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31. 发明申请

US20080004418A1 Method of Preparing Polycarbonate 有权
标题翻译：聚碳酸酯的制备方法
公开(公告)号：US20080004418A1
公开(公告)日：2008-01-03
申请号：US11427885
申请日：2006-06-30
申请人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski
发明人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski
IPC分类号： C08G64/00
CPC分类号： C08G64/14 , C08G64/307
摘要： Polycarbonates incorporating terminal carbonate groups derived from ester-substituted activated carbonates in a transesterification process have unfavorable properties with respect to color, hydrolytic stability and thermal stability, particularly when the polycarbonate containing such end groups is molded. The number of activated carbonate end groups formed during the melt transesterification formation of polycarbonate can be reduced by reacting a dihydroxy compound with an activated diaryl carbonate in the presence of an esterification catalyst to produce a polycarbonate, in the presence of a monohydroxy chainstopper such as para-cumyl phenol in an amount that results in 35 to 65 mol % of the end groups being derived from the monohydroxy chainstopper. Suitably, the reactants are provided such that the molar ratio of activated diaryl carbonate to the total of dihydroxy compound plus ½ the chainstopping reagent that is less than 1.
摘要翻译：在酯交换方法中，衍生自酯取代的活性碳酸酯的末端碳酸酯基团的聚碳酸酯在颜色，水解稳定性和热稳定性方面具有不利的性质，特别是当含有这样的端基的聚碳酸酯被成型时。在聚碳酸酯的熔融酯交换形成期间形成的活化碳酸酯端基的数量可以通过在酯化催化剂的存在下使二羟基化合物与活化的碳酸二芳基酯反应来制备聚碳酸酯，在单羟基链断裂剂例如对 - 辛基苯酚，其量导致35-65mol％端基衍生自单羟基链断裂剂。适当地，提供反应物使得活化的碳酸二芳基酯与二羟基化合物的总和加上1/2的阻滞剂的摩尔比小于1。

32. 发明授权

US06870025B2 Method of polycarbonate preparation 有权
标题翻译：聚碳酸酯制备方法
公开(公告)号：US06870025B2
公开(公告)日：2005-03-22
申请号：US10326933
申请日：2002-12-23
申请人： Patrick Joseph McCloskey , Jan Pleun Lens , James Anthony Cella , Jan Henk Kamps , Kathryn Lynn Longley , Narayan Ramesh , Warren William Reilly , Paul Michael Smigelski, Jr. , Marc Brian Wisnudel
发明人： Patrick Joseph McCloskey , Jan Pleun Lens , James Anthony Cella , Jan Henk Kamps , Kathryn Lynn Longley , Narayan Ramesh , Warren William Reilly , Paul Michael Smigelski, Jr. , Marc Brian Wisnudel
IPC分类号： C08G63/64 , C08G64/00 , C08G64/04 , C08G64/14 , C08G64/30 , C08L23/00 , C08L67/00 , C08L69/00
CPC分类号： C08G63/64 , C08G64/04 , C08G64/14 , C08G64/307 , C08L23/00 , C08L67/00 , C08L69/00 , C08L69/005 , C08L2666/18 , C08L2666/06
摘要： Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4′-biphenol have been prepared by the melt reaction of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.
摘要翻译：含有低或不可检测水平的弗里斯重排产物并且包含衍生自间苯二酚，氢醌，甲基氢醌，双酚A和4,4'-联苯酚中的一种或多种的重复单元的聚碳酸酯已经通过一种或多种上述二羟基芳族化合物与酯取代的二芳基碳酸酯如碳酸双甲基水杨酸酯。低产量或在许多情况下，不可检测的是，在由高效催化剂体系获得的产品聚碳酸酯中发现了油炸产品重排产物的水平，该催化剂体系抑制了Fries反应，并且相对于类似物所需的温度使用较低的熔体聚合温度使用碳酸二苯酯的聚合反应

