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31. 发明申请

US20080249309A1 Organic semiconductor materials and precursors thereof 有权
标题翻译：有机半导体材料及其前体
公开(公告)号：US20080249309A1
公开(公告)日：2008-10-09
申请号：US12011030
申请日：2008-01-23
申请人： Antonio Facchetti , Tobin J. Marks , He Yan
发明人： Antonio Facchetti , Tobin J. Marks , He Yan
IPC分类号： C07D471/06 , H01L51/40
CPC分类号： C07D471/06 , C07D471/12 , H01L51/0053 , Y02E10/549
摘要： The present teachings provide novel organic semiconductor compounds and their soluble precursors, methods for preparing these compounds and precursors, as well as compositions, materials, articles, structures, and devices that incorporate such compounds.
摘要翻译：本发明提供新颖的有机半导体化合物及其可溶性前体，制备这些化合物和前体的方法，以及掺入这些化合物的组合物，材料，制品，结构和装置。

32. 发明申请

US20080224127A1 Gate dielectric structures, organic semiconductors, thin film transistors and related methods 审中-公开
标题翻译：栅介质结构，有机半导体，薄膜晶体管及相关方法
公开(公告)号：US20080224127A1
公开(公告)日：2008-09-18
申请号：US11895000
申请日：2007-08-22
申请人： Tobin J. Marks , Antonio Facchetti , Myung-Han Yoon
发明人： Tobin J. Marks , Antonio Facchetti , Myung-Han Yoon
IPC分类号： H01L51/40 , H01L51/00
CPC分类号： H01L51/0533 , H01L51/0036 , H01L51/0068
摘要： Gate dielectric structures comprising an organic polymeric component, and organic semiconductor components, as can be used to fabricate thin film transistor devices.
摘要翻译：包括可用于制造薄膜晶体管器件的有机聚合物组分和有机半导体组分的栅介质结构。

33. 发明申请

US20080167435A1 Organic semiconductor materials and methods of preparing and use thereof 有权
标题翻译：有机半导体材料及其制备和使用方法
公开(公告)号：US20080167435A1
公开(公告)日：2008-07-10
申请号：US11977418
申请日：2007-10-24
申请人： Tobin J. Marks , Antonio Facchetti , He Yan
发明人： Tobin J. Marks , Antonio Facchetti , He Yan
IPC分类号： C08F226/06 , C07D491/06 , C07D491/048
CPC分类号： C07D519/00 , C08F226/06 , C09B5/62 , C09B69/103 , H01L51/0026 , H01L51/004 , H01L51/0053 , H01L51/0058 , H01L51/0545 , H01L51/0558 , H01L2924/19041
摘要： Solution-processable organic n-type semiconductor materials are provided with processes for preparing the same. Composites and electronic devices including the organic n-type semiconductor materials also are provided.
摘要翻译：可溶液加工的有机n型半导体材料具有制备方法。还提供了包括有机n型半导体材料的复合材料和电子器件。

34. 发明申请

US20080161524A1 Photopolymer-based dielectric materials and methods of preparation and use thereof 有权
标题翻译：基于光聚合物的介电材料及其制备方法和用途
公开(公告)号：US20080161524A1
公开(公告)日：2008-07-03
申请号：US11998159
申请日：2007-11-28
申请人： He Yan , Antonio Facchetti , Tobin J. Marks
发明人： He Yan , Antonio Facchetti , Tobin J. Marks
IPC分类号： C08F118/14 , C08F120/10 , C08F136/02 , C08J7/18
CPC分类号： C08F220/10
摘要： Photopolymer-based dielectric materials are provided with methods for preparing the same. Composites and electronic devices including such dielectric materials also are provided.
摘要翻译：提供基于光聚合物的介电材料具有制备该介电材料的方法。还提供了包括这种电介质材料的复合材料和电子器件。

35. 发明授权

US06855274B1 Layer by layer self-assembly of large response molecular electro-optic materials by a desilylation strategy 有权
标题翻译：通过去硅烷化策略逐层自组装大响应分子电光材料
公开(公告)号：US06855274B1
公开(公告)日：2005-02-15
申请号：US09815951
申请日：2001-03-22
申请人： Tobin J. Marks , Milko E. van der Boom
发明人： Tobin J. Marks , Milko E. van der Boom
IPC分类号： G02F1/065 , G02F1/361 , G02F1/37 , F21V9/00 , G02F1/35
CPC分类号： G02F1/065 , G02F1/3612 , G02F1/3614 , G02F1/37 , Y10T428/31663
摘要： The preparation of robust, thin film materials with large second-order optical nonlinearities through the covalent self-assembly of chromophoric compositions and innovative use of silyl chemistry.
摘要翻译：通过发色组合物的共价自组装和甲硅烷基化学的创新使用，制备具有大二阶光学非线性的坚固的薄膜材料。

