crystal-line material.
摘要翻译：用于直接合成Cu-SAPO-34的方法包括至少以下步骤：制备含有水，至少一种硅源，至少一种Al源，至少一种P源，至少一种Cu源的混合物，至少一个OSDA1（其中OSDA1是任何多胺）和至少一个OSDA2（其中OSDA2是能够指导SAPO-34的合成的任何有机分子）; 并且其中最终合成混合物具有下一摩尔组成：a Si：0.5 Al:b P：c Cu：d OSDA1：e OSDA2：fH20其中a在0.01至0.3的范围内; 其中b在0.2〜0.49的范围内; 其中c在0.001至0.6的范围内; 其中d在0.001至0.6的范围内; 其中e在0.001至2的范围内; 其中f在1至200的范围内; 在80-200℃下对混合物进行水热处理，直到形成结晶材料，并回收晶体线材料。

33. 发明授权

US08269048B2 Allylic oxidation method for the preparation of fragrances using metal-organic compounds and gold catalysts 有权
标题翻译：使用金属有机化合物和金催化剂制备香料的烯丙氧基法
公开(公告)号：US08269048B2
公开(公告)日：2012-09-18
申请号：US12888688
申请日：2010-09-23
申请人： Onofre Casanova Navarro , Avelino Corma Canós , Sara Iborra Jornet
发明人： Onofre Casanova Navarro , Avelino Corma Canós , Sara Iborra Jornet
IPC分类号： C07C45/28
CPC分类号： C07C45/34 , B01J23/66 , B01J35/0013 , B01J35/1019 , B01J37/031 , B01J37/035 , C07C29/50 , C07C45/39 , C07C2602/24 , C07C35/32 , C07C49/633
摘要： The present invention refers to a method for allylic catalytic oxidation to obtain α,β-unsaturated ketones and alcohols from bicyclic compounds reacted with oxygen and catalysts comprising metal-organic compounds and gold nanoparticles. The present invention also relates to a method for the preparation of fragrances using the above methods or products of the above method.
摘要翻译：本发明涉及一种烯丙基氧化以从与氧反应的二环化合物和包含金属 - 有机化合物和金纳米颗粒的催化剂中获得α，β-不饱和酮和醇的方法。本发明还涉及使用上述方法或上述方法的产品制备香料的方法。

34. 发明授权

US07857981B2 Bimetallic catalyst for the treatment of water containing nitrates 失效
标题翻译：用于处理含硝酸盐的水的双金属催化剂
公开(公告)号：US07857981B2
公开(公告)日：2010-12-28
申请号：US12195401
申请日：2008-08-20
申请人： Avelino Corma Canós , Antonio Eduardo Palomares Gimeno , Jose Gregorio Prato Moreno
发明人： Avelino Corma Canós , Antonio Eduardo Palomares Gimeno , Jose Gregorio Prato Moreno
IPC分类号： C02F1/70 , A62D3/37 , B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： C02F1/70 , B01J23/005 , B01J23/007 , B01J23/89 , B01J23/8926 , B01J35/1019 , B01J37/0205 , B01J37/03 , C02F2101/163 , C02F2101/166 , C02F2101/38
摘要： A catalyst which, by means of a reduction reaction at ambient temperature, permits the elimination of nitrates and nitrites in waters. The catalyst comprises a combination of a noble metal and a non-noble metal supported on or incorporated into the structure of a support which, in elemental and anhydrous form, has the formula XYMgAl, in which X is at least one noble metal, Y is at least one non-noble metal, Mg is magnesium and Al is aluminum, the Mg and Al preferably forming the structure of a hydrotalcite or a mixed oxide deriving from a hydrotalcite.
摘要翻译：通过在环境温度下的还原反应允许在水中除去硝酸盐和亚硝酸盐的催化剂。该催化剂包含贵金属和非贵金属的组合，其负载在或并入其中以元素和无水形式具有式XYMgAl的载体结构，其中X为至少一种贵金属，Y为至少一种非贵金属，Mg是镁，Al是铝，Mg和Al优选形成由水滑石衍生的水滑石或混合氧化物的结构。

