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21. 发明授权

US08071060B2 Flue gas control system of coal combustion boiler and operating method thereof 有权
标题翻译：燃煤锅炉烟气控制系统及其运行方法
公开(公告)号：US08071060B2
公开(公告)日：2011-12-06
申请号：US12812866
申请日：2009-01-20
申请人： Nobuyuki Ukai , Shintaro Honjo , Susumu Okino
发明人： Nobuyuki Ukai , Shintaro Honjo , Susumu Okino
IPC分类号： B01D53/34 , B01D53/50 , B01D53/56 , B01D53/64 , B01D53/74
CPC分类号： F23J15/003 , B01D53/501 , B01D53/64 , B01D53/75 , B01D53/79 , B01D53/8625 , B01D2251/10 , B01D2251/2062 , B01D2251/404 , B01D2253/102 , B01D2257/602 , B01J20/0266 , B01J20/0285 , B01J20/20 , B01J45/00 , C02F1/001 , C02F1/283 , C02F1/42 , C02F1/52 , C02F1/683 , C02F2101/20 , C02F2103/18 , C02F2209/003 , C02F2303/18 , F23J15/006 , F23J15/025 , F23J15/04 , F23J2215/20 , F23J2215/60 , F23J2219/20 , F23J2219/30 , Y02A50/2348
摘要： A flue gas control system of a coal combustion boiler comprises an HCl atomizer that sprays hydrogen chloride to flue gas from a coal combustion boiler that uses coal as a fuel; NOx removing apparatus that removes nitrogen oxides by ammonia denitration by adding ammonia to the flue gas after spraying hydrogen chloride and oxidizes mercury; an air preheater that recovers heat in the gas after removal of nitrogen oxides; a precipitator that removes particulates in the gas; an activated carbon atomizer that sprays activated carbon into the gas after particulate collection; a bag filter that collects activated carbon having adsorbed mercury; a desulfurizer that removes sulfur oxides in the flue gas after removal of activated carbon; a stack that discharges the gas which has undergone desulfurization to outside; and an ORP meter that measures an oxidation reduction potential for feeding air to a slurry absorbent in the desulfurizer.
摘要翻译：煤燃烧锅炉的烟气控制系统包括将氯化氢喷射到使用煤作为燃料的燃煤锅炉的烟道气中的HCl雾化器; NOx去除装置，其通过在喷洒氯化氢之后向废气中加入氨并通过氨脱硝来氧化汞; 一个空气预热器，在除去氮氧化物之后回收气体中的热量; 除尘器，用于除去气体中的微粒; 一种在颗粒物收集之后将活性炭喷射到气体中的活性炭雾器; 收集具有吸附汞的活性炭的袋式过滤器; 去除活性炭后除去烟道气中的硫氧化物的脱硫剂; 将经过脱硫的气体排出到外部的叠层; 以及测量用于将空气送入脱硫器中的浆料吸收剂的氧化还原电位的ORP计量器。