36. 发明授权

US06586763B2 Organic light-emitting diodes and methods for assembly and emission control 有权
公开(公告)号：US06586763B2
公开(公告)日：2003-07-01
申请号：US09360249
申请日：1999-07-23
申请人： Tobin J. Marks , Qingwu Wang
发明人： Tobin J. Marks , Qingwu Wang
IPC分类号： H01L3524
CPC分类号： H01L51/5012 , B82Y10/00 , B82Y20/00 , B82Y30/00 , H01L51/0012 , H01L51/0034 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/0059 , H01L51/0069 , H01L51/007 , H01L51/0077 , H01L51/0078 , H01L51/0081 , H01L51/0094 , H01L51/0595 , H01L51/5048 , H01L51/5088 , H01L51/5096 , H01L2251/308 , H01L2251/558 , Y10S257/908
摘要： New organic light-emitting diodes and related electroluminescent devices and methods for fabrication, using siloxane self-assembly techniques.

37. 发明授权

US06544922B1 Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts 失效
标题翻译：含环戊二烯基的低价早期过渡金属烯烃聚合催化剂
公开(公告)号：US06544922B1
公开(公告)日：2003-04-08
申请号：US10198241
申请日：2002-07-18
申请人： Tobin J. Marks , Lubin Luo , Sung Cheol Yoon
发明人： Tobin J. Marks , Lubin Luo , Sung Cheol Yoon
IPC分类号： C08F464
CPC分类号： C08F220/14 , B01J31/2295 , B01J2231/12 , B01J2531/46 , C08F4/6192 , C08F4/65908 , C08F4/6592 , C08F10/00 , C08F12/08 , C08F212/08 , Y10S526/943
摘要： A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR′n}+{A}− wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C1-C20 hydrocarbyl; R′ are independently selected from hydride, C1-C20 hydrocarbyl, SiR″3, NR″2, OR″, SR″, GeR″3, and SnR″3 containing groups (R″=C1-C10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.
摘要翻译：通过用包含Cp *是环戊二烯基或取代的环戊二烯基部分的催化剂前体的还原剂进行原位还原来形成可用于聚合和共聚极性和非极性烯烃单体的催化剂体系; M是早期过渡金属; R是C1-C20烃基; R'独立地选自氢化物，C 1 -C 20烃基，SiR''3，NR''2，OR“，SR”，GeR'3和含SnR'3的基团（R“= C1- C10烃基）; n是选择以平衡M的氧化态的整数; 而A是合适的非配位阴离子助催化剂或前体。该催化剂体系可以形成包含苯乙烯和甲基丙烯酸甲酯的间同立构聚合物的立构规环烯烃聚合物，以及极性和非极性烯烃单体如甲基丙烯酸甲酯和苯乙烯的全同立构共聚物。

38. 发明授权

US06403732B2 Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon 有权
标题翻译：其有效路易斯酸具有增强的效用，其用途和基于其的产品
公开(公告)号：US06403732B2
公开(公告)日：2002-06-11
申请号：US09863721
申请日：2001-05-23
申请人： Tobin J. Marks , You-Xian Chen
发明人： Tobin J. Marks , You-Xian Chen
IPC分类号： C07F1700
CPC分类号： B01J31/2295 , B01J31/146 , B01J31/1608 , B01J2531/39 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/61908 , C08F4/6592 , C08F10/00 , C08G65/12 , C08G65/20 , Y10S526/943 , C08F4/52
摘要： The organo-Lewis acids are novel triarylboranes which are are highly fluorinated. Triarylboranes of one such type contain at least one ring substituent other than fluorine. These organoboranes have a Lewis acid strength essentially equal to or greater than that of the corresponding organoborane in which the substituent is replaced by fluorine, or have greater solubility in organic solvents. Another type of new organoboranes have 1-3 perfluorinated fused ring groups and 2-0 perfluorophenyl groups. When used as a cocatalyst in the formation of novel catalytic complexes with d- or f-block metal compounds having at least one leaving group such as a methyl group, these triorganoboranes, because of their ligand abstracting properties, produce corresponding anions which are capable of only weakly, if at all, coordinating to the metal center, and thus do not interfere in various polymerization processes such as are described.
摘要翻译：有机路易斯酸是高度氟化的新型三芳基硼烷。一种这样的三芳基硼烷含有除氟以外的至少一个环取代基。这些有机硼烷具有基本上等于或大于其中取代基被氟代替的有机硼烷的路易斯酸强度，或者在有机溶剂中具有更大的溶解度。另一种新型有机硼烷具有1-3个全氟化稠环基团和2-0个全氟苯基。当作为助催化剂用于与具有至少一个离去基团如甲基的d-或f-嵌段金属化合物形成新的催化络合物时，由于它们的配体抽出性质，这些三有机硼烷产生相应的阴离子，其能够只有在与金属中心配位的情况下才是弱的，因此不会干扰如所述的各种聚合方法。