33. 发明授权

US06420512B1 Extrusion method for making polycarbonate 有权
标题翻译：制造聚碳酸酯的挤出方法
公开(公告)号：US06420512B1
公开(公告)日：2002-07-16
申请号：US09911439
申请日：2001-07-24
申请人： Patrick Joseph McCloskey , James Day , Paul Michael Smigelski , John Lester Maxam , John Aibangbee Osaheni
发明人： Patrick Joseph McCloskey , James Day , Paul Michael Smigelski , John Lester Maxam , John Aibangbee Osaheni
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： Extrusion of a mixture of an ester-substituted diaryl carbonate, such as bis-methyl salicyl carbonate, a dihydroxy aromatic compound such as bisphenol A and a transesterification catalyst such as tetrabutyl phosphonium acetate (TBPA) affords polycarbonate having a weight average molecular weight of greater than 20,000 Daltons. The extruder is equipped with one or more vacuum vents to remove by-product ester-substituted phenol. Similarly, a precursor polycarbonate having ester-substituted phenoxy endgroups, for example methyl salicyl endgroups, when subjected to extrusion affords a polycarbonate having a significantly increased molecular weight relative to the precursor polycarbonate. The reaction to form a higher molecular weight polycarbonate may be catalyzed by residual transesterification catalyst present in the precursor polycarbonate, or by a combination of any residual catalyst and an additional catalyst such as TBPA introduced in the extrusion step. Fries rearrangement products are not observed in the product polycarbonates.
摘要翻译：酯取代的碳酸二芳基酯如碳酸双甲酯，双酚A等二羟基芳族化合物和乙酸四丁基鏻（TBPA）等酯交换催化剂的混合物的挤出，得到重均分子量大的聚碳酸酯超过20,000道尔顿。挤出机配备有一个或多个真空通风口以除去副产物酯取代的苯酚。类似地，具有酯取代的苯氧基端基的前体聚碳酸酯，例如甲基水杨基端基，当进行挤出时，得到相对于前体聚碳酸酯具有显着增加的分子量的聚碳酸酯。形成较高分子量聚碳酸酯的反应可以通过存在于前体聚碳酸酯中的残留酯交换催化剂，或者通过任何残余催化剂和另外的催化剂如在挤出步骤中引入的TBPA的组合来催化。在产品聚碳酸酯中没有观察到薯条重排产物。

34. 发明授权

US06184334B2 Alkali metal salts of oxoacids of sulfur as polymerization catalysts 有权
标题翻译：硫的含氧酸的碱金属盐作为聚合催化剂
公开(公告)号：US06184334B2
公开(公告)日：2001-02-06
申请号：US09411274
申请日：1999-10-04
申请人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr.
发明人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr.
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： The present invention relates to a method for the preparation of polycarbonate comprising preparing a polycarbonate by a melt process by reacting a diphenol and a diaryl carbonate in the presence of a catalytically effective amount of one or more alkali metal salts of oxoacids of sulfur.
摘要翻译：本发明涉及一种制备聚碳酸酯的方法，包括通过在催化有效量的一种或多种含硫酸的硫酸的碱金属盐的存在下使二酚和碳酸二芳基酯通过熔融法制备聚碳酸酯。

35. 发明申请

US20120025172A1 ORGANIC LIGHT EMITTING DEVICE WITH OUTCOUPLING LAYER FOR IMPROVED LIGHT EXTRACTION 有权
标题翻译：有机发光装置，具有改进的光提取功能
公开(公告)号：US20120025172A1
公开(公告)日：2012-02-02
申请号：US12846236
申请日：2010-07-29
申请人： Paul Michael Smigelski, JR. , Joseph John Shiang
发明人： Paul Michael Smigelski, JR. , Joseph John Shiang
IPC分类号： H01L51/52
CPC分类号： H01L51/5268 , H01L2251/5369
摘要： An organic light emitting device comprises an outcoupling layer having relatively high aspect ratio nanowires imbedded within an optically thick transparent high optical index film. The incorporation of nanowires increases the optical index of a light emitting assembly and provides a means for extracting light from a light emitting assembly of the organic light emitting device.
摘要翻译：有机发光器件包括嵌入在光学厚的透明高光学折射率膜内的相对高的纵横比的纳米线的外耦合层。纳入线的并入增加了发光组件的光学折射率，并且提供了用于从有机发光器件的发光组件提取光的装置。

