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21. 发明授权

US08178741B2 Method and apparatus for regenerating catalyst during oxygenates to olefins reaction 有权
标题翻译：在含氧化合物到烯烃反应过程中再生催化剂的方法和装置
公开(公告)号：US08178741B2
公开(公告)日：2012-05-15
申请号：US12793340
申请日：2010-06-03
申请人： Chunshe J. Cao , James H. Beech, Jr. , Michael P. Nicoletti , Thomas H. Colle , Teng Xu , Stephen N. Vaughn
发明人： Chunshe J. Cao , James H. Beech, Jr. , Michael P. Nicoletti , Thomas H. Colle , Teng Xu , Stephen N. Vaughn
IPC分类号： C07C1/00 , B01J20/34 , B01J19/00
CPC分类号： B01J38/02 , B01J29/90 , B01J38/32 , C07C1/20 , C07C2529/85 , Y02P20/584 , C07C11/02
摘要： Disclosed herein is a method of recovery of the activity of a molecular sieve catalyst following use of the catalyst in an OTO conversion process. This is achieved by a regeneration apparatus and a method of regenerating a molecular sieve catalyst, comprising two stages. In a pretreatment stage, the catalyst is pretreated under pretreatment conditions by heating the catalyst to a temperature of between 320° C. to 700° C. in an oxygen depleted medium for a residence time of between 1 minute to two hours; and, in a regeneration stage, the catalyst is regenerated under regeneration conditions by heating the catalyst at a temperature of between 200° C. to 700° C. in an oxidizing medium for a residence time of between 1 to 60 minutes.
摘要翻译：本文公开了在OTO转化方法中使用催化剂后回收分子筛催化剂的活性的方法。这是通过再生装置和再生分子筛催化剂的方法实现的，包括两个阶段。在预处理阶段，催化剂在预处理条件下通过将催化剂在耗氧贫乏的介质中在320℃至700℃之间的温度下进行预处理，停留时间为1分钟至2小时; 并且在再生阶段，催化剂在再生条件下通过在氧化介质中在200℃至700℃的温度下加热催化剂，停留时间为1至60分钟而再生。

22. 发明申请

US20110021857A1 Method And Apparatus For Regenerating Catalyst During Oxygenates To Olefins Reaction 有权
标题翻译：氧化催化剂再生催化剂对烯烃反应的方法与装置
公开(公告)号：US20110021857A1
公开(公告)日：2011-01-27
申请号：US12793340
申请日：2010-06-03
申请人： Chunshe J. Cao , James H. Beech, JR. , Michael P. Nicoletti , Thomas H. Colle , Teng Xu , Stephen N. Vaughn
发明人： Chunshe J. Cao , James H. Beech, JR. , Michael P. Nicoletti , Thomas H. Colle , Teng Xu , Stephen N. Vaughn
IPC分类号： C07C1/00 , B01J20/34 , B01J19/00
CPC分类号： B01J38/02 , B01J29/90 , B01J38/32 , C07C1/20 , C07C2529/85 , Y02P20/584 , C07C11/02
摘要： Disclosed herein is a method of recovery of the activity of a molecular sieve catalyst following use of the catalyst in an OTO conversion process. This is achieved by a regeneration apparatus and a method of regenerating a molecular sieve catalyst, comprising two stages. In a pretreatment stage, the catalyst is pretreated under pretreatment conditions by heating the catalyst to a temperature of between 320° C. to 700° C. in an oxygen depleted medium for a residence time of between 1 minute to two hours; and, in a regeneration stage, the catalyst is regenerated under regeneration conditions by heating the catalyst at a temperature of between 200° C. to 700° C. in an oxidizing medium for a residence time of between 1 to 60 minutes.
摘要翻译：本文公开了在OTO转化方法中使用催化剂后回收分子筛催化剂的活性的方法。这是通过再生装置和再生分子筛催化剂的方法实现的，包括两个阶段。在预处理阶段，催化剂在预处理条件下通过将催化剂在耗氧贫乏的介质中在320℃至700℃之间的温度下进行预处理，停留时间为1分钟至2小时; 并且在再生阶段，催化剂在再生条件下通过在氧化介质中在200℃至700℃的温度下加热催化剂，停留时间为1至60分钟而再生。

