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21. 发明申请

WO2009016153A2 PHOSPHORUS MODIFIED MOLECULAR SIEVES, THEIR USE IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：磷酸改性分子筛，它们在有机物转化成烯烃中的用途
公开(公告)号：WO2009016153A2
公开(公告)日：2009-02-05
申请号：PCT/EP2008/059883
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , NESTERENKO, Nikolai , VERMEIREN, Walter , MINOUX, Delphine , VAN DONK, Sander
发明人： NESTERENKO, Nikolai , VERMEIREN, Walter , MINOUX, Delphine , VAN DONK, Sander
IPC分类号： B01J29/85 , C01B39/02 , C07C2/08 , C07C11/02 , C07C1/20
CPC分类号： C07C1/322 , B01J29/40 , B01J29/85 , B01J2229/36 , B01J2229/37 , C01B39/026 , C07C1/20 , C07C1/22 , C07C1/26 , C07C2/06 , C07C4/06 , C07C7/04 , C07C2529/85 , C10G3/00 , C10G2300/202 , C10G2300/4081 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C11/06
摘要： The present invention is a phosphorous modified zeolite (A) made by a process comprising in that order: selecting a zeolite with low Si/AI ratio (advantageously lower than 30) among H + or NH 4 + -form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870°C for 0.01-200h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.3 wt% of P; separation of the solid from the liquid; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step. The present invention also relates to a process (hereunder referred as "XTO process") for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted with the above catalyst (in the XTO reactor) under conditions effective to convert at least a portion of the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The present invention also relates to a process (hereunder referred as "combined XTO and OCP process") to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the above catalyst at conditions effective to convert at least a portion of the feedstock to form an XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明是通过以下方法制备的磷改性沸石（A）：在MFI，MEL，FER，MOR的H +或NH4 +形式中选择具有低Si / Al比（有利地低于30）的沸石，斜发沸石，所述沸石优选不直接添加有机模板; 在400〜870℃的温度范围内蒸煮0.01〜200h; 在有效从沸石中除去大部分Al并引入至少0.3wt％P的条件下，用含有P源的酸性水溶液浸出; 从液体中分离固体; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。本发明还涉及从含氧，含卤素或含硫有机原料制造烯烃产物的方法（以下称为“XTO法”），其中所述含氧卤化物或含硫的在有效将至少一部分含氧，含卤素或含硫有机原料转化为烯烃产物（XTO反应器流出物）的条件下，有机原料与上述催化剂（在XTO反应器中）接触。本发明还涉及从含氧的含卤化物或含硫有机原料制备轻质烯烃的方法（以下称为“组合的XTO和OCP方法”），包括：使含有氧的含卤素的或含硫有机原料在具有上述催化剂的XTO反应器中，在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下使OCP反应器中的所述重质烃馏分接触。

22. 发明申请

WO2012016787A1 PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 审中-公开
标题翻译：从ISOBUTANOL制造OLEFINS的过程
公开(公告)号：WO2012016787A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/061583
申请日：2011-07-08
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
发明人： ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C1/20 , C07C4/06 , C07C11/06
CPC分类号： C07C1/24 , B01J29/40 , B01J2229/42 , C07C1/22 , C07C4/06 , C07C6/04 , C07C2529/40 , C08F10/02 , C10G3/42 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： The present invention relates to a process for the conversion of an alcohol mixture (A) comprising about 20 w% to 100% isobutanol to make essentially propylene, comprising : a)introducing in a reactor (A) a stream comprising the mixture (A), optionally water, optionally an inert component, b)contacting said stream with a catalyst (A1) at a temperature above 450°C in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c)recovering from said reactor (A) an effluent comprising : ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d)fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，，任选的水，任选的惰性组分，b）在有效使至少一部分异丁醇和其它醇脱水的条件下，在所述反应器（A）中在高于450℃的温度下将所述物流与催化剂（A1）接触，如果任何并且开裂，c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的混合物（A）的醇，各种烃和步骤a），d的任选的惰性组分的流出物）分馏步骤c）的所述流出物以产生至少一个乙烯流，丙烯流，基本上由具有4个碳原子或更多个碳原子的烃组成的馏分，水和步骤a）的任选的惰性组分，任选地将乙烯整体或部分在反应器（A）的入口，任选地在反应器（A）的入口处循环基本上由具有4个碳原子或更多碳原子的烃组成的馏分。

