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31. 发明授权

US08702973B2 Process for upgrading one or more hydrocarbons boiling in a naphtha range 有权
标题翻译：升级在石脑油范围内沸腾的一种或多种烃的方法
公开(公告)号：US08702973B2
公开(公告)日：2014-04-22
申请号：US13048863
申请日：2011-03-15
申请人： Colleen Costello , Suheil F. Abdo , Keith Adrian Holder , Ashley James Austin , Willie J. Morrissette, Jr.
发明人： Colleen Costello , Suheil F. Abdo , Keith Adrian Holder , Ashley James Austin , Willie J. Morrissette, Jr.
IPC分类号： C10G45/08 , C10G45/02 , C10G45/04
CPC分类号： C10G45/08 , C10G2300/1044 , C10G2300/202 , C10G2300/4018
摘要： One exemplary embodiment can be a process for upgrading one or more hydrocarbons boiling in a naphtha range including less than about 5%, by weight, one or more alkenes and about 2,000-about 5,000 wppm, S, comprised in one or more sulfur-containing compounds, based on the weight of the one or more hydrocarbons. The process can include contacting the one or more hydrocarbons with a catalyst. The catalyst may include about 0.1-about 10%, by weight, NiO, about 5-about 50%, by weight, MoO3, and about 0.1-about 10%, by weight, P, with the balance of the catalyst comprising Al2O3. The process can obtain an upgraded one or more hydrocarbons having a thiol concentration of no more than about 20 wppm, S, based on the sulfur comprised in one or more thiol compounds divided by the weight of the upgraded one or more hydrocarbons.
摘要翻译：一个示例性实施方案可以是用于升级一种或多种在石脑油范围内沸腾的烃的方法，所述烃包括一个或多个含硫的包含小于约5重量％的一种或多种烯烃和约2,000-约5,000wppm的S 化合物，基于一种或多种烃的重量。该方法可包括使一种或多种烃与催化剂接触。该催化剂可以包括约0.1-约10重量％的NiO，约5-约50重量％的MoO 3和约0.1-约10重量％的P，其余的催化剂包含Al 2 O 3。该方法可以基于一种或多种硫醇化合物中包含的硫除以升级的一种或多种烃的重量，获得硫醇浓度不超过约20wppm S的升级的一种或多种烃。

32. 发明授权

US08404103B2 Combination of mild hydrotreating and hydrocracking for making low sulfur diesel and high octane naphtha 有权
标题翻译：结合轻度加氢处理和加氢裂化制备低硫柴油和高辛烷值的石脑油
公开(公告)号：US08404103B2
公开(公告)日：2013-03-26
申请号：US13286769
申请日：2011-11-01
申请人： Bart Dziabala , Vasant P. Thakkar , Suheil F. Abdo
发明人： Bart Dziabala , Vasant P. Thakkar , Suheil F. Abdo
IPC分类号： C10G47/00 , C10G47/02
CPC分类号： C10G65/12 , C10G2300/1037 , C10G2300/202 , C10G2300/301 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , C10G2400/04
摘要： Methods are disclosed for the hydrotreating and hydrocracking of highly aromatic distillate feeds such as light cycle oil (LCO) to produce ultra low sulfur gasoline and diesel fuel. Optimization of hydrotreater severity improves the octane quality of the gasoline or naphtha fraction. In particular, the operation of the hydrotreater at reduced severity to allow at least about 20 ppm by weight of organic nitrogen into the hydrocracker feed is shown to lead to these important benefits. Post-treating of the hydrocracker effluent over an additional hydrotreating catalyst bed may be desired to meet specifications for ultra low sulfur fuel components.
摘要翻译：公开了用于加氢处理和加氢裂解高芳烃馏出物如轻循环油（LCO）以产生超低硫汽油和柴油燃料的方法。加氢处理剂严重性的优化提高了汽油或石脑油馏分的辛烷值。特别地，加氢处理器以较低的苛刻度运行，使至少约20ppm重量的有机氮进入加氢裂化器进料显示出这些重要的益处。在另外的加氢处理催化剂床上后处理加氢裂化器流出物可能需要满足超低硫燃料组分的规格。

