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21. 发明授权

US5696055A Pollen suppressant comprising a 5-oxy- or amino substituted cinnoline 失效
标题翻译：含有5-氧基或氨基取代的噌啉的花粉抑制剂
公开(公告)号：US5696055A
公开(公告)日：1997-12-09
申请号：US818732
申请日：1992-01-06
申请人： Jeffrey Labovitz , William J. Guilford , Yi Liang , Lawrence Fang , Thomas G. Patterson
发明人： Jeffrey Labovitz , William J. Guilford , Yi Liang , Lawrence Fang , Thomas G. Patterson
IPC分类号： A01H1/02 , A01N43/58 , C07D237/28
CPC分类号： A01H1/02 , A01N43/58 , C07D237/28
摘要： Pollen suppressants of the formula ##STR1## wherein X represents a group of the formula OR.sup.1 or NR.sup.1 R.sup.2 wherein R.sup.1 represents a C.sub.1 -C.sub.4 alkyl (optionally substituted with a C.sub.1 -C.sub.4 alkoxy group, 1 to 3 halogen atoms, or a carboxy or C.sub.1 -C.sub.4 alkylcarbonyl group), alkenyl (optionally substituted with 1 to 3 halogen atoms), or alkynyl group and R.sup.2 represents H or CH.sub.3, with the proviso that when R.sup.1 is C.sub.3, R.sup.2 is CH.sub.3 ; Y is hydrogen, C.sub.1 -C.sub.22 linear alkyl or alkenyl containing up to four C.dbd.C double bonds, C.sub.3 -C.sub.6 branched alkyl or alkenyl, C.sub.2 -C.sub.4 alkoxyalkyl, cyclohexylmethyl, halogenated C.sub.1 -C.sub.4 alkyl, phenyl, benzyl, --(CH.sub.2 CH.sub.2 O).sub.m CH.sub.2 CH.sub.3 in which m is an integer from 1 to 5, or --CH(CH.sub.2 OR.sup.4)CH.sub.2 OR.sup.5 or --CH.sub.2 CHOR.sup.4 CH OR.sup.5 in which either R.sup.4 or R.sup.5 but not both represent a C.sub.1 -C.sub.22 linear alkyl- or alkenyl-carbonyl group containing up to four C--C double bonds; and R represents C.sub.1 -C.sub.4 alkyl, phenyl, naphthyl, or phenyl or naphthyl substituted with one to three substituents selected from the group consisting of halogen, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, and cyano; and salts thereof are disclosed along with methods of producing these compounds and of using them to produce hybrid seed in self-fertilizing plants.
摘要翻译：其中X表示式OR1或NR1R2的基团，其中R1表示C1-C4烷基（任选被C 1 -C 4烷氧基，1至3个卤素原子或羧基或C 1 -C 4烷氧基取代）的花粉抑制剂， C4烷基羰基），烯基（任选被1至3个卤素原子取代）或炔基，R 2表示H或CH 3，条件是当R 1为C 3时，R 2为CH 3; Y是氢，含有最多四个C = C双键的C1-C22直链烷基或烯基，C3-C6支链烷基或烯基，C2-C4烷氧基烷基，环己基甲基，卤代C1-C4烷基，苯基，苄基， - （CH2CH2O） mCH2CH3，其中m是1至5的整数，或-CH（CH 2 OR 4）CH 2 OR 5或-CH 2 CHOR 4 CH OR 5，其中R 4或R 5不是均表示含有至多4个CC的C 1 -C 22直链烷基或链烯基 - 羰基双重债券苯基，萘基或被一至三个选自卤素，三卤代甲基，C 1 -C 4烷氧基，C 1 -C 4烷基和氰基的取代基取代的苯基或萘基; 以及它们的盐以及这些化合物的制备方法以及使用它们在自体施肥植物中产生杂交种子。

