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21. 发明授权

US08399097B2 High clarity laminated articles comprising an ionomer interlayer 有权
标题翻译：包含离聚物夹层的高透明层压制品
公开(公告)号：US08399097B2
公开(公告)日：2013-03-19
申请号：US12610688
申请日：2009-11-02
申请人： Stephen J. Bennison , Richard Allen Hayes , Steven C. Pesek , W Alexander Shaffer , Charles Anthony Smith
发明人： Stephen J. Bennison , Richard Allen Hayes , Steven C. Pesek , W Alexander Shaffer , Charles Anthony Smith
IPC分类号： B32B17/10 , B32B27/32 , B32B15/08 , B32B27/36
CPC分类号： C08F220/06 , B32B17/10018 , B32B17/10036 , B32B17/10743 , Y10T428/31507 , Y10T428/31645 , Y10T428/31692 , Y10T428/31938
摘要： A safety laminate comprises an interlayer that comprises an ionomer that is the neutralized product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of a first α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of a first α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms; and has a melt flow rate of about 10 to about 4000 g/10 min. When neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. The ionomer composition may further comprise a second ionomer that has a melt flow rate of about 10 g/10 min or less.
摘要翻译：安全层压板包括中间层，其包含作为前体酸共聚物的中和物的离聚物。前体酸共聚物包含具有2至10个碳原子的第一α-烯烃和约20至约30重量％的具有3-8个碳原子的第一个α，β-烯属不饱和羧酸的共聚单元的共聚单元; 并具有约10至约4000g / 10min的熔体流动速率。当中和至约40％至约90％的水平时，当包含基本上由钠阳离子组成的抗衡离子时，前体酸共聚物产生熔体流动速率为约0.7至约25g / 10min的钠离聚物，不可检测的或低于约3.0J / g的冷冻焓。离聚物组合物还可以包含熔体流动速率为约10g / 10分钟或更短的第二离聚物。

22. 发明授权

US08399096B2 High-clarity ionomer compositions and articles comprising the same 有权
标题翻译：高透明度离聚物组合物和包含其的制品
公开(公告)号：US08399096B2
公开(公告)日：2013-03-19
申请号：US12610678
申请日：2009-11-02
申请人： Karlheinz Hausmann , Richard Allen Hayes , Steven C. Pesek , W Alexander Shaffer , Charles Anthony Smith
发明人： Karlheinz Hausmann , Richard Allen Hayes , Steven C. Pesek , W Alexander Shaffer , Charles Anthony Smith
IPC分类号： B32B17/10 , B32B27/32 , B32B15/08 , B32B27/36 , C08F20/06
CPC分类号： C08F8/44 , Y10T428/1352 , Y10T428/269 , Y10T428/31507 , Y10T428/31645 , Y10T428/31692 , Y10T428/31938 , C08F210/02 , C08F220/06
摘要： An ionomer composition comprises an ionomer that is the neutralized product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt %, based on the total weight of the precursor acid copolymer, of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms; a melt flow rate of about 10 to about 4000 g/10 min; and, when neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. Further provided are articles comprising the ionomer composition.
摘要翻译：离聚物组合物包含作为前体酸共聚物的中和物的离聚物。前体酸共聚物包含基于前体酸共聚物的总重量的具有2至10个碳原子的α-烯烃和约20至约30重量％的共聚单元的共聚单元，α和bgr-烯属不饱和单体具有3-8个碳原子的羧酸; 约10至约4000g / 10min的熔体流动速率; 并且当被中和至约40％至约90％的水平时，并且当包含基本上由钠阳离子组成的抗衡离子时，前体酸共聚物产生具有约0.7至约25g / 10min的熔体流动速率的钠离聚物和不可检测或小于约3.0J / g的冷冻焓。还提供了包含离聚物组合物的制品。