33. 发明授权

US07815792B2 Selective naphtha desulfurization process and catalyst 有权
标题翻译：选择性石脑油脱硫工艺及催化剂
公开(公告)号：US07815792B2
公开(公告)日：2010-10-19
申请号：US12605730
申请日：2009-10-26
申请人： Lorenz J. Bauer , Suheil F. Abdo , Laura E. Leonard , Peter Kokayeff
发明人： Lorenz J. Bauer , Suheil F. Abdo , Laura E. Leonard , Peter Kokayeff
IPC分类号： C10G25/00 , C10G29/00 , C10G45/00 , C10G51/00 , C10G55/00 , C10G57/00 , B01J23/00 , B01J29/00 , B01J21/00 , B01J20/00
CPC分类号： B01J37/0221 , B01J23/24 , B01J23/74 , B01J23/85 , B01J23/882 , B01J35/008 , B01J37/0248 , C10G45/04 , C10G45/06 , C10G45/12 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2400/02
摘要： A process and catalyst for the selective hydrodesulfurization of a naphtha containing olefins. The process produces a naphtha stream having a reduced concentration of sulfur while maintaining the maximum concentration of olefins.
摘要翻译：用于含有烯烃的石脑油的选择性加氢脱硫的方法和催化剂。该方法产生具有降低的硫浓度的石脑油流，同时保持烯烃的最大浓度。

34. 发明授权

US07585489B2 Catalytic naphtha cracking catalyst and process 有权
标题翻译：催化石脑油裂解催化剂及工艺
公开(公告)号：US07585489B2
公开(公告)日：2009-09-08
申请号：US12198911
申请日：2008-08-27
申请人： Hayim Abrevaya , Suheil F. Abdo , R. Lyle Patton
发明人： Hayim Abrevaya , Suheil F. Abdo , R. Lyle Patton
IPC分类号： C01B39/02 , C01B39/44 , B01J29/06 , B01J29/65 , B01J29/70
CPC分类号： C07C4/06 , B01J29/18 , B01J29/65 , B01J29/70 , B01J29/7007 , B01J29/7011 , B01J29/7023 , B01J29/7042 , B01J29/7046 , B01J29/80 , B01J29/90 , B01J35/002 , B01J2229/12 , B01J2229/16 , B01J2229/32 , B01J2229/42 , B01J2229/62 , C07C2529/65 , C10G2400/20 , Y02P20/52 , Y02P20/584 , C07C11/06 , C07C11/04
摘要： A process is disclosed for enhancing the production of light olefins using a catalyst with small pores. The catalyst comprises a molecular sieve having 10 membered rings with channels of limited length. The molecular sieve has a high silica to alumina ratio and has pores sized to limit production of aromatics in the cracking process.
摘要翻译：公开了一种使用具有小孔的催化剂增强轻质烯烃生产的方法。该催化剂包括具有10个长度环通道的分子筛。分子筛具有高的二氧化硅与氧化铝的比例，并具有孔径以限制裂化过程中芳族化合物的生产。

35. 发明授权

US07452391B2 Feedforward control processes for variable output hydrogen generators 失效
标题翻译：可变输出氢发生器的前馈控制过程
公开(公告)号：US07452391B2
公开(公告)日：2008-11-18
申请号：US10522274
申请日：2003-07-30
申请人： Bradley P. Russell , John R. Harness , Paul G. Blommel , Daniel R. Sioui , Suheil F. Abdo , Kurt M. Vanden Bussche , Robert J. Sanger
发明人： Bradley P. Russell , John R. Harness , Paul G. Blommel , Daniel R. Sioui , Suheil F. Abdo , Kurt M. Vanden Bussche , Robert J. Sanger
IPC分类号： C10J1/28 , H01M8/00 , H01M8/04 , H01M8/18 , C01B3/00 , C01B3/32 , G05D7/00 , G05D16/00 , G05B17/00
CPC分类号： B01J8/001 , B01J19/0006 , B01J2219/00006 , B01J2219/00164 , B01J2219/00191 , C01B3/48 , C01B2203/00 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/047 , C01B2203/0495 , C01B2203/066 , C01B2203/0811 , C01B2203/0844 , C01B2203/0877 , C01B2203/0883 , C01B2203/1052 , C01B2203/1082 , C01B2203/1241 , C01B2203/127 , C01B2203/1276 , C01B2203/1288 , C01B2203/1294 , C01B2203/142 , C01B2203/143 , C01B2203/146 , C01B2203/147 , C01B2203/1604 , C01B2203/1614 , C01B2203/1661 , C01B2203/1685 , C01B2203/169 , C01B2203/1695 , C01B2203/80 , C01B2203/82 , Y02E60/324
摘要： Hydrogen generators and integrated hydrogen generator/fuel cells systems are operated by determining the condition of the hydrogen generator and the condition of the fuel to the hydrogen generator for selection of predetermined flow rates for each of the externally-provided raw materials. The processes of the invention can provide rapid transitions between hydrogen production rates while enabling enhanced efficiency and stability during transient operations.
摘要翻译：氢发生器和集成的氢发生器/燃料电池系统通过确定氢发生器的状况和向氢发生器的燃料状态来选择每个外部提供的原料的预定流量来运行。本发明的方法可以提供氢生产速率之间的快速转变，同时在瞬态操作期间提高效率和稳定性。

