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21. 发明申请

US20090098438A1 ION CONDUCTIVE MATERIAL, CONDUCTIVE FILM FOR FUEL CELL, FILM ELECTRODE BONDED BODY AND FUEL CELL 失效
标题翻译：离子导电材料，燃料电池导电膜，电极接触体和燃料电池
公开(公告)号：US20090098438A1
公开(公告)日：2009-04-16
申请号：US12282630
申请日：2007-02-20
申请人： Toyoki Kunitake , Yoshitaka Aoki , Emi Muto
发明人： Toyoki Kunitake , Yoshitaka Aoki , Emi Muto
IPC分类号： H01M8/10
CPC分类号： H01B1/122 , C03C3/06 , C03C4/18 , C03C17/3417 , C03C2217/23 , C03C2217/24 , C03C2217/242 , C03C2217/948 , C03C2218/113 , H01M8/1016 , H01M8/1246 , H01M2300/0071 , Y02E60/525 , Y02P70/56
摘要： A novel ion conductive material is provided. The ion conductive material composed of an amorphous material is employed.
摘要翻译：提供了一种新型的离子导电材料。使用由非晶材料构成的离子导电材料。

22. 发明申请

US20070212514A1 Thin Film Material and Method for Producing Same 审中-公开
标题翻译：薄膜材料及其制造方法
公开(公告)号：US20070212514A1
公开(公告)日：2007-09-13
申请号：US10558402
申请日：2004-05-28
申请人： Jian-guo Huang , Toyoki Kunitake
发明人： Jian-guo Huang , Toyoki Kunitake
IPC分类号： B32B7/00 , B05D3/00
CPC分类号： B01D71/024 , B01D67/0044 , B01D67/0079 , B01D67/009 , B01D69/105 , B01D2325/04 , C09C3/006 , Y10T428/24
摘要： There is disclosed a method for producing a thin film material, comprising plugging pores in a surface of a porous substrate with a polymer compound, forming a metal oxide thin film or an organic/metal oxide composite thin film on the plugged porous substrate, and removing the polymer compound or both of the polymer compound and an organic compound in the thin film. The metal oxide thin film or the organic/metal oxide composite thin film can be uniformly formed without defects directly on the porous substrate by the method.
摘要翻译：公开了一种薄膜材料的制造方法，其特征在于，在多孔基材的表面上用高分子化合物堵塞孔，在封孔多孔基材上形成金属氧化物薄膜或有机/金属氧化物复合薄膜，除去所述高分子化合物或所述高分子化合物和所述薄膜中的有机化合物两者。该金属氧化物薄膜或有机/金属氧化物复合薄膜可以通过该方法直接均匀地形成在多孔基材上。

23. 发明授权

US06107084A Method for the preparation of an immobilized protein ultrathin film reactor and a method for a chemical reaction by using an immobilized protein ultrathin film reactor 失效
标题翻译：固定化蛋白质超薄膜反应器的制备方法和使用固定化蛋白质超薄膜反应器的化学反应方法
公开(公告)号：US06107084A
公开(公告)日：2000-08-22
申请号：US730929
申请日：1996-10-16
申请人： Mitsuhiko Onda , Yuri Lvov , Katsuhiko Ariga , Toyoki Kunitake
发明人： Mitsuhiko Onda , Yuri Lvov , Katsuhiko Ariga , Toyoki Kunitake
IPC分类号： C12M1/40 , C12M1/42 , C12N11/08 , C12N11/14 , C12P1/00 , C12M1/00 , G01N1/04 , G01N33/53
CPC分类号： C12P1/00 , C12M21/02 , C12M21/18 , C12M35/02 , C12N11/08 , Y10S436/81
摘要： A method for the preparation of an immobilized protein ultrathin film reactor by immersing a solid support alternately into an aqueous solution of protein, and into an aqueous solution of polyion charged oppositely to said protein and preparing a structurally controlled ultrathin film of mono- or multi- protein layers on a said solid support with precision at molecular level. And a method for chemical reaction of a substrate by preparing an immobilized protein ultrathin film reactor composed of multiple layers of protein on a solid support by above mentioned method, and initiating a chemical change of the substrate molecules using obtained immobilized protein ultrathin film reactor.
摘要翻译：一种通过将固体支持物交替浸入蛋白质水溶液中制备固定化蛋白质超薄膜反应器的方法，并将其与所述蛋白质相反地加入到与聚合蛋白质相反的聚离子水溶液中，并制备结构可控的超细薄膜，蛋白质层在所述固体支持物上具有分子水平的精确度。以及通过上述方法制备由固体支持体上的多层蛋白质组成的固定化蛋白质超薄膜反应器的底物的化学反应的方法，使用得到的固定化蛋白质超薄膜反应器引发底物分子的化学变化。

