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21. 发明申请

US20090143617A1 METHOD FOR PREPARING (E3, Z5) -3,5-ALKADIENYL ACETATE 有权
标题翻译：制备（E3，Z5）-3,5-亚氨基乙酸酯的方法
公开(公告)号：US20090143617A1
公开(公告)日：2009-06-04
申请号：US12323823
申请日：2008-11-26
申请人： MIYOSHI YAMASHITA , Takehiko Fukumoto
发明人： MIYOSHI YAMASHITA , Takehiko Fukumoto
IPC分类号： C07C57/18
CPC分类号： C07C41/48 , C07C29/10 , C07C41/50 , C07C67/08 , C07C69/007 , C07C69/145 , C07C33/02 , C07C43/30
摘要： Provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate and (E3,Z5)-3,5-dodecadienyl acetate which is a sex pheromone of Brazilian apple leafminer. Specifically, provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate, comprising steps of hydrolyzing 5,5-diethoxy-(Z3)-3-pentenyl methoxymethyl ether in the presence of an acid to obtain 4-formyl-(E3)-butenyl methoxymethyl ether; reacting the 4-formyl-(E3)-butenyl methoxymethyl ether with alkylidene triphenylphosphorane in accordance with the Wittig reaction to obtain (E3,Z5)-3,5-alkadienyl methoxymethyl ether; and obtaining (E3,Z5)-3,5-alkadienyl acetate using the (E3,Z5)-3,5-alkadienyl methoxymethyl ether as a starting substance.
摘要翻译：提供一种制备（E3，Z5）-3,5-链二烯酸乙酸酯和（E3，Z5）-3,5-十二烷基乙酸酯的方法，其是巴西苹果叶片的性信息素。具体地说，提供了制备（E3，Z5）-3,5-链二烯基乙酸酯的方法，包括在酸存在下水解5,5-二乙氧基 - （Z 3）-3-戊烯基甲基甲基醚的步骤，得到4- 甲酰基 - （E3） - 丁烯基甲氧基甲基醚; 根据Wittig反应使4-甲酰基 - （E3） - 丁烯基甲氧基甲基醚与亚烷基三苯基正膦反应，得到（E3，Z5）-3,5-二甲氧基甲基醚; 并使用（E3，Z5）-3,5-链二烯基甲氧基甲基醚作为起始物质获得（E3，Z5）-3,5-链二烯酸乙酯。

22. 发明授权

US5714649A 1-Halo-cis-3-tetradecenes and processes for the preparation of cis-Olefin compounds by using same 失效
标题翻译： 1-顺 - 顺-3-十四碳烯和通过使用它们制备顺式烯烃化合物的方法
公开(公告)号：US5714649A
公开(公告)日：1998-02-03
申请号：US575333
申请日：1995-12-20
申请人： Takehiko Fukumoto , Daisuke Iwai , Shigeo Okano , Hiroshi Suzuki , Mitsuyoshi Oshima
发明人： Takehiko Fukumoto , Daisuke Iwai , Shigeo Okano , Hiroshi Suzuki , Mitsuyoshi Oshima
IPC分类号： A01N27/00 , C07C1/32 , C07C11/02 , C07C17/16 , C07C21/04 , C07C21/14 , C07C21/17 , C07F1/02 , C07F3/02 , C07C19/08
CPC分类号： C07C11/02 , C07C17/16 , C07C21/04 , C07C21/14 , C07C21/17
摘要： Disclosed are compounds suitable for use as raw materials which enable cis-olefin compounds useful as physiologically active substances such as the sex pheromones of various insects, or as intermediates for the synthesis thereof to be prepared on an industrial scale at a reasonable cost, and processes for the preparation of cis-olefin compounds by using the same. For this purpose, novel compounds (i.e., 1-halo-cis-3-tetradecenes) of the general formula (I) CH.sub.3 (CH.sub.2).sub.9 CH.dbd.CH(CH.sub.2).sub.2 X (I) wherein X is a halogen atom, are used as raw materials for the preparation of cis-olefin compounds.
摘要翻译：公开了适合用作原料的化合物，其使得可用作诸如各种昆虫的性信息素的生理活性物质的顺式烯烃化合物或其合成成本的工业规模的合成中间体，以及方法用于通过使用它们制备顺式烯烃化合物。为此，将通式（I）CH（CH 2）9 CH = CH（CH 2）2 X（I）的新化合物（即1-卤代 - 顺式-3-十四碳烯）其中X为卤素原子用作用于制备顺式烯烃化合物的原料。

