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    • 38. 发明申请
    • PROCESS FOR PRODUCING MODIFIED RUBBER MOULDING MATERIALS FROM REACTION MIXTURES CONTAINING DERIVATIVES OF ACRYLAMIDES OR METHACRYLAMIDES
    • 工艺生产含有反应混合物中的丙烯酰胺衍生物和甲基丙烯酰胺的橡胶改性模塑料
    • WO1996015168A1
    • 1996-05-23
    • PCT/EP1995004477
    • 1995-11-14
    • BASF AKTIENGESELLSCHAFTMC KEE, Graham, EdmundGAUSEPOHL, HermannROSENAU, BernhardHECKMANN, Walter
    • BASF AKTIENGESELLSCHAFT
    • C08F265/04
    • C08F265/04C08L51/06C08L2666/04
    • In a process for producing modified rubber moulding materials, a first mixture (A) that contains at least one alkyl acrylate or methacrylate (a) having the general formula (I), in which R stands for a hydrogen atom or a methyl group and R stands for an alkyl group with 1 to 32 carbon atoms, a compound (b) having the general formula (II), in which R stands for a hydrogen atom or a methyl group, R stands for a hydrogen atom or an alkyl group with 1 to 8 carbon atoms, R stands for a hydrogen atom or a methyl group and R stands for a hydrogen atom, an alkyl group with 1 to 10 carbon atoms, preferably hydrogen, and optionally a first or several other monomers (c), is polymerised together with free radicals into a rubber (B). In a second step, the thus obtained rubber (B) is mixed with a second or several other monomers (d), preferably dissolved or swollen therein, to form a second mixture (C). In a third step, the second mixture (C) is polymerised together with free radicals into the modified rubber moulding material (D).
    • 在用于制备橡胶改性的模制组合物的方法是在第一阶段中,包括至少一种丙烯酸烷基酯或甲基丙烯酸酯的第一混合物(A)的(a)通式(I)中R <1>是一个氢原子或一个甲基,R的 <2>表示具有1至32个碳原子的化合物的烷基(b)中的通式(II)其中R <3>是氢原子或甲基,R <4>是氢原子或具有1至烷基 8个碳原子,R <5>是一个氢原子或一个甲基,R <6>表示氢原子,碳原子数1〜10,优选为氢,并且如果需要的第一单体(c)或更多的烷基,具有 自由基,得到的橡胶(B)聚合,在第二阶段中,将得到的橡胶(B),以形成与第二单体(d)的第二混合物(C)以上的混合,优选溶解或在此溶胀,和在一个 第三阶段中,混合(C)与自由基,得到橡胶改性的模制材料(D)之后,形成第二聚合混合物。