24. 发明授权

US07592039B2 Method for producing nanotube material and nanotube material 失效
标题翻译：制造纳米管材料和纳米管材料的方法
公开(公告)号：US07592039B2
公开(公告)日：2009-09-22
申请号：US10558305
申请日：2004-03-17
申请人： Jian-guo Huang , Toyoki Kunitake
发明人： Jian-guo Huang , Toyoki Kunitake
IPC分类号： B05D7/22 , B32B5/16
CPC分类号： C01G19/02 , B82Y30/00 , C01B13/14 , C01B33/18 , C01G19/00 , C01G23/047 , C01G23/053 , C01G25/02 , C01P2004/03 , C01P2004/04 , C01P2004/13 , C01P2004/64 , C30B29/602 , Y10T428/13
摘要： There are provided a method capable of mass-producing a nanotube material easily with low costs, and a nanotube material. The method of the present invention for producing a nanotube material has at least forming a metal oxide thin film or an organic/metal oxide composite thin film on an inner wall of a porous substrate and removing the porous substrate. The nanotube material of the invention has a structure provided from a body comprising a metal oxide thin film or an organic/metal oxide composite thin film formed on an inner wall of the porous substrate, from which a portion corresponding to the porous substrate is removed.
摘要翻译：提供了能够以低成本容易地批量生产纳米管材料的方法和纳米管材料。用于制造纳米管材料的本发明的方法至少在多孔基材的内壁上形成金属氧化物薄膜或有机/金属氧化物复合薄膜，并除去多孔基材。本发明的纳米管材料具有从多孔基材的内壁上形成的金属氧化物薄膜或有机/金属氧化物复合薄膜的主体构成的结构，从该多孔基材的内壁除去与多孔基材相当的部分。

25. 发明申请

US20090092814A1 Method for Manufacturing Polymer Thin Film and Polymer Thin Film 审中-公开
标题翻译：制造聚合物薄膜和聚合物薄膜的方法
公开(公告)号：US20090092814A1
公开(公告)日：2009-04-09
申请号：US12226412
申请日：2007-03-08
申请人： Toyoki Kunitake , Hirohmi Watanabe
发明人： Toyoki Kunitake , Hirohmi Watanabe
IPC分类号： B32B27/00 , B05D3/02
CPC分类号： B29C41/12
摘要： The present invention provides a method for manufacturing a polymer thin film having high strength, flexibility, accuracy, and a large surface area. A method for manufacturing a polymer thin film, comprising: providing a layer of thermally-crosslinkable resin composition on a support; cross-linking a thermoplastic resin in the layer of thermally-crosslinkable resin composition thus provided; and after the thermoplastic resin is cross-linked, separating the support from the layer of thermally-crosslinkable resin composition.
摘要翻译：本发明提供一种高强度，柔韧性，精度高，表面积大的聚合物薄膜的制造方法。一种制造聚合物薄膜的方法，包括：在载体上提供一层热交联性树脂组合物; 在如此提供的热交联性树脂组合物层中交联热塑性树脂; 并且在热塑性树脂交联后，将载体与热交联性树脂组合物层分离。

26. 发明授权

US6020175A Multiple layered functional thin films 失效
标题翻译：多层功能薄膜
公开(公告)号：US6020175A
公开(公告)日：2000-02-01
申请号：US926493
申请日：1997-09-10
申请人： Mitsuhiko Onda , Yuri Lvov , Katsuhiko Ariga , Toyoki Kunitake
发明人： Mitsuhiko Onda , Yuri Lvov , Katsuhiko Ariga , Toyoki Kunitake
IPC分类号： B01J19/00 , B05C3/18 , B05D1/20 , B32B9/00 , C07K17/04 , C09B67/02 , C12N11/00 , C12N11/04 , H01L51/50 , H05B33/10 , C07K17/00 , C07K17/08 , C12N11/08
CPC分类号： C09B67/0097 , C07K17/04 , C12N11/00 , C12N11/04 , Y10S530/81 , Y10S530/811 , Y10S530/813 , Y10S530/815 , Y10S530/817
摘要： Multiple layered functional thin films fixed on a solid support are provided which comprise multiple layers of functional molecules (such as enzymes and other proteins, pigments and dyes) admixed with polymer ions in combination with multiple layers of polymer ions without the functional molecules. The films are prepared by immersing a solid support having an electric charge in an admixed polymer ion-functional molecule solution having a net electric charge opposite to that of the solid support followed by immersing the solid support in a polymer ion solution having a net electric charge opposite to that of the admixed polymer ion-functional molecule solution, and repeating at least once the immersings of the solid support in the solutions. Alternatively, the films are prepared by immersing the solid support in a polymer ion solution having a net electric charge opposite to that of the solid support followed by immersing the solid support in an admixed polymer ion-functional molecule solution having a net electric charge opposite to that of the polymer ion solution, and repeating at least once the immersings of the solid support in the solutions.
摘要翻译：提供了固定在固体支持物上的多层功能性薄膜，其包含与聚合物离子混合的多层功能分子（如酶和其他蛋白质，颜料和染料），并与多层聚合物离子结合而没有功能分子。通过将具有电荷的固体支持物浸渍在具有与固体支持物的电荷相反的净电荷的混合聚合物离子功能分子溶液中，然后将固体支持物浸入具有净电荷的聚合物离子溶液中来制备膜与混合的聚合物离子功能分子溶液相反，并且至少一次将固体载体沉积在溶液中。或者，通过将固体支持物浸入具有与固体支持物的电荷相反的净电荷的聚合物离子溶液中，然后将固体支持物浸入与电荷相反的混合聚合物离子功能分子溶液中来制备膜聚合物离子溶液的重量，并且至少一次将固体载体浸入溶液中。