35. 发明授权

US07378059B2 Downflow test unit for the study of catalysts in short contact time reactions between the catalyst and the reagents 有权
标题翻译：用于研究催化剂与催化剂与试剂之间短时间反应的下流试验装置
公开(公告)号：US07378059B2
公开(公告)日：2008-05-27
申请号：US10850356
申请日：2004-05-20
申请人： Avelino Corma Canós , Laurent L. A. Sauvanaud , Francisco V. Melo Faus
发明人： Avelino Corma Canós , Laurent L. A. Sauvanaud , Francisco V. Melo Faus
IPC分类号： G01N31/10 , B01J8/12 , B01J19/30 , C10G11/14 , C10G11/18
CPC分类号： G01N31/10 , B01J19/0046 , B01J19/0093 , B01J29/084 , B01J2219/00286 , B01J2219/00423 , B01J2219/00477 , B01J2219/00495 , B01J2219/0059 , B01J2219/00596 , B01J2219/00707 , B01J2219/00745 , B01J2219/00747 , B01J2219/00788 , B01J2219/00822 , B01J2219/00835 , B01J2219/00862 , B01J2219/00873 , B01J2219/00889 , B01J2219/00891 , B01J2219/00905 , B01J2219/00957 , B01J2219/00961 , B01J2219/00963 , C10G11/18 , C40B30/08 , C40B40/18 , C40B60/14
摘要： A test unit for the study of catalysts in short contact time reactions between a catalyst and at least one reagent, with a down transported flow reactor (4), with a load inlet (13, 13a, 13b) and a discharge outlet (14) linked with an admission inlet (15) to an upper chamber (39) of a separator (5) internally divided into an upper chamber (39) and a lower chamber (41) by a porous element (40) that is permeable to gases and impermeable to solid particles of catalyst, and a first preheater (1) provided with an outlet (2, 2a) connected with the inlet (13, 13a, 13b) of the reactor (4) via a load duct (42) in such a way that arranged between the outlet (2, 2a) and the load inlet (13, 13a, 13b) are some obturator means (3, 3a) in which the catalyst is heated to a desired temperature before they are loaded into the reactor (4).
摘要翻译：一种用于研究催化剂与至少一种试剂之间的短接触时间反应的催化剂的测试单元，其具有向下输送的流动反应器（4）和负载入口（13,13a，13b）和排出口（ 14）通过可渗透的多孔元件（40）与入口入口（15）连接到分隔器（5）的上室（39），内隔室分隔成上室（39）和下室（41）气体和不可渗透的催化剂的固体颗粒;以及第一预热器（1），其具有通过负载管道（1）与反应器（4）的入口（13,13a，13b）连接的出口（2,2a） 42）以布置在出口（2a）和负载入口（13,13a，13b）之间的方式设置有一些闭塞装置（3,3a），其中催化剂被加热到所需温度然后将其装入反应器（4）。

36. 发明授权

US07008611B2 Microporous crystalline zeolite material (ITQ-20) and production method thereof 失效
标题翻译：微孔结晶沸石材料（ITQ-20）及其制备方法
公开(公告)号：US07008611B2
公开(公告)日：2006-03-07
申请号：US10630366
申请日：2003-07-30
申请人： Avelino Corma Canós , Urbano Díaz Morales , Vicente Fornes Segui
发明人： Avelino Corma Canós , Urbano Díaz Morales , Vicente Fornes Segui
IPC分类号： C01B39/48
CPC分类号： C01B39/04 , B01J29/035 , B01J29/04 , B01J29/70 , C01B33/38 , C01B37/02 , C01B39/48
摘要： The invention relates to a microporous crystalline zeolite material having the empirical formula x(M1/nXO2):yYO2:(1−y)SiO2 wherein x has a value less than 0.02; y has a value less than 0.1; M is at least an inorganic cation with a +n charge; X is at least a chemical element having oxidation state +3, preferably selected from the group consisting of Al, Ga, B, Cr, Fe, and Y is at least a chemical element with oxidation state +4, preferably selected from the group consisting of Ge, Ti, Sn, V. The inventive material can be obtained by means of a process comprising: preparing a laminar precursor, crystallized from a reaction mixture; swelling the precursor in a solution in order to obtain a swollen laminar material; which is then washed and dried to obtain a swollen solid; delaminating the solid to obtain a delaminated material in suspension; separating the delaminating material and eliminating the organic remnants by cationic exchange and/or calcination.
摘要翻译：本发明涉及一种微孔结晶沸石材料，其具有以下经验公式：？？in-line-formula description =“In-line Formulas”end =“lead”？> x（M 1 / n X 0 < ＆lt; 2＆gt;）＆gt; yY 2＆lt; 2＆gt;（1-y）SiO 2 <？in-line-formula description =“In-line Formulas”end = “尾”→其中x具有小于0.02的值; y的值小于0.1; M至少为+ n电荷的无机阳离子; X至少为具有氧化态+3的化学元素，优选选自Al，Ga，B，Cr，Fe，Y至少为氧化态为+ 4的化学元素，优选选自 Ge，Ti，Sn，V。本发明的材料可以通过以下方法获得，该方法包括：制备从反应混合物中结晶的层状前体; 在溶液中溶胀前体以获得溶胀的层状材料; 然后将其洗涤并干燥以获得溶胀的固体; 分解固体以获得悬浮液中的分层材料; 通过阳离子交换和/或煅烧分离分层材料并除去有机残余物。

