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21. 发明申请

WO2009016153A2 PHOSPHORUS MODIFIED MOLECULAR SIEVES, THEIR USE IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：磷酸改性分子筛，它们在有机物转化成烯烃中的用途
公开(公告)号：WO2009016153A2
公开(公告)日：2009-02-05
申请号：PCT/EP2008/059883
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , NESTERENKO, Nikolai , VERMEIREN, Walter , MINOUX, Delphine , VAN DONK, Sander
发明人： NESTERENKO, Nikolai , VERMEIREN, Walter , MINOUX, Delphine , VAN DONK, Sander
IPC分类号： B01J29/85 , C01B39/02 , C07C2/08 , C07C11/02 , C07C1/20
CPC分类号： C07C1/322 , B01J29/40 , B01J29/85 , B01J2229/36 , B01J2229/37 , C01B39/026 , C07C1/20 , C07C1/22 , C07C1/26 , C07C2/06 , C07C4/06 , C07C7/04 , C07C2529/85 , C10G3/00 , C10G2300/202 , C10G2300/4081 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C11/06
摘要： The present invention is a phosphorous modified zeolite (A) made by a process comprising in that order: selecting a zeolite with low Si/AI ratio (advantageously lower than 30) among H + or NH 4 + -form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870°C for 0.01-200h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.3 wt% of P; separation of the solid from the liquid; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step. The present invention also relates to a process (hereunder referred as "XTO process") for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted with the above catalyst (in the XTO reactor) under conditions effective to convert at least a portion of the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The present invention also relates to a process (hereunder referred as "combined XTO and OCP process") to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the above catalyst at conditions effective to convert at least a portion of the feedstock to form an XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明是通过以下方法制备的磷改性沸石（A）：在MFI，MEL，FER，MOR的H +或NH4 +形式中选择具有低Si / Al比（有利地低于30）的沸石，斜发沸石，所述沸石优选不直接添加有机模板; 在400〜870℃的温度范围内蒸煮0.01〜200h; 在有效从沸石中除去大部分Al并引入至少0.3wt％P的条件下，用含有P源的酸性水溶液浸出; 从液体中分离固体; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。本发明还涉及从含氧，含卤素或含硫有机原料制造烯烃产物的方法（以下称为“XTO法”），其中所述含氧卤化物或含硫的在有效将至少一部分含氧，含卤素或含硫有机原料转化为烯烃产物（XTO反应器流出物）的条件下，有机原料与上述催化剂（在XTO反应器中）接触。本发明还涉及从含氧的含卤化物或含硫有机原料制备轻质烯烃的方法（以下称为“组合的XTO和OCP方法”），包括：使含有氧的含卤素的或含硫有机原料在具有上述催化剂的XTO反应器中，在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下使OCP反应器中的所述重质烃馏分接触。

22. 发明申请

WO2008012218A1 PRODUCTION OF OLEFINS 审中-公开
标题翻译：生产油脂
公开(公告)号：WO2008012218A1
公开(公告)日：2008-01-31
申请号：PCT/EP2007/057260
申请日：2007-07-13
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , DATH, Jean-Pierre , VERMEIREN, Walter
发明人： DATH, Jean-Pierre , VERMEIREN, Walter
IPC分类号： C10G11/05 , C07C11/06 , C07C4/06
CPC分类号： C10G11/05 , C10G2300/1037 , C10G2300/4018 , C10G2400/20
摘要： A process for converting a hydrocarbon feedstock to provide an effluent containing light olefins, the process comprising passing a hydrocarbon feedstock, the feedstock containing at least 25wt % C5+ paraffins, through a reactor containing a crystalline silicate catalyst to produce an effluent including propylene.
摘要翻译：一种用于转化烃原料以提供含有轻质烯烃的流出物的方法，该方法包括将含有至少25重量％的C 5+链烷烃的原料的烃原料通过含有结晶硅酸盐催化剂的反应器，以产生包含丙烯的流出物。