23. 发明申请

WO2012016786A1 PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 审中-公开
标题翻译：从ISOBUTANOL制造OLEFINS的过程
公开(公告)号：WO2012016786A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/061582
申请日：2011-07-08
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
发明人： ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C1/20 , C07C4/06 , C07C11/06
CPC分类号： C07C1/24 , C07C1/20 , C07C1/22 , C07C2/12 , C07C4/06 , C07C11/06 , C07C29/00 , C07C2529/40 , C07C2529/85 , C08F210/02 , C08F210/06 , C12P7/16 , Y02P30/42
摘要： The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w% to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), mixed with astream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 500°C in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising : ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，与包含具有4个或更多碳原子的烯烃（C 4 +烯烃），任选的水，任选的惰性组分的流动（D1）混合，b）在所述反应器（500℃）中使所述料流与催化剂（A1）在500℃以上接触 A）在有效使所述异丁醇和其它醇的至少一部分脱水的条件下（如果有的话）和破裂，c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的醇混合物（A），各种烃和步骤a）的任选的惰性组分，d）将步骤c）的所述流出物分馏以产生至少一种乙烯料流，丙烯料流，基本上由具有4个碳原子的烃组成的馏分或更多，水和th 任选地在反应器（A）的入口处全部或部分地循环乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分，。

24. 发明申请

WO2009146954A1 PROCESS FOR MAKING CRYSTALLINE METALLOSILICATES 审中-公开
标题翻译：制备晶体金属硅酸盐的方法
公开(公告)号：WO2009146954A1
公开(公告)日：2009-12-10
申请号：PCT/EP2009/052169
申请日：2009-02-24
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , BULUT, Metin , JACOBS, Pierre , MINOUX, Delphine , NESTERENKO, Nikolai , DATH, Jean-Pierre , VAN DONK, Sander
发明人： BULUT, Metin , JACOBS, Pierre , MINOUX, Delphine , NESTERENKO, Nikolai , DATH, Jean-Pierre , VAN DONK, Sander
IPC分类号： B01J29/40 , C01B39/36 , C10G11/05 , C01B39/40
CPC分类号： B01J29/40 , B01J2229/62 , C01B37/005 , C01B39/02 , C01B39/023 , C01B39/38 , C01B39/40 , C07C2/864 , C07C2529/70 , C10G29/205 , C10G2300/70 , Y02P20/52 , C07C15/08
摘要： The present invention relates to a process for making a crystalline metallosilicate composition and comprising crystallites having an inner part (the core) and an outer part (the outer layer or shell) such that : the ratio Si/Metal is higher in the outer part than in the inner part, the crystallites have a continuous distribution of metal and silicon over the crystalline cross-section, said process comprising : a) providing an aqueous medium comprising OH - anions and a metal source, b) providing an aqueous medium comprising an inorganic source of silicon and optionally a templating agent, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to partly crystallize the desired metallosilicate, e) cooling down the reaction mixture a)+b)+c) to about room temperature, f) decreasing the pH of the reaction mixture by at least 0.1 preferably by 0.3 to 4, more preferably by 0.5 to 3, g) subjecting the resulting mixture of step f) at conditions effective to continue the crystallization of the desired metallosilicate, h) recovering the desired metallosilicate, wherein at step d) in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is - /SiO 2 is at least 0.3, advantageously from 0.3 to 0.62, preferably from 0.31 to 0.61, more preferably from 0.32 to 0.61, very preferably from 0.33 to 0.6.
摘要翻译：本发明涉及一种制备结晶金属硅酸盐组合物的方法，包括具有内部（芯）和外部（外层或外壳）的微晶，使得外部部分的Si /金属比高于在内部，微晶在结晶横截面上具有金属和硅的连续分布，所述方法包括：a）提供包含OH-阴离子和金属源的水性介质，b）提供包含无机的水性介质硅源和任选的模板剂，c）任选地提供包含任选的二氧化硅有机源的非水性液体介质，d）在有效地使所需金属硅酸盐部分结晶的条件下，将介质a），b）和任选的c） e）将反应混合物a）+ b）+ c）冷却至约室温，f）将反应混合物的pH降低至少0.1，优选0.3至4，更优选0 g）使所得到的步骤f）的混合物在有效继续所需金属硅酸盐结晶的条件下进行; h）回收所需的金属硅酸盐，其中在混合物中的步骤d）a）+ b）+ c）在结晶之前，Si org / Si无机物的比率为 - / SiO 2为至少0.3，有利地为0.3至0.62，优选为0.31至0.61，更优选为0.32至0.61，非常优选为0.33至0.6。