23. 发明申请

US20130001110A1 ANNULAR SUSTAINED RELEASE PREPARATION AND PRODUCTION METHOD THEREOF 审中-公开
标题翻译：环保可持续发展的准备和生产方法
公开(公告)号：US20130001110A1
公开(公告)日：2013-01-03
申请号：US13634734
申请日：2011-03-22
申请人： Ryuichi Saguchi , Takehiko Fukumoto
发明人： Ryuichi Saguchi , Takehiko Fukumoto
IPC分类号： A01P19/00 , B65B7/00 , B65D77/00
CPC分类号： A01M1/2044
摘要： Provided is an annular sustained release preparation to be used by opening a center portion thereof, the preparation having a strength enough to avoid cleaving at a welded end portion. More specifically, provided is an annular sustained release preparation comprising at least two polymer tubes having both ends sealed and integrated by pressure-welding or at least one polymer tube and at least one polymer rod having both ends sealed and integrated by pressure-welding; and a sex pheromone liquid contained by at least one of the tubes or the tube; wherein an annular space can be formed by pulling the tubes or the tube and the rod apart from each other at a center portion therebetween, the central portion not having been pressure-welded; and an angle formed between a line connecting respective centers of diameters of the tubes welded to each other or the tube and the rod welded to each other and the pressure application direction is from 0 to 45°.
摘要翻译：提供一种通过打开其中心部分而使用的环形缓释制剂，该制剂具有足以避免在焊接端部处分裂的强度。更具体地，提供了一种环形缓释制剂，其包括至少两个聚合物管，其两端通过压焊或至少一个聚合物管密封并整合，并且至少一个聚合物棒的两端通过压焊密封和集成; 和由至少一个管或管包含的性信息素液体; 其中可以通过在它们之间的中心部分处拉动所述管或所述管和所述杆彼此分离而形成环形空间，所述中心部分未被压焊; 并且在彼此焊接的管或连接管的直径的管线与彼此焊接的杆和压力施加方向之间形成的角度为0至45°。

24. 发明申请

US20060093638A1 Sustained pheromone releaser 有权
标题翻译：持续的信息素释放者
公开(公告)号：US20060093638A1
公开(公告)日：2006-05-04
申请号：US11257957
申请日：2005-10-25
申请人： Tatsuya Hojo , Ryuichi Saguchi , Takehiko Fukumoto , Noboru Aiba
发明人： Tatsuya Hojo , Ryuichi Saguchi , Takehiko Fukumoto , Noboru Aiba
IPC分类号： A01N25/00
CPC分类号： A01N25/18
摘要： Provided is a sustained releaser of a sex pheromone having a high release rate, especially preferably of a sex pheromone of an aliphatic acetate compound having 10 to 16 carbon atoms, wherein the release of the sex pheromone is controlled so that it can be released at a constant rate over a control period of a pest insect. More specifically, provided is a sustained pheromone releaser comprising a polymer container and having, enclosed therein, a mixture having a melting point of 15 to 35° C. and being obtained by mixing a sex pheromone substance and a compound having a melting point of 10 to 40° C.
摘要翻译：提供具有高释放速度的性信息素的持续释放剂，特别优选具有10至16个碳原子的脂族乙酸酯化合物的性信息素，其中性信息素的释放被控制，使得其可以在在病虫害控制期间的恒定速率。更具体地说，提供了一种持续的信息素释放剂，其包含聚合物容器，并且在其中包含熔点为15至35℃的混合物，并且通过混合性信息素物质和熔点为10的化合物至40℃

25. 发明授权

US5532421A Method for the isomerization of cis-alkenyl compounds 失效
标题翻译：顺式 - 烯基化合物的异构化方法
公开(公告)号：US5532421A
公开(公告)日：1996-07-02
申请号：US275753
申请日：1994-07-19
申请人： Takanobu Terauchi , Toyohisa Sakurada , Takehiko Fukumoto , Hiroshi Suzuki
发明人： Takanobu Terauchi , Toyohisa Sakurada , Takehiko Fukumoto , Hiroshi Suzuki
IPC分类号： B01J27/24 , C07B35/08 , C07B61/00 , C07C5/22 , C07C11/02 , C07C11/107 , C07C17/358 , C07C21/04 , C07C29/56 , C07C33/025 , C07C51/353 , C07C51/62 , C07C57/12 , C07C57/66 , C07C67/293 , C07C67/333 , C07C69/007 , C07C69/145 , C07C69/533 , C07C69/58 , C07C5/27
CPC分类号： C07C5/2206 , C07B35/08 , C07C29/56 , C07C33/025 , C07C51/353 , C07C51/62 , C07C67/333 , C07B2200/09 , C07C2527/25
摘要： An object of the present invention is to provide a method for the preparation of geometrical isomers which are important as constituents of synthetic pheromones, synthetic perfumes, terpenes and the like (i.e., a method for the isomerization of cis-alkenyl compounds to their trans-isomers). In this method, the above-described object is accomplished by reacting a cis-alkenyl compound in the presence of nitric acid used as the sole catalyst.
摘要翻译：本发明的目的是提供一种制备作为合成信息素，合成香料，萜烯等的成分重要的几何异构体的方法（即将顺式 - 链烯基化合物异构化成其反式 - 异构体）。在该方法中，上述目的是通过使用作为唯一催化剂的硝酸存在下的顺式链烯基化合物进行。