23. 发明授权

US07579511B1 Process for making cyclohexylbenzene 有权
标题翻译：制备环己基苯的方法
公开(公告)号：US07579511B1
公开(公告)日：2009-08-25
申请号：US12287655
申请日：2008-10-10
申请人： Jihad Mohammed Dakka , Lorenzo Cophard DeCaul , Teng Xu
发明人： Jihad Mohammed Dakka , Lorenzo Cophard DeCaul , Teng Xu
IPC分类号： C07C2/64 , C07C2/66
CPC分类号： C07C2/74 , C07C2601/14 , C07C13/28
摘要： Provided is a process for making cyclohexylbenzene. The process includes the following steps: (a) contacting benzene and hydrogen in the presence of a first catalyst under hydroalkylation conditions sufficient to form a first effluent stream having cyclohexylbenzene, cyclohexane, methyl cyclopentane, and unreacted benzene; (b) supplying at least part of said first effluent stream to a first separation system to divide said first effluent stream part into a cyclohexane/methylcyclopentane-rich stream, a cyclohexane-rich stream, a benzene-rich stream, and a dicyclohexyl benzene-rich stream; (c) recycling at least part of the benzene-rich stream to the contacting step (a); (d) contacting the cyclohexane/methylcyclopentane-rich stream with a second catalyst that catalyzes dehydrogenation and exhibits low acidity under conditions sufficient to convert at least a portion of the cyclohexane to benzene and at least a portion of the methylcyclopentane to linear and/or branched paraffins to form a second effluent stream; and (e) recycling at least part of the second effluent stream to the contacting step (a).
摘要翻译：提供了制备环己基苯的方法。该方法包括以下步骤：（a）在足以形成具有环己基苯，环己烷，甲基环戊烷和未反应苯的第一流出物流的加氢烷基化条件下，在第一催化剂存在下使苯和氢接触; （b）将至少部分所述第一流出物流供应到第一分离系统以将所述第一流出物流部分分解成富环己烷/甲基环戊烷流，富环己烷流，富含苯的流和二环己基苯 - 富流（c）将至少部分富含苯的物流再循环至接触步骤（a）; （d）使环己烷/甲基环戊烷流与催化脱氢的第二催化剂接触，并且在足以将至少一部分环己烷转化为苯和至少一部分甲基环戊烷的条件下呈现低酸度至线性和/或支化石蜡形成第二流出物流; 和（e）将至少部分第二流出物流再循环到接触步骤（a）。

24. 发明申请

US20090030253A1 Production of Aromatics from Aliphatics 有权
标题翻译：从芳烃生产芳烃
公开(公告)号：US20090030253A1
公开(公告)日：2009-01-29
申请号：US12166153
申请日：2008-07-01
申请人： Teng Xu , Kenneth R. Clem , Jeremy J. Patt , J. Scott Buchanan , Larry L. Iaccino
发明人： Teng Xu , Kenneth R. Clem , Jeremy J. Patt , J. Scott Buchanan , Larry L. Iaccino
IPC分类号： C07C2/00
CPC分类号： C07C2/76 , C07C15/02
摘要： In a process for converting a low carbon number aliphatic hydrocarbon to higher hydrocarbons including aromatic hydrocarbons, a feed containing the aliphatic hydrocarbon is contacted with a dehydrocyclization catalyst under conditions effective to convert the aliphatic hydrocarbon to aromatic hydrocarbons and produce an effluent stream comprising aromatic hydrocarbons and hydrogen. The dehydrocyclization catalyst comprises a metal or metal compound and a molecular sieve wherein the ratio of the amount of any Bronsted acid sites in the catalyst to the amount of said metal in the catalyst is less than 0.4 mol/mol of said metal.
摘要翻译：在将低碳数脂肪族烃转化成包括芳烃的高级烃的方法中，将含有脂族烃的进料与脱氢环化催化剂在有效将脂肪烃转化为芳族烃并产生包含芳族烃的流出物流的条件下接触，氢。脱氢环化催化剂包括金属或金属化合物和分子筛，其中催化剂中任何布朗斯台德酸位点的量与催化剂中所述金属的量的比例小于所述金属的0.4mol / mol。

