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    • 36. 发明授权
    • Finely divided isometric hexaferrite pigments with a W-structure,
processes for their preparation and their use
    • 具有W结构的细分等轴六方晶系颜料,其制备方法及其用途
    • US4773938A
    • 1988-09-27
    • US918574
    • 1986-10-14
    • Gunter BuxbaumUlrich MeisenFlorian Haberey
    • Gunter BuxbaumUlrich MeisenFlorian Haberey
    • C01G49/00C04B35/26C09C1/22C09C1/24G11B5/706H01F1/11C04B14/00
    • C04B35/2608C01G49/009C04B35/2633C09C1/22G11B5/70678C01P2002/32C01P2004/03C01P2004/20C01P2004/54C01P2006/42
    • Finely divided magnetic particles of hexaferrite pigments with a W-structure having the compositionE.sub.x M.sub.m (I) M.sub.n (II) Fe.sub.18 -(m+n)O.sub.27-y D.sub.ywhereinE is at least one element from the group comprising alkaline earth metals, alkali metals, lanthanides or lead,M(I) and M(II) are independently at least element from the group comprising metals or semi-metals andD is at least one element from the group of halogens and chalcogens and0.8.ltoreq.x.ltoreq.1.2,1.0.ltoreq.m.ltoreq.3.0,0.ltoreq.n.ltoreq.8.0,0.ltoreq.y.ltoreq.5.0 andn is the same as y when n>0with the proviso that electroneutrality is preserved,and wherein the hexaferrite pigment particles have substantially the same dimensions in all directions in space are useful in producing magnetic recording media, such as tapes, and are produced by melting a mixture of (=i) metal oxides, hydroxides, hydroxyoxides, carbonates, nitrates or mixtures thereof corresponding to the composition of the W-hexaferrite pigments together with (ii) boron oxide, boric acid, metal borates, SiO.sub.2 or mixtures thereof at temperatures of from 1100.degree. to 1450.degree. C. and then chilling the melt obtained to .ltoreq.600.degree. C. and then tempering the chilled melt at temperatures of from 1000.degree. to 1400.degree. C. for 1 second to 2 hours.
    • 具有组成为Ex Mm(I)Mn(II)Fe18-(m + n)O27-yDy的W结构的六方晶系颜料的细分磁性颗粒,其中E是至少一种元素,包括碱土金属,碱 金属,镧系元素或铅,M(I)和M(II)独立地是至少包含金属或半金属的元素,D是来自卤素和硫属元素的至少一种元素, 当n> 0时,n与y相同,条件是电中性是(i = 0)= 1.0, 并且其中六方晶系颜料颗粒在空间中在所有方向上具有基本相同的尺寸可用于制造磁记录介质,例如带,并且通过熔融(= i)金属氧化物,氢氧化物,羟基氧化物,碳酸酯的混合物 ,硝酸盐或其混合物,其与W-六铁素体颜料的组成以及(ii)氧化硼,硼酸,金属硼酸盐,SiO 2或其混合物,然后将所获得的熔体冷却至600℃,然后在1000-1400℃的温度下回火冷却的熔体1秒至 2小时。