22. 发明申请

US20110052470A1 AIR POLLUTION CONTROL SYSTEM AND METHOD FOR COAL COMBUSTION BOILER 有权
标题翻译：空气污染控制系统和煤燃烧锅炉的方法
公开(公告)号：US20110052470A1
公开(公告)日：2011-03-03
申请号：US12863334
申请日：2009-01-20
申请人： Nobuyuki Ukai , Shintaro Honjo , Susumu Okino
发明人： Nobuyuki Ukai , Shintaro Honjo , Susumu Okino
IPC分类号： B01D53/50 , B01J19/00
CPC分类号： F23J15/003 , B01D53/64 , B01D53/75 , B01D53/80 , B01D2251/404 , B01D2251/608 , B01D2257/302 , B01D2257/404 , B01D2257/602 , B01D2258/0283 , B01D2259/126 , F23J15/006 , F23J15/025 , F23J15/04 , F23J2215/101 , F23J2215/20 , F23J2215/60 , F23J2217/60 , F23J2219/20 , F23J2219/40 , Y02A50/2348
摘要： An air pollution control system for a coal combustion boiler according to the present invention includes: a NOx removing apparatus (13) that reduces nitrogen oxide contained in flue gas emitted from this coal combustion boiler (11), an air pre-heater (14) that recovers heat in the gas, a precipitator 15 that reduces particulates from the gas, a liquid-gas contact type desulfurizer (16) that removes sulfur oxide by way of a limestone-gypsum method and reduces mercury oxide in the gas, a stack (17) that releases the gas after SOx removal to the exterior, and a solid-liquid separator (22) that extracts limestone-gypsum containing slurry (21) from the desulfurizer (16) to the exterior and performs a solid-liquid separation, where water (23) separated in the solid-liquid separator (22) is removed, and concentrated slurry (24) is sent back to the bottom of the desulfurizer (16) to make the gypsum concentration of slurry (25) equal to or higher than 10 percent in the desulfurizer (16).
摘要翻译：根据本发明的燃煤锅炉的空气污染控制系统包括：减少从该燃煤锅炉（11）排出的烟道气中所含的氮氧化物的NOx去除装置（13），空气预热器（14）其回收气体中的热量，减少来自气体的微粒的沉淀器15，通过石灰石 - 石膏法除去硫氧化物并减少气体中的氧化汞的液 - 气接触型脱硫器（16），堆（ 17），其将去除SOx后的气体释放到外部;以及固体 - 液体分离器（22），其将从所述脱硫器（16）提取的含石灰石 - 石膏的浆料（21）提供到外部并进行固液分离，其中去除在固液分离器（22）中分离出的水（23），将浓缩浆液（24）送回脱硫器（16）的底部，使浆料（25）的石膏浓度等于或高于 10％在脱硫器（16）。

23. 发明授权

US07749455B2 Apparatus for treating COS for gas produced by gasification and method for treating COS 有权
标题翻译：用于处理通过气化产生的气体的COS的装置和用于处理COS的方法
公开(公告)号：US07749455B2
公开(公告)日：2010-07-06
申请号：US10522604
申请日：2003-08-06
申请人： Masahiro Harada , Shintaro Honjo , Makoto Susaki , Kazuo Ishida , Hajime Nagano , Susumu Okino , Kozo Iida , Akira Johana
发明人： Masahiro Harada , Shintaro Honjo , Makoto Susaki , Kazuo Ishida , Hajime Nagano , Susumu Okino , Kozo Iida , Akira Johana
IPC分类号： G05D7/00 , B01D53/04 , B01D53/34 , B01D53/52 , B01D53/86 , B01J8/02 , B01J35/02 , C01B17/00 , C01B17/16 , C01B31/00 , C10G17/00 , C10G45/00
CPC分类号： B01J23/866 , B01D53/885 , C10K1/34
摘要： A COS treatment apparatus for a gasified gas includes an O2 removal catalyst and a COS conversion catalyst located on the downstream side of a gasified gas flow with respect to the O2 removal catalyst. Also, a COS treatment apparatus includes a TiO2 catalyst that carries Cr2O3 or NiO. Further, a COS treatment method includes a first step in which O2 is removed by the reaction with H2S and CO, and a second step in which COS is converted to H2S.
摘要翻译：用于气化气体的COS处理装置包括相对于除去氧化催化剂的气化气体流的下游侧的除氧催化剂和COS转化催化剂。此外，COS处理装置包括载持Cr 2 O 3或NiO的TiO 2催化剂。此外，COS处理方法包括通过与H 2 S和CO的反应除去O 2的第一步骤和将COS转化为H 2 S的第二步骤。

24. 发明授权

US07572420B2 Method for removing mercury in exhaust gas and system therefor 有权
公开(公告)号：US07572420B2
公开(公告)日：2009-08-11
申请号：US10815419
申请日：2004-04-01
申请人： Shintaro Honjo , Toru Takashina , Kozo Iida , Susumu Okino , Yasuhiro Takeuchi
发明人： Shintaro Honjo , Toru Takashina , Kozo Iida , Susumu Okino , Yasuhiro Takeuchi
IPC分类号： B01D53/64
CPC分类号： B01D53/501 , B01D53/8665 , B01D2257/602 , F23J15/006 , F23J2215/60 , F23J2219/40
摘要： The present invention provides a method for removing mercury in exhaust gas, in which mercury in exhaust gas discharged from combustion equipment is removed, characterized by including a mercury oxidation process in which mercury in the exhaust gas is converted to mercury chloride in the presence of a catalyst; a contact process in which the exhaust gas is brought into contact with an absorbing solution in a scrubber to absorb and remove mercury components from the exhaust gas; and a control process in which blowing of air or addition of an oxidizing agent into the scrubber is accomplished, and the amount of blown air or the added amount of oxidizing agent is regulated to control the oxidation-reduction potential of the absorbing agent, and a system for removing mercury in exhaust gas. According to the mercury removing method in accordance with the present invention, a phenomenon that mercury chloride is reduced into metallic mercury by SO2 etc. and the metallic mercury scatters in the exhaust gas can be prevented, and mercury in the exhaust gas can be decreased effectively.