39. 发明授权

US06291695B1 Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon 有权
标题翻译：其有效路易斯酸具有增强的效用，其用途和基于其的产品
公开(公告)号：US06291695B1
公开(公告)日：2001-09-18
申请号：US09329765
申请日：1999-06-10
申请人： Tobin J. Marks , You-Xian Chen
发明人： Tobin J. Marks , You-Xian Chen
IPC分类号： C07F1700
CPC分类号： B01J31/2295 , B01J31/146 , B01J31/1608 , B01J2531/39 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/61908 , C08F4/6592 , C08F10/00 , C08G65/12 , C08G65/20 , Y10S526/943 , C08F4/52
摘要： The organo-Lewis acids are novel triarylboranes which are highly fluorinated. Triarylboranes of one such type contain at least one ring substituent other than fluorine. These organoboranes have a Lewis acid strength essentially equal to or greater than that of the corresponding organoborane in which the substituent is replaced by fluorine, or have greater solubility in organic solvents. Another type of new organoboranes have 1-3 perfluorinated fused ring groups and 2-0 perfluorophenyl groups. When used as a cocatalyst in the formation of novel catalytic complexes with d- or f-block metal compounds having at least one leaving group such as a methyl group, these triorganoboranes, because of their ligand abstracting properties, produce corresponding anions which are capable of only weakly, if at all, coordinating to the metal center, and thus do not interfere in various polymerization processes such as are described.
摘要翻译：有机路易斯酸是高度氟化的新型三芳基硼烷。一种这样的三芳基硼烷含有除氟以外的至少一个环取代基。这些有机硼烷具有基本上等于或大于其中取代基被氟代替的有机硼烷的路易斯酸强度，或者在有机溶剂中具有更大的溶解度。另一种新型有机硼烷具有1-3个全氟化稠环基团和2-0个全氟苯基。当作为助催化剂用于与具有至少一个离去基团如甲基的d-或f-嵌段金属化合物形成新的催化络合物时，由于它们的配体抽出性质，这些三有机硼烷产生相应的阴离子，其能够只有在与金属中心配位的情况下才是弱的，因此不会干扰如所述的各种聚合方法。

40. 发明授权

US6096905A Treatment of a composition comprising a trimethylolalkane bis-monolinear formal 有权
标题翻译：包含三羟甲基烷烃双 - 单变体形式的组合物的处理
公开(公告)号：US6096905A
公开(公告)日：2000-08-01
申请号：US324435
申请日：1999-06-01
申请人： Carolyn Supplee , Tobin J. Marks , William E. Slinkard , Edward G. Zey
发明人： Carolyn Supplee , Tobin J. Marks , William E. Slinkard , Edward G. Zey
IPC分类号： C07D317/12 , C07B61/00 , C07C29/10 , C07C29/128 , C07C31/22 , C07D319/06
CPC分类号： C07D319/06
摘要： A process for treating a composition containing a substantial proportion of trimethylolpropane bis-monolinear formal (TMP-BMLF) or trimethylolethane bis-monolinear formal (TME-BMLF), e.g., a heavy ends residue obtained from the purification of a crude trimethylolpropane (TMP) or trimethylolethane (TME) product, wherein the composition is contacted at an elevated temperature with a strong acid catalyst, e.g., methanesulfonic acid, to produce a composition containing significantly increased amounts of TMP and trimethylolpropane monocyclic formal (TMP-MCF) or TME and trimethylolethane monocyclic formal (TME-MCF) respectively.
摘要翻译：一种用于处理含有相当比例的三羟甲基丙烷双 - 单体形式（TMP-BMLF）或三羟甲基乙烷双 - 单体形式（TME-BMLF）的组合物的方法，例如从纯化三羟甲基丙烷（TMP）获得的重馏分残余物，或三羟甲基乙烷（TME）产物，其中组合物在高温下与强酸催化剂（例如甲磺酸）接触以产生含有显着增加量的TMP和三羟甲基丙烷单环形式（TMP-MCF）或TME和三羟甲基乙烷的组合物单体形式（TME-MCF）。

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