25. 发明申请

WO2011089263A1 METHOD FOR MAKING A CATALYST COMPRISING A PHOSPHORUS MODIFIED ZEOLITE TO BE USED IN AN ALCOHOLS DEHYDRATION PROCESS 审中-公开
标题翻译：制备包含用于酒精脱水过程中的磷酸改性沸石的催化剂的方法
公开(公告)号：WO2011089263A1
公开(公告)日：2011-07-28
申请号：PCT/EP2011/050964
申请日：2011-01-25
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , NESTERENKO, Nikolai , VAN DONK, Sander , MINOUX, Delphine , DATH, Jean-Pierre
发明人： NESTERENKO, Nikolai , VAN DONK, Sander , MINOUX, Delphine , DATH, Jean-Pierre
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , B01J27/16 , B01J29/06 , B01J29/40 , B01J29/85 , B01J37/0009 , B01J37/0045 , B01J37/06 , B01J37/08 , B01J37/28 , B01J2229/18 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C2529/40 , C07C2529/85 , C07C11/02
摘要： The present invention is the use of a catalyst to convert an alcohol into light olefins in a dehydration process wherein said catalyst comprises a phosphorus modified zeolite and is made by a method comprising the following steps in this order, a) the essential portion of the phosphorus is introduced into a zeolite comprising at least one ten members ring in the structure, b) the phosphorus modified zeolite of step a) is mixed with at least a component selected among one or more binders, salts of alkali-earth metals, salts of rare-earth metals, clays and shaping additives, b)* making a catalyst body from mixture b), c) an optional drying step or an optional drying step followed by a washing step, d) a calcination step, d*) an optional washing step followed by drying, e) optionally a small portion of phosphorus is introduced in the course of step b) or b)* or at end of step b) or b)*.
摘要翻译：本发明是在脱水方法中使用催化剂将醇转化成轻质烯烃，其中所述催化剂包含磷改性沸石，并通过包括以下步骤的方法制备：a）磷的主要部分被引入到在结构中包含至少一个十元环的沸石中，b）步骤a）的磷改性沸石与至少一种选自一种或多种粘合剂，碱土金属盐，稀有盐 - 矿物金属，粘土和成型添加剂，b）*从混合物b）制备催化剂体，c）任选的干燥步骤或任选的干燥步骤，然后进行洗涤步骤，d）煅烧步骤，d *）任选洗涤步骤，然后干燥，e）任选地在步骤b）或b）*或步骤b）或b）*的末端引入少量的磷。

26. 发明申请

WO2012016788A1 PROCESS TO MAKE OLEFINS FROM METHANOL AND ISOBUTANOL 审中-公开
标题翻译：从甲醇和异丁醇制备油脂的方法
公开(公告)号：WO2012016788A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/061587
申请日：2011-07-08
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
发明人： ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C1/20 , C07C4/06 , C07C11/06
CPC分类号： C07C1/22 , B01J29/40 , B01J2229/42 , C07C1/20 , C07C1/24 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/42 , C07C11/02 , C07C11/06 , C07C11/08 , C07C11/04
摘要： The present invention relates to a process for making essentially ethylene and propylene comprising : a) providing an alcohol mixture (A) comprising about 20 w% to 100% isobutanol, b) introducing in a reactor (A) a stream comprising the mixture (A) mixed with methanol or dimethyl ether or mixture thereof, optionally water, optionally an inert component, c) contacting said stream with a catalyst (A1) in said reactor (A), the MTO reactor, at conditions effective to convert at least a part of the alcohol mixture (A) and at least a part of the methanol and/or dimethyl ether to olefins, d) recovering from said reactor (A) an effluent comprising : ethylene, propylene, butene, water, optionally unconverted alcohols, various hydrocarbons, and the optional inert component of step b), e) fractionating said effluent of step d) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种基本上制备乙烯和丙烯的方法，其包括：a）提供包含约20重量％至100重量％异丁醇的醇混合物（A），b）在反应器（A）中引入包含混合物（A ）与甲醇或二甲醚或其混合物，任选的水，任选的惰性组分混合，c）使所述流与所述反应器（A）中的催化剂（A1），所述MTO反应器在有效地转化至少一部分的醇混合物（A）和至少一部分甲醇和/或二甲醚至烯烃，d）从所述反应器（A）回收包含乙烯，丙烯，丁烯，水，任选未转化的醇，各种烃和步骤b）的任选的惰性组分，e）将步骤d）的所述流出物分馏以产生至少一种乙烯流，丙烯料流，基本上由具有4个或更多个碳原子的烃组成的馏分，水和任选的惰性合作步骤a）的组分，任选地在反应器（A）的入口处全部或部分地回收乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分。