23. 发明授权

US08399081B2 Solar cell modules comprising encapsulant sheets with low haze and high moisture resistance 有权
标题翻译：太阳能电池组件包括具有低雾度和高耐湿性的密封片
公开(公告)号：US08399081B2
公开(公告)日：2013-03-19
申请号：US12610435
申请日：2009-11-02
申请人： Richard Allen Hayes , Steven C. Pesek , W Alexander Shaffer , Charles Anthony Smith , George Wyatt Prejean
发明人： Richard Allen Hayes , Steven C. Pesek , W Alexander Shaffer , Charles Anthony Smith , George Wyatt Prejean
IPC分类号： B32B27/32 , B32B15/08 , B32B17/10 , H01L31/048 , H01L31/042 , H01L21/56 , C08F8/00 , C08F20/06
CPC分类号： B32B17/10743 , B32B17/10853 , H01L31/0481 , Y02E10/50 , Y10T428/1352 , Y10T428/269 , Y10T428/31645 , Y10T428/31855
摘要： A solar cell module comprising a solar cell layer and an ionomer sheet comprising a sodium/zinc mixed ionomer that is the neutralization product of a precursor acid copolymer; wherein the precursor acid copolymer comprises copolymerized units of an α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms based on the total weight of the precursor acid copolymer; wherein the precursor acid copolymer has a melt flow rate of about 70 to about 1000 g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg; and wherein when about 40% to about 90% of the total content of the carboxylic acid groups present in the precursor acid copolymer are neutralized to carboxylate groups to comprise carboxylate groups and counterions that consist essentially of sodium ions, the resulting sodium ionomer has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry in accordance with ASTM D3418.
摘要翻译：一种太阳能电池组件，包括太阳能电池层和离子聚合物片，其包含作为前体酸共聚物的中和产物的钠/锌混合离聚物; 其中所述前体酸共聚物包括具有2至10个碳原子的α-烯烃和约20至约30重量％共聚单元的基于所述共聚单元的具有3至8个碳原子的α，bgr- - 烯键式不饱和羧酸的共聚单元前体酸共聚物的总重量; 其中所述前体酸共聚物的熔体流动速率为约70至约1000g / 10min，根据ASTM D1238在190℃和2.16kg下测定; 并且其中当存在于前体酸共聚物中的羧酸基团的总含量的约40％至约90％被中和到羧酸酯基团以包含基本上由钠离子组成的羧酸酯基团和抗衡离子时，所得钠离子共聚物具有冷冻当通过根据ASTM D3418的差示扫描量热法测定时，不可检测的焓或小于约3.0J / g的焓。

24. 发明授权

US08334033B2 Ionomer compositions with low haze and high moisture resistance and articles comprising the same 有权
标题翻译：具有低雾度和高防潮性的离子聚合物组合物和包含其的制品
公开(公告)号：US08334033B2
公开(公告)日：2012-12-18
申请号：US12610881
申请日：2009-11-02
申请人： Karlheinz Hausmann , Richard Allen Hayes , Steven C. Pesek , W Alexander Shaffer , Charles Anthony Smith
发明人： Karlheinz Hausmann , Richard Allen Hayes , Steven C. Pesek , W Alexander Shaffer , Charles Anthony Smith
IPC分类号： B32B27/32 , B32B15/08 , B32B17/10 , C08F8/00 , C08F20/06
CPC分类号： B32B17/10036 , B32B17/10743 , C08F8/44 , C08F210/02 , C08F2800/20 , C08L23/0876 , C08L2205/02 , Y10T428/1352 , Y10T428/265 , Y10T428/269 , Y10T428/31645 , Y10T428/31855 , C08L2666/06 , C08F220/06
摘要： A sodium/zinc mixed ionomer comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 10 to about 4000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry. Further provided are articles comprising or prepared from the sodium/zinc mixed ionomer.
摘要翻译：钠/锌混合离聚物包括羧酸根基团和基本上由钠阳离子和锌阳离子组成的抗衡离子的组合。钠/锌混合离聚物是前体酸共聚物的中和产物。前体酸共聚物包括α-烯烃和α，β-烯键式不饱和羧酸的共聚单元，其熔体流动速率为约10至约4000g / 10min。此外，当将前体酸共聚物中和至约40％至约90％的水平时，并且当包含基本上由钠离子组成的抗衡离子时，产生具有不可检测或较少的冷冻焓的钠离聚物当用差示扫描量热法测定时，约为3.0J / g。还提供了包含或由钠/锌混合离聚物制备的制品。

