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    • 29. 发明专利
    • DE1583863B2
    • 1972-03-02
    • DE1583863
    • 1967-10-17
    • C01G31/04C22B34/22C22B55/00
    • 1,142,054. Vanadium, tungsten, molybdenum and niobium chlorides. BRITISH TITAN PRODUCTS CO. Ltd. 4 Oct., 1967 [17 Oct., 1966], No. 46412/66. Heading C1A. Vanadium is recovered from vanadium containing solids by suspending the solids in a liquid which dissolves chlorine and treating with chlorine under superatmospheric pressure to produce vanadium chloride, e.g. as oxychloride. Preferred pressures are 5 to 250 p.s.i.g. and preferred temperatures are 20 to 250‹ C. The solids may be 5 to 60% by weight of the suspension. The process is especially suitable for recovering vanadium from titanium containing sludge from the purification of TiCl 4 with mineral oil. The preferred liquid for the process is TiCl 4 . Tungsten, molybdenum and niobium, if present, may also be recovered as chlorides.