36. 发明授权

US06573214B2 Preferential oxidation catalyst 有权
标题翻译：优先氧化催化剂
公开(公告)号：US06573214B2
公开(公告)日：2003-06-03
申请号：US09877980
申请日：2001-06-08
申请人： Suheil F. Abdo , Cynthia A. DeBoy , Geralyn F. Schroeder
发明人： Suheil F. Abdo , Cynthia A. DeBoy , Geralyn F. Schroeder
IPC分类号： B01J2356
CPC分类号： H01M8/0662 , B01J21/04 , B01J23/462 , B01J35/109 , B01J37/12 , B01J37/16 , C01B3/583 , C01B2203/044 , C01B2203/047
摘要： Disclosed is a hydrogen generation process for use with fuel cells which includes a preferential oxidation step to reduce the concentration of carbon monoxide. The preferential oxidation step includes contacting a fuel stream comprising hydrogen and carbon monoxide in the presence of an oxygen at a preferential oxidation temperature of between about 70° and about 160° C. with preferential oxidation catalyst for reducing the concentration of carbon monoxide to produce a treated fuel gas stream comprising less than about 50 ppm-vol carbon monoxide. The preferential oxidation catalyst comprises ruthenium metal disposed on an alumina carrier having a low density and a high porosity. Superior performance at low preferential oxidation temperatures below 130° C. was observed when the alumina carrier contained a bimodal pore distribution with an average pore distribution of from about 20 to about 3000 angstroms. The preferential oxidation catalyst may be employed to reduce carbon monoxide in fuel gas streams supplied to fuel cells wherein carbon monoxide will poison the active noble metal membrane and higher preferential oxidation temperatures may reduce the hydrogen content of the gas stream.
摘要翻译：公开了一种用于燃料电池的氢气生成方法，其包括优先氧化步骤以降低一氧化碳的浓度。优选氧化步骤包括在优选氧化温度为约70°至约160℃之间的氧气存在下使包含氢气和一氧化碳的燃料流与优先氧化催化剂接触，以降低一氧化碳的浓度，从而产生处理的燃料气流包含小于约50ppm体积的一氧化碳。优选的氧化催化剂包括设置在低密度和高孔隙率的氧化铝载体上的钌金属。当氧化铝载体含有平均孔分布为约20至约3000埃的双峰孔分布时，观察到低于130℃的低优先氧化温度下的优异性能。可以使用优先氧化催化剂来减少供应到燃料电池的燃料气流中的一氧化碳，其中一氧化碳将中毒活性贵金属膜，并且较高的优先氧化温度可降低气流的氢含量。