25. 发明授权

US07411106B2 Molecular sieve compositions, catalyst thereof, their making and use in conversion processes 有权
标题翻译：分子筛组合物，其催化剂，其制备和在转化过程中的应用
公开(公告)号：US07411106B2
公开(公告)日：2008-08-12
申请号：US11713873
申请日：2007-03-05
申请人： Teng Xu , Stephen N. Vaughn , Richard B. Hall , Doron Levin , James Clark Vartuli
发明人： Teng Xu , Stephen N. Vaughn , Richard B. Hall , Doron Levin , James Clark Vartuli
IPC分类号： C07C1/00 , C07C1/20
CPC分类号： B01J37/0009 , B01J21/06 , B01J21/10 , B01J23/10 , B01J29/85 , B01J35/0006 , B01J35/023 , B01J35/10 , B01J2229/42 , C07C1/20 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2521/16 , C07C2523/10 , C07C2529/83 , C07C2529/85 , Y02P30/42 , C07C11/02
摘要： The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene The catalyst composition comprises a molecular sieve and at least one metal oxide, such as a magnesium oxide that, when saturated with acetone and contacted with said acetone for 1 hour at 25° C., converts more than 80% of the acetone.
摘要翻译：本发明涉及一种催化剂组合物，其制备方法及其在将原料，优选氧化原料转化为一种或多种烯烃，优选乙烯和/或丙烯中的用途。催化剂组合物包含分子筛和至少一种金属氧化物，例如氧化镁，当用丙酮饱和并与所述丙酮在25℃下接触1小时时，其转化超过80％的丙酮。

26. 发明授权

US07247764B2 Conversion process 有权
公开(公告)号：US07247764B2
公开(公告)日：2007-07-24
申请号：US10462256
申请日：2003-06-16
申请人： Marcel J. G. Janssen , Teng Xu , Cor F. Van Egmond , Keith H. Kuechler , Stephen N. Vaughn , James Harding Beech, Jr.
发明人： Marcel J. G. Janssen , Teng Xu , Cor F. Van Egmond , Keith H. Kuechler , Stephen N. Vaughn , James Harding Beech, Jr.
IPC分类号： C07C1/00 , C07C1/20
CPC分类号： C07C1/20 , B01J29/85 , C07C2529/00 , Y02P30/42 , C07C11/02
摘要： The invention relates to a conversion process for making olefin(s) using a molecular sieve catalyst composition. More specifically, the invention is directed to a process for converting a feedstock comprising an oxygenate in the presence of a molecular sieve catalyst composition, wherein the feedstock is free of or substantially free of metal salts.

27. 发明授权

US07238846B2 Conversion process 有权
标题翻译：转换过程
公开(公告)号：US07238846B2
公开(公告)日：2007-07-03
申请号：US10218728
申请日：2002-08-14
申请人： Marcel J. G. Janssen , Teng Xu , Cor F. Van Egmond , Keith F. Kuechler , Stephen N. Vaughn
发明人： Marcel J. G. Janssen , Teng Xu , Cor F. Van Egmond , Keith F. Kuechler , Stephen N. Vaughn
IPC分类号： C07C1/00 , C07C1/20
CPC分类号： C07C1/20 , B01J29/85 , C07C2529/00 , Y02P30/42 , C07C11/02
摘要： The invention relates to a conversion process for making olefin(s) using a molecular sieve catalyst composition. More specifically, the invention is directed to a process for converting a feedstock comprising an oxygenate in the presence of a molecular sieve catalyst composition, wherein the feedstock is free of or substantially free of metal salts.
摘要翻译：本发明涉及使用分子筛催化剂组合物制备烯烃的转化方法。更具体地，本发明涉及在分子筛催化剂组合物存在下转化含有氧化合物的原料的方法，其中原料不含或基本上不含金属盐。