25. 发明申请

US20100108125A1 SOLAR CELL MODULE HAVING A LOW HAZE ENCAPSULANT LAYER 有权
标题翻译：具有低密度封装层的太阳能电池模块
公开(公告)号：US20100108125A1
公开(公告)日：2010-05-06
申请号：US12475776
申请日：2009-06-01
申请人： RICHARD ALLEN HAYES , Rebecca L. Smith , Kristof Proost , Steven C. Pesek , Charles Anthony Smith
发明人： RICHARD ALLEN HAYES , Rebecca L. Smith , Kristof Proost , Steven C. Pesek , Charles Anthony Smith
IPC分类号： H01L31/048 , H01L31/042 , B32B37/02
CPC分类号： B32B17/10743 , B32B9/005 , B32B15/04 , B32B17/10018 , B32B17/10036 , B32B17/10853 , B32B27/06 , B32B27/08 , B32B27/18 , B32B27/20 , B32B27/283 , B32B27/286 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/308 , B32B27/34 , B32B27/36 , B32B27/365 , B32B27/38 , B32B27/40 , B32B2255/26 , B32B2270/00 , B32B2307/3065 , B32B2307/308 , B32B2307/412 , B32B2307/54 , B32B2307/558 , B32B2327/12 , B32B2457/00 , H01L31/0481 , Y02E10/549 , Y02P70/521 , Y10T156/10 , Y10T156/1093 , C08F210/02 , C08F220/06 , C08F2500/12
摘要： A solar cell module comprising a solar cell layer and a sheet comprising at least one layer of a sodium ionomer composition, wherein the sodium ionomer composition consists essentially of a sodium ionomer that is an ionic, neutralized derivative of a precursor α-olefin carboxylic acid copolymer, wherein about 10% to about 35% of the total content of the carboxylic acid groups present in the precursor α-olefin carboxylic acid copolymer have been neutralized with sodium ions, and wherein the precursor α-olefin carboxylic acid copolymer comprises (i) copolymerized units of an α-olefin having 2 to 10 carbons and (ii) about 20 to about 25 wt %, based on the total weight of the α-olefin carboxylic acid copolymer, of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8.
摘要翻译：一种太阳能电池模块，包括太阳能电池层和包含至少一层钠离子交联聚合物组合物的片材，其中所述钠离子共聚物组合物基本上由钠离子共聚物组成，所述钠离子交联剂是前体α-烯烃羧酸共聚物的离子型中和衍生物其中存在于前体α-烯烃羧酸共聚物中的羧酸基团的总含量的约10％至约35％已用钠离子中和，并且其中前体α-烯烃羧酸共聚物包含（i）共聚合具有2-10个碳原子的α-烯烃的单元和（ii）基于α-烯烃羧酸共聚物的总重量的约20至约25重量％的α，b-烯属不饱和羧酸的共聚单元酸为3〜8。

26. 发明申请

US20090297747A1 MOLDED ARTICLES COMPRISING IONOMER COMPOSITIONS 审中-公开
标题翻译：包含离子组合物的模制文章
公开(公告)号：US20090297747A1
公开(公告)日：2009-12-03
申请号：US12475737
申请日：2009-06-01
申请人： KARLHEINZ HAUSMANN , Steven C. Pesek , Charles Anthony Smith
发明人： KARLHEINZ HAUSMANN , Steven C. Pesek , Charles Anthony Smith
IPC分类号： B32B1/02 , B32B5/00 , B29C47/00 , B29C49/00 , B29C43/00 , B29C45/00
CPC分类号： B32B27/28 , B32B27/08 , B32B27/20 , B32B2262/101 , B32B2307/3065 , B32B2307/40 , B32B2437/02 , B32B2439/00 , B32B2457/00 , B32B2535/00 , B32B2607/00 , C08F8/44 , C08F220/06 , C08F2800/20 , C08F2810/50 , C08L23/0876 , Y10T428/1352 , C08F210/02
摘要： A molded article comprises an ionomer composition and has improved optical properties. The ionomer composition comprises an ionomer that is produced by partially neutralizing a precursor acid copolymer ant that has a melt index of about 400 g/10 min or less. The precursor acid copolymer comprises copolymerized units of an a-olefin having 2 to 10 carbons and, based on the total weight of the precursor acid copolymer, about 19.5 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbons.
摘要翻译：模制品包含离聚物组合物并具有改善的光学性能。离子键合物组合物包含通过部分中和熔体指数为约400g / 10min或更低的前体酸共聚物is制备的离聚物。前体酸共聚物包含具有2至10个碳的α-烯烃的共聚单元，并且基于前体酸共聚物的总重量，约19.5至约30重量％的α，β-烯属不饱和羧酸的共聚单元具有3至8个碳。