25. 发明授权

US07521032B2 Method for removing mercury in exhaust gas 有权
标题翻译：废气中汞去除方法
公开(公告)号：US07521032B2
公开(公告)日：2009-04-21
申请号：US10767783
申请日：2004-01-29
申请人： Shintaro Honjo , Kozo Iida , Susumu Okino , Kazuto Kobayashi , Kenichi Okada , Naoyuki Kamiyama , Shigeru Nojima , Yasuhiro Takeuchi , Tsuyoshi Ohishi
发明人： Shintaro Honjo , Kozo Iida , Susumu Okino , Kazuto Kobayashi , Kenichi Okada , Naoyuki Kamiyama , Shigeru Nojima , Yasuhiro Takeuchi , Tsuyoshi Ohishi
IPC分类号： B01D53/52
CPC分类号： B01D53/64 , B01D2257/406 , B01D2257/602 , F23J15/006 , F23J2215/60 , F23J2219/10 , F23J2219/40
摘要： The present invention provides a system for removing mercury in exhaust gas, in which mercury is removed from exhaust gas of a boiler, characterized in that between a denitrification apparatus and a wet type desulfurization apparatus, an NH3 decomposition catalyst and a mercury oxidation catalyst are provided, and mercury having been oxidized into mercury chloride is removed by the wet type desulfurization apparatus. Also, it provides a method for removing mercury in exhaust gas, characterized in that the mercury removing method includes an NH3 decomposition process and a mercury oxidation process, which are provided between the denitrification process and a wet desulfurization process, and mercury having been oxidized into mercury chloride is removed in the wet desulfurization process.
摘要翻译：本发明提供了一种用于去除废气中的汞的系统，其中从锅炉废气中除去汞，其特征在于，在脱氮装置和湿式脱硫装置之间，提供NH 3分解催化剂和汞氧化催化剂并且通过湿式脱硫装置除去氧化成氯化汞的汞。另外，本发明提供一种除去排气中的汞的方法，其特征在于，除汞方法包括在脱氮工序与湿式脱硫工序之间设置的NH 3分解工序和水银氧化工序，将氧化为在湿式脱硫工艺中除去氯化汞。

26. 发明申请

US20080138264A1 Method and device for removing mercury 有权
标题翻译：去除汞的方法和装置
公开(公告)号：US20080138264A1
公开(公告)日：2008-06-12
申请号：US11798365
申请日：2007-05-14
申请人： Shintaro Honjo , Susumu Okino , Yasuhiro Takeuchi , Seiji Kagawa , Yoshio Nakayama
发明人： Shintaro Honjo , Susumu Okino , Yasuhiro Takeuchi , Seiji Kagawa , Yoshio Nakayama
IPC分类号： B01D53/64 , F01N3/00
CPC分类号： B01D53/64 , B01D53/75 , B01D53/77 , B01D53/86 , B01D2251/206 , B01D2251/502 , B01D2257/302 , B01D2257/404 , B01D2257/602 , F23J2215/60 , Y02A50/2348 , Y10S423/05
摘要： A mercury removing device includes a gasification unit that converts a non-gaseous-mercury-chlorinating agent, which is non-gaseous at room temperature and normal pressure, into gaseous-mercury-chlorinating agent by heating the non-gaseous-mercury-chlorinating agent with heat of hot air generated by using the exhaust gas or hot air generated by using an air heater installed in a flue that conveys the exhaust gas. The gaseous-mercury-chlorinating agent produced in this manner is supplied to the exhaust gas in the flue.
摘要翻译：一种除汞装置包括：气化单元，其将室温和常压下的非气态非气态氯化汞转化为气态氯化汞气体，通过加热非气态氯化汞利用通过使用安装在输送废气的烟道中的空气加热器产生的排气或热空气产生的热空气。以这种方式生产的气态汞氯化剂被供给到烟道中的废气。