37. 发明授权

US06299995B1 Process for carbon monoxide preferential oxidation for use with fuel cells 失效
标题翻译：用于燃料电池的一氧化碳优先氧化方法
公开(公告)号：US06299995B1
公开(公告)日：2001-10-09
申请号：US09584316
申请日：2000-05-31
申请人： Suheil F. Abdo , Cynthia A. DeBoy , Geralyn F. Schroeder
发明人： Suheil F. Abdo , Cynthia A. DeBoy , Geralyn F. Schroeder
IPC分类号： H01M804
CPC分类号： H01M8/0662 , B01J21/04 , B01J23/462 , B01J35/109 , B01J37/12 , B01J37/16 , C01B3/583 , C01B2203/044 , C01B2203/047
摘要： Disclosed is a hydrogen generation process for use with fuel cells which includes a preferential oxidation step to reduce the concentration of carbon monoxide. The preferential oxidation step includes contacting a fuel stream comprising hydrogen and carbon monoxide in the presence of an oxygen at a preferential oxidation temperature of between about 70° and about 160° C. with preferential oxidation catalyst for reducing the concentration of carbon monoxide to produce a treated fuel gas stream comprising less than about 50 ppm-vol carbon monoxide. The preferential oxidation catalyst comprises ruthenium metal disposed on an alumina carrier having a low density and a high porosity. Superior performance at low preferential oxidation temperatures below 130° C. was observed when the alumina carrier contained a bimodal pore distribution with an average pore distribution of from about 20 to about 3000 angstroms. The preferential oxidation catalyst may be employed to reduce carbon monoxide in fuel gas streams supplied to fuel cells wherein carbon monoxide will poison the active noble metal membrane and higher preferential oxidation temperatures may reduce the hydrogen content of the gas stream.
摘要翻译：公开了一种用于燃料电池的氢气生成方法，其包括优先氧化步骤以降低一氧化碳的浓度。优选氧化步骤包括在优选氧化温度为约70°至约160℃之间的氧气存在下使包含氢气和一氧化碳的燃料流与优先氧化催化剂接触，以降低一氧化碳的浓度，从而产生处理的燃料气流包含小于约50ppm体积的一氧化碳。优选的氧化催化剂包括设置在低密度和高孔隙率的氧化铝载体上的钌金属。当氧化铝载体含有平均孔分布为约20至约3000埃的双峰孔分布时，观察到低于130℃的低优先氧化温度下的优异性能。可以使用优先氧化催化剂来减少供应到燃料电池的燃料气流中的一氧化碳，其中一氧化碳将中毒活性贵金属膜，并且较高的优先氧化温度可降低气流的氢含量。

38. 发明授权

US5686375A Hydroprocessing catalyst and its use 失效
标题翻译：加氢催化剂及其用途
公开(公告)号：US5686375A
公开(公告)日：1997-11-11
申请号：US313723
申请日：1994-09-27
申请人： Pradeep S. Iyer , Howard D. Simpson , Suheil F. Abdo
发明人： Pradeep S. Iyer , Howard D. Simpson , Suheil F. Abdo
IPC分类号： B01J23/85 , B01J23/883 , B01J27/188 , B01J27/19 , B01J37/02 , C10G45/08 , C10G49/04 , B01J21/04
CPC分类号： B01J35/002 , B01J23/85 , B01J23/883 , B01J27/188 , B01J27/19 , B01J37/0205 , C10G45/08 , C10G49/04
摘要： A catalyst containing an overlayer of a catalytic promoter on a porous refractory support containing an underbedded Group VIII metal-containing component. The catalyst is prepared by sequential incorporation of the Group VIII metal followed by the additional catalytic promoter component, usually a Group VIB metal, with the porous refractory oxide support. Underbedded nickel components on the catalyst are characterized by a unique Raman spectrum exhibiting Raman bands in the region of about 240 cm.sup.-1 to about 250 cm.sup.-1 and in the region of about 595 cm.sup.-1 to about 605 cm.sup.-1. The catalyst has a MoO.sub.3 /NiO weight ratio less than 6 to 1 and more than 4 weight percent of NiO. The catalyst is especially useful for simultaneous hydrodenitrogenation and hydrodesulfurization of a gas oil, particularly when the refractory oxide support has a narrow pore size distribution.
摘要翻译：一种含有催化促进剂的覆盖层的催化剂，该催化剂载体包含含有第VIII族含金属的组分的多孔耐火载体。催化剂通过将第Ⅷ族金属随后加入另外的催化促进剂组分（通常为VIB族金属）与多孔难熔氧化物载体连续制备。催化剂上的嵌入的镍组分的特征在于在约240cm -1至约250cm -1的区域和约595cm -1至约605cm -1的区域中显示拉曼带的独特的拉曼光谱。该催化剂的MoO 3 / NiO重量比小于6至1且大于4重量％的NiO。催化剂特别适用于瓦斯油的同时加氢脱氮和加氢脱硫，特别是当难熔氧化物载体具有窄的孔径分布时。