27. 发明授权

US07851694B2 Embossed high modulus encapsulant sheets for solar cells 有权
标题翻译：用于太阳能电池的压花高模量密封片
公开(公告)号：US07851694B2
公开(公告)日：2010-12-14
申请号：US11491341
申请日：2006-07-21
申请人： Jerrel C. Anderson , Richard Allen Hayes , Geraldine M. Lenges , Charles Anthony Smith
发明人： Jerrel C. Anderson , Richard Allen Hayes , Geraldine M. Lenges , Charles Anthony Smith
IPC分类号： H01L31/00
CPC分类号： B32B17/10587 , B32B17/10743 , B32B17/10853 , B32B17/10862 , B32B27/32 , H01L31/048 , H01L31/0481 , Y02E10/50
摘要： A thermoplastic film or sheet having a thickness of about 1 mil (0.026 mm) to about 20 mils (0.51 mm) containing a surface embossed layer comprising a copolymer of alpha olefin(s) with alpha, beta ethylenically unsaturated carboxylic acid comonomer(s), ionomers derived therefrom and combinations thereof useful for making solar cell laminates, wherein the surface is embossed with a pattern which provides channels for de-airing, the channels having depth of about 20 microns or less, a width of about 30 microns to about 300 microns and spaced about 0.1 mm to about 1 mm apart, and use thereof in photovoltaic cells and the manufacture thereof.
摘要翻译：具有约1密耳（0.026mm）至约20密耳（0.51mm）的厚度的热塑性膜或片材，其包含含有α烯烃与α，β-烯属不饱和羧酸共聚单体的共聚物的表面压花层，，衍生自其的离聚物及其组合可用于制造太阳能电池层压板，其中该表面用提供用于脱气的通道的图案压花，具有约20微米或更小的深度的通道，约30微米至约300的宽度微米并间隔约0.1mm至约1mm，并在光伏电池中的应用及其制造。

28. 发明申请

US20080017241A1 Embossed high modulus encapsulant sheets for solar cells 有权
标题翻译：用于太阳能电池的压花高模量密封片
公开(公告)号：US20080017241A1
公开(公告)日：2008-01-24
申请号：US11491341
申请日：2006-07-21
申请人： Jerrel C. Anderson , Richard Allen Hayes , Geraldine M. Lenges , Charles Anthony Smith
发明人： Jerrel C. Anderson , Richard Allen Hayes , Geraldine M. Lenges , Charles Anthony Smith
IPC分类号： H02N6/00
CPC分类号： B32B17/10587 , B32B17/10743 , B32B17/10853 , B32B17/10862 , B32B27/32 , H01L31/048 , H01L31/0481 , Y02E10/50
摘要： A thermoplastic film or sheet having a thickness of about 1 mil (0.026 mm) to about 20 mils (0.51 mm) containing a surface embossed layer comprising a copolymer of alpha olefin(s) with alpha, beta ethylenically unsaturated carboxylic acid comonomer(s), ionomers derived therefrom and combinations thereof useful for making solar cell laminates, wherein the surface is embossed with a pattern which provides channels for de-airing, the channels having depth of about 20 microns or less, a width of about 30 microns to about 300 microns and spaced about 0.1 mm to about 1 mm apart, and use thereof in photovoltaic cells and the manufacture thereof.
摘要翻译：具有约1密耳（0.026mm）至约20密耳（0.51mm）的厚度的热塑性膜或片材，其包含含有α烯烃与α，β-烯属不饱和羧酸共聚单体的共聚物的表面压花层，，衍生自其的离聚物及其组合可用于制造太阳能电池层压板，其中该表面用提供用于脱气的通道的图案压花，具有约20微米或更小的深度的通道，约30微米至约300的宽度微米并间隔约0.1mm至约1mm，并在光伏电池中的应用及其制造。

