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31. 发明申请

US20160229799A1 PROCESS FOR OBTAINING METHIONINE 有权
标题翻译：获得甲磺酸的方法
公开(公告)号：US20160229799A1
公开(公告)日：2016-08-11
申请号：US15021541
申请日：2014-09-10
申请人： Stefan REICHERT , Harald JAKOB , Hans Joachim HASSELBACH , Martin KÖRFER
发明人： Stefan REICHERT , Harald JAKOB , Hans Joachim HASSELBACH , Martin KOERFER
IPC分类号： C07C321/14
CPC分类号： C07C321/14 , C07B2200/13 , C07C319/20 , C07C319/26 , C07C319/28 , C07C323/58
摘要： The invention relates to a method for crystallizing D,L-methionine from aqueous solutions and/or suspensions containing D,L-methionine and D,L-methionine ammonium salts, having a Met content of 70-180 g/kg, an NH4+ content of 1-5 g/kg, in the presence of a crystallization additive, which comprises a nonionic or anionic surfactant or a mixture of various nonionic or anionic surfactants, in which the temperature of the solution and/or suspension is lowered directly or stepwise from T1=85-110° C. to T2=30-50° C., so that D,L-methionine precipitates as a solid.
摘要翻译：本发明涉及从含有D，L-甲硫氨酸和D，L-甲硫氨酸铵盐的水溶液和/或悬浮液中结晶D，L-甲硫氨酸的方法，其Met含量为70-180g / kg，NH4 +含量在结晶添加剂存在下，其包含非离子或阴离子表面活性剂或各种非离子或阴离子表面活性剂的混合物，其中溶液和/或悬浮液的温度直接或逐步从 T1 = 85-110℃至T2 = 30-50℃，因此D，L-甲硫氨酸作为固体沉淀。

32. 发明授权

US09029597B2 Method for the conversion of methylmercaptopropionaldehyde formed from crude acrolein and crude methyl mercaptan 有权
标题翻译：由粗丙烯醛和粗甲硫醇形成的甲基巯基丙醛的转化方法
公开(公告)号：US09029597B2
公开(公告)日：2015-05-12
申请号：US13597852
申请日：2012-08-29
申请人： Martin Steffan , Hans Joachim Hasselbach , Martin Koerfer , Harald Jakob , Jignesh Gangadwala
发明人： Martin Steffan , Hans Joachim Hasselbach , Martin Koerfer , Harald Jakob , Jignesh Gangadwala
IPC分类号： C07C319/12 , C07C319/20 , C07C319/28
CPC分类号： C07C319/12 , C07C319/20 , C07C319/28 , Y02P20/127 , C07C323/58
摘要： A reactive rectification column suitable for the production of 2-hydroxy-4-methylmercaptobutyric acid and/or methionine contains a weir having a height of 100 mm or more.
摘要翻译：适合于生产2-羟基-4-甲基巯基丁酸和/或甲硫氨酸的反应性精馏塔含有高度为100mm以上的堰。

33. 发明申请

US20140213819A1 METHOD FOR THE PRODUCTION OF 2-HYDROXY-4-(METHYLTHIO)BUTYRONITRILE FROM 3-(METHYLTHIO)PROPANAL AND HYDROGEN CYANIDE 有权
标题翻译：从3-（甲基）丙醛和氢氰化物生产2-羟基-4-（甲基）苯并呋喃的方法
公开(公告)号：US20140213819A1
公开(公告)日：2014-07-31
申请号：US14227418
申请日：2014-03-27
申请人： Dieter BUSS , Martin STEURENTHALER , Michael R. RINNER , Stephan KRETZ , Hans Joachim HASSELBACH , Caspar-Heinrich FINKELDEI , Martin KOERFER , Pablo ZACCHI
发明人： Dieter BUSS , Martin STEURENTHALER , Michael R. RINNER , Stephan KRETZ , Hans Joachim HASSELBACH , Caspar-Heinrich FINKELDEI , Martin KOERFER , Pablo ZACCHI
IPC分类号： C07C319/20
CPC分类号： C07C319/20 , C07C323/60 , C07C323/58 , C07C323/52
摘要： A method for the production of 2-hydroxy-4-(methylthio)butyronitrile having good storage stability in a multi-zone reactor, is provided. 3-methylmercaptopropionaldehyde is reacted with hydrogen cyanide in the presence of a base as catalyst in a main reaction zone of the multizone reactor to form a reaction mixture comprising the 2-hydroxy-4-(methylthio)butyronitrile, unreacted 3-methylmercaptopropionaldehyde, the catalyst and residual amounts of gaseous hydrogen cyanide. The residual gaseous hydrogen cyanide is removed from the main reaction zone to an absorption and post-reaction zone of the reactor which comprises a mixture of 3-methylmercaptopropionaldehyde and the catalyst; and the gaseous hydrogen cyanide is further reacted with the 3-methylmercaptopropionaldehyde in the absorption and post reaction zone. A molar ratio of hydrogen cyanide to 3-(methylthio)propanal in the main reaction zone is from 0.98 to 1.03.
摘要翻译：提供了一种在多区域反应器中制备具有良好储存稳定性的2-羟基-4-（甲硫基）丁腈的方法。在多基团反应器的主反应区中，3-甲基巯基丙醛与作为催化剂的碱存在下，与氰化氢反应形成包含2-羟基-4-（甲硫基）丁腈，未反应的3-甲基巯基丙醛，催化剂和残留量的氰化氢气体。将残留的气态氰化氢从主反应区移除到包含3-甲基巯基丙醛和催化剂的混合物的反应器的吸收和后反应区域; 并且氰化氢气体在吸收和后反应区域中与3-甲基巯基丙醛进一步反应。主反应区氰化氢与3-（甲硫基）丙醛的摩尔比为0.98-1.03。