27. 发明授权

US08398754B2 Proton conducting membrane and method for producing proton conducting membrane 有权
标题翻译：质子导电膜及其制造方法
公开(公告)号：US08398754B2
公开(公告)日：2013-03-19
申请号：US12680174
申请日：2008-09-25
申请人： Toyoki Kunitake , Yuanzhi Li , Yoshitaka Aoki , Emi Muto
发明人： Toyoki Kunitake , Yuanzhi Li , Yoshitaka Aoki , Emi Muto
IPC分类号： B01D53/22
CPC分类号： H01M8/1016 , B01D67/0048 , B01D71/024 , B01D2325/14 , C04B35/486 , C04B35/624 , C04B2235/3225 , C04B2235/421 , C04B2235/441 , C04B2235/447 , C04B2235/448 , C04B2235/449 , H01M8/1246 , H01M2300/0071 , H01M2300/0074 , Y02E60/525 , Y02P70/56
摘要： A proton conducting membrane comprising, as a main component, a ceramic structure in which an oxygen atom of a metal oxide is bonded through the oxygen atom with at least one group derived an oxygen acid selected from —B(O)3—, —S(═O)2(O)2—, —P(═O)(O)3—, —C(═O)(O)2—, and —N(O)3—, wherein the metal oxide and said at least one group derived from the oxygen acid share the oxygen atom, the proton conducting membrane being made by a sol-gel reaction of the oxygen acid or its precursor and a precursor of the metal oxide in order to obtain a sol-gel reaction product, followed by heating of the sol-gel reaction product at a temperature in a range of 100° C. to 600° C., the oxygen acid or its precursor being selected from a boric acid, a sulfuric acid, a phosphoric acid, a carbonic acid, a nitric acid, and precursors thereof. Thus, a novel proton conducting membrane is provided.
摘要翻译：一种质子传导膜，其以主要成分为主成分，其中金属氧化物的氧原子通过氧原子与至少一个衍生自选自-B（O）3 - ，-S （ΟO）2（O）2 - ， - （O）（O）3 - ， - C（= O）（O）2 - 和-N（O）3 - ，其中金属氧化物和由氧原子衍生的至少一个共享氧原子，质子传导膜通过氧酸或其前体与金属氧化物的前体的溶胶 - 凝胶反应制成，以获得溶胶 - 凝胶反应产物，然后在100℃至600℃的温度范围内加热溶胶 - 凝胶反应产物，氧酸或其前体选自硼酸，硫酸，磷酸，碳酸，硝酸及其前体。因此，提供了一种新颖的质子传导膜。

28. 发明申请

US20100284880A1 PROTON CONDUCTING MEMBRANE AND METHOD FOR PRODUCING PROTON CONDUCTING MEMBRANE 有权
标题翻译：原子导电膜及其制造方法
公开(公告)号：US20100284880A1
公开(公告)日：2010-11-11
申请号：US12680174
申请日：2008-09-25
申请人： Toyoki Kunitake , Yuanzhi Li , Yoshitaka Aoki , Emi Muto
发明人： Toyoki Kunitake , Yuanzhi Li , Yoshitaka Aoki , Emi Muto
IPC分类号： C01B17/00 , C01B15/16 , C01F17/00
CPC分类号： H01M8/1016 , B01D67/0048 , B01D71/024 , B01D2325/14 , C04B35/486 , C04B35/624 , C04B2235/3225 , C04B2235/421 , C04B2235/441 , C04B2235/447 , C04B2235/448 , C04B2235/449 , H01M8/1246 , H01M2300/0071 , H01M2300/0074 , Y02E60/525 , Y02P70/56
摘要： A proton conducting membrane comprising, as a main component, a ceramic structure in which an oxygen atom of a metal oxide is bonded through the oxygen atom with at least one group derived an oxygen acid selected from —B(O)3—, —S(═O)2(O)2—, —P(═O)(O)3—, —C(═O)(O)2—, and —N(O)3—, wherein the metal oxide and said at least one group derived from the oxygen acid share the oxygen atom, the proton conducting membrane being made by a sol-gel reaction of the oxygen acid or its precursor and a precursor of the metal oxide in order to obtain a sol-gel reaction product, followed by heating of the sol-gel reaction product at a temperature in a range of 100° C. to 600° C., the oxygen acid or its precursor being selected from a boric acid, a sulfuric acid, a phosphoric acid, a carbonic acid, a nitric acid, and precursors thereof. Thus, a novel proton conducting membrane is provided.
摘要翻译：一种质子传导膜，其以主要成分为主成分，其中金属氧化物的氧原子通过氧原子与至少一个衍生自选自-B（O）3 - ，-S （ΟO）2（O）2 - ， - （O）（O）3 - ， - C（= O）（O）2 - 和-N（O）3 - ，其中金属氧化物和由氧原子衍生的至少一个共享氧原子，质子传导膜通过氧酸或其前体与金属氧化物的前体的溶胶 - 凝胶反应制成，以获得溶胶 - 凝胶反应产物，然后在100℃至600℃的温度范围内加热溶胶 - 凝胶反应产物，氧酸或其前体选自硼酸，硫酸，磷酸，碳酸，硝酸及其前体。因此，提供了一种新颖的质子传导膜。

