会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 26. 发明授权
    • Compositions comprising CF.sub.3 CF.sub.2 CHF.sub.2 and their manufacture
    • 包含CF 3 CF 2 CHF 2的组合物及其制备
    • US6107267A
    • 2000-08-22
    • US137342
    • 1998-08-20
    • V. N. Mallikarjuna RaoAllen Capron SievertMunirpallam A. Subramanian
    • V. N. Mallikarjuna RaoAllen Capron SievertMunirpallam A. Subramanian
    • B01D3/36C11D7/30C11D7/50
    • C11D7/5036B01D3/36C11D7/30
    • A process is disclosed for recovering HF from a product mixture including HF and CF.sub.3 CF.sub.2 CHF.sub.2. The process involves (1) distilling the product mixture to remove all products which have a lower boiling point than the lowest boiling azeotrope containing HF and CF.sub.3 CF.sub.2 CHF.sub.2 ; and (2) distilling the azeotrope to recover HF as an azeotropic composition containing HF and CF.sub.3 CF.sub.2 CHF.sub.2. Also disclosed are compositions of hydrogen fluoride in combination with an effective amount of CF.sub.3 CF.sub.2 CHF.sub.2 to form an azeotrope or azeotrope-like composition with hydrogen fluoride, (e.g., compositions containing from about 57.1 to 67.2 mole percent CF.sub.3 CF.sub.2 CHF.sub.2).A process for producing certain compositions comprising(a) CF.sub.3 CF.sub.2 CHF.sub.2 and (b) at least one saturated halogenated hydrocarbon and/or ether having the formula:C.sub.n H.sub.2n+2-a-b Cl.sub.a F.sub.b O.sub.cwherein n is an integer from 1 to 4, a is an integer from 0 to 2n+1, b is an integer from 1 to 2n+2-a, and c is 0 or 1, provided that when c is 1 then n is an integer from 2 to 4 (and provided that component (b) does not include CF.sub.3 CF.sub.2 CF.sub.2) is also disclosed. This process involves (A) combining (i) an azeotropic composition of CF.sub.3 CF.sub.2 CHF.sub.2 and HF with (ii) at least one fluorination precursor compound wherein the precursor component (ii) is the fluorination precursor to component (b); and (B) reacting a sufficient amount of the HF from the azeotropic composition (i) with precursor component (ii), to provide a composition containing components (a) and (b) in the desired ratio. In addition, certain compositions are disclosed which include (a) CF.sub.3 CF.sub.2 CHF.sub.2 and (b) at least two saturated halogenated hydrocarbons and/or ethers having the formula:C.sub.n H.sub.2n+2-a-b Cl.sub.a F.sub.b O.sub.cwherein the molar ratio of said at least one compound to HFC-227ca is between about 1:99 and about 43:57 and c is 1 for at least one of the component (b) compounds.
    • 公开了从包含HF和CF 3 CF 2 CHF 2的产物混合物中回收HF的方法。 该方法包括(1)蒸馏产物混合物以除去所有具有比含有HF和CF 3 CF 2 CHF 2的最低沸点共沸物沸点低的产物; 和(2)蒸馏共沸物以回收HF作为含有HF和CF 3 CF 2 CHF 2的共沸组合物。 还公开了氟化氢与有效量的CF 3 CF 2 CHF 2组合以与氟化氢形成共沸物或类共沸组合物的组合物(例如,含有约57.1至67.2摩尔%CF 3 CF 2 CHF 2的组合物)。 一种制备某些组合物的方法,其包含(a)CF 3 CF 2 CHF 2和(b)至少一种具有下式的饱和卤代烃和/或醚:n为1至4的整数,a为从 0〜2n + 1,b为1〜2n + 2-a的整数,c为0或1,条件是当c为1时,n为2〜4的整数((b)成分 也不包括CF 3 CF 2 CF 2)。 该方法包括:(i)将CF 3 CF 2 CHF 2和HF的共沸组合物与(ii)至少一种氟化前体化合物组合(其中前体组分(ii)是组分(b)的氟化前体); 和(B)使足够量的来自共沸组合物(i)的HF与前体组分(ii)反应,从而以所需的比例提供含有组分(a)和(b)的组合物。 此外,公开了某些组合物,其包括(a)CF 3 CF 2 CHF 2和(b)至少两种具有下式的饱和卤代烃和/或醚:CnH2n + 2-a-bClaFbOc,其中所述至少一种化合物与HFC- 对于至少一种组分(b)化合物,227ca为约1:99至约43:57,c为1。