22. 发明授权

US5129939A Pollen suppressant comprising a 5-oxy- or amino-substituted cinnoline 失效
标题翻译：含有5-氧基或氨基取代的噌啉的花粉抑制剂
公开(公告)号：US5129939A
公开(公告)日：1992-07-14
申请号：US614380
申请日：1990-11-16
申请人： Jeffrey Labovitz , William J. Guilford , Yi Liang , Lawrence Fang , Thomas G. Patterson
发明人： Jeffrey Labovitz , William J. Guilford , Yi Liang , Lawrence Fang , Thomas G. Patterson
IPC分类号： A01H1/02 , A01N43/58 , C07D237/28
CPC分类号： C07D237/28 , A01H1/02 , A01N43/58
摘要： Pollen suppressants of the formula ##STR1## wherein X represents a group of the formula OR.sup.1 or NR.sup.1 R.sup.2 wherein R.sup.1 represents a C.sub.1 -C.sub.4 alkyl (optionally substituted with a C.sub.1 -C.sub.4 alkoxy group, 1 to 3 halogen atoms, or a carboxy or C.sub.1 -C.sub.4 alkylcarbonyl group), alkenyl (optionally substituted with 1 to 3 halogen atoms), or alkynyl group and R.sup.2 represents H or CH.sub.3, with the proviso that when R.sup.1 is CH.sub.3, R.sup.2 is CH.sub.3 ; Y is hydrogen, C.sub.1 -C.sub.22 linear alkyl or alkenyl containing up to four C.dbd.C double bonds, C.sub.3 -C.sub.6 branched alkyl or alkenyl, C.sub.2 -C.sub.4 alkoxyalkyl, cyclohexylmethyl, halogenated C.sub.1 -C.sub.4 alkyl, phenyl, benzyl, --(CH.sub.2 CH.sub.2 O).sub.m CH.sub.2 CH.sub.3 in which m is an integer from 1 to 5, or --CH(CH.sub.2 OR.sup.4)CH.sub.2 OR.sup.5 or --CH.sub.2 CHOR.sup.4 CH.sub.2 OR.sup.5 in which either R.sup.4 or R.sup.5 but not both represent a C.sub.1 -C.sub.22 linear alkyl- or alkenyl-carbonyl group containing up to four C--C double bonds; and R represents C.sub.1 -C.sub.4 alkyl, phenyl, naphthyl, or phenyl or naphthyl substituted with one to three substituents selected from the group consisting of halogen, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, and cyano; and salts thereof are disclosed along with methods of producing these compounds and of using them to produce hybrid seed in self-fertilizing plants.
摘要翻译：其中X表示式OR1或NR1R2的基团，其中R1表示C1-C4烷基（任选被C 1 -C 4烷氧基，1至3个卤素原子或羧基或C 1 -C 4烷氧基取代）的花粉抑制剂， C4烷基羰基），烯基（任选被1至3个卤素原子取代）或炔基，R 2表示H或CH 3，条件是当R 1为CH 3时，R 2为CH 3; Y是氢，含有最多四个C = C双键的C1-C22直链烷基或烯基，C3-C6支链烷基或烯基，C2-C4烷氧基烷基，环己基甲基，卤代C1-C4烷基，苯基，苄基， - （CH2CH2O） mCH2CH3，其中m是1至5的整数，或-CH（CH 2 OR 4）CH 2 OR 5或-CH 2 CHOR 4 CH 2 OR 5，其中R 4或R 5不是均表示包含至多四个CC双重的C 1 -C 22直链烷基或链烯基 - 羰基债券苯基，萘基或被一至三个选自卤素，三卤代甲基，C 1 -C 4烷氧基，C 1 -C 4烷基和氰基的取代基取代的苯基或萘基; 以及它们的盐以及这些化合物的制备方法以及使用它们在自体施肥植物中产生杂交种子。

