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21. 发明授权

US06743745B2 Process for production of molecular sieve adsorbent blends 有权
标题翻译：生产分子筛吸附剂混合物的方法
公开(公告)号：US06743745B2
公开(公告)日：2004-06-01
申请号：US10054041
申请日：2002-01-22
申请人： Dave Jaussaud , Kerry Weston , Armin Pfenninger , Beat Kleeb
发明人： Dave Jaussaud , Kerry Weston , Armin Pfenninger , Beat Kleeb
IPC分类号： B01J2906
CPC分类号： B01D53/02 , B01D2253/108 , B01J20/183 , B01J20/30 , Y02C10/08
摘要： A process for the production of a molecular sieve adsorbent blend product with improved performance characteristics produced by preparing a zeolite powder, preparing a highly dispersed attapulgite fiber binder, mixing the zeolite powder with the highly dispersed attapulgite binder to form a mixture, forming molecular sieve adsorbent products into a shaped material and calcining the shaped material, wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml.
摘要翻译：一种生产分子筛吸附剂共混产物的方法，其具有通过制备沸石粉末，制备高度分散的绿坡缕石纤维粘合剂，混合沸石粉末与高度分散的绿坡缕石粘合剂形成混合物而形成的改进的性能特征，形成分子筛吸附剂产品成型成型材料并煅烧成型材料，其中根据DIN / ISO 787测量的高度分散的绿坡缕石纤维的攻丝松密度大于约550g / ml。

22. 发明授权

US06734323B2 Process for the preparation of zeolitic catalysts 有权
标题翻译：沸石催化剂的制备方法
公开(公告)号：US06734323B2
公开(公告)日：2004-05-11
申请号：US09725292
申请日：2000-11-29
申请人： Giuseppe Botti , Angela Carati , Leonardo Dalloro
发明人： Giuseppe Botti , Angela Carati , Leonardo Dalloro
IPC分类号： B01J2906
CPC分类号： C01B37/00 , B01J29/40 , B01J29/89 , B01J35/08 , B01J37/0045 , B01J37/0072 , B01J37/0219 , C01B39/026 , C07C231/10
摘要： The present invention relates to a process for the preparation of zeolitic catalysts comprising zeolite and oligomeric silica, which can be used in industrial reactors. The process consists in directly mixing the suspension, resulting from the synthesis of the zeolite, with an oligomeric silica sol, obtained from the hydrolysis of a tetra-alkyl ortho silicate in the presence of tetra-alkylammonium hydroxide, and in subjecting the mixture to rapid drying, by feeding to a spray-dry.
摘要翻译：本发明涉及一种制备包含沸石和低聚二氧化硅的沸石催化剂的方法，其可用于工业反应器。该方法包括将由沸石合成得到的悬浮液与四烷基氢氧化铵存在下的四烷基原硅酸盐水解得到的低聚二氧化硅溶胶直接混合，并将混合物快速干燥，通过送入喷雾干燥。

23. 发明授权

US06696378B2 Fluid catalytic cracking catalyst manufacturing process 失效
标题翻译：流化催化裂化催化剂制造工艺
公开(公告)号：US06696378B2
公开(公告)日：2004-02-24
申请号：US09942971
申请日：2001-08-31
申请人： Clark W. Gibson , Mitchell J. Willis , George E. Gantt , Robert E. Barnes , David M. Stockwell
发明人： Clark W. Gibson , Mitchell J. Willis , George E. Gantt , Robert E. Barnes , David M. Stockwell
IPC分类号： B01J2906
CPC分类号： B01J37/0045 , B01J21/16 , B01J29/084 , B01J37/0009 , C10G11/05
摘要： An in situ process for making improved zeolitic fluid cracking catalysts by spray drying a mixture of (i) hydrous kaolin and/or metakaolin, and (ii) calcined aluminum source, said calcined aluminum source being derived from a pulverized, ultrafine kaolin, calcining the resulting microspheres to convert hydrous kaolin to metakaolin, and reacting microspheres composed of a mixture of metakaolin and calcined aluminum source with an alkaline sodium silicate solution. The weight percent of metakaolin in the calcined microspheres is greater than the calcined aluminum source content.
摘要翻译：通过喷雾干燥（i）含水高岭土和/或偏高岭土的混合物和（ii）煅烧铝源来制备改进的沸石流体裂化催化剂的原位方法，所述煅烧铝源源自粉碎的超细高岭土，煅烧将含水高岭土转化为偏高岭土，并将由偏高岭土和煅烧铝源的混合物组成的微球与碱性硅酸钠溶液反应。煅烧微球中偏高岭土的重量百分数大于煅烧铝源含量。

