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    • 22. 发明授权
    • Battery structure and lithium secondary battery using the same
    • 电池结构和锂二次电池使用相同
    • US08021790B2
    • 2011-09-20
    • US12282149
    • 2007-12-13
    • Nobuhiro Ota
    • Nobuhiro Ota
    • H01M6/18
    • H01M10/0562H01M10/052H01M2300/0068H01M2300/0071
    • A battery structure includes a positive electrode layer, a solid electrolyte layer, and a negative electrode layer disposed in that order, wherein the solid electrolyte layer has a chemical composition, excluding incidental impurities, represented by the formula aLi·bX·cS·dY, where X is at least one element of phosphorus (P) and boron (B), Y is at least one element of oxygen (O) and nitrogen (N), the sum of a, b, c, and d is 1, a is 0.20 to 0.52, b is 0.10 to 0.20, c is 0.30 to 0.55, and d is 0 to 0.30. The solid electrolyte layer includes a portion A in contact with the negative electrode layer and a portion B in contact with the positive electrode layer, and d in the portion A is larger than d in the portion B. A lithium secondary battery includes the battery structure.
    • 电池结构包括依次设置的正极层,固体电解质层和负极层,其中固体电解质层具有不包括由式aLi·bX·cS·dY表示的杂质的化学组成, 其中X是磷(P)和硼(B)的至少一种元素,Y是氧(O)和氮(N)的至少一种元素,a,b,c和d的和为1,a 为0.20〜0.52,b为0.10〜0.20,c为0.30〜0.55,d为0〜0.30。 固体电解质层包括与负极层接触的部分A和与正极层接触的部分B,并且部分A中的d在部分B中大于d。锂二次电池包括电池结构 。
    • 23. 发明申请
    • LITHIUM BATTERY
    • 锂电池
    • US20090068563A1
    • 2009-03-12
    • US12208497
    • 2008-09-11
    • Ryoko KandaNobuhiro OtaTakashi UemuraKentaro YoshidaMitsuyasu Ogawa
    • Ryoko KandaNobuhiro OtaTakashi UemuraKentaro YoshidaMitsuyasu Ogawa
    • H01M6/18
    • H01M10/0525H01M4/13H01M4/485H01M10/0562H01M10/0585Y10T29/49115
    • A lithium battery includes a substrate, a positive electrode layer, a negative electrode layer, and a sulfide solid electrolyte layer disposed between the positive electrode layer and the negative electrode layer, the positive electrode layer, the negative electrode layer, and the sulfide solid electrolyte layer being provided on the substrate. In this lithium battery, the positive electrode layer is formed by a vapor-phase deposition method, and a buffer layer that suppresses nonuniformity of distribution of lithium ions near the interface between the positive electrode layer and the sulfide solid electrolyte layer is provided between the positive electrode layer and the sulfide solid electrolyte layer. As the buffer layer, a lithium-ion conductive oxide, in particular, LixLa(2-x)/3TiO3 (x=0.1 to 0.5), Li7+xLa3Zr2O12+(x/2) (−5≦×≦3, preferably −2≦×≦2), or LiNbO3 is preferably used.
