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    • 23. 发明授权
    • Composite membrane and method for making the same
    • 复合膜及其制造方法
    • US06723241B2
    • 2004-04-20
    • US10005455
    • 2001-11-02
    • William E. Mickols
    • William E. Mickols
    • B01D3900
    • B01D69/125B01D71/56
    • A composite membrane and method for making the same, comprising a porous support and a crosslinked polyamide surface. The subject membrane provides improved flux and/or rejection rates. The subject membrane is further capable of operating at lower operating pressures. The subject method includes reacting a polyfunctional amine with a polyfunctional acyl halide to form a polyamide. The method includes the step of contacting a phosphorous containing compound with the polyfunctional acyl halide prior to and/or during the reaction between the polyfunctional acyl halide and a polyfunctional amine. The subject process is easily adapted to commercial scale manufacturing processes and is particularly suited for making nanofiltration and reverse osmosis composite membranes.
    • 复合膜及其制造方法,包括多孔载体和交联聚酰胺表面。 本发明的膜提供改善的通量和/或排除率。 本膜还能够在较低的操作压力下操作。 本发明方法包括使多官能胺与多官能酰卤反应形成聚酰胺。 该方法包括在多官能酰基卤和多官能胺之前和/或期间使含磷化合物与多官能酰基卤接触的步骤。 本发明方法容易适应于商业规模的制造工艺,并且特别适用于制备纳滤和反渗透复合膜。
    • 28. 发明授权
    • Composite polyamide reverse osmosis membrane and method of producing the same
    • 复合聚酰胺反渗透膜及其制备方法
    • US06368507B1
    • 2002-04-09
    • US09172594
    • 1998-10-14
    • Ja-Young KooYoung Seo YoonNowon KimJong-Eun Kim
    • Ja-Young KooYoung Seo YoonNowon KimJong-Eun Kim
    • B01D3900
    • B01D71/56B01D69/125
    • A composite polyamide reverse osmosis membrane and method of producing same. In one embodiment, the membrane is made by coating a porous polysulfone support for about 40 seconds with an aqueous solution containing (i) a polyfunctional amine in the form of 2 wt % of meta-phenylenediamine (MPD), (ii) a polar solvent in the form of 0.3 wt % 2-ethyl-1,3-hexanediol (EHD), and (iii) an amine salt-forming combination of 2.3 wt % camphorsulfonic acid (CSA) and 1.1 wt % triethylamine (TEA). Next, the excess aqueous solution is removed, and the coated support is dipped for about 1 minute in a 0.1 wt % organic solvent solution of trimesoyl chloride (TMC) in a mixture of alkanes having from 8 to 12 carbon atoms. After draining the organic solvent solution off, the resulting composite membrane is heated at 90° C. for about 3.5 minutes and then rinsed in a 0.2% Na2CO3 aqueous solution at room temperature. The resultant membrane exhibits a flux of 47.9 gfd and a salt rejection of 97.6% when used at 225 psi for an aqueous solution containing 2000 ppm of NaCl. In another embodiment, the aqueous solution contains (i) a polyfunctional amine in the form of 2 wt % of MPD, (ii) a combination of polar solvents in the form of 0.3 wt % of EHD and 2 wt % of dimethyl sulfoxide, and (iii) an amine salt-forming combination of 1 wt % of 1,1,3,3-tetramethylguanidine and 1.6 wt % toluene sulfonic acid. The resultant membrane exhibits a flux of 63.7 gfd and a salt rejection of 90.8% when used at 225 psi for an aqueous solution containing 2000 ppm of NaCl.
    • 一种复合聚酰胺反渗透膜及其制造方法。 在一个实施方案中,膜是通过用含有(i)2重量%间苯二胺(MPD)形式的多官能胺,(ii)极性溶剂(MPI)的水溶液涂覆多孔聚砜载体约40秒制备的, 以0.3重量%的2-乙基-1,3-己二醇(EHD)的形式,和(iii)2.3重量%樟脑磺酸(CSA)和1.1重量%三乙胺(TEA)的胺盐形成组合。 接下来,除去过量的水溶液,并将涂覆的载体在具有8至12个碳原子的烷烃的混合物的0.1重量%的均苯三酰氯(TMC)的有机溶剂溶液中浸渍约1分钟。 在排出有机溶剂溶液后,将所得复合膜在90℃下加热约3.5分钟,然后在室温下在0.2%Na 2 CO 3水溶液中漂洗。 对于含有2000ppm NaCl的水溶液,当在225psi下使用时,得到的膜表现出47.9gfd的通量和97.6%的拒水率。 在另一个实施方案中,水溶液包含(i)2重量%MPD形式的多官能胺,(ii)0.3重量%的EHD和2重量%的二甲基亚砜形式的极性溶剂的组合,以及 (iii)1重量%的1,1,3,3-四甲基胍和1.6重量%的甲苯磺酸的胺盐形成组合。 对于含有2000ppm NaCl的水溶液,当在225psi下使用时,得到的膜表现出63.7gfd的通量和90.8%的拒水率。