36. 发明申请

US20090215620A1 ENHANCED SECURITY OF OPTICAL ARTICLE 有权
标题翻译：光学文章的增强安全
公开(公告)号：US20090215620A1
公开(公告)日：2009-08-27
申请号：US12403739
申请日：2009-03-13
申请人： James Anthony Cella , David Gilles Gascoyne , Ben Purushotam Patel , Paul Michael Smigelski, JR. , James Mitchell White , Gregory Allen O'Neil , Andrea Jeannine Peters , Matthew Jeremiah Misner , Trevor James Dale , Whitney Jeanne Olson , Marc Brian Wisnudel
发明人： James Anthony Cella , David Gilles Gascoyne , Ben Purushotam Patel , Paul Michael Smigelski, JR. , James Mitchell White , Gregory Allen O'Neil , Andrea Jeannine Peters , Matthew Jeremiah Misner , Trevor James Dale , Whitney Jeanne Olson , Marc Brian Wisnudel
IPC分类号： B41M5/24
CPC分类号： C09D11/50 , G11B23/0042 , G11B23/284
摘要： An optical article comprising a primary mark disposed on the optical article and a secondary mark disposed on the optical article in close proximity to the primary mark. The primary mark comprises a first optical-state change material and the secondary mark comprises a second optical-state change material. The optical article is transformed from a pre-activated state to an activated state when a localized authorized activation method is used that selectively activates the primary mark. The optical article is transformed from a pre-activated state to an deactivated state when a non-localized unauthorized activation method is used that activates the secondary mark along with the primary mark resulting in the second optical-state change material undergoing a reverse color change when compared to the first optical-state change material. An optical article with a single mark including multiple color change optical-state change material is also disclosed. Methods of covering and encapsulating the marks are also disclosed.
摘要翻译：一种光学制品，包括设置在光学制品上的初级标记，以及设置在光学制品上靠近初级标记的次级标记。主标记包括第一光学状态变化材料，第二标记包括第二光学状态变化材料。当使用选择性地激活主标记的局部授权的激活方法时，光学制品从预激活状态转变为激活状态。当使用非局部未授权的激活方法时，将光学物品从预激活状态转变为去激活状态，该非激活状态激活辅助标记连同主标记，导致第二光学状态变化材料经历反向颜色变化，当与第一种光学状态变化材料相比。还公开了具有包括多个变色光学变化材料的单个标记的光学制品。还公开了覆盖和封装标记的方法。

37. 发明申请

US20080004417A1 Polycarbonates and method of preparing same 有权
标题翻译：聚碳酸酯及其制备方法
公开(公告)号：US20080004417A1
公开(公告)日：2008-01-03
申请号：US11427861
申请日：2006-06-30
申请人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski
发明人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski
IPC分类号： C08G64/00
CPC分类号： C08G64/307 , C08G64/04
摘要： Polycarbonates incorporating terminal carbonate groups derived from ester-substituted activated carbonates, for example terminal methyl salicyl carbonate (TMSC) derived from the use of BMSC as the activated carbonate in a transesterification process, have unfavorable properties with respect to color, hydrolytic stability and thermal stability, particularly when the polycarbonate containing such end groups is molded. The number of activated carbonate end groups formed during the melt transesterification formation of polycarbonate can be reduced, however, without sacrificing the benefits of using an activated diaryl carbonate, and without requiring a separate reaction or additional additives by reacting a dihydroxy compound with an activated diaryl carbonate in the presence of an esterification catalyst to produce a polycarbonate, wherein the molar ratio of activated diaryl carbonate to dihydroxy compound is less than 1 when expressed to at least three decimal places, for example 0.996 or less.
摘要翻译：由酯取代的活性碳酸酯衍生的末端碳酸酯基团的聚碳酸酯，例如在酯交换法中使用BMSC作为活性碳酸酯的末端甲基水杨酸碳酸酯（TMSC）在颜色，水解稳定性和热稳定性方面具有不利的性质特别是当含有这种端基的聚碳酸酯被模制时。然而，在聚碳酸酯的熔融酯交换形成期间形成的活化碳酸酯端基的数量可以降低，但不会牺牲使用活性碳酸二芳基酯的优点，并且不需要单独的反应或另外的添加剂，通过使二羟基化合物与活化的二芳基在酯化催化剂存在下制备碳酸酯以制备聚碳酸酯，其中活化的碳酸二芳酯与二羟基化合物的摩尔比当表示至少三位小数，例如0.996或更小时小于1。