27. 发明申请

WO2011113837A1 PROCESS TO MAKE PROPYLENE FROM ETHYLENE AND EITHER DIMETHYL ETHER, OR METHANOL AND DIMETHYL ETHER 审中-公开
标题翻译：从乙烯和二甲基醚，或甲醇和二甲醚制得丙烯的方法
公开(公告)号：WO2011113837A1
公开(公告)日：2011-09-22
申请号：PCT/EP2011/053906
申请日：2011-03-15
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , STRUELENS, Pieter , JACOBS, Pierre , NESTERENKO, Nikolai , MINOUX, Delphine , VAN DONK, Sander , DATH, Jean-Pierre
发明人： STRUELENS, Pieter , JACOBS, Pierre , NESTERENKO, Nikolai , MINOUX, Delphine , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C2/86 , C07C11/06
CPC分类号： C07C2/862 , C07C2/864 , C07C2/865 , C07C11/06
摘要： The present invention is a process to make propylene comprising : a)providing a reaction zone containing a catalyst; b) introducing a feedstock comprising ethylene, dimethyl ether or methanol and dimethyl ether comprising at least 1000 wppm of dimethyl ether, optionally steam into said reaction zone and into contact with said catalyst; c) operating said reaction zone at temperature and pressure conditions to produce an effluent comprising propylene, hydrocarbons, steam, optionally unconverted methanol and /or unconverted dimethyl ether and optionally unconverted ethylene; d) sending the effluent of step c) to a fractionation zone to recover propylene optionally methanol and /or dimethyl ether and optionally ethylene; e)optionally recycling at least a part of methanol and /or dimethyl ether and optionally recycling at least a part of ethylene to the reaction zone at step b); wherein the catalyst is an acid and the temperature at the inlet of the reaction zone is under 280°C and advantageously from 50 to 280°C.
摘要翻译：本发明是制备丙烯的方法，包括：a）提供含有催化剂的反应区; b）将包含至少1000wppm二甲醚的乙烯，二甲醚或甲醇和二甲醚的原料引入所述反应区并与所述催化剂接触; c）在温度和压力条件下操作所述反应区以产生包含丙烯，烃，蒸汽，任选未转化的甲醇和/或未转化的二甲醚和任选未转化的乙烯的流出物; d）将步骤c）的流出物送入分馏区以回收丙烯任选的甲醇和/或二甲醚和任选的乙烯; e）任选地在步骤b）将至少一部分甲醇和/或二甲醚再循环至反应区中任选地将至少一部分乙烯循环; 其中催化剂是酸，并且反应区入口处的温度低于280℃，有利地为50-280℃。