27. 发明申请

US20050046052A1 Exhaust gas treating tower 审中-公开
标题翻译：废气处理塔
公开(公告)号：US20050046052A1
公开(公告)日：2005-03-03
申请号：US10875513
申请日：2004-06-25
申请人： Kenichi Okada , Toru Takashina , Susumu Okino , Naoyuki Kamiyama , Tsumoru Nakamura , Shintaro Honjo , Kouzou Takano , Tsuyoshi Oishi , Koichiro Iwashita
发明人： Kenichi Okada , Toru Takashina , Susumu Okino , Naoyuki Kamiyama , Tsumoru Nakamura , Shintaro Honjo , Kouzou Takano , Tsuyoshi Oishi , Koichiro Iwashita
IPC分类号： B01D53/50 , B01D53/78 , F02M1/00
CPC分类号： B01D53/78 , B01D53/504
摘要： Provided is an exhaust gas treating tower in which exhaust gas flow velocity is increased more than a prior art case so that exhaust gas treating efficiency can be enhanced or the exhaust gas treating tower can be made compact if equivalent performance is to be maintained. Also, an exhaust gas treating tower ensuring a liquid recovery is provided. In an exhaust gas treating tower 10A, liquid columns C are generated and also a liquid drop generating member 20 is provided to thereby generate liquid drops M therearound to be floated. Also, liquid is spouted from spray nozzles to thereby generate liquid films F in area different from the liquid columns C. In an exhaust gas treating tower 110, a liquid drop eliminator 120 is provided upstream of a mist eliminator 118. Interval P1 of collecting plates 121 of the liquid drop eliminator 120 is made larger than interval P2 of collecting plates 119 of the mist eliminator 118. Thereby, liquid drops having larger particle diameter contained in the exhaust gas are collected by the liquid drop eliminator 120.
摘要翻译：提供了一种排气处理塔，其中废气流速比现有技术的情况更多地增加，使得如果要保持等效的性能，则可以提高废气处理效率或者可以使排气处理塔更紧凑。此外，还提供了确保液体回收的废气处理塔。在废气处理塔10A中，产生液柱C，并且还设有液滴产生部件20，从而在其周围产生浮液。此外，从喷嘴喷出液体，从而在与液柱C不同的区域产生液膜F.在废气处理塔110中，在除雾器118的上游设置有液滴消除器120.集尘板的间隔P1 液滴消除器120的121被制成大于除雾器118的收集板119的间隔P2。从而，排气中包含的具有较大粒径的液滴由液滴消除器120收集。

28. 发明授权

US06638485B1 Process for treating exhaust gas and exhaust gas treating equipment 失效
标题翻译：处理废气和废气处理设备的方法
公开(公告)号：US06638485B1
公开(公告)日：2003-10-28
申请号：US09022817
申请日：1998-02-12
申请人： Kozo Iida , Toru Takashina , Shintaro Honjo
发明人： Kozo Iida , Toru Takashina , Shintaro Honjo
IPC分类号： B01D5364
CPC分类号： B01D53/64 , B01D53/501 , B01D53/8628 , B01D53/8665 , F23J2215/60 , Y02A50/2349
摘要： A process for treating an exhaust gas contaminated with dust, Hg, NOx, and SOx is provided by adding a mercury chlorinating agent, such as, for example, HCl, NH4Cl, or Cl2, and ammonia to the exhaust gas so that the mercury in the exhaust gas is converted to HgCl2. The dust, HgCl2, NOx, NH3, and SOx containing the exhaust gas may then be passed through a reactor containing a catalyst such as, for example, V2O5 and/or MoO3 supported on TiO2, which promotes the reaction between the NOx and NH3 to result in the formation of N2 and H2O. The HgCl2 and SOx containing exhaust gas is then passed through a scrubbing tower where the gas is scrubbed with aqueous solutions of absorbents such as CaCO3 and Ca(OH)2, so that HgCl2 and SOx are removed from the exhaust gas. The cleaned exhaust gas is discharged through a stack.
摘要翻译：通过向排气中加入汞氯化剂，例如HCl，NH 4 Cl或Cl 2，以及氨，来处理污染了灰尘，Hg，NOx和SOx的废气的方法，废气转化为HgCl2。然后可以将含有废气的灰尘，HgCl 2，NO x，NH 3和SO x通过含有催化剂的反应器，例如负载在TiO 2上的V 2 O 5和/或MoO 3，其促进NOx和NH 3之间的反应导致形成N2和H2O。然后将含有HgCl 2和SO x的废气通过洗涤塔，在该塔中，气体用CaCO 3和Ca（OH）2等吸收剂的水溶液洗涤，从而从废气中除去HgCl 2和SO x。净化的废气通过堆放出。