23. 发明申请

WO2005016856A1 PRODUCTION OF OLEFINS 审中-公开
标题翻译：生产油脂
公开(公告)号：WO2005016856A1
公开(公告)日：2005-02-24
申请号：PCT/EP2004/009142
申请日：2004-08-12
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , DATH, Jean-Pierre , VERMEIREN, Walter
发明人： DATH, Jean-Pierre , VERMEIREN, Walter
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , B01J29/40 , B01J2229/16 , B01J2229/36 , B01J2229/42 , C07C4/06 , C07C2529/40 , Y02P20/52 , Y02P30/42 , C07C11/06 , C07C11/04
摘要： A process for converting a hydrocarbon feedstock to provide an effluent containing light olefins, the process comprising passing a hydrocarbon feedstock comprising a mixture of a first portion, containing one or more olfeins of C 4 or greater, and a second portion, containing at least one C 1 to C 6 aliphatic hetero compound selected from alcohols, ethers, carbonyl compounds and mixtures thereof, through a reactor containing a crystalline silicate catalyst to produce an effluent including propylene, the crystalline silicate being selected from at least one of an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ratio of from 150 to 800 which has been subjected to a steaming step.
摘要翻译：一种用于转化烃原料以提供含有轻质烯烃的流出物的方法，该方法包括使包含含有一种或多种C4或更多烯醇的第一部分的混合物的烃原料和含有至少一种C1 通过包含结晶硅酸盐催化剂的反应器制备包含丙烯的流出物的选自醇，醚，羰基化合物及其混合物的C 6脂肪族杂化合物，所述结晶硅酸盐选自MFI型结晶硅酸盐中的至少一种，其具有至少180的硅/铝原子比和经过蒸汽步骤的硅/铝原子比为150至800的MEL型结晶硅酸盐。

24. 发明申请

WO2011089235A1 DEHYDRATION OF ALCOHOLS ON A CRYSTALLINE SILICATE OF LOW Si/Al RATIO 审中-公开
标题翻译：醇在低Si / Al比例的晶体硅酸中的脱水
公开(公告)号：WO2011089235A1
公开(公告)日：2011-07-28
申请号：PCT/EP2011/050855
申请日：2011-01-21
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , MINOUX, Delphine , NESTERENKO, Nikolai , ADAM, Cindy , VAN DONK, Sander , VERMEIREN, Walter
发明人： MINOUX, Delphine , NESTERENKO, Nikolai , ADAM, Cindy , VAN DONK, Sander , VERMEIREN, Walter
IPC分类号： C07C1/24 , C07C11/04
CPC分类号： C07C1/24 , B01J29/65 , B01J29/90 , B01J2229/16 , B01J2229/36 , C07C2529/65 , C07C2529/70 , C07C2529/85 , C23C18/00 , C25D7/0664 , C25D17/00 , Y02P20/52 , Y02P20/584 , C07C11/04
摘要： The present invention (in a first embodiment) relates to a process for the dehydration of an alcohol having at least 2 carbon atoms to make the corresponding olefin, comprising: introducing in a reactor a stream (A) comprising at least an alcohol, optionally water, optionally an inert component, contacting said stream with a catalyst in said reactor at conditions effective to dehydrate at least a portion of the alcohol to make an olefin, recovering from said reactor an olefin containing stream (B), wherein, the catalyst is a crystalline silicate of the group FER, MWW, EUO, MFS, ZSM- 48, MTT or TON having Si/Al under 100, or a dealuminated crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT or TON having Si/Al under 100, or a phosphorus modified crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT or TON having Si/Al under 100, the WHSV of the alcohol is at least 4 h -1 and/or the temperature ranges from 320°C to 600°C.
摘要翻译：本发明（在第一实施方案中）涉及使具有至少2个碳原子的醇脱水以制备相应烯烃的方法，包括：在反应器中引入至少包含醇，任选的水任选的惰性组分，在所述反应器中使所述料流与催化剂接触的条件下，使所述醇的至少一部分脱水以制备烯烃，从所述反应器回收含烯烃流（B），其中所述催化剂为具有Si / Al低于100的组FER，MWW，EUO，MFS，ZSM-48，MTT或TON的结晶硅酸盐，或FER，MWW，EUO，MFS，ZSM-48，MTT或TON组的脱铝结晶硅酸盐 Si / Al低于100，或具有Si / Al低于100的FER，MWW，EUO，MFS，ZSM-48，MTT或TON的磷改性结晶硅酸盐，醇的WHSV为至少4h -1 和/或温度范围为320℃至600℃。