26. 发明授权

US5292973A Phosphine oxide removal from compounds formed by a Wittig reaction 失效
标题翻译：由Wittig反应形成的化合物中除去氧化膦
公开(公告)号：US5292973A
公开(公告)日：1994-03-08
申请号：US81961
申请日：1993-06-24
申请人： Takehiko Fukumoto , Akira Yamamoto
发明人： Takehiko Fukumoto , Akira Yamamoto
IPC分类号： C07C17/26 , C07C17/38 , C07C29/32 , C07C29/86 , C07C33/025 , C07F9/02 , C07C29/38 , C07C29/19
CPC分类号： C07F9/025 , C07C17/2635 , C07C17/38 , C07C29/32 , C07C29/86 , C07C33/025 , C07B2200/09
摘要： An improvement is proposed for the removal of the precipitates of a phosphine oxide compound as a by-product from a mixture thereof with an olefin compound obtained by the Wittig reaction for the preparation of the olefin compound from a phosphorane compound and a carbonyl compound. Instead of the conventional procedure of filtration to remove the precipitates, the mixture in a hydrocarbon solvent, after replacement of a non-hydrocarbon solvent with a hydrocarbon solvent, if necessary, is admixed with a lower carboxylic acid such as acetic acid so that the precipitates of the phosphine oxide are dissolved forming a viscous fluid which is immiscible with the mixture of the olefin compound and the hydrocarbon solvent. The fluid containing the dissolved phosphine oxide compound can be easily removed by phase separation so that a great increase is obtained in the yield of the desired olefin compound.
摘要翻译：提出了从作为副产物的氧化膦化合物与其与通过用于从正膦烷化合物和羰基化合物制备烯烃化合物的Wittig反应获得的烯烃化合物的混合物中除去沉淀物的改进。代替常规的过滤方法除去沉淀物，如果需要，用烃溶剂置换非烃溶剂后，在烃溶剂中的混合物与低级羧酸如乙酸混合，使得沉淀物的氧化膦溶解形成与烯烃化合物和烃溶剂的混合物不混溶的粘性流体。含有溶解的氧化膦化合物的流体可以通过相分离容易地除去，从而在所需的烯烃化合物的产率上获得大的增加。

27. 发明授权

US5162596A Z-12-heptadecen-1-yne 失效
标题翻译： Z-12-HEPTADECEN-1-YNE
公开(公告)号：US5162596A
公开(公告)日：1992-11-10
申请号：US837025
申请日：1992-02-14
申请人： Takehiko Fukumoto , Akira Yamamoto , Mitsuyoshi Oshima
发明人： Takehiko Fukumoto , Akira Yamamoto , Mitsuyoshi Oshima
IPC分类号： C07C11/28
CPC分类号： C07C11/28
摘要： Disclosed is a novel ene-yne compound Z-12-heptadecen-1-yne expressed by the structural formula CH.sub.3 (CH.sub.2).sub.3 CH.sup.(Z) =CH(CH.sub.2).sub.9 C=CH, which is useful as an intermediate in the synthetic preparation of several diene compounds having activity as a sex pheromone of the insects belonging to the lepidopteran order, such as E,Z-2,13-octadecadienyl acetate and E,Z-2,13-octadecadienal, having two double bonds at the 2- and 13-positions. The inventive compound can be synthesized by the reaction of 1-bromo-Z-10-pentadecene with sodium acetylide dispersed in an organic solvent in the presence of liquid ammonia.
摘要翻译：公开了由结构式CH 3（CH 2）3 CH（Z）= CH（CH 2）9 C = CH表示的新型烯类化合物Z-12-十七碳烯-1-炔，其可用作合成制剂中的中间体具有属于鳞翅目类昆虫的性信息素的几种二烯化合物，例如E，Z-2,13-十八碳二烯酸乙酯和E，Z-2,13-十八碳二烯醛，在2-和 13个职位。本发明化合物可以通过在液氨存在下分散在有机溶剂中的1-溴代-Z-十五碳烯与乙炔化钠的反应来合成。