29. 发明授权

US07407895B2 Process for producing dielectric insulating thin film, and dielectric insulating material 失效
标题翻译：电介质绝缘薄膜的制造方法以及介电绝缘材料
公开(公告)号：US07407895B2
公开(公告)日：2008-08-05
申请号：US10550016
申请日：2004-03-26
申请人： Toyoki Kunitake , Yoshitaka Aoki
发明人： Toyoki Kunitake , Yoshitaka Aoki
IPC分类号： H01L21/00
CPC分类号： C23C18/1216 , C23C18/1212 , C23C18/1225 , C23C18/1245 , C23C18/1254 , C23C18/1275 , H01L21/31683
摘要： Provided is a method for producing, in a simple manner, a general-purpose dielectric insulating thin film that has a varying dielectric constant and accepts an accurate film thickness control and a control of the composition, the structure and the thickness thereof. The process includes a step (A) of making a substrate having a hydroxyl group in its surface or having a hydroxyl group introduced into its surface, adsorb a metal compound having a functional group capable of reacting with a hydroxyl group for condensation and capable of forming a hydroxyl group through hydrolysis, a step (B) of removing the excessive metal compound from the substrate surface, a step (C) of hydrolyzing the metal compound to form a metal oxide layer, and a step (D) of treating the metal oxide layer according to any one treating method selected from the group consisting of oxygen plasma treatment, ozone oxidation treatment, firing treatment and rapid thermal annealing treatment to thereby obtain a dielectric insulating thin film.
摘要翻译：本发明提供一种简单的制造具有不同介电常数的通用介电绝缘薄膜的方法，该方法能够接受精确的膜厚度控制以及其组成，结构和厚度的控制。该方法包括在其表面制备具有羟基或具有引入其表面的羟基的基材的步骤（A），吸附具有能够与羟基反应的官能团的金属化合物用于冷凝并能够形成通过水解的羟基，从基材表面除去过量的金属化合物的工序（B），将金属化合物水解形成金属氧化物层的工序（C），以及处理金属氧化物的工序（D）根据选自氧等离子体处理，臭氧氧化处理，烧成处理和快速热退火处理的任一种处理方法，从而获得介电绝缘薄膜。

30. 发明授权

US06677043B2 Nano-wrapped molecular materials 失效
标题翻译：纳米包裹分子材料
公开(公告)号：US06677043B2
公开(公告)日：2004-01-13
申请号：US10096275
申请日：2002-03-13
申请人： Toyoki Kunitake , Izumi Ichinose
发明人： Toyoki Kunitake , Izumi Ichinose
IPC分类号： B32B566
CPC分类号： C01B13/32 , B22F1/0018 , B22F1/0062 , B82Y30/00 , C01P2002/84 , C01P2004/03 , C01P2004/64 , Y10T428/265 , Y10T428/2991 , Y10T428/2995 , Y10T428/2998
摘要： Nano-wrapped molecular materials comprising molecule, molecular aggregate, or nanoparticle which has the surface at least partially covered with an ultrathin film containing oxygen-metal bond was disclosed. The nano-wrapped molecular materials successfully retain or are dramatically improved in the intrinsic physical and chemical properties of the individual molecules or nanoparticles.
摘要翻译：公开了包含分子，分子聚集体或纳米颗粒的纳米包裹的分子材料，其表面至少部分地被含有氧 - 金属键的超薄膜覆盖。纳米包裹的分子材料在单个分子或纳米颗粒的固有物理和化学性质中成功地保留或显着改进。

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