25. 发明申请

WO2009156433A2 PROCESS TO MAKE OLEFINS FROM ORGANICS 审中-公开
标题翻译：从有机物制备烯烃的方法
公开(公告)号：WO2009156433A2
公开(公告)日：2009-12-30
申请号：PCT/EP2009/057887
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , NESTERENKO, Nikolai , VERMEIREN, Walter , GRASSO, Giacomo , VAN DONK, Sander , GARCIA, Wolfgang
发明人： NESTERENKO, Nikolai , VERMEIREN, Walter , GRASSO, Giacomo , VAN DONK, Sander , GARCIA, Wolfgang
IPC分类号： C07C1/20 , C07C4/06 , B01J37/28 , B01J29/40
CPC分类号： C07C1/22 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J37/10 , B01J38/12 , B01J2229/16 , B01J2229/186 , B01J2229/36 , C07C1/20 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G9/00 , C10G55/04 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur- containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧的含卤化物或含硫有机原料制备轻质烯烃的方法，包括：a）提供包含含有10个成员的沸石分子筛和在其微孔结构中较大的通道，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区中循环，使得至少一部分再生催化剂通过OC反应区，将OC反应区中的至少一部分催化剂通入XTO反应区，并将XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃部分的XTO反应器流出物的条件下，将XTO反应器中的含氧，含卤素或含硫有机原料与催化剂接触 ; d）从所述重质烃馏分中分离出所述轻质烯烃; e）使OC反应器中的所述重质烃馏分与催化剂在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下接触。

