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31. 发明授权

US4042324A Process for inhibiting the corrosions and deposition of boiler scale in water-conveying systems 失效
标题翻译：防止锅炉水垢在水输送系统中的腐蚀和沉积的过程
公开(公告)号：US4042324A
公开(公告)日：1977-08-16
申请号：US654885
申请日：1976-02-03
申请人： Theodor Auel , Hannsjorg Ulrich , Horst-Dieter Wasel-Nielen , Gero Heymer
发明人： Theodor Auel , Hannsjorg Ulrich , Horst-Dieter Wasel-Nielen , Gero Heymer
IPC分类号： C02F5/14 , C07F9/38 , C23F11/167 , C02B5/06 , C23F11/16
CPC分类号： C23F11/1676 , C02F5/14 , C07F9/3808 , C23F11/167
摘要： Corrosion and deposition of boiler scale in water-conveying systems are inhibited. To this end the water is admixed with at least one carboxy-alkane compound of phosphorus of the general formula: ##STR1## in which each of the substituents R.sup.1, R.sup.2, R.sup.3, and R.sup.4 stands for hydrogen or an alkyl group having from 1 to 4 carbon atoms, R.sup.5 stands for hydrogen, an OH-group or an alkyl group having from 1 to 3 carbon atoms, and n stands for 0 or 1, or with at least one water-soluble salt thereof.
摘要翻译：锅炉秤在输水系统中的腐蚀和沉积受到抑制。为此，将水与至少一种以下通式的磷的羧基烷烃化合物混合：其中每个取代基R 1，R 2，R 3和R 4代表氢或具有1至 4个碳原子，R5代表氢，OH-基团或具有1至3个碳原子的烷基，n代表0或1，或其至少一种水溶性盐。

32. 发明授权

US4923691A Aluminum nitride powder and a process for the preparation thereof 失效
标题翻译：氮化铝粉末及其制备方法
公开(公告)号：US4923691A
公开(公告)日：1990-05-08
申请号：US364013
申请日：1989-06-09
申请人： Dieter Peters , Gero Heymer , Christian May
发明人： Dieter Peters , Gero Heymer , Christian May
IPC分类号： C01B21/072
CPC分类号： C01B21/072 , C01P2002/60 , C01P2004/62 , C01P2006/12 , C01P2006/60
摘要： An aluminum nitride powder has a crystallite size of 40 to 150 nm, measured by powder diffractometry and evaluated by the method of Scherrer, a primary particle size of 0.1 to 0.5 .mu.m, a specific surface according to BET of 5 to 50 m.sup.2 /g and a degree of whiteness of more than 91%, measured using light of a 400 to 700 nm wavelength against barium sulfate analytical reagent as standard of whitness.To prepare this aluminum nitride powder, metallic aluminum and monoamminealuminum chloride [AlCl.sub.3 (NH.sub.3)] are first molten together in an inert gas atmosphere at temperatures above 125.degree. C. and allowed to react with one another with evolution of hydrogen. 8 to 20 g of ammonia are then introduced per hour per mol of monoamminealuminum chloride into the aluminum-containing monoamminealuminum chloride melt at temperatures between 250.degree. and 400.degree. C., aluminum nitride being precipitated as a solid until the conversion of the aluminum is complete. The temperature of the melt is finally raised to more than 400.degree. C.
摘要翻译：氮化铝粉末的微晶尺寸为40〜150nm，用粉末衍射法测定，用Scherrer法评价，一次粒径为0.1〜0.5μm，BET比表面积为5〜50m 2 / g 白度为91％以上，采用400〜700nm波长的光作为白度标准测定硫酸钡分析试剂。为了制备这种氮化铝粉末，首先在惰性气体气氛中，在高于125℃的温度下将金属铝和一氯化铝[AlCl 3（NH 3）]熔融在一起，并使其彼此发生氢气反应。然后在250-400℃的温度下将8至20g的氨每小时每摩尔氯化单铝酸铵引入含铝单胺氯化铝熔体中，将氮化铝作为固体沉淀直到铝的转化完全。熔体的温度最终升至400℃以上。