37. 发明授权

US09199955B2 Production of liquid fuels (sylvan-liquid-fuels) from 2-methylfuran 有权
标题翻译：从2-甲基呋喃生产液体燃料（乙醇 - 液体燃料）
公开(公告)号：US09199955B2
公开(公告)日：2015-12-01
申请号：US13491910
申请日：2012-06-08
申请人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
发明人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
IPC分类号： C10G1/00 , C07C27/00 , C10L1/00 , C07D307/38 , C10G3/00
CPC分类号： C07D307/38 , C10G3/42 , C10G3/45 , C10G3/47 , C10G3/50 , Y02P30/20
摘要： The present invention describes a procedure for the production of liquid fuel having a content high in alkanes and low in oxygenated compounds, comprising as a minimum: a first step of alkylation of 2-methylfuran (commonly denominated Sylvan) with a furan alcohol 2 having the formula: (2), wherein R1 is H or an aliphatic or aromatic or heteroaromatic moiety, R2 is H or an aliphatic or aromatic or heteroaromatic moiety, and R3 is H, hydroxymethyl or an aliphatic or aromatic or heteroaromatic moiety, in the presence of a catalyst, a second step of hydrogenation and dehydration of the compound obtained in step 1 in the presence of hydrogen, utilizing suitable hydrogenation and dehydration catalysts.
摘要翻译：本发明描述了生产具有高烷烃含量和低氧化合物含量低的液体燃料的方法，该方法至少包括：将呋喃醇2与2-甲基呋喃（通常称为Sylvan）烷基化的第一步骤式（2）其中R 1为H或脂族或芳族或杂芳族部分，R 2为H或脂族或芳族或杂芳族部分，且R 3为H，羟甲基或脂族或芳族或杂芳族部分，催化剂，在氢存在下，使用合适的氢化和脱水催化剂氢化和脱水步骤1中获得的化合物的第二步骤。

38. 发明申请

US20150118134A1 METHOD AND SYSTEM FOR THE PURIFICATION OF EXHAUST GAS FROM AN INTERNAL COMBUSTION ENGINE 有权
标题翻译：从内燃机中净化排气的方法和系统
公开(公告)号：US20150118134A1
公开(公告)日：2015-04-30
申请号：US14391926
申请日：2012-04-27
申请人： Manuel Moliner Marin , Cristina Franch Marti , Antonio Eduardo Palomares Gimeno , Avelino Corma Canós , Peter N.R. Vennestrøm , Marie Grill , Arkady Kustov , Joakim Reimer Thøgersen
发明人： Manuel Moliner Marin , Cristina Franch Marti , Antonio Eduardo Palomares Gimeno , Avelino Corma Canós , Peter N.R. Vennestrøm , Marie Grill , Arkady Kustov , Joakim Reimer Thøgersen
IPC分类号： B01D53/94
CPC分类号： B01D53/9418 , B01D53/9431 , B01D2251/206 , B01D2255/20761 , B01D2255/50 , B01D2255/915 , B01D2257/404 , B01D2258/012 , B01J23/72 , B01J29/76 , B01J29/85 , B01J35/1019 , B01J35/1038 , B01J37/0246 , B01J2229/20 , F01N3/023 , F01N3/035 , F01N3/2066 , F01N13/001 , F01N13/008 , F01N2330/06 , F01N2370/04 , F01N2610/02 , Y02T10/24
摘要： The invention provides a method and system for the purification of exhaust gas from an internal combustion engine, comprising a filter and a SCR catalyst. The filter is periodically regenerated increasing the temperature of the exhaust gas up to 850° C. and the water vapour content up to 100% by volume. The SCR catalyst comprises a hydrothermally microporous stable zeolite and/or zeotype having the AEI type framework and being promoted with copper.
摘要翻译：本发明提供一种用于净化来自内燃机的废气的方法和系统，该内燃机包括一个过滤器和一个SCR催化剂。周期性地再生过滤器，将排气温度提高到850℃，水汽含量高达100体积％。 SCR催化剂包含水热微孔稳定的沸石和/或具有AEI型骨架并且被铜促进的类型。