26. 发明申请

WO2009098269A1 PROCESS TO MAKE OLEFINS FROM ETHANOL 审中-公开
标题翻译：从乙醇制备油脂的方法
公开(公告)号：WO2009098269A1
公开(公告)日：2009-08-13
申请号：PCT/EP2009/051342
申请日：2009-02-05
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander , GRASSO, Giacomo
发明人： MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander , GRASSO, Giacomo
IPC分类号： C07C11/06 , C07C11/04 , C07C1/24 , C07C4/06
CPC分类号： C07C11/04 , C07C1/24 , C07C4/06 , C07C11/06
摘要： The present invention relates to a process for the conversion of ethanol to make essentially ethylene and propylene, comprising : a) introducing in a reactor (A) (also called the first low temperature reaction zone) a stream comprising ethanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) in said reactor (A) at conditions effective to dehydrate at least a portion of the ethanol to essentially ethylene, c) recovering from said reactor an effluent comprising : essentially ethylene, minor amounts of various hydrocarbons, water, optionally unconverted ethanol and the optional inert component of step a), d) fractionating said effluent of step c) to remove water, unconverted ethanol, optionally the inert component, and optionally the whole or a part of the various hydrocarbons to get a stream (D) comprising essentially ethylene and optionally the inert component, e) introducing at least a part of said stream (D) mixed with a stream (D1 ) comprising olefins having 4 carbon atoms or more (C4+ olefins) in a OCP reactor (also called the second high temperature reaction zone) under the condition that the mixture (D)+(D1) comprises at least 10wt% of C4+ olefins, f) contacting said stream comprising at least a part of (D) and the stream (D1 ) in said OCP reactor with a catalyst which is selective towards light olefins in the effluent, to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, g) fractionating said effluent of step f) to produce at least an ethylene stream, a propylene stream and a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, optionally recycling ethylene in whole or in part at the inlet of the OCP reactor of step f), or at the inlet of the reactor (A) or in part at the inlet of the OCP reactor of step f) and in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the OCP reactor.
摘要翻译：本发明涉及一种将乙醇转化成基本上乙烯和丙烯的方法，其包括：a）在反应器（A）（也称为第一低温反应区）中引入包含乙醇，任选的水，任选地，惰性组分，b）在有效将至少一部分乙醇脱水至基本上乙烯的条件下，使所述料流与所述反应器（A）中的催化剂（A1）接触; c）从所述反应器回收包含：基本上乙烯，次要的流出物各种烃，水，任选未转化的乙醇和步骤a）的任选的惰性组分的量，d）将步骤c）的所述流出物分馏以除去水，未转化的乙醇，任选的惰性组分，以及任选的全部或部分各种烃以得到基本上包含乙烯和任选的惰性组分的物流（D），e）将至少一部分与流（D1）com混合的所述物流（D）在混合物（D）+（D1）包含至少10重量％的C 4 +烯烃的条件下，在OCP反应器（也称为第二高温反应区）中具有4个碳原子或更多个（C 4 +烯烃）使所述OCP反应器中包含至少一部分（D）和物流（D1）的物流与流出物中的轻质烯烃选择性的催化剂接触，以产生具有低于原料，g）对步骤f）的所述流出物进行分馏以产生至少一种乙烯流，丙烯料流和基本上由具有4个碳原子或更多碳原子的烃组成的馏分，任选地在乙烯流入口处全部或部分回收乙烯 OCP反应器，或在反应器（A）的入口或部分在步骤f）的OCP反应器的入口处，部分地在反应器（A）的入口处，可任选地再循环基本上组分的馏分的碳氢化合物 OCP或更多在OCP反应器的入口处。