33. 发明授权

US4906445A Continuous process for complete removal or organic impurities from and complete decolorization of prepurified wet-process phosphoric acid 失效
标题翻译：用于完全去除或有机杂质的连续方法和完全脱湿的湿法磷酸完全脱色
公开(公告)号：US4906445A
公开(公告)日：1990-03-06
申请号：US311640
申请日：1989-02-16
申请人： Gunther Schimmel , Gerhard Bettermann , Gero Heymer , Friedrich Kolkmann
发明人： Gunther Schimmel , Gerhard Bettermann , Gero Heymer , Friedrich Kolkmann
IPC分类号： C01B25/234 , C01B25/235 , C01B25/46
CPC分类号： C01B25/461 , C01B25/235
摘要： A continuous process is indicated for complete removal of organic impurities from and complete decolorization of pre-purified wet-process phosphoric acid which has been purified by an extractive method using an organic solvent, freed from residual hydrofluoric acid by steam stripping and treated with hydrogen peroxide at elevated temperature, which comprises mixing the pre-purified wet-process phosphoric acid and the hydrogen peroxide in a mixing zone at a temperature of from 100.degree. to 200.degree. C., preferably 140.degree. to 160.degree. C., and allowing them to react at this temperature for a further 1 to 4 hours, cooling to from 85.degree. to 90.degree. C. the pre-purified wet-process phosphoric acid treated in this way and pumping it at this temperature with exclusion of air firstly through an activated charcoal bed which has been prepared on the basis of peat and has been steam-activated and has a BET surface area of from 800 to 1000 m.sup.2 /g, and subsequently through a silicon carbide and/or graphite bed while maintaining a pumping rate of less than 0.5 m.sup.3 /h of wet-process phosphoric acid per m.sup.3 of activated charcoal bed.
摘要翻译：指示完全除去有机杂质并完全脱色预纯化的湿法磷酸的连续方法，其通过萃取方法使用有机溶剂纯化，通过汽提除去残留的氢氟酸并用过氧化氢处理在高温下，其包括在预先纯化的湿法磷酸和过氧化氢的混合区中在100至200℃，优选140至160℃的温度下混合，并使它们在该温度下再反应1至4小时，冷却至85℃至90℃，预纯化的湿法磷酸以此方式处理并在该温度下泵送，首先通过活性炭排除空气基于泥炭制备并已蒸汽活化并具有800至1000m2 / g的BET表面积的床，随后通过碳化硅和/或石墨b 同时保持每立方米活性炭床的湿法磷酸的泵送速率小于0.5m 3 / h。

34. 发明授权

US4600565A Process for making manganese (II) salt solutions containing ammonium salt 失效
标题翻译：制备含有铵盐的锰（II）盐溶液的方法
公开(公告)号：US4600565A
公开(公告)日：1986-07-15
申请号：US708299
申请日：1985-03-05
申请人： Klaus Lehr , Bernhard Hofmann , Gero Heymer
发明人： Klaus Lehr , Bernhard Hofmann , Gero Heymer
IPC分类号： C01G45/00 , C22B47/00
CPC分类号： C01G45/00 , C22B47/00
摘要： Manganese(II)salt solutions containing ammonium salt are made by subjecting a manganese-containing compound to processing treatment with an ammonium salt solution. A boiling temperature of 57.degree.-68.degree. C. is established in the suspension to be subjected to the processing treatment, by application of a vacuum. The ammonium salt solution used contains 0.5-2.5 mol/l diammonium sulfate or 1.0-5.0 mol/l ammonium nitrate.
摘要翻译：含有铵盐的锰（II）盐溶液通过使含锰化合物用铵盐溶液进行处理来制备。通过施加真空在待处理处理的悬浮液中建立沸点为57-68℃的温度。使用的铵盐溶液含有0.5-2.5mol / l硫酸二铵或1.0-5.0mol / l硝酸铵。

35. 发明授权

US4530769A Process for separating carbon black from an aqueous suspension 失效
标题翻译：从水性悬浮液中分离炭黑的方法
公开(公告)号：US4530769A
公开(公告)日：1985-07-23
申请号：US479965
申请日：1983-03-29
申请人： Manfred Wolter , Friedrich-Wilhelm Dorn , Gero Heymer , Hans-Werner Stephan
发明人： Manfred Wolter , Friedrich-Wilhelm Dorn , Gero Heymer , Hans-Werner Stephan
IPC分类号： B01D25/12 , C09C1/48 , C10G31/09 , B01D29/10
CPC分类号： C09C1/487 , C01P2006/12
摘要： The disclosure relates to a process for the discontinuous separation of a solid consisting predominantly of carbon black from its aqueous suspension by filtration. To this end, the disclosure provides for use to be made of a tube pressure filter which is operated under a final pressure of 30 to 100 bars.
摘要翻译：本公开涉及通过过滤从其水悬浮液中主要由炭黑组成的固体的不连续分离的方法。为此，本公开提供了用于在30至100巴的最终压力下操作的管式压力过滤器的使用。

