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    • 23. 发明授权
    • Water dilutable, polyester polyols and their use in coating compositions
    • 水可稀释的聚酯多元醇及其在涂料组合物中的用途
    • US5349041A
    • 1994-09-20
    • US61640
    • 1993-05-12
    • Harald BlumLothar KahlNusret YuvaManfred Bock
    • Harald BlumLothar KahlNusret YuvaManfred Bock
    • C08G18/42C08G18/08C08G18/40C08G18/44C08G18/46C08G18/66C08G63/60C08G63/64C08G63/685C08G63/91C09D167/00C09D167/02C09D175/04C09D175/06C09J167/00C09J167/02C09J175/00C09J175/06C09K3/10C08G18/32C08G18/38
    • C09K3/1021C08G18/0823C08G18/44C08G18/6659C09D175/04C08G2190/00C09K2200/0645C09K2200/0655Y10S528/904
    • The present invention relates to water dilutable, urethane group-containing polyester polyols having an acid number of 6 to 45 mg KOH/g, wherein 25 to 100% of the acid groups are neutralized by bases, a hydroxyl number of 20 to 250 mg KOH/g, a molecular weight (M.sub.w) of 2,000 to 150,000 and a urethane content (--NH--CO--O--) of 2 to 16% by weight, wherein the polyester polyol is the at least partly neutralized reaction product ofa) 35 to 90% by weight of branched polyester polyols having a hydroxyl number of 40 to 600 and prepared froma1) 0 to 60% by weight of monocarboxylic acids,a2) 6 to 65% by weight of di- and/or tricarboxylic acids or their anhydrides,a3) 10 to 70% by weight of alcohols,a4) 0 to 35% by weight of monoalcohols,a5) 0 to 30% by weight of hydroxycarboxylic acids, aminocarboxylic acids, lactones, lactams and aminoalcohols anda6) 0 to 45% by weight of polycarbonate polyols,b) 0.5 to 8.5% by weight of hydroxycarboxylic acidsc) 0 to 15% by weight of compounds containing OH, NH and/or NH.sub.2 groups and having a molecular weight of 32 to 500,d) 3 to 33% by weight of compounds containing isocyanate groups and having a molecular weight of 168 to 2,000 ande) 0 to 45% by weight of polycarbonate polyols,wherein the percentages of a) to e) and a1) to a6) add up to 100% and wherein the urethane group-containing polyester polyols contain 1 to 25% by weight of carbonate groups (--0--CO--O--) incorporated through components e) and/or a6).
    • 本发明涉及酸值为6〜45mg KOH / g的水可稀释的含氨基甲酸酯基的聚酯多元醇,其中25〜100%的酸基被碱中和,羟基数为20〜250mg KOH / g,分子量(Mw)为2000〜150,000,氨基甲酸酯含量(-NH-CO-O-)为2〜16重量%,其中聚酯多元醇为a)35的至少部分中和的反应产物 至90重量%的羟基数为40至600的支链聚酯多元醇,并由a1)0至60重量%的单羧酸制备,a2)6至65重量%的二 - 和/或三羧酸或它们的 酸酐,a3)10至70重量%的醇,a4)0至35重量%的一元醇,a5)0至30重量%的羟基羧酸,氨基羧酸,内酯,内酰胺和氨基醇,和a)0至45 重量百分比的聚碳酸酯多元醇,b)0.5至8.5%重量的羟基羧酸c)0至15%(重量)的含 OH,NH和/或NH 2基团,分子量为32〜500,d)3〜33重量%的含异氰酸酯基,分子量为168〜2000的化合物,e)0〜45重量% 聚碳酸酯多元醇,其中a)至e)和a1)至a6)的百分比加至100%,其中含氨基甲酸酯基的聚酯多元醇含有1至25重量%的碳酸酯基(-O-CO-O- )通过组分e)和/或a6)合并。