27. 发明申请

WO2009098267A1 PROCESS TO MAKE OLEFINS FROM ETHANOL 审中-公开
标题翻译：从乙醇制备油脂的方法
公开(公告)号：WO2009098267A1
公开(公告)日：2009-08-13
申请号：PCT/EP2009/051340
申请日：2009-02-05
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander , GRASSO, Giacomo
发明人： MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander , GRASSO, Giacomo
IPC分类号： C07C1/24 , C07C11/02
CPC分类号： C10G11/05 , C07C1/20 , C07C1/24 , C07C4/06 , C07C11/06 , C07C2529/035 , C07C2529/70 , C07C2529/85 , Y02P30/42 , C07C11/04
摘要： The present invention relates to a process for the conversion of ethanol to make essentially ethylene and propylene, comprising : a) introducing in a reactor (A) (also called the first low temperature reaction zone) a stream comprising ethanol under a partial pressure at least about 0.2 MPa, optionally water, optionally an inert component; b) contacting said stream with a catalyst (A1) in said reactor (A) at conditions effective to convert at least a portion of the ethanol to essentially ethylene, propylene and olefins having 4 carbon atoms or more (C4+ olefins); c) recovering from said reactor an effluent comprising : ethylene and C4+ fraction containng mainly olefins having 4 carbon atoms or more (C4+ olefins), propylene and various hydrocarbons, water, optionally unconverted ethanol and the optional inert component of step a); d) fractionating said effluent of step c) to remove water, unconverted ethanol, optionally the inert component, optionally the propylene and optionally the whole or a part of the various hydrocarbons to get a stream (D) comprising essentially ethylene, olefins having 4 carbon atoms or more (C4+ olefins) and optionally the inert component; e) introducing at least a part of said stream (D) optionally mixed with a stream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins) in a OCP reactor (also called the second high temperature reaction zone) under the condition that said mixture (D)+(D1) comprises at least 10wt% of C4+ olefins; f) contacting said stream comprising at least a part of (D) and the optional (D1) in said OCP reactor with a catalyst which is selective towards light olefins in the effluent, to produce an effluent with an olefin content of lower molecular weight than that of the feedstock; g) fractionating said effluent of step f) to produce at least an ethylene stream, a propylene stream and a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, optionally recycling ethylene in whole or in part at the inlet of the OCP reactor of step f), or at the inlet of the reactor (A) or in part at the inlet of the OCP reactor of step f) and in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the OCP reactor.
摘要翻译：本发明涉及一种将乙醇转化成基本上乙烯和丙烯的方法，包括：a）至少在部分压力下将反应器（A）（也称为第一低温反应区）引入包含乙醇的料流约0.2MPa，任选的水，任选的惰性组分; b）在有效将至少一部分乙醇转化成基本上为具有4个碳原子或更多个（C 4 +烯烃）的乙烯，丙烯和烯烃的条件下，使所述料流与所述反应器（A）中的催化剂（A1）接触; c）从所述反应器回收流出物，其包含：乙烯和C4 +馏分主要含有具有4个碳原子或更多个（C 4 +烯烃）的烯烃，丙烯和各种烃，水，任选未转化的乙醇和步骤a）的任选的惰性组分; d）将步骤c）的所述流出物分馏以除去水，未转化的乙醇，任选的惰性组分，任选的丙烯和任选的各种烃的全部或部分，以获得基本上包含乙烯，含有4个碳的烯烃原子或更多（C4 +烯烃）和任选的惰性组分; e）在OCP反应器（也称为第二高温反应区）中将至少一部分所述物流（D）任选与包含具有4个碳原子或更多个（C 4 +烯烃）的烯烃的物流（D1）所述混合物（D）+（D1）包含至少10重量％的C 4 +烯烃; f）使所述OCP反应器中包含至少一部分（D）和任选的（D1）的物流与在流出物中对轻质烯烃有选择性的催化剂接触，以产生具有低于原料的; g）将步骤f）的所述流出物分馏以产生至少一种乙烯流，丙烯料流和基本上由具有4个碳原子或更多碳原子的烃组成的馏分，任选地将乙烯全部或部分在OCP反应器的入口步骤f），或在反应器（A）的入口处或部分在步骤f）的OCP反应器的入口处，部分地在反应器（A）的入口处，可任选地再循环基本上由以下物质组成的馏分：具有在OCP反应器的入口处具有4个或更多个碳原子。