28. 发明申请

US20050101815A1 Catalyst pretreatment with dimethyl ether in an oxygenate to olefins reaction system 失效
标题翻译：催化剂预处理用二甲醚在含氧化合物到烯烃反应体系中
公开(公告)号：US20050101815A1
公开(公告)日：2005-05-12
申请号：US10712668
申请日：2003-11-12
申请人： Teng Xu , Kenneth Clem , Keith Kuechler
发明人： Teng Xu , Kenneth Clem , Keith Kuechler
IPC分类号： B01J29/85 , C07C1/20 , C07C1/00
CPC分类号： C07C1/20 , B01J29/85 , C07C2529/84 , C07C2529/85 , Y02P20/52 , Y02P30/42 , C07C11/06 , C07C11/04 , C07C11/02
摘要： This invention relates to processes for converting oxygenates to olefins and olefins to polyolefins. The processes include a step of pretreating molecular sieve used in the conversion of oxygenate to olefin with a dimethyl ether composition. Fresh or regenerated molecular sieve, which is low in carbon content, is contacted or pretreated with the dimethyl ether composition to form a hydrocarbon co-catalyst within the pore structure of the molecular sieve, and the pretreated molecular sieve containing the co-catalyst is used to convert oxygenate to a lighter olefin product.
摘要翻译：本发明涉及将含氧化合物转化为烯烃和烯烃到聚烯烃的方法。该方法包括用二甲基醚组合物预处理用于将含氧化合物转化为烯烃的分子筛的步骤。碳含量低的新鲜或再生分子筛与二甲醚组合物接触或预处理，以在分子筛的孔结构内形成烃助催化剂，并使用含有助催化剂的预处理分子筛将含氧化合物转化为较轻的烯烃产物。

29. 发明授权

US09715434B1 System and method for estimating storage space needed to store data migrated from a source storage to a target storage 有权
公开(公告)号：US09715434B1
公开(公告)日：2017-07-25
申请号：US13250678
申请日：2011-09-30
申请人： Teng Xu , Windsor W. Hsu , Lan Chin
发明人： Teng Xu , Windsor W. Hsu , Lan Chin
IPC分类号： G06F3/06 , G06F17/30 , G06F11/14
CPC分类号： G06F11/1453 , G06F3/0608 , G06F3/0641 , G06F3/0647 , G06F3/067 , G06F3/0685 , G06F17/30091 , G06F17/30097 , G06F17/30156 , G06F17/30159
摘要： Techniques for data migration of a storage system are described herein. According to one embodiment, for at least one of segments of a file to be migrated from a source storage tier to a target storage tier, a fingerprint of the segment is transmitted to the target storage tier. In response to a response received from the target storage tier indicating that the segment has not been stored in the target tier based on the fingerprint, a storage space of the target tier estimated for migrating the file is incremented. One or more segments of the file that have not been stored in the target tier are migrated if the one or more segments of the file fit in the target storage tier based on the estimated storage space of the target tier.

30. 发明授权

US09280550B1 Efficient storage tiering 有权
标题翻译：高效的存储分层
公开(公告)号：US09280550B1
公开(公告)日：2016-03-08
申请号：US12983281
申请日：2010-12-31
申请人： Windsor W. Hsu , Teng Xu
发明人： Windsor W. Hsu , Teng Xu
IPC分类号： G06F7/00 , G06F17/00 , G06F17/30
CPC分类号： G06F17/30156 , G06F3/0608 , G06F3/061 , G06F3/0641 , G06F3/0649 , G06F3/0685 , G06F11/1453 , G06F17/30153 , G06F17/30221
摘要： A method, article of manufacture, and apparatus for transferring data from a source tier to a target tier. In some embodiments, this may include dividing an object stored in the source tier into a plurality of segments, determining if the target tier is missing at least one of the segments, writing the missing segments to the target tier, and deleting the object from the source tier. In some embodiments, the object's metadata is updated to indicate that the object is in the target tier.
摘要翻译：一种用于将数据从源层传送到目标层的方法，制造和装置。在一些实施例中，这可以包括将存储在源层中的对象划分成多个段，确定目标层是否丢失了至少一个段，将缺失的段写入目标层，以及从目标层中删除对象源层。在一些实施例中，对象的元数据被更新以指示对象在目标层中。

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