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    • 32. 发明申请
    • AROMATIC ALKYLATION PROCESS WITH DIRECT RECYCLE
    • 具有直接回归的芳香烷基化方法
    • WO2004062782A2
    • 2004-07-29
    • PCT/US2004/000058
    • 2004-01-06
    • FINA TECHNOLOGY, INC.BUTLER, James, R.MERRILL, JamesKELLY, Kevin
    • BUTLER, James, R.MERRILL, JamesKELLY, Kevin
    • B01J
    • C07C15/073C07C2/66C07C6/126C07C2529/06C07C2529/70Y02P20/544Y02P20/582Y02P20/584
    • Process for the alkylation of an aromatic substrate with partial recycling of the alkylated product. A feedstock comprising an aromatic substrate and an alkylating agent is introduced into an alkylation reaction zone and into contact with a molecular sieve catalyst to produce an alkylation product which is withdrawn from the alkylation reaction zone and split into two portions. A first portion is recycled back to the alkylation reaction zone and supplied to the alkylation zone. A second portion is supplied to a suitable recovery zone for the separation of alkylated aromatic components from the unreacted aromatic substrate. The alkylation reaction zone may be operated under conditions in which the aromatic substrate is in the supercritical phase, and may comprise a plurality of catalyst beds wherein the recycled portion of the alkylation reaction product is subdivided into subproducts with one subproduct recycled to the inlet of the alkylation reaction zone and another subproduct introduced into the alkylation reaction zone between catalyst beds.
    • 烷基化产物的部分再循环烷基化方法。 将包含芳族底物和烷基化剂的原料引入烷基化反应区并与分子筛催化剂接触以产生从烷基化反应区取出并分成两部分的烷基化产物。 将第一部分循环回到烷基化反应区并供给至烷基化区。 将第二部分供应到合适的回收区,用于将烷基化芳族组分与未反应的芳族底物分离。 烷基化反应区可以在芳族底物处于超临界阶段的条件下操作,并且可以包括多个催化剂床,其中烷基化反应产物的再循环部分被再分成副产物,其中一个副产物被再循环到 烷基化反应区和引入催化剂床之间的烷基化反应区的另一个副产物。