24. 发明授权

US06645899B1 Method of the removal of the templating agent from synthetic zeolites 有权
标题翻译：从合成沸石中除去模板剂的方法
公开(公告)号：US06645899B1
公开(公告)日：2003-11-11
申请号：US09712213
申请日：2000-11-15
申请人： Stefano Palmery , Fausto Genoni , Guido Spano′ , Leonardo Dalloro , Alberto Cesana , Roberto Buzzoni
发明人： Stefano Palmery , Fausto Genoni , Guido Spano′ , Leonardo Dalloro , Alberto Cesana , Roberto Buzzoni
IPC分类号： B01J2906
CPC分类号： B01J29/035 , B01J29/06 , B01J29/40 , B01J29/7007 , B01J29/7034 , B01J29/89 , B01J2229/40 , C01B37/00 , C01B37/02 , C01B39/026 , C07C249/04 , C07D201/04 , C07C251/44
摘要： The present invention relates to a method for the removal of the templating agent from synthetic zeolites in general and in particular from silicalite, titanium silicalite and from composite materials containing zeolites and for their activation as catalysts. The method consists in treating the above materials with solvents in vapor phase and at a low temperature.
摘要翻译：本发明涉及通常从合成沸石中去除模板剂的方法，特别是从硅沸石，钛硅沸石以及含有沸石的复合材料中除去模板剂的方法，以及它们作为催化剂的活化。该方法包括用溶剂处理上述物质在气相和低温下。

25. 发明授权

US06617276B1 Hydrocarbon trap/catalyst for reducing cold-start emissions from internal combustion engines 有权
标题翻译：用于减少内燃机冷起动排放的烃捕集阱/催化剂
公开(公告)号：US06617276B1
公开(公告)日：2003-09-09
申请号：US09621596
申请日：2000-07-21
申请人： Todd Howard Ballinger , Paul Joseph Andersen
发明人： Todd Howard Ballinger , Paul Joseph Andersen
IPC分类号： B01J2906
CPC分类号： B01D53/945 , B01D53/944 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/204 , B01D2255/50 , B01D2255/912 , Y02A50/2324 , Y02T10/22
摘要： An active metal, particularly cesium, impregnated hydrocarbon adsorbent, such as zeolite, comprises an improved hydrocarbon trap/oxidizing catalyst for use in effectively adsorbing hydrocarbons during automotive cold-start and subsequently desorbing, oxidizing and removing hydrocarbons during warmer operating conditions. The active metal modified hydrocarbon adsorbent may be combined in other forms of multi-layer automotive exhaust gas catalytic structures.
摘要翻译：活性金属，特别是铯，浸渍的烃类吸附剂，如沸石，包括一种改进的烃捕集器/氧化催化剂，用于在汽车冷启动期间有效吸附碳氢化合物，随后在较暖的运行条件下解吸，氧化和除去碳氢化合物。活性金属改性烃类吸附剂可以以其它形式的多层汽车废气催化结构组合。

26. 发明授权

US06617275B1 Process for preparing a catalyst for aromatic production 有权
标题翻译：制备芳香族生产催化剂的方法
公开(公告)号：US06617275B1
公开(公告)日：2003-09-09
申请号：US10022107
申请日：2001-12-13
申请人： Sanjay B. Sharma , John Kulach , Aaron James Imrie
发明人： Sanjay B. Sharma , John Kulach , Aaron James Imrie
IPC分类号： B01J2906
CPC分类号： B01J29/061 , B01J29/405 , B01J2229/20 , B01J2229/42
摘要： A novel process for converting C2 to C6 aliphatic hydrocarbons to aromatics and catalyst for use in this process are disclosed. The catalyst that contains a zeolite having a silica to alumina molar ratio greater than about 20 and a pore diameter from about 5 Å to about 6 Å, an essentially non-acidic binder, and a gallium component. The binder is selected from silica, zirconia, titania, and mixtures thereof and results in a catalyst formulation having both enhanced selectivity to desired C6-C9 aromatic products and improved stability compared to prior art compositions. Preferred zeolites that can be used include those of the MFI structure type, with ZSM-5 being a specific example.
摘要翻译：公开了一种用于将C2转化为C6脂族烃到用于该方法中的芳族化合物和催化剂的新方法。含有二氧化硅与氧化铝摩尔比大于约20，孔直径为约5至约6的沸石，基本上非酸性粘合剂和镓组分的沸石的催化剂。粘合剂选自二氧化硅，氧化锆，二氧化钛及其混合物，并且导致与现有技术组合物相比，具有对期望的C 6 -C 9芳香族产物的增强的选择性和改善的稳定性的催化剂制剂。可以使用的优选的沸石包括MFI结构类型的沸石，ZSM-5是具体实例。

27. 发明授权

US06524984B2 Process for preparing bound zeolites 有权
公开(公告)号：US06524984B2
公开(公告)日：2003-02-25
申请号：US09159751
申请日：1998-09-24
申请人： Angela Carati , Giuseppe Bellussi , Maria Angela Mantegazza , Giudo Petrini
发明人： Angela Carati , Giuseppe Bellussi , Maria Angela Mantegazza , Giudo Petrini
IPC分类号： B01J2906
CPC分类号： C01B37/005 , B01J29/06 , B01J29/40 , B01J2229/32 , C01B37/02 , C01B39/40 , Y10S423/22 , Y10S423/29
摘要： A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.