34. 发明申请

US20130245318A1 METHOD FOR THE CONVERSION OF METHYLMERCAPTOPROPIONALDEHYDE FORMED FROM CRUDE ACROLEIN AND CRUDE METHYL MERCAPTAN 有权
标题翻译：甲基麦芽糖衍生物由赤藓糖醇和甲基丙烯酸甲酯形成的转化方法
公开(公告)号：US20130245318A1
公开(公告)日：2013-09-19
申请号：US13597852
申请日：2012-08-29
申请人： Martin Steffan , Hans Joachim Hasselbach , Martin Koerfer , Harald Jakob , Jignesh Gangadwala
发明人： Martin Steffan , Hans Joachim Hasselbach , Martin Koerfer , Harald Jakob , Jignesh Gangadwala
IPC分类号： C07C319/12
CPC分类号： C07C319/12 , C07C319/20 , C07C319/28 , Y02P20/127 , C07C323/58
摘要： A reactive rectification column suitable for the production of 2-hydroxy-4-methylmercaptobutyric acid and/or methionine contains a weir having a height of 100 mm or more.
摘要翻译：适合于生产2-羟基-4-甲基巯基丁酸和/或甲硫氨酸的反应性精馏塔含有高度为100mm以上的堰。

35. 发明申请

US20120215021A1 STORAGE-STABLE 2-HYDROXY-4-(METHYLTHIO)BUTYRONITRILE 有权
标题翻译：储存稳定的2-羟基-4-（甲基）恶唑烷酮
公开(公告)号：US20120215021A1
公开(公告)日：2012-08-23
申请号：US13402032
申请日：2012-02-22
申请人： Dieter Buss , Martin Steurenthaler , Hans Joachim Hasselbach , Michael R. Rinner , Benjamin Fonfe , Martin Koerfer , Stephan Kretz
发明人： Dieter Buss , Martin Steurenthaler , Hans Joachim Hasselbach , Michael R. Rinner , Benjamin Fonfe , Martin Koerfer , Stephan Kretz
IPC分类号： C07C321/14 , C07C319/20
CPC分类号： C07C319/20 , C07C319/26 , C07C323/60 , C07C323/58 , C07C323/52
摘要： A storage stable mixture containing 86 to 97% by weight of 2-hydroxy-4-methylthiobutyronitrile, 2 to 14% by weight of water, 0.05 to 0.5% by weight of HCN and having a pH of 1 to 4, measured using a pH electrode at 23° C. is provided. A method to produce the storage stable mixture and its use in manufacture of DL-methionine or 2-hydroxy-4-methylthiobutyric acid is also provided.
摘要翻译：含有86-97重量％的2-羟基-4-甲基硫代丁腈，2-14重量％的水，0.05-0.5重量％的HCN和pH为1-4的储存稳定的混合物，使用pH 提供23℃的电极。还提供了制备储存稳定混合物的方法及其在制备DL-甲硫氨酸或2-羟基-4-甲硫基丁酸中的用途。