39. 发明授权

US08735621B2 Preparation of carbamates with solid catalysts 有权
标题翻译：用固体催化剂制备氨基甲酸酯
公开(公告)号：US08735621B2
公开(公告)日：2014-05-27
申请号：US13002439
申请日：2008-12-16
申请人： Avelino Corma Canós , Raquel Juarez Marin , Hermenegildo Garcia Gomez
发明人： Avelino Corma Canós , Raquel Juarez Marin , Hermenegildo Garcia Gomez
IPC分类号： C07C261/00 , C07C269/00 , C07C271/00
CPC分类号： C07C263/04 , B01J23/10 , B01J23/52 , B01J23/63 , B01J23/66 , B01J23/83 , B01J31/06 , B01J2531/18 , C07C269/04 , C07C271/28 , C07C265/14
摘要： Carbamate preparation process comprising, the reaction between at least: an amine or polyamines, an organic carbonate of formula (OR)(OR′)C═O, a catalyst which is formed by at least a support selected from at least a metal oxide, a microporous material, a mesoporous material, an anionic laminar compound of hydrotalcite type or their derivatives or an organic polymer and which may further contain a metal from groups 8, 9, 10 and 11 of the periodical system. The carbonates obtained can be transformed in their corresponding isocyanates.
摘要翻译：氨基甲酸酯制备方法，其包括至少：胺或多胺，式（OR）的有机碳酸酯（OR'）C = O之间的反应，由至少选自至少一种金属氧化物，微孔材料，介孔材料，水滑石类型的阴离子层状化合物或其衍生物或有机聚合物，并且其还可以含有周期性体系的第8,9,10和11族的金属。得到的碳酸酯可以转化成其相应的异氰酸酯。

40. 发明授权

US07344697B2 Microporous crystalline zeolite material, zeolite ITQ-28, production method thereof and use of same 失效
标题翻译：微孔结晶沸石材料，沸石ITQ-28，其制备方法及用途
公开(公告)号：US07344697B2
公开(公告)日：2008-03-18
申请号：US11392473
申请日：2006-03-29
申请人： Avelino Corma Canós , María José Sabater Picot , Susana Valencia Valencia
发明人： Avelino Corma Canós , María José Sabater Picot , Susana Valencia Valencia
IPC分类号： C01B39/46 , C01B39/48
CPC分类号： C01B37/005 , B01J29/035 , B01J29/70 , B01J29/87 , B01J29/89 , C01B37/02 , C01B39/065 , C01B39/48
摘要： The invention relates to a microporous crystalline zeolite material, zeolite ITQ-28, the production method thereof and the use of same. More specifically, the invention relates to a microporous crystalline zeolite material, ITQ-28, which, in the calcined state and in the absence of defects in the crystalline lattice thereof, manifested by the presence of silanols, is characterised by having empirical formula x (M1/nXO2): y YO2: SiO2, wherein: M is selected from H+, at least one inorganic cation with charge +n, preferably alkalines or alkaline earths, and a mixture of both; X is at least one chemical element in oxidation state +3, preferably Al, Ga, B, Fe, Cr or mixtures thereof; Y is at least a chemical element in oxidation state +4, which is different from Si, preferably Ge, Ti, Sn, V or mixtures of same; x has a value of between 0 and 0.2 inclusive; and y has a value of between 0 and 0.1 inclusive. The invention is further characterised in that the material as it is synthesised has an x-ray diffraction pattern with at least values of angle 2θ (degrees) and the relative intensities given in table 1. The invention also relates to the method of preparing said material and to the use thereof in the conversion of organic compounds.
摘要翻译：本发明涉及微孔结晶沸石材料，沸石ITQ-28，其制备方法及其用途。更具体地说，本发明涉及一种微孔结晶沸石材料ITQ-28，其在煅烧状态中并且在其不存在其晶格缺陷的情况下，通过硅烷醇的存在而表现出来，其特征在于具有经验式x（ M 1 / n 2 XO 2）：y Y 2 O 2 SiO 2其中：M选自H 至少一种带电荷的无机阳离子，优选碱金属或碱土金属，以及二者的混合物; X是氧化态+3，优选Al，Ga，B，Fe，Cr或其混合物中的至少一种化学元素; Y至少是氧化态+4的化学元素，其不同于Si，优选Ge，Ti，Sn，V或其混合物; x的值在0和0.2之间; y的值在0和0.1之间。本发明的特征还在于其合成的材料具有x射线衍射图，其至少具有角度2θ（度）和表1中给出的相对强度。本发明还涉及制备所述材料的方法以及其在有机化合物的转化中的用途。

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