23. 发明授权

US4756740A Pollen suppressant comprising a fused pyridazine 失效
标题翻译：含有稠合哒嗪的花粉抑制剂
公开(公告)号：US4756740A
公开(公告)日：1988-07-12
申请号：US863082
申请日：1986-05-14
申请人： Jeffrey N. Labovitz , Lawrence Fang
发明人： Jeffrey N. Labovitz , Lawrence Fang
IPC分类号： A01H1/02 , A01N43/58 , A01N43/90 , C07D237/28 , C07D471/04 , C07D487/04 , C07D491/04 , C07D495/04 , C07D237/26
CPC分类号： C07D471/04 , A01H1/02 , A01N43/58 , A01N43/90 , C07D237/28 , C07D487/04 , C07D491/04 , C07D495/04
摘要： Pollen suppressants of the formula ##STR1## wherein Z represents a divalent organic radical of the formula --CH.dbd.CH--CH.dbd.CH--, --CH.dbd.CH--CH.dbd.N--, --CH.dbd.CH--N.dbd.CH--, --CH.dbd.CH--NH--, --CH.dbd.CH--O--, or --CH.dbd.CH--S-- or said radical in which an H of Z is replaced with a halogen atom with the proviso that no more than three H of Z are replaced by fluorine; a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkanoyl, cyano, nitro, hydroxy, or trihalomethyl group; or a group of the formula --NR.sup.1 R.sup.2 wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group; Y is Y.sup.1 R.sup.3 or NR.sup.4 R.sup.5 wherein Y.sup.1 is oxygen or sulfur; R.sup.3 hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxyalkyl, cyclohexylmethyl, halogenated C.sub.1 -C.sub.4 alkyl, phenyl, or benzyl; and R.sup.4 and R.sup.5 are independently selected from the group consisting of hydrogen, C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 alkyl substituted with carboxyl or C.sub.1 -C.sub.4 alkoxycarbonyl; and R represents C.sub.1 -C.sub.4 alkyl, phenyl, naphthyl, or phenyl or naphthyl substituted with one to three substituents selected from the group consisting of halogen, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, and cyano, are disclosed along with methods of producing these compounds and of using them to produce hybrid seeds in self-fertilizing plants.
摘要翻译：其中Z表示式-CH = CH-CH = CH-，-CH = CH-CH = N - ， - CH = CH-N = CH-，-CH = CH-的二价有机基团的花粉抑制剂 = CH-NH-，-CH = CH-O-或-CH = CH-S-或其中Z的H被卤素原子替代的所述基团，条件是不超过三个Z的Z被替换由氟; C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4烷酰基，氰基，硝基，羟基或三卤代甲基; 或式-NR1R2的基团，其中R1和R2独立地表示氢原子或C1-C4烷基; Y是Y 1 R 3或NR 4 R 5，其中Y 1是氧或硫; R 3氢，C 1 -C 4烷基，C 1 -C 4烷氧基烷基，环己基甲基，卤代C 1 -C 4烷基，苯基或苄基; 并且R 4和R 5独立地选自氢，C 1 -C 4烷基或被羧基或C 1 -C 4烷氧基羰基取代的C 1 -C 4烷基; 苯基，萘基或被一至三个选自卤素，三卤代甲基，C 1 -C 4烷氧基，C 1 -C 4烷基和氰基的取代基取代的苯基或萘基与方法生产这些化合物并使用它们在自体施肥植物中产生杂种种子。

24. 发明授权

US5304672A Method for the preparation of substituted 1,4-dihydro-4-oxo-cinnoline-3-carboxylic acid, esters and salts thereof, and intermediates used in their preparation 失效
标题翻译：制备取代的1,4-二氢-4-氧代 - 噌啉-3-羧酸的方法，其酯和盐及其制备中使用的方法
公开(公告)号：US5304672A
公开(公告)日：1994-04-19
申请号：US973629
申请日：1992-11-09
申请人： Jeffrey Labovitz , William J. Guilford , Lawrence Fang , Yi Liang
发明人： Jeffrey Labovitz , William J. Guilford , Lawrence Fang , Yi Liang
IPC分类号： C07D237/28 , C07C69/76
CPC分类号： C07D237/28
摘要： A method for the preparation of compounds of the formula ##STR1## wherein X represents a group of the formula OR.sub.1 or NR.sub.1 R.sub.2, wherein R.sub.1 and R.sub.2 independently represent H or an organic group that forms a stable covalent bond with the N or 0 of said X; Y is H or an organic group that forms a stable ester with the adjacent COO group; R is an alkyl or aryl group optionally substituted with one or more stable organic substituents; each R.sub.3 independently represents a stable organic group; and n is an integer from 0 to 3;the method using new intermediates of the formula ##STR2## wherein R.sub.3 and Y have the foregoing meanings;W is either F or Cl; andR.sub.9 is a hydrocarbon such as a C.sub.1 -C.sub.4 alkyl or alkenyl group.
摘要翻译：一种制备式（I）化合物的方法，其中X代表式OR1或NR1R2的基团，其中R1和R2独立地表示H或与N或O形成稳定的共价键的有机基团的X Y是H或与相邻COO基形成稳定酯的有机基团; R是任选被一个或多个稳定的有机取代基取代的烷基或芳基; 每个R 3独立地表示稳定的有机基团; n为0〜3的整数，使用式（VI）的新中间体的方法，其中R3和Y具有上述含义; W是F或Cl; 并且R 9是烃，例如C 1 -C 4烷基或烯基。