36. 发明授权

US07833508B2 Reaction vessel and process for its use 有权
标题翻译：反应容器及其使用方法
公开(公告)号：US07833508B2
公开(公告)日：2010-11-16
申请号：US12501114
申请日：2009-07-10
申请人： Hubert Redlingshöfer , Jan-Olaf Barth , Caspar-Heinrich Finkeldei , Hans Joachim Hasselbach , Stephan Kretz , Harald Heinzel , Christoph Weckbecker
发明人： Hubert Redlingshöfer , Jan-Olaf Barth , Caspar-Heinrich Finkeldei , Hans Joachim Hasselbach , Stephan Kretz , Harald Heinzel , Christoph Weckbecker
IPC分类号： B01J10/00 , C01B17/16
CPC分类号： B01J8/025 , B01J10/005 , B01J19/246 , C01B17/162
摘要： The invention relates to a reaction vessel in which hydrogen sulphide is prepared from sulphur and hydrogen, wherein the reaction vessel consists partly or entirely of a material which is resistant to the reaction mixture, its compounds or elements and retains its resistance even at high temperatures.
摘要翻译：本发明涉及一种其中由硫和氢制备硫化氢的反应容器，其中反应容器部分或全部由对反应混合物，其化合物或元素具有抗性并且甚至在高温下也保持其电阻的材料组成。

37. 发明申请

US20100015037A1 REACTION VESSEL AND PROCESS FOR ITS USE 有权
标题翻译：反应容器及其使用方法
公开(公告)号：US20100015037A1
公开(公告)日：2010-01-21
申请号：US12501114
申请日：2009-07-10
申请人： Hurbert Redlingshöfer , Jan-Olaf Barth , Caspar-Heinrich Finkeldei , Hans Joachim Hasselbach , Stephan Kretz , Harald Heinzel , Christoph Weckbecker
发明人： Hurbert Redlingshöfer , Jan-Olaf Barth , Caspar-Heinrich Finkeldei , Hans Joachim Hasselbach , Stephan Kretz , Harald Heinzel , Christoph Weckbecker
IPC分类号： C01B17/16 , B01J7/00
CPC分类号： B01J8/025 , B01J10/005 , B01J19/246 , C01B17/162
摘要： The invention relates to a reaction vessel in which hydrogen sulphide is prepared from sulphur and hydrogen, wherein the reaction vessel consists partly or entirely of a material which is resistant to the reaction mixture, its compounds or elements and retains its resistance even at high temperatures.
摘要翻译：本发明涉及一种其中由硫和氢制备硫化氢的反应容器，其中反应容器部分或全部由对反应混合物，其化合物或元素具有抗性并且甚至在高温下也保持其电阻的材料组成。

38. 发明授权

US07119228B2 Process for producing methionine 有权
标题翻译：生产甲硫氨酸的方法
公开(公告)号：US07119228B2
公开(公告)日：2006-10-10
申请号：US11054424
申请日：2005-02-10
申请人： Dieter Buss , Ron Stockfleth , Martin Körfer , Jürgen Stock , Ralf Goedecke , Hans-Joachim Hasselbach , Gundolf Hornung
发明人： Dieter Buss , Ron Stockfleth , Martin Körfer , Jürgen Stock , Ralf Goedecke , Hans-Joachim Hasselbach , Gundolf Hornung
IPC分类号： C07C51/00
CPC分类号： C07C319/28 , C07C319/20 , C07C323/58
摘要： The present invention is directed to an improved process for producing methionine in which the by-product methionyl-methionine is quickly converted to the product methionine by a hydrolysis reaction. The process is performed at high temperatures (200° C. to 280° C.) and short residence times (20 s to 200 s) and results in an improved yield of end product methionine.
摘要翻译：本发明涉及一种生产甲硫氨酸的改进方法，其中副产物甲硫氨酰 - 甲硫氨酸通过水解反应快速转化为产物甲硫氨酸。该过程在高温（200℃至280℃）和短停留时间（20秒至200秒）下进行，并导致最终产物甲硫氨酸的产率提高。