28. 发明申请

WO2009065898A1 PRODUCTION OF LIGHT OLEFINS AND ISOPRENE FROM BUTANE 审中-公开
标题翻译：从丁醇生产轻油脂和异丙酚
公开(公告)号：WO2009065898A1
公开(公告)日：2009-05-28
申请号：PCT/EP2008/065926
申请日：2008-11-20
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , VERMEIREN, Walter , BOUVART, François
发明人： VERMEIREN, Walter , BOUVART, François
IPC分类号： C07C11/18
CPC分类号： C07C11/04 , C07C4/04 , C07C5/333 , C07C7/04 , C07C11/06 , C07C11/10 , C07C407/00 , C07C9/10 , C07C9/12 , C07C11/09 , C07C409/04
摘要： Process for the selective production of ethylene, propylene and isoprene from light hydrocarbons comprising: a) fractionating a butane fraction in a de-isobutanizer to obtain an enriched iso-butane fraction and an enriched normal-butane fraction, b) cracking said normal-butane fraction and optionally an ethane fraction, optionally a propane fraction, in a non-catalytic cracking zone to produce an olefin rich stream, c) treating said olefin rich stream in a separating section to recover : an ethylene stream, a propylene stream, d) transforming the recovered iso-butane of step a) into iso-butene or t-butyl hydroperoxide or partly into iso-butene and partly into t-butyl hydroperoxide, e) optionally reacting iso-butene of step d), if any, with formaldehyde to make isoprene, f) optionally reacting t-butyl hydroperoxide of step d), if any, with an olefin to give an epoxide and t-butanol and further separating t-butanol, or optionally having t-butyl hydroperoxide of step d), if any, decomposed to t-butanol and reacted with formaldehyde to give isoprene, or reacting a part of the t-butyl hydroperoxide of step d) with an olefin and having the remaining part decomposed to t-butanol and reacted with formaldehyde to give isoprene, g) dehydrating the t-butanol recovered at step f), if any, into iso-butene and reacting said iso-butene with formaldehyde to make isoprene, or reacting directly the t-butanol recovered at step f), if any, with formaldehyde to make isoprene, or dehydrating the t-butanol recovered at step f), if any, into iso-butene, hydrogenating said iso-butene to iso-butane and oxidizing said iso-butane into t-butyl hydroperoxide, and recycling said t-butyl hydroperoxide, or dehydrating the t-butanol recovered at step f), if any, into iso-butene, then disproportionating said iso-butene and propylene recovered at step c) (or 2-butene recovered at step c)), separating an isoamylene stream and converting the isoamylene into isoprene by dehydrogenation, or making any combination of above routes of said step g), h) optionally disproportionating iso-butene of step d), if any, and propylene recovered at step c) (or 2-butene recovered at step c)), separating an isoamylene stream and converting the isoamylene into isoprene by dehydrogenation, at least one of steps e), f) and h) is not optional.
摘要翻译：从轻烃中选择性生产乙烯，丙烯和异戊二烯的方法，包括：a）在去异丁烷化器中分馏丁烷馏分以获得富集的异丁烷馏分和富含正丁烷馏分，b）裂化所述正丁烷馏分和任选的乙烷馏分，任选的丙烷馏分，以产生富烯烃流，c）在分离段中处理所述富烯烃流以回收：乙烯料流，丙烯料流，d）将步骤a）的回收的异丁烷转化为异丁烯或叔丁基过氧化氢或部分转化为异丁烯，部分转化为叔丁基过氧化氢，e）任选地使步骤d）的异丁烯与甲醛制备异戊二烯，f）任选地使步骤d）的叔丁基过氧化氢与烯烃反应，得到环氧化物和叔丁醇，并进一步分离叔丁醇或任选具有步骤d）的叔丁基过氧化氢，如果有的话，分解 d与叔丁醇反应并与甲醛反应得到异戊二烯，或使步骤d）的叔丁基过氧化氢的一部分与烯烃反应并将其余部分分解成叔丁醇并与甲醛反应得到异戊二烯，g）使步骤f）中回收的叔丁醇脱水成异丁烯，并使所述异丁烯与甲醛反应制备异戊二烯，或直接与步骤f）回收的叔丁醇反应生成甲醛或将在步骤f）中回收的叔丁醇脱水，如果有的话，将异丁烯氢化成异丁烯，将所述异丁烷氧化成叔丁基过氧化氢，并将所述叔丁基过氧化氢或将在步骤f）回收的叔丁醇脱水成异丁烯，然后歧化在步骤c）回收的所述异丁烯和丙烯（或步骤c）回收的2-丁烯）），将异戊烯流并通过脱氢将异戊烯转化为异戊二烯，或进行任何反应所述步骤g）的上述路线的bination，h）任选歧化步骤d）的异丁烯（如果有的话）和在步骤c）回收的丙烯（或在步骤c）回收的2-丁烯），分离异戊烯流并转化异戊烯通过脱氢进入异戊二烯，步骤e），f）和h）中的至少一个不是任选的。

