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    • 23. 发明授权
    • Method and a device for destruction of organic material in injection water
    • 注入水中有机物质的破坏方法和装置
    • US07802623B2
    • 2010-09-28
    • US12158602
    • 2006-12-11
    • Helge LundeDavid Pinchin
    • Helge LundeDavid Pinchin
    • E21B43/20C02F1/46
    • C02F1/4674C02F1/32C02F1/52C02F1/722C02F1/76C02F1/78C02F2101/30C02F2303/08C02F2305/023Y10S507/905
    • A method and a device (2) for destruction of organic material in injection water for an injection well (4), in which a means (10) for introduction of water in the injection well (4), and at least one electrochemical cell (16) with associated operating means are used for in situ electrolytic generation from water of at least short-lived, free hydroxyl radicals. The distinctive characteristic of the invention is that it comprises the following steps: (A) to connect the at least one electrochemical cell (16) to the injection well (4); and (B) by means of said operating means, to conduct the injection water through said cell (16) for in situ generation of at least free hydroxyl radicals from the injection water, insofar as free hydroxyl radicals immediately destruct organic material that they engage in the injection water. The invention also comprises use of water, which is to be injected into an injection well (4), as a source material for in situ electrolytic generation of said hydroxyl radicals for immediately destruction of organic material in the injection water.
    • 一种用于在喷射井(4)的注入水中破坏有机材料的方法和装置(2),其中用于在注入井(4)中引入水的装置(10)和至少一个电化学电池 16)与相关联的操作装置用于从至少短寿命的游离羟基自由基的水中原位电解生成。 本发明的特征在于它包括以下步骤:(A)将至少一个电化学电池(16)连接到注入井(4); 和(B)通过所述操作装置将注入水通过所述细胞(16),以便从注射水中原位产生游离羟基自由基,只要游离羟基自由基立即破坏它们所接触的有机材料即可 注射水。 本发明还包括将要注入注射井(4)中的水作为用于原位电解产生所述羟基自由基以便立即破坏注射用水中的有机材料的源材料。
    • 27. 发明授权
    • Shale hydration inhibition agent and method of use
    • 页岩水化抑制剂及其使用方法
    • US06857485B2
    • 2005-02-22
    • US10195686
    • 2002-07-15
    • Arvind D. PatelEmanuel StamatakisEric DavisSteve Cliffe
    • Arvind D. PatelEmanuel StamatakisEric DavisSteve Cliffe
    • C09K8/06C09K8/12C09K8/20C09K8/22C09K8/24C09K8/62E21B21/06E21B21/00C09K7/02
    • C09K8/206C09K8/06C09K8/12C09K8/22C09K8/24C09K8/62C09K2208/12E21B21/068Y10S507/905
    • A water-base drilling fluid for use in drilling wells through a formation containing a shale which swells in the presence of water. The drilling fluid preferably includes: an aqueous based continuous phase, a weight material, and a shale hydration inhibition agent having the formula: H2N—R—{OR′}x—Y.[H+B−]d in which R and R′ are alkylene groups having 1 to 6 carbon atom and x is a value from about 1 to about 25. The Y group should be an amine or alkoxy group, preferably a primary amine or a methoxy group. The acid H+B− is a protic acid selected from the group consisting of inorganic acids and organic acids, illustrative examples of which include: hydrochloric, hydrobromic, sulfuric, phosphoric, nitric, boric, perchloric, formic, acetic, halogenated acetic, propionic, butyric, maleic, fumeric, glycolic, lactic, citric and combinations of these. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale. Also inclusive of the present invention is a method of reducing the swelling of shale clay encountered during the drilling of a subterranean well, the method comprising circulating in the well a water-base drilling fluid formulated in accordance with the present invention.
    • 一种用于钻井的水基钻井液,通过含有在水存在下膨胀的页岩的地层。 钻井液优选包括:水基连续相,重量物质和具有下式的页岩水合抑制剂:其中R和R'是具有1至6个碳原子的亚烷基,x是约1至 约25.Y基应为胺或烷氧基,优选伯胺或甲氧基。 酸H +是选自无机酸和有机酸的质子酸,其示例性实例包括:盐酸,氢溴酸,硫酸,磷酸,硝酸,硼酸,高氯酸,甲酸,乙酸, 卤代乙酸,丙酸,丁酸,马来酸,富马酸,乙醇酸,乳酸,柠檬酸和它们的组合。 页岩水化抑制剂应以足够的浓度存在,以减少页岩的膨胀。 还包括本发明的是减少在钻井期间遇到的页岩粘土膨胀的方法,所述方法包括在井中循环根据本发明配制的水基钻井液。