28. 发明申请

WO2009146955A1 PROCESS FOR MAKING CRYSTALLINE METALLOSILICATES 审中-公开
标题翻译：制备晶体金属硅酸盐的方法
公开(公告)号：WO2009146955A1
公开(公告)日：2009-12-10
申请号：PCT/EP2009/052170
申请日：2009-02-24
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , BULUT, Metin , JACOBS, Pierre , MINOUX, Delphine , NESTERENKO, Nikolai , DATH, Jean-Pierre , VAN DONK, Sander
发明人： BULUT, Metin , JACOBS, Pierre , MINOUX, Delphine , NESTERENKO, Nikolai , DATH, Jean-Pierre , VAN DONK, Sander
IPC分类号： B01J29/40 , C01B39/36 , C10G11/05
CPC分类号： C01B37/005 , B01J29/40 , B01J29/42 , B01J29/48 , C01B39/02 , C01B39/38 , C01P2002/72
摘要： The present invention provides a method for preparing a metallosilicate of MFI type, wherein organic templates, seeding techniques, using low aliphatic alcohols miscible with water or homogeneous starting solutions are not required. The present invention relates to a process for making a crystalline metallosilicate with high Si/Metal ratio comprising: a) providing an aqueous medium comprising OH− anions and a metal source, b) providing an aqueous medium comprising an inorganic water insoluble source of silicon, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to crystallize the desired metallosilicate, e) recovering the desired metallosilicate, wherein in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is 2 is at least 0.3, advantageously from 0.3 to 0.62, preferably from 0.31 to 0.61, more preferably from 0.32 to 0.61, very preferably from 0.33 to 0.6 and there is essentially no template. In another embodiment steps e), f) and g) are inserted before recovering the desired metallosilicate : e) cooling down the reaction mixture a)+b)+c) to about room temperature, f) decreasing the pH of the reaction mixture by at least 0.1 preferably by 0.3 to 4, more preferably by 0.5 to 3, g) subjecting the resulting mixture of step f) at conditions effective to continue the crystallization of the desired metallosilicate.
摘要翻译：本发明提供了一种制备MFI型金属硅酸盐的方法，其中不需要使用与水混合的低脂肪醇或均相起始溶液的有机模板，接种技术。本发明涉及一种制备具有高Si /金属比的结晶金属硅酸盐的方法，其包括：a）提供包含OH-阴离子和金属源的水性介质，b）提供包含无机水不溶性硅源的水性介质， c）任选地提供包含任选的二氧化硅有机源的非水液体培养基，d）在有效使结晶期望的金属硅酸盐的条件下混合培养基a），b）和任选的c），e）回收所需的金属硅酸盐，其中混合物a）+ b）+ c），在结晶之前，Si org / Si无机物的比率为2为至少0.3，有利地为0.3至0.62，优选为0.31至0.61，更优选为0.32至0.61，非常优选为 0.33〜0.6，基本上没有模板。在另一个实施方案中，在回收期望的金属硅酸盐之前，插入步骤e），f）和g）步骤：e）将反应混合物a）+ b）+ c）冷却至约室温，f）将反应混合物的pH降低至少0.1，优选0.3至4，更优选0.5至3，g）使所得到的步骤f）的混合物在有效继续所需金属硅酸盐结晶的条件下进行。

29. 发明申请

WO2009146953A1 PROCESS FOR MAKING CRYSTALLINE METALLOSILICATES 审中-公开
标题翻译：制备晶体金属硅酸盐的方法
公开(公告)号：WO2009146953A1
公开(公告)日：2009-12-10
申请号：PCT/EP2009/052168
申请日：2009-02-24
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , BULUT, Metin , JACOBS, Pierre , MINOUX, Delphine , NESTERENKO, Nikolai , DATH, Jean-Pierre , VAN DONK, Sander
发明人： BULUT, Metin , JACOBS, Pierre , MINOUX, Delphine , NESTERENKO, Nikolai , DATH, Jean-Pierre , VAN DONK, Sander
IPC分类号： B01J29/40 , C01B39/40 , C10G11/05 , C01B39/36
CPC分类号： B01J29/40 , B01J2229/62 , C01B37/005 , C01B39/02 , C01B39/04 , C01B39/38 , C01B39/40 , C07C2/864 , C07C2529/70 , C10G29/205 , Y02P20/52 , C07C15/08
摘要： The present invention relates to a process for making a crystalline metallosilicate composition comprising crystallites having an inner part (the core) and an outer part (the outer layer or shell) such that : the ratio Si/metal is higher in the outer part than in the inner part, the crystallites have a continuous distribution of metal and silicon over the crystalline cross-section, said process comprising : a) providing an aqueous medium comprising OH - anions and a metal source, b) providing an aqueous medium comprising an inorganic source of silicon and optionally a templating agent, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to crystallyze the desired metallosilicate, e) recovering the desired metallosilicate, wherein in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is - /SiO 2 is at least 0.3, advantageously from 0.3 to 0.62, preferably from 0.31 to 0.61, more preferably from 0.32 to 0.61, very preferably from 0.33 to 0.6 and the pH of the mixture a)+b)+c), before crystallization, is higher than 13, preferably higher than 13.1, more preferably higher than 13.2, still more preferably higher than 13.3 and most preferred higher than 13.4.
摘要翻译：本发明涉及一种制备结晶金属硅酸盐组合物的方法，其包含具有内部部分（芯部）和外部部分（外层或外壳）的微晶，使得：外部部分的Si /金属比例高于所述内部部分，所述微晶在结晶截面上具有金属和硅的连续分布，所述方法包括：a）提供包含OH-阴离子和金属源的水性介质，b）提供包含无机源的水性介质的硅和任选的模板剂，c）任选地提供包含任选的二氧化硅有机源的非水性液体培养基，d）在有效地使所需的金属硅酸盐水解的条件下，将培养基a），b）和任选的c））回收所需的金属硅酸盐，其中在混合物a）+ b）+ c）中，在结晶之前，Si org / Si无机物的比率为至少0.3，有利地为0.3至0.62，优选为0.31至0.61，更优选为0.32至0.61，非常优选为0.33至0.6，结晶前混合物a）+ b）+ c）的pH高于13，优选高于13.1，更优选高于超过13.2，还更优选高于13.3，最优选高于13.4。