29. 发明申请

WO2009016155A2 USE OF PHOSPHORUS MODIFIED MOLECULAR SIEVES IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：磷酸改性分子筛在有机物转化成烯烃中的应用
公开(公告)号：WO2009016155A2
公开(公告)日：2009-02-05
申请号：PCT/EP2008/059885
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , NESTERENKO, Nikolai , VERMEIREN, Walter , MINOUX, Delphine , VAN DONK, Sander
发明人： NESTERENKO, Nikolai , VERMEIREN, Walter , MINOUX, Delphine , VAN DONK, Sander
IPC分类号： C07C1/20 , C07C11/02 , B01J29/00 , B01J29/85 , C01B39/02 , C07C2/08
CPC分类号： C07C1/20 , B01J29/40 , B01J37/28 , B01J2229/18 , B01J2229/37 , C07C1/322 , C07C4/06 , C07C2529/85 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OCP process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins; wherein said P-modified zeolite (A) is made by a process comprising in that order: selecting a zeolite (advantageously with Si/AI ratio between 4 and 500) among H + or NH 4 + -form of MFI, MEL, FER, MOR, clinoptilolite; introducing P at conditions effective to introduce advantageously at least 0.05 wt% of P; separation of the solid from the liquid if any; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step.
摘要翻译：本发明涉及一种在组合的XTO-OCP方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：将含氧的含卤素或含硫的在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下，在XTO反应器中的有机原料具有由P改性沸石（A）制成的催化剂; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下，使所述OCP反应器中的所述重质烃馏分与由P-改性沸石（A）制成的催化剂接触; 其中所述P型改性沸石（A）通过以下方法制备：在MFI，MEL，FER，MOR，HNO 3的H +或NH 4 +形式中选择沸石（有利地具有4至500的Si / Al比）斜发沸石; 在有效引入至少0.05重量％的P的条件下引入P; 从液体中分离出固体物质; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。

30. 发明申请

WO2008110530A1 MTO PROCESS BASED ON MEAPO MOLECULAR SIEVES COMBINED WITH AN OCP PROCESS TO MAKE OLEFINS 审中-公开
标题翻译：基于与OCP方法组合的MEAPO分子筛的MTO方法制备OLEFINS
公开(公告)号：WO2008110530A1
公开(公告)日：2008-09-18
申请号：PCT/EP2008/052816
申请日：2008-03-10
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , VERMEIREN, Walter , NESTERENKO, Nikolai
发明人： VERMEIREN, Walter , NESTERENKO, Nikolai
IPC分类号： C07C1/20 , C07C4/06 , C07C11/04 , C07C11/06 , C08F10/02 , C08F10/06
CPC分类号： C07C11/04 , C01B3/44 , C07C1/20 , C07C1/26 , C07C4/06 , C07C11/06 , C07C17/10 , C07C2529/035 , C07C2529/40 , C07C2529/85 , C10G3/45 , C10G3/49 , C10G2300/202 , C10G2300/4081 , C10G2300/802 , C10G2400/20 , Y02P20/52 , Y02P30/42 , C07C9/00 , C07C19/075
摘要： The present invention relates to a process to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in a primary reactor with a catalyst made of a metalloaluminophosphate (MeAPO) molecular sieve with lamellar crystal morphology at conditions effective to convert at least a portion of the feedstock to form a first reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in a second reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins; wherein said MeAPO has an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula H x Me y Al z P k O 2 in which, y+z+k=1 x = 10 and advantageously ranges from 10 to 100.
摘要翻译：本发明涉及从含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：将初级反应器中的含氧，含卤化物或含硫有机原料与催化剂接触在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃部分的第一反应器流出物的条件下，由具有层状晶体形态的金属铝磷酸盐（MeAPO）分子筛制成; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下使所述重质烃馏分在第二反应器中接触; 其中所述MeAPO具有在无水基础上的经验化学组成，在合成和煅烧之后，由下式表示：其中R 1，R 2，R 3，其中，y + z + k = 1 x <= yy具有范围从0.0008至0.4，有利地为0.005至0.18 z的值具有范围 0.25至0.67和有利地从0.38至0.55k的值具有0.2至0.67的值，有利地为0.36至0.54，所述分子筛主要具有平板晶体形态，其中宽度（W）和厚度（T）：W / T> 10，有利地在10-100范围内。

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