25. 发明授权

US4561881A Pollen suppressant comprising a pyridazolylamine 失效
标题翻译：含有哒唑胺的花粉抑制剂
公开(公告)号：US4561881A
公开(公告)日：1985-12-31
申请号：US532094
申请日：1983-09-14
申请人： Jeffrey N. Labovitz , Lawrence Fang
发明人： Jeffrey N. Labovitz , Lawrence Fang
IPC分类号： A01H1/02 , A01N43/58 , A01N43/713 , C07D237/24 , C07D403/04 , C07D237/34 , C07D401/12
CPC分类号： C07D403/04 , A01H1/02 , A01N43/58 , A01N43/713 , C07D237/24
摘要： A pollen suppressant of the formula ##STR1## wherein R.sup.1 and R.sup.4 independently represent C.sub.1 -C.sub.4 alkyl, phenyl, naphthyl, or phenyl or naphthyl substituted with one to three substituents selected from the group consisting of halogen, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, and cyano; R.sup.2 is ##STR2## where R.sup.5 is a C.sub.1 -C.sub.12 alkyl group, optionally substituted with one or more halogen atoms, or an aryl group selected from the group consisting of 6-membered rings containing 0-3 nitrogens and fused bicyclic 10-membered rings containing 6 atoms in each ring and 0-3 nitrogens per ring with the remaining atoms in the ring or rings of said aryl group being carbon atoms, said aryl group being optionally substituted with a C.sub.1 -C.sub.4 alkyl group or an electron-withdrawing group, R.sup.3 is hydrogen, a halogen a C.sub.1 -C.sub.4 alkyl group, a carboxy group or an agronomically acceptable alkali metal salt thereof, or a group of the formula --COOR.sup.6 or --CONR.sup.6 R.sup.7 where R.sup.6 is a C.sub.1 -C.sub.4 alkyl group and R.sup.7 is R.sup.6 or hydrogen, is disclosed along with methods of producing these compounds and of using them to produce hybrid seeds in self-fertilizing plants.
摘要翻译：其中R1和R4独立地表示C1-C4烷基，苯基，萘基或被一至三个选自卤素，三卤代甲基，C1-C4烷氧基，C1-C4烷基的取代基取代的苯基或萘基的花粉抑制剂 -C4烷基和氰基; R 2是，其中R 5是任选被一个或多个卤素原子取代的C 1 -C 12烷基，或选自含有0-3个氮的6元环和稠合的双环10元环的芳基每个环中含有6个原子，每个环有0-3个氮原子，所述芳基的环或其中的剩余原子是碳原子，所述芳基任选被C 1 -C 4烷基或吸电子基团取代， R 3是氢，卤素，C 1 -C 4烷基，羧基或其农业上可接受的碱金属盐，或式-COOR 6或-CONR 6 R 7的基团，其中R 6是C 1 -C 4烷基，且R 7是R 6或氢以及生产这些化合物的方法以及使用它们在自体施肥植物中产生杂种种子。

26. 发明授权

US5183891A Method for the preparation of substituted 1,4-dihydro-4-oxo-cinnoline-3-carboxylic acid, esters and salts thereof, and intermediates used in their preparation 失效
标题翻译：制备取代的1,4-二氢-4-氧代 - 噌啉-3-羧酸的方法，其酯和盐及其制备中使用的方法
公开(公告)号：US5183891A
公开(公告)日：1993-02-02
申请号：US434077
申请日：1989-11-09
申请人： Jeffrey Labovitz , William J. Guilford , Lawrence Fang , Yi Liang
发明人： Jeffrey Labovitz , William J. Guilford , Lawrence Fang , Yi Liang
IPC分类号： C07D237/28
CPC分类号： C07D237/28
摘要： A method for the preparation of compounds of the formula ##STR1## wherein X represents a group of the formula OR.sub.1 or NR.sub.1 R.sub.2, wherein R.sub.1 and R.sub.2 independently represent H or an organic group that forms a stable covalent bond with the N or O of said X; Y is H or an organic group that forms a stable ester with the adjacent COO group; R is an alkyl or aryl group optionally substituted with one or more stable organic substituents; each R.sub.3 independently represents a stable organic group; and n is an integer from 0 to 3;the method using new intermediates of the formula ##STR2## wherein R.sub.3 and Y have the foregoing meanings; W is either F or Cl;and R.sub.9 is a hydrocarbon such as a C.sub.1 -C.sub.4 alkyl or alkenyl group.
摘要翻译：制备式（I）的化合物的方法，其中X表示式OR1或NR1R2的基团，其中R1和R2独立地表示H或与N或O形成稳定的共价键的有机基团的X Y是H或与相邻COO基形成稳定酯的有机基团; R是任选被一个或多个稳定的有机取代基取代的烷基或芳基; 每个R 3独立地表示稳定的有机基团; n为0〜3的整数，使用式（VI）的新中间体的方法，其中R3和Y具有上述含义; W是F或Cl; 并且R 9是烃，例如C 1 -C 4烷基或烯基。

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