36. 发明授权

US4525333A Process for separating gallium and indium from aqueous solutions 失效
标题翻译：从水溶液中分离镓和铟的工艺
公开(公告)号：US4525333A
公开(公告)日：1985-06-25
申请号：US531156
申请日：1983-09-09
申请人： Gunther Schimmel , Gero Heymer , Werner Krause , Werner Pieper
发明人： Gunther Schimmel , Gero Heymer , Werner Krause , Werner Pieper
IPC分类号： C22B58/00 , C01G15/00 , C22B3/38
CPC分类号： C01G15/003 , C22B3/0067 , C22B3/0087 , Y02P10/234
摘要： The disclosure relates to a process for separating gallium and indium from an aqueous solution by subjecting this latter to liquid/liquid extraction with the use of certain classes of organylphosphonic acid esters and separating the resulting liquid phases from one another.
摘要翻译：本公开涉及通过使用后者使用某些种类的有机膦酸酯并将所得液相彼此分离来从水溶液中分离镓和铟的方法。

37. 发明授权

US4466948A Process for removing heavy metal ions and arsenic from wet-processed phosphoric acid 失效
标题翻译：从湿法处理的磷酸中去除重金属离子和砷的工艺
公开(公告)号：US4466948A
公开(公告)日：1984-08-21
申请号：US508272
申请日：1983-06-24
申请人： Gunther Schimmel , Reinhard Gradl , Gero Heymer
发明人： Gunther Schimmel , Reinhard Gradl , Gero Heymer
IPC分类号： C01B25/237 , C01B25/238 , C01G1/00 , C01G3/00 , C01G11/00 , C01G13/00 , C01G21/00 , C01G28/00 , C22B3/38 , C01B25/16 , B01D11/00 , B03C1/00 , C01G17/00
CPC分类号： C01G3/003 , C01B25/238 , C01G11/003 , C01G13/003 , C01G21/003 , C01G28/001 , C22B3/007 , C22B3/24 , Y02P10/234
摘要： The disclosure relates to a process for removing heavy metal ions and arsenic from wet-processed phosphoric acid, wherein the crude wet-processed phosphoric acid is treated at temperatures between 10.degree. and 100.degree. C. initially with a diorganyldithiosphosphoric acid ester and then with an adsorbent, and the phoshoric acid so purified is separated from the ester and adsorbent. More particularly, the wet-processed phosphoric acid is treated with the diorganyldithiophosphoric acid ester at temperatures higher than 50.degree. C. and with the adsorbent at temperatures lower than 50.degree. C.
摘要翻译：本公开涉及从湿法处理的磷酸中除去重金属离子和砷的方法，其中粗制湿法处理的磷酸最初用二有机基二硫代磷酸酯在10℃至100℃的温度下处理，然后用吸附剂，如此纯化的磷酸与酯和吸附剂分离。更具体地说，湿法处理的磷酸在二氧化二硫代磷酸酯的温度高于50℃下处理，吸附剂在低于50℃的温度下处理。

38. 发明授权

US4385041A Process for making aqueous alkali metal phosphate solutions 失效
标题翻译：制备碱金属磷酸盐水溶液的方法
公开(公告)号：US4385041A
公开(公告)日：1983-05-24
申请号：US326078
申请日：1981-11-30
申请人： Klaus Jodden , Gero Heymer
发明人： Klaus Jodden , Gero Heymer
IPC分类号： C01B25/30 , C01B15/16 , C01B25/26
CPC分类号： C01B25/30
摘要： The invention relates to a process for making aqueous alkali metal phosphate solutions by subjecting aqueous alkali metal phosphite solutions to catalytic oxidation with oxygen or air. More particularly, oxygen or air in stoichiometric excess proportions is introduced into the aqueous alkali metal phosphite solution at about 30.degree. to 110.degree. C., at a pH-value of 0 to about 8, and in the presence of SiO.sub.2 or aluminum silicate containing at most 10 weight % Al.sub.2 O.sub.3, for as long as necessary to achieve conversion of the alkali metal phosphite to alkai metal phosphate. After completion of the oxidation, the aqueous solution is separated from the catalyst.
摘要翻译：本发明涉及通过使碱金属亚磷酸盐水溶液用氧气或空气进行催化氧化来制备碱金属磷酸盐水溶液的方法。更具体地说，在约30℃至110℃，pH值为0至约8的条件下，在含碱金属亚磷酸盐水溶液中的化学计量过量的氧气或空气中，在含有至多10重量％的Al 2 O 3，只要需要实现碱金属亚磷酸盐转化为磷酸金属。氧化完成后，将水溶液与催化剂分离。