39. 发明授权

US5494568A Hydrocarbon conversion process 失效
标题翻译：烃转化过程
公开(公告)号：US5494568A
公开(公告)日：1996-02-27
申请号：US381585
申请日：1995-01-31
申请人： Howard D. Simpson , Suheil F. Abdo
发明人： Howard D. Simpson , Suheil F. Abdo
IPC分类号： B01J23/85 , B01J23/883 , B01J27/188 , B01J27/19 , B01J37/02 , C10G45/08 , C10G49/04
CPC分类号： B01J35/002 , B01J23/85 , B01J23/883 , B01J27/188 , B01J27/19 , B01J37/0205 , C10G45/08 , C10G49/04
摘要： A catalyst containing an overlayer of a catalytic promoter on a porous refractory support containing an underbedded Group VIII metal-containing component. The catalyst is prepared by sequential incorporation of the Group VIII metal followed by the additional catalytic promoter component, usually a Group VIB metal, with the porous refractory oxide support. The catalyst has a MoO.sub.3 /NiO weight ratio less than 6 to 1 and more than 4 weight percent of NiO. The catalyst is especially useful for simultaneous hydrodenitrogenation and hydrodesulfurization of a gas oil, particularly when the refractory oxide support has a narrow pore size distribution.
摘要翻译：一种含有催化促进剂的覆盖层的催化剂，该催化剂载体包含含有第VIII族含金属的组分的多孔耐火载体。催化剂通过将第Ⅷ族金属随后加入另外的催化促进剂组分（通常为VIB族金属）与多孔难熔氧化物载体连续制备。该催化剂的MoO 3 / NiO重量比小于6至1且大于4重量％的NiO。催化剂特别适用于瓦斯油的同时加氢脱氮和加氢脱硫，特别是当难熔氧化物载体具有窄的孔径分布时。

40. 发明授权

US4923592A Nickel-containing hydrocracking catalyst and process 失效
标题翻译：含镍加氢裂化催化剂及工艺
公开(公告)号：US4923592A
公开(公告)日：1990-05-08
申请号：US279780
申请日：1988-12-05
申请人： Suheil F. Abdo
发明人： Suheil F. Abdo
IPC分类号： B01J29/072 , B01J29/08 , B01J29/14 , B01J29/76 , C10G47/02 , C10G47/20 , C10G49/04
CPC分类号： C10G47/20 , B01J29/072 , B01J29/084 , B01J29/146 , B01J29/76 , B01J2229/16
摘要： A process for producing a high octane gasoline from a hydrocarbon feedstock in which the feedstock is contacted in the presence of hydrogen under hydrocracking conditions, preferably ammonia-rich hydrocracking conditions, with a hydrocracking catalyst comprising at least one hydrogenation metal component in combination with a cracking component. The preferred cracking components are Y zeolites and the catalyst preferably contains a nickel hydrogenation metal component, particularly in an amount greater than 13 weight percent, calculated as NiO. The catalyst may also contain a Group VIB metal component, such as a molybdenum component, particularly in a mole ratio greater than about 2 to 1, calculated as NiO to Group VIB metal trioxide. It has been found that such a process produces gasoline fractions having substantially increased research and motor octane numbers.
摘要翻译：一种从烃原料生产高辛烷值汽油的方法，其中原料在氢气存在下在氢气存在下在加氢裂化条件下，优选富氨加氢裂化条件下与加氢裂化催化剂接触，加氢裂化催化剂包含至少一种氢化金属组分，零件。优选的裂化组分是Y沸石，催化剂优选包含镍加氢金属组分，特别是以NiO计，其量大于13重量％。催化剂还可以含有VIB族金属组分，例如钼组分，特别是摩尔比大于约2:1，以NiO与VIB族金属氧化物计算。已经发现，这种方法产生具有显着增加的研究和马达辛烷值的汽油馏分。

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