28. 发明授权

US4918252A 1-halo-(Z,E)-7,10-dodecadiene and a method for the preparation thereof 失效
标题翻译： 1-卤代（Z，E）-7,10-十二碳二烯及其制备方法
公开(公告)号：US4918252A
公开(公告)日：1990-04-17
申请号：US333462
申请日：1989-02-05
申请人： Takehiko Fukumoto , Akira Yamamoto
发明人： Takehiko Fukumoto , Akira Yamamoto
IPC分类号： C07C17/00 , C07C17/26 , C07C17/263 , C07C17/354 , C07C21/19 , C07C21/22 , C07C67/00 , C07C67/08 , C07C69/145
CPC分类号： C07C21/19 , C07C17/2632
摘要： A novel and efficient synthetic route is proposed for the preparation of (Z,E)-9,12-tetradecadienyl acetate as a sex pheromone compound used for population control of the pest insects belonging to the genus of Spodoptera via an intermediate 1-halo-(Z,E)-7,10-dodecadiene, which is a novel compound not known in the prior art. This novel compound is synthesized by reacting a Grignard reagent XMgC.tbd.C(CH.sub.2).sub.6 X,X being Cl or Br, with (E)-2-butenyl chloride or bromide to form an ene-yne compound of the formula CH.sub.3 CH.dbd..sup.(E) CHCH.sub.2 C.tbd.C(CH.sub.2).sub.6 X and then partially hydrogenating this ene-yne compound.

29. 发明授权

US4912253A Method for the preparation of an unsaturated alcohol or ester thereof 失效
标题翻译：制备不饱和醇或其酯的方法
公开(公告)号：US4912253A
公开(公告)日：1990-03-27
申请号：US347399
申请日：1989-05-04
申请人： Takehiko Fukumoto , Akira Yamamoto
发明人： Takehiko Fukumoto , Akira Yamamoto
IPC分类号： C07C27/00 , C07C29/36 , C07C33/02 , C07C33/025 , C07C33/048 , C07C33/20 , C07C67/00 , C07C69/145
CPC分类号： C07C29/36
摘要： An efficient method is proposed for the synthesis of an unsaturated alcohol of the general formula R--CH.dbd.CH(CH.sub.2).sub.n+1 OH, in which R is a hydrogen atom or a monovalent hydrocarbon group having 1 to 10 carbon atoms and the subscript n is an integer in the range from 3 to 10, in which an acetate of the formula R--CH.dbd.CHCH.sub.2 OCOCH.sub.3 is subjected to a coupling reaction with a Grignard reagent of the formula X.sup.1 Mg(CH.sub.2).sub.n OMgX.sup.2, in which X.sup.1 and X.sup.2 are each a halogen atom, and then the reaction product is hydrolyzed. When the reaction product of the coupling reaction is reacted with acetic anhydride instead of hydrolysis, the corresponding acetate can readily be obtained. These unsaturated alcohols and acetates form a class of important biologically active compounds or intermediates thereof including sex pheromone compounds of insects.
摘要翻译：提出了合成通式为R-CH = CH（CH 2）n + 1OH的不饱和醇的有效方法，其中R为氢原子或具有1-10个碳原子的一价烃基，下标n 是3至10的整数，其中式R-CH = CHCH2OCOCH3的乙酸酯与式X1Mg（CH2）nOMgX2的格氏试剂进行偶联反应，其中X1和X2各自为卤素原子，然后反应产物水解。当偶联反应的反应产物与乙酸酐反应而不是水解时，可以容易地获得相应的乙酸酯。这些不饱和醇和乙酸酯形成一类重要的生物活性化合物或其中间体，包括昆虫的性信息素化合物。

30. 发明授权

US10117426B2 Annular sustained release preparation and production method thereof 有权
公开(公告)号：US10117426B2
公开(公告)日：2018-11-06
申请号：US13634734
申请日：2011-03-22
申请人： Ryuichi Saguchi , Takehiko Fukumoto
发明人： Ryuichi Saguchi , Takehiko Fukumoto
IPC分类号： B65D85/00 , A01M1/20
摘要： Provided is an annular sustained release preparation having at least two polymer tubes having both ends sealed and integrated by pressure-welding or at least one polymer tube and at least one polymer rod having both ends sealed and integrated by pressure-welding; and a sex pheromone liquid contained by at least one of the tubes or the tube; wherein an annular space can be formed by pulling the tubes or the tube and the rod apart from each other at a center portion therebetween, the central portion not having been pressure-welded; and an angle formed between a line connecting respective centers of diameters of the tubes welded to each other or the tube and the rod welded to each other and the pressure application direction is from 0 to 45°.

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