30. 发明申请

WO2012016785A1 COMBINED PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 审中-公开
标题翻译：从ISOBUTANOL制造OLEFINS的组合方法
公开(公告)号：WO2012016785A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/061581
申请日：2011-07-08
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
发明人： ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C1/20 , C07C4/06 , C07C11/06 , C07C1/24
CPC分类号： C07C1/24 , B01J21/04 , B01J29/40 , B01J29/65 , C07C4/06 , C07C2521/04 , C07C2529/40 , C07C2529/65 , C07C2529/85 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w% to 100% isobutanol to make essentially propylene, comprising : a) introducing in a reactor (A) (also called the first reaction zone or low temperature reaction zone) a stream comprising the mixture (A), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1 ) in said reactor (A) at conditions effective to dehydrate : at least a portion of the isobutanol to essentially butenes, at least a portion of other alcohols, if any, to essentially olefins other than butene having the same carbon number as the alcohol precursor, c) recovering from said reactor (A) an effluent comprising : butenes, optionally olefins other than butene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to remove a portion or all the water, unconverted alcohols, optionally the inert component, and optionally the whole or a part of the various hydrocarbons to get a stream (D) comprising essentially olefins and optionally the inert component, e) introducing at least a part of said stream (D) in an OCP reactor (also called the second reaction zone or high temperature zone), f) contacting said stream comprising at least a part of (D), optionally in combination with a stream (D1 ) comprising olefins having 4 carbon atoms or more (C4+ olefins), in said OCP reactor with a catalyst which is selective towards light olefins in the effluent, to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, g) fractionating said effluent of step f) to produce at least an ethylene stream, a propylene stream and a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, optionally recycling ethylene in whole or in part at the inlet of the OCP reactor of step f), or at the inlet of the reactor (A) or at the inlet of both the OCP reactor of step f) and the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the OCP reactor.
摘要翻译：本发明涉及一种将包含约20W％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）（也称为第一反应区或低温反应区）包含混合物（A）的物流，任选的水，任选的惰性组分，b）在有效脱水的条件下使所述物流与所述反应器（A）中的催化剂（A1）接触：至少部分异丁醇至基本上丁烯，至少一部分其它醇（如果有的话）至具有与醇前体相同碳数的丁烯以外的基本上烯烃，c）从所述反应器（A）回收包含丁烯，任选烯烃除了丁烯，水，任选的未转化的混合物（A）的醇，各种烃和步骤a）的任选的惰性组分，d）分级步骤c）的所述流出物以除去未转化的部分或全部水醇，任选的惰性组分，以及任选的各种烃的全部或部分，以获得基本上含有烯烃和任选的惰性组分的流（D），e）将至少一部分所述流（D）引入OCP 反应器（也称为第二反应区或高温区），f）使包含至少一部分（D）的物流，任选与包含具有4个碳原子或更多个（C4 +烯烃）的烯烃的物流（D1）在所述OCP反应器中具有对流出物中的轻质烯烃具有选择性的催化剂，以产生具有比原料低的分子量的烯烃含量的流出物，g）将步骤f）的所述流出物分馏以产生至少一种乙烯流，丙烯料流和基本上由具有4个或更多碳原子的烃组成的馏分，任选地在步骤f）的OCP反应器的入口处全部或部分地回收乙烯，或在反应器的入口处（A）或在步骤f）的OCP反应器和反应器（A）的入口处，任选地在OCP反应器的入口处循环基本上由具有4个碳原子或更多个碳原子的烃组成的馏分。

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