39. 发明授权

US4163760A Continuous production of organic phosphines 失效
标题翻译：连续生产有机膦
公开(公告)号：US4163760A
公开(公告)日：1979-08-07
申请号：US872250
申请日：1978-01-25
申请人： Georg Elsner , Gero Heymer , Hans-Werner Stephan
发明人： Georg Elsner , Gero Heymer , Hans-Werner Stephan
IPC分类号： C07F9/50 , C07F9/6568 , C07F9/54
CPC分类号： C07F9/5059 , C07F9/65683
摘要： Organic phosphines are produced by reacting an alkylene, cycloalkylene or aralkylene in the presence of a free radical-yielding catalyst. More specifically, a pressure reactor, which is provided in its interior with mixing elements, kept free from oxygen, and subdivided so as to comprise an upper cooling zone and a lower reaction zone, is continuously supplied from above with (a) a solution of the alkylene, cycloalkylene or aralkylene and the catalyst in an inert solvent, and (b) a stoichiometric excess of hydrogen phosphide, the said (a) and (b) reactants being supplied jointly with but separately from one another; the (a) and (b) reactants are mixed in the upper cooling zone of the reactor at about 0.degree. to 35.degree. C. and under a PH.sub.3 -pressure of about 80 to 300 bars; the resulting mixture, which travels downwardly in the reactor, is reacted in the lower reaction zone at about 90.degree. to 190.degree. C., the reactants being allowed to remain in the reactor for a period of time about 13 to 15 times longer than the half life period of the catalyst; the reaction mixture is removed through the bottom portion of the reactor and subjected to distillation so as to separate the organic phosphines.
摘要翻译：有机膦通过在产生自由基的催化剂存在下使亚烷基，亚环烷基或亚芳烷基反应来制备。更具体地，在其内部设置有保持无氧的并且被分为包括上部冷却区和下部反应区的混合元件的压力反应器从上方连续地供给（a）所述（a）和（b）反应物是由彼此共同供应的;（b）化学计量过量的磷酸氢盐，所述（a）和（b）（a）和（b）反应物在反应器的上部冷却区中在约0℃至35℃下混合，并在约80至300巴的PH3压力下混合; 在反应器中向下移动的所得混合物在下部反应区中在约90℃至190℃下反应，使反应物在反应器中保留约13至15倍的时间催化剂的半衰期; 将反应混合物通过反应器的底部除去并进行蒸馏以分离有机膦。

40. 发明授权

US3980711A Production of methylphosphine oxides 失效
标题翻译：生产甲基膦氧化物
公开(公告)号：US3980711A
公开(公告)日：1976-09-14
申请号：US549174
申请日：1975-02-12
申请人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
发明人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
IPC分类号： B01J31/00 , C07F9/53 , C07F9/02
CPC分类号： C07F9/53
摘要： Methylphosphine oxides of the general formula (I) ##EQU1## are produced from hydroxymethylphosphines of the general formula (II) ##EQU2## in which formulae R and R' each stand for identical or different alkyl-, cycloalkyl-, aralkyl- or aryl groups having from 1 to 18 carbon atoms, or carrying substituents being inert under the reaction conditions.The methylphosphine oxides are more particularly produced by subjecting the hydroxymethylphosphines to a rearrangement reaction with the aid of radical-yielding compounds.
摘要翻译：由通式（I）R HOCH2-P ANGLE（II）R'的羟甲基膦制备通式（I）的二甲基膦氧化物。其中式R和R'各自为代表具有1至18个碳原子的相同或不同的烷基 - ，环烷基 - ，芳烷基 - 或芳基，或在反应条件下携带取代基是惰性的。

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