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    • 27. 发明申请
    • Magnesium cell with improved electrolyte
    • 具有改善电解质的镁电池
    • US20100310933A1
    • 2010-12-09
    • US12455885
    • 2009-06-09
    • Zhiping JiangRimma SirotinaNikolay Iltchev
    • Zhiping JiangRimma SirotinaNikolay Iltchev
    • H01M6/04H01M4/58
    • H01M6/168H01M4/38H01M4/466H01M4/5815H01M6/166H01M2300/0025H01M2300/0037
    • An improved electrolyte for a cell having an anode comprising magnesium or magnesium alloy. The cell's cathode may desirably include iron disulfide (FeS2) as cathode active material. The improved electrolyte comprises a magnesium salt, preferably magnesium perchlorate dissolved in an organic solvent which preferably includes acetonitrile or mixture of tetrahydrofuran and propylene carbonate. The electrolyte includes an additive to retard the buildup of deleterious passivation coating on the magnesium anode surface, thereby enhancing cell performance. Such additive may preferably include 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF4), 1-butyl-3-methylimidazolium hexafluorophosphate (BMIMPF6), lithium hexafluorophosphate (LiPF6), or aluminum chloride (AlCl3)
    • 用于具有包含镁或镁合金的阳极的电池的改进的电解质。 电池的阴极可以理想地包括二硫化铁(FeS 2)作为阴极活性材料。 改进的电解质包括镁盐,优选溶解在有机溶剂中的高氯酸镁,优选包括乙腈或四氢呋喃和碳酸亚丙酯的混合物。 电解质包括一种添加剂,用于延缓镁阳极表面上有害钝化涂层的积聚,从而提高电池性能。 这种添加剂可优选包括1-丁基-3-甲基咪唑鎓四氟硼酸盐(BMIMBF4),1-丁基-3-甲基咪唑六氟磷酸盐(BMIMPF6),六氟磷酸锂(LiPF 6)或氯化铝(AlCl 3)