38. 发明授权

US07115700B2 Method of polycarbonate preparation 有权
公开(公告)号：US07115700B2
公开(公告)日：2006-10-03
申请号：US11133827
申请日：2005-05-19
申请人： James Anthony Cella , Jan Henk Kamps , Jan Pleun Lens , Kathryn Lynn Longley , Patrick Joseph McCloskey , Narayan Ramesh , Warren William Reilly , Paul Michael Smigelski, Jr. , Marc Brian Wisnudel
发明人： James Anthony Cella , Jan Henk Kamps , Jan Pleun Lens , Kathryn Lynn Longley , Patrick Joseph McCloskey , Narayan Ramesh , Warren William Reilly , Paul Michael Smigelski, Jr. , Marc Brian Wisnudel
IPC分类号： C08G63/00
CPC分类号： C08G63/64 , C08G64/04 , C08G64/14 , C08G64/307 , C08L23/00 , C08L67/00 , C08L69/00 , C08L69/005 , C08L2666/18 , C08L2666/06
摘要： Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4′-biphenol have been prepared by the melt reaction of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.

39. 发明授权

US06960641B2 Method of making block copolymers by solid state polymerization 有权
标题翻译：通过固态聚合制备嵌段共聚物的方法
公开(公告)号：US06960641B2
公开(公告)日：2005-11-01
申请号：US10743241
申请日：2003-12-22
申请人： Gregory Allen O'Neil , James Day , Daniel Joseph Brunelle , Joseph Anthony Suriano , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr.
发明人： Gregory Allen O'Neil , James Day , Daniel Joseph Brunelle , Joseph Anthony Suriano , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr.
IPC分类号： C08G81/00 , C08G63/64 , C08G63/80 , C08G64/00
CPC分类号： C08G63/64 , C08G63/80
摘要： A method of preparing block copolymers by solid state polymerization is described. A mixture of a partially crystalline polycarbonate having activated terminal aryloxy groups, for example terminal methyl salicyl groups, when heated together with an oligomeric polyester having reactive terminal hydroxy groups under solid state polymerization conditions affords block copolymers. The activated terminal aryloxy groups play a key role in preserving the block lengths of the starting materials. A control sample in which the partially crystalline polycarbonate lacks activated terminal aryloxy groups, for example polycarbonates substituted by phenol, affords a much lower molecular weight, more highly randomized copolymer product. The product block copolymers are useful as “weatherable” plastic materials.
摘要翻译：描述了通过固态聚合制备嵌段共聚物的方法。当在固态聚合条件下与具有反应性末端羟基的低聚聚酯一起加热时，具有活化的末端芳氧基的部分结晶的聚碳酸酯，例如末端甲基水杨酸酯的混合物得到嵌段共聚物。活化的末端芳氧基在保留原料的块长度方面起关键作用。其中部分结晶聚碳酸酯缺乏活化的末端芳氧基的对照样品，例如被苯酚取代的聚碳酸酯，得到低得多的分子量，更高度随机的共聚物产物。产品嵌段共聚物可用作“耐候性”塑料材料。

40. 发明授权

US06790929B2 Method for making an aromatic polycarbonate 有权
标题翻译：制备芳族聚碳酸酯的方法
公开(公告)号：US06790929B2
公开(公告)日：2004-09-14
申请号：US10389009
申请日：2003-03-17
申请人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
发明人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
IPC分类号： C08G6400
CPC分类号： B29C47/0004 , B29C47/0009 , B29C47/60 , B29C47/76 , B29C47/767 , B29C67/246 , B29K2069/00 , C08G64/081 , C08G64/14 , C08G64/205 , C08G64/307
摘要： This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising ester-substituted phenoxy terminal groups.
摘要翻译：本发明涉及从低聚聚碳酸酯溶液制备聚碳酸酯的挤压方法。首先在中等温度下平衡双（甲基水杨酸）碳酸酯（BMSC），BPA和酯交换催化剂的混合物，以提供聚碳酸酯低聚物在水杨酸甲酯中的溶液。然后将溶液进料到脱挥发分挤出机中，其中聚合反应完成并除去水杨酸甲酯溶剂。包含低聚物聚碳酸酯的溶液也可以在压力下预加热到高于水杨酸甲酯沸点的温度，随后进料到脱挥发分的挤出机中，以便迅速地从溶剂中闪蒸。该方法提供聚碳酸酯比未反应的单体进料到挤出机的相应方法具有更高的效率。另外，本发明的方法不需要分离包含酯取代的苯氧基末端基团的前体聚碳酸酯。

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