39. 发明授权

US06265617B1 Process for the preparation of 3,5,5-trimethylcyclohexa-3-en-1-one (&bgr;-isophorone) by isomerization of 3,5,5- trimethylcyclohexa-2-en-1-one (&agr;-isophorone) 失效
标题翻译：通过3,5,5-三甲基环己-2-烯-1-酮（α-异佛尔酮）的异构化制备3,5,5-三甲基环己-3-烯-1-酮（β-异佛尔酮）的方法
公开(公告)号：US06265617B1
公开(公告)日：2001-07-24
申请号：US09310971
申请日：1999-05-13
申请人： Steffen Krill , Stephan Kretz , Hans-Joachim Hasselbach , Klaus Huthmacher , Rainer Hahn , Hermann Schmitt
发明人： Steffen Krill , Stephan Kretz , Hans-Joachim Hasselbach , Klaus Huthmacher , Rainer Hahn , Hermann Schmitt
IPC分类号： C07C4500
CPC分类号： C07C45/67 , C07C45/82 , C07C49/603
摘要： A process for the preparation of 3,5,5-trimethylcyclohexa-3-en-1-one (&bgr;-isophorone) by isomerization of 3,5,5-trimethylcyclohexa-2-en-1-one (&agr;-isophorone) in the liquid phase in the presence of a salt-like or organometallic catalyst. By using catalytic quantities of alkali-metal salts or alkaline-earth salts and/or their organometallic compounds, and without addition of a further auxiliary substance, the space-time yield in the preparation of &bgr;-isophorone is high. &bgr;-Isophorone is particularly suitable as an intermediate product for the preparation of ketoisophorone.
摘要翻译：通过3,5,5-三甲基环己-2-烯-1-酮（α-异佛尔酮）异构化制备3,5,5-三甲基环己-3-烯-1-酮（β-异佛尔酮）的方法在盐状或有机金属催化剂存在下的液相。通过使用催化量的碱金属盐或碱土金属盐和/或其有机金属化合物，并且不加入另外的辅助物质，β-异佛尔酮的制备中的时空产率高。 β-异佛尔酮特别适合用作制备酮异二酮的中间产物。

40. 发明授权

US6140536A Process for obtaining 2-hydroxy-4-methylthiobutyric acid (MHA) 有权
标题翻译：获得2-羟基-4-甲硫基丁酸（MHA）的方法
公开(公告)号：US6140536A
公开(公告)日：2000-10-31
申请号：US91796
申请日：1998-09-01
申请人： Hans Albrecht Hasseberg , Hans Joachim Hasselbach , Klaus Huthmacher , Volker Hafner , Harald Heinzel , Barbara Jager
发明人： Hans Albrecht Hasseberg , Hans Joachim Hasselbach , Klaus Huthmacher , Volker Hafner , Harald Heinzel , Barbara Jager
IPC分类号： C07C319/20 , C07C319/28 , C07C323/52 , C07C315/00
CPC分类号： C07C319/28 , C07C319/20
摘要： A method for the isolation of 2-hydroxy-4-methylthiobutyric acid (MHA), wherein MHA is isolated from a reaction mixture obtained by addition of hydrogen cyanide (HCN) to methylmercaptopropionaldehyde (MMP) and hydrolysis by sulphuric acid of the methylmercaptopropionaldehyde cyanohydrin (MMP-CH) thus obtained. The reaction mixture is brought into contact in a liquid/liquid extraction system with an organic solvent substantially immiscible with water, in order to form an extraction solution which contains the solvent and the MHA transferred out of the reaction mixture. By bringing the salt content of the reaction mixture, prior to the liquid/liquid extraction, to a concentration of about >50 wt. % (wt./wt.), preferably >55 wt. %, referred to the sum of the inorganic constituents of the reaction mixture, the coordinated use of energy in the total system is improved, the evaporation of strongly corrosive solutions is avoided, the efficiency of the hydrolysis step is increased and the distribution coefficients during the extraction are improved. The MHA is isolated as the extract from this extraction solution by evaporation, and may be used as animal feed supplement.
摘要翻译： PCT No.PCT / EP96 / 05437 Sec。 371日期：1998年9月1日 102（e）1998年9月1日PCT PCT 1996年12月5日PCT公布。公开号WO97 / 23452 日期1997年7月3日分离2-羟基-4-甲硫基丁酸（MHA）的方法，其中MHA是通过将氰化氢（HCN）加入到甲基巯基丙醛（MMP）中并通过硫酸水解而获得的反应混合物中分离的的甲基巯基丙醛氰醇（MMP-CH）。使反应混合物在液/液萃取系统中与基本上与水不混溶的有机溶剂接触，以形成含有溶剂和从反应混合物中转移的MHA的萃取溶液。通过使液体/液体萃取之前的反应混合物的盐含量达到约> 50wt。％（重量/重量），优选> 55重量％％，是指反应混合物的无机成分之和，改善了总体系中能量的协调使用，避免了强腐蚀性溶液的蒸发，提高了水解步骤的效率，提高了分散系数提取提高。通过蒸发将MHA作为来自该提取溶液的提取物分离，并且可以用作动物饲料添加剂。

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