29. 发明授权

US08420034B2 Method and apparatus for treating exhaust gas 有权
标题翻译：废气处理方法及装置
公开(公告)号：US08420034B2
公开(公告)日：2013-04-16
申请号：US12670871
申请日：2009-02-26
申请人： Katsumi Nochi , Yoshiaki Obayashi , Masashi Kiyosawa , Shintaro Honjo
发明人： Katsumi Nochi , Yoshiaki Obayashi , Masashi Kiyosawa , Shintaro Honjo
IPC分类号： B01D47/00 , B01D53/50 , C01G23/00 , C01F1/00
CPC分类号： B01D53/8656 , B01D53/501 , B01D53/64 , B01D53/8625 , B01D53/869 , B01D2251/2062 , B01D2251/304 , B01D2251/404 , B01D2255/102 , B01D2255/20707 , B01D2255/20715 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01D2255/2092 , B01D2255/30 , B01D2255/50 , B01D2257/302 , B01D2257/404 , B01D2257/602
摘要： In an exhaust gas treatment, the amount of a highly corrosive mercury-halogenating agent to be added is reduced with the mercury-removing efficiency maintained high.A mercury-halogenating agent (40) and ammonia (30) are added to combustion exhaust gas from a boiler, the exhaust gas containing NOx, SOx and mercury. The exhaust gas is brought into contact with a CO/HC oxidation catalyst (50) and is then subjected to reduction denitration (60) in the presence of a solid catalyst. Thereafter, metallic mercury is oxidized to halogenated mercury. Then, the exhaust gas is wet-desulfurized (100) with the alkaline absorbing solution, and the halogenated mercury is removed.
摘要翻译：在废气处理中，要加入的高度腐蚀性的汞卤化剂的量随着除汞效率的提高而降低。向来自锅炉的燃烧废气中加入汞卤化剂（40）和氨（30），该废气含有NOx，SOx和汞。使废气与CO / HC氧化催化剂（50）接触，然后在固体催化剂存在下进行还原脱硝（60）。此后，金属汞被氧化成卤化汞。然后，用碱性吸收溶液对废气进行湿式脱硫（100），除去卤化汞。

30. 发明授权

US07622092B2 Method and device for removing mercury 有权
标题翻译：去除汞的方法和装置
公开(公告)号：US07622092B2
公开(公告)日：2009-11-24
申请号：US11798365
申请日：2007-05-14
申请人： Shintaro Honjo , Susumu Okino , Yasuhiro Takeuchi , Seiji Kagawa , Yoshio Nakayama
发明人： Shintaro Honjo , Susumu Okino , Yasuhiro Takeuchi , Seiji Kagawa , Yoshio Nakayama
IPC分类号： B01D53/50 , B01D53/56 , B01D53/64 , B01D53/74 , B01D53/75 , B01D53/76
CPC分类号： B01D53/64 , B01D53/75 , B01D53/77 , B01D53/86 , B01D2251/206 , B01D2251/502 , B01D2257/302 , B01D2257/404 , B01D2257/602 , F23J2215/60 , Y02A50/2348 , Y10S423/05
摘要： A mercury removing device includes a gasification unit that converts a non-gaseous-mercury-chlorinating agent, which is non-gaseous at room temperature and normal pressure, into gaseous-mercury-chlorinating agent by heating the non-gaseous-mercury-chlorinating agent with heat of hot air generated by using the exhaust gas or hot air generated by using an air heater installed in a flue that conveys the exhaust gas. The gaseous-mercury-chlorinating agent produced in this manner is supplied to the exhaust gas in the flue.
摘要翻译：一种除汞装置包括：气化单元，其将室温和常压下的非气态非气态氯化汞转化为气态氯化汞气体，通过加热非气态氯化汞利用通过使用安装在输送废气的烟道中的空气加热器产生的排气或热空气产生的热空气。以这种方式生产的气态汞氯化剂被供给到烟道中的废气。

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