28. 发明授权

US06489259B2 Mixed zeolite NOx catalyst 失效
公开(公告)号：US06489259B2
公开(公告)日：2002-12-03
申请号：US09751928
申请日：2000-12-29
申请人： William J. LaBarge , Mark Hemingway , Joachim Kupe , Galen B. Fisher
发明人： William J. LaBarge , Mark Hemingway , Joachim Kupe , Galen B. Fisher
IPC分类号： B01J2906
CPC分类号： B01D53/945 , B01J29/005 , B01J29/084 , B01J29/163 , B01J29/42 , B01J29/80 , B01J29/83 , B01J37/0246 , Y02A50/235 , Y02C20/10 , Y02T10/22
摘要： A multiple zeolite catalyst mixture for purifying exhaust gases from an internal combustion engine, comprising: a first NO2 to N2 to conversion catalyst component; a second O3 conversion catalyst component; a third HC conversion catalyst component; a fourth N2O decomposition catalyst component; and, a fifth VOC reduction catalyst component; wherein the catalyst component mixture includes about 50 to 75 weight percent of the first and second catalyst components, and about 25 to 50 weight percent of the third, fourth, and fifth catalyst components.

29. 发明授权

US06323147B1 Titanium-containing silicon oxide catalyst 有权
标题翻译：含钛氧化硅催化剂
公开(公告)号：US06323147B1
公开(公告)日：2001-11-27
申请号：US09364268
申请日：1999-07-30
申请人： Jun Yamamoto , Junpei Tsuji
发明人： Jun Yamamoto , Junpei Tsuji
IPC分类号： B01J2906
CPC分类号： C07D301/19 , B01J29/89 , B01J35/002 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1057 , B01J35/1066 , B01J35/108 , C07D303/04 , Y02P20/52
摘要： A titanium-containing silicon oxide catalyst satisfying all of the following conditions (1) to (4): (1): an average pore size of 10 Å or more, (2): a pore size of 90% or more of the total pore volume of 5 to 200 Å, (3): a specific pore volume of 0.2 cm3/g or more, and (4): a quarternary ammonium ion represented by the following general formula (I) is used as a template and then said template is removed by solvent extraction operation; [NR1R2R3R4]+ (I) wherein, R1 represents a linear or branched hydrocarbon chain having 2 to 36 carbon atoms, and R2 to R4 represent an alkyl group having 1 to 6 carbon atoms, a method for producing said catalyst, and a method for producing propylene oxide by reacting propylene with a hydroperoxide, except for ethylbenzene hydroperoxide, in the presence of said catalyst.
摘要翻译：满足以下所有条件（1）〜（4）：（1）的含钛氧化硅催化剂：平均孔径为10以上，（2）：孔径为总计的90％以上孔体积为5〜200，（3）：比孔体积为0.2cm 3 / g以上，（4）：以下述通式（I）表示的季铵离子作为模板，通过溶剂萃取操作除去模板;其中，R1表示碳原子数2〜36的直链或支链烃链，R2〜R4表示碳原子数1〜6的烷基，所述催化剂的制造方法，用于在所述催化剂存在下，通过丙烯与氢过氧化物反应制备环氧丙烷，除了乙苯氢过氧化物。

30. 发明授权

US06319873B1 Biological activator for a septic tank 失效
标题翻译：化粪池生物活化剂
公开(公告)号：US06319873B1
公开(公告)日：2001-11-20
申请号：US07985354
申请日：1992-12-01
申请人： Philip Herve
发明人： Philip Herve
IPC分类号： B01J2906
CPC分类号： C02F3/34 , C02F3/10 , C02F3/28 , Y02W10/15
摘要： This invention relates to a biological activator for a septic tank of the type comprising a product in the form of solid particles, which is non-corrosive, non-toxic, finely divided, and of large specific area, comprising a colloidal phase in suspension and a flocculent phase, having a reducing power of mineral origin, its function being to form a support for anaerobic microbial flora in a septic tank in order to increase the bacterial saturation density in a septic tank for an equivalent quantity of nutrients, its specific area being (in m2/g) between about 25 and 66, more particularly between about 35 and 66, and advantageously between about 46 and 60, and a cation exchange capacity (in meq/100 g) between about 9 and 38, more particularly between about 14 and 38, and advantageously between about 24 and 35.
摘要翻译：本发明涉及一种用于化粪池的生物活化剂，其包括固体颗粒形式的产品，其是非腐蚀性的，无毒的，细碎的，并且具有大的比表面积，其包含悬浮液中的胶体相和具有矿物来源的还原能力的絮状相，其功能是在化粪池中形成用于厌氧微生物菌群的载体，以增加化粪池中的等量的营养物质的细菌饱和密度，其特定面积为（m 2 / g）在约25和66之间，更特别地在约35和66之间，有利地在约46和60之间，阳离子交换容量（meq / 100g）在约9和38之间，更特别地在约 14和38，有利地在约24和35之间。

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