    • 锂电池包括设置在正极层和负极层之间的基板,正极层,负极层和硫化物固体电解质层,正极层,负极层和硫化物固体电解质 层设置在基板上。 在该锂电池中,通过气相沉积法形成正极层,并且在正极层和硫化物固体电解质层之间的界面附近抑制锂离子分布的不均匀性的缓冲层设置在阳极 电极层和硫化物固体电解质层。 作为缓冲层,特别是LixLa(2-x)/ 3TiO3(x = 0.1〜0.5),Li7 + xLa3Zr2O12 +(x / 2)(-5≤x≤3)的锂离子传导性氧化物 -2 <= x <= 2),或者优选使用LiNbO 3。
    • 24. 发明申请
    • Thin Film Lithium Battery
    • 薄膜锂电池
    • US20080102363A1
    • 2008-05-01
    • US11795490
    • 2006-09-12
    • Takashi UemuraMitsuyasu OgawaNobuhiro OtaKatsuji Emura
    • Takashi UemuraMitsuyasu OgawaNobuhiro OtaKatsuji Emura
    • H01M10/36
    • H01M10/052H01M4/134H01M4/66H01M10/0472H01M10/056H01M2300/0094Y10T29/49108
    • A thin film lithium battery is provided which can realize a high yield by solving various problems caused by a pin hole formed in a solid electrolyte layer.A thin film lithium battery according to the present invention is a thin film lithium battery in which a positive electrode layer 20, a negative electrode layer 50, a solid electrolyte layer 40 provided therebetween, and a collector 10 electrically connected to at least one of the positive electrode layer 20 and the negative electrode layer 50 are laminated to each other. When this battery is viewed in plan along the lamination direction of the above individual layers, the positive electrode layer 20 and the negative electrode layer 50 are disposed at positions so as not to be overlapped with each other. By the structure as described above, even if a pin hole is formed in the solid electrolyte layer 40, short-circuiting between the two electrode layers 20 and 50, which is caused by this pin hole, can be prevented.
    • 提供了一种薄膜锂电池,其可以通过解决由固体电解质层中形成的针孔引起的各种问题而实现高产率。 根据本发明的薄膜锂电池是其中设置有正电极层20,负电极层50,固体电解质层40以及与至少一个电极层电连接的集电极10的薄膜锂电池 正极层20和负极层50彼此层叠。 沿着上述各层的层叠方向平面地观察该电池时,将正极层20和负极层50配置在不重叠的位置。 通过如上所述的结构,即使在固体电解质层40中形成针孔,也能够防止由该针孔引起的两个电极层20,50之间的短路。
    • 28. 发明申请
    • POSITIVE-ELECTRODE MEMBER AND METHOD FOR PRODUCING THE SAME
    • 正电极部件及其制造方法
    • US20120052383A1
    • 2012-03-01
    • US13319096
    • 2010-03-12
    • Nobuhiro OtaTakashi UemuraMitsuyasu OgawaRyoko Kanda
    • Nobuhiro OtaTakashi UemuraMitsuyasu OgawaRyoko Kanda
    • H01M4/70H01M4/04H01M4/64
    • H01M4/0404H01M4/043H01M4/0471H01M4/13H01M4/139H01M4/62H01M4/70
    • A positive-electrode member for producing a nonaqueous electrolyte battery having a high discharge capacity and an excellent cycle characteristic, and a method for producing the positive-electrode member are provided. The positive-electrode member includes a positive-electrode collector composed of a metal; and a positive-electrode active-material layer (positive-electrode active-material portion) 10B that allows for electron transfer between the positive-electrode collector and the positive-electrode active-material layer 10B. The positive-electrode active-material layer 10B includes positive-electrode active-material particles 1 and a solid electrolyte 2 that fixes the particles 1. The contours of the particles 1 that are next to each other partially conform to each other. To produce such a positive-electrode member, a raw-material sol obtained by mixing positive-electrode active-material particles with substances that turn into a solid electrolyte through polycondensation by heating is applied to a positive-electrode collector, and the resultant member is heated and subsequently pressed.
    • 提供一种具有高放电容量和优异的循环特性的非水电解质电池的制造用正极部件和制造正极部件的方法。 正极构件包括由金属构成的正极集电体; 以及允许正极集电体和正极活性物质层10B之间的电子转移的正极活性物质层(正极活性物质部)10B。 正极活性物质层10B包括固定颗粒1的正极活性物质颗粒1和固体电解质2.彼此相邻的颗粒1的轮廓部分地彼此匹配。 为了制造这样的正极构件,将正极活性物质粒子与通过加热缩聚成固体电解质的物质混合而得到的原料溶胶被施加到正极集电体,所得到的构件是 加热并随后按压。