29. 发明申请

US20160071320A1 HUD Object Design and Method 审中-公开
标题翻译： HUD对象设计与方法
公开(公告)号：US20160071320A1
公开(公告)日：2016-03-10
申请号：US14786094
申请日：2014-05-29
申请人： Charles Anthony SMITH
发明人： Charles Anthony Smith
IPC分类号： G06T19/00 , G02B27/01 , G02B27/22 , G06T19/20
CPC分类号： G06T19/006 , G02B27/017 , G02B27/22 , G02B2027/0134 , G02B2027/0138 , G02B2027/014 , G02B2027/0178 , G02B2027/0187 , G06T19/20 , G06T2219/024 , G06T2219/2016
摘要： The invention features a rectangular 3-D modeling grid called a display environment that may be mapped to one or more sensor(s) to provide a heads up display device the ability to generate and view an Augmented Reality first; person view of custom 3-D objects. Location sensors create the positioning and perimeter of the display environment. The Display Environment may Sbe navigated by the combination of the display device's physical movement sensed by motion sensors and the display device's physical location based on its proximity to synchronized location sensors. Sensors on the display device recognize when the device is moving with respect to the Display Environment to initiate re-rendering of its 3-D model being displayed. Movement of the display device enable first person 3-D model illustrative and perspective views which may also be used to design 3-D models with customizable scale, orientation, positioning physics, and artificial intelligence.
摘要翻译：本发明的特征在于一种称为显示环境的矩形3维建模网格，其可被映射到一个或多个传感器以提供抬头显示设备首先生成和查看增强现实的能力; 人物视图的自定义3D对象。位置传感器创建显示环境的定位和周边。显示环境可以通过由运动传感器感测的显示设备的物理运动和显示设备的物理位置的组合基于其与同步位置传感器的接近度来导航。显示设备上的传感器识别设备何时相对于显示环境移动，以启动正在显示的3D模型的重新渲染。显示装置的移动使得第一人称3-D模型的说明性和透视图也可用于设计具有可定制的刻度，定位，定位物理和人造智能的3-D模型。

30. 发明申请

US20100227135A1 LIGHT WEIGHT GLASS LAMINATES 审中-公开
标题翻译：轻量玻璃层压板
公开(公告)号：US20100227135A1
公开(公告)日：2010-09-09
申请号：US12719381
申请日：2010-03-08
申请人： NAOTO TAKAGI , Jun Koishikawa , Kristof Proost , Jane Kapur , Charles Anthony Smith
发明人： NAOTO TAKAGI , Jun Koishikawa , Kristof Proost , Jane Kapur , Charles Anthony Smith
IPC分类号： B32B7/02 , B32B17/10
CPC分类号： B32B7/02 , B32B3/06 , B32B17/10018 , B32B17/10036 , B32B17/10045 , B32B17/10293 , B32B17/10743 , B32B17/1088 , B32B17/10972 , Y10T428/24777 , Y10T428/24967 , Y10T428/266 , Y10T428/269
摘要： Provided herein are light weight glass laminates having ionomeric interlayers and at least one glass layer. In particular, the weight of the glass laminates is reduced by reducing the thickness of the at least one glass layer to about 2.0 mm or less, or to about 1.5 mm or less. The light weight laminates retain favorable performance properties such as have good Pummel adhesion levels, good moisture resistance, and low stress. Further provided are lightweight glass laminates equipped with integral mounting devices.
摘要翻译：本文提供了具有离聚物中间层和至少一个玻璃层的轻质玻璃层压体。特别地，通过将至少一个玻璃层的厚度减小到约2.0mm或更小，或者为约1.5mm或更小，玻璃层压体的重量减小。轻质层压板保持良好的性能，如具有良好的Pummel粘附水平，良好的耐湿性和低应力。还提供了装有一体式安装装置的轻质玻璃层压板。

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