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21. 发明公开

EP2436716A1 Fluorooxyalkylene group-containing polymer composition, a surface treatment agent comprising the same and an article treated with the agent 有权
标题翻译： FLUOROXYALKYLENGRUPPENHALTIGE聚合物组合物，表面处理剂和医学方法处理条
公开(公告)号：EP2436716A1
公开(公告)日：2012-04-04
申请号：EP11182448.8
申请日：2011-09-23
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Yamane, Yuji , Sakano, Yasunori , Yamaguchi, Koichi , Koike, Noriyuki , Kishita, Hirofumi
IPC分类号： C08G65/00 , G02B1/10 , C08G77/46 , C08G77/24 , C08L101/10
CPC分类号： C08G77/46 , C08G65/007 , C08G65/336 , C08G77/24 , C08G2650/48 , C09D171/02 , Y10T428/3154
摘要： A fluorooxyalkylene group-containing polymer composition comprising a liner fluorooxyalkylene group-containing polymer represented by the formula (1) which has a hydrolysable group at a terminal and is hereinafter called "one-terminal modified polymer", and a liner fluorooxyalkylene group-containing polymer represented by the following formula (2) which has hydrolysable groups at the both terminals and is hereinafter called "both-terminal modified polymer", wherein an amount of the both-terminal modified polymer is 0. 1 mole % or more and less than 10 mole %, relative to a total mole of the one-terminal modified polymer and the both-terminal modified polymer.
摘要翻译：甲含氟氧亚烷基的聚合物组合物，包括由下式表示的内衬含氟氧亚烷基系聚合物（1），在末端具有可水解基团，并且在被称为“单末端改性的聚合物”后，和基团的衬垫含氟聚合物由下式（2），其具有在两端可水解基团，并且在所谓的“两末端改性的聚合物”之后，worin在两末端改性聚合物的量表示的是0。1摩尔％以上且小于10 摩尔％，相对于单末端改性的聚合物的总摩尔和两末端改性的聚合物。

22. 发明授权

EP2316869B1 Fluorooxyalkylene group-containing polymer composition, a surface treatment comprising the same and an article treated with the agent 有权
标题翻译： Fluoroxyalkylengruppenhaltige聚合物组合物，表面处理从而与第剂处理过的
公开(公告)号：EP2316869B1
公开(公告)日：2011-11-02
申请号：EP10188316.3
申请日：2010-10-21
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Yamane, Yuji , Koike, Noriyuki , Kishita, Hirofumi , Yamaguchi, Koichi
IPC分类号： C08G65/00 , C08G65/22 , C08G65/336 , C09D7/00 , C09D171/00
CPC分类号： G02B1/14 , C08G65/007 , C08G65/336 , C08G2650/48 , C08L71/02 , C09D5/165 , C09D171/02 , G02B1/105 , G02B27/0006 , C08L2666/22
摘要： An object of the present invention is to provide a fluorooxyalkylene group-containing polymer composition, which yields a coating having excellent adhesior to a substrate, good water- and oil- repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance and good stain resistance, and to provide a surface treatment agent comprising the same. The present inventors have found that a composition comprising a fluorooxyalkylene group-containing polymer having a fluorinated group and a hydrolyzable group at each terminal and a fluorooxyalkylene group-containing polymer having hydrolyzable groups at both terminals can form a coating which has excellent water- and oil- repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance, and good stain resistance.

23. 发明公开

EP2011831A2 Coating composition and a coating therefrom having waterdrop sliding property 有权
标题翻译： Beschichtungszusammensetzung und Beschichtung daraus mit Wassertropfengleitfunktion
公开(公告)号：EP2011831A2
公开(公告)日：2009-01-07
申请号：EP08159520.9
申请日：2008-07-02
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Yamane, Yuji , Koike, Noriyuki , Yamaguchi, Koichi , Kishita, Hirohumi
IPC分类号： C08L83/12
CPC分类号： C08L83/12 , C09D183/12 , Y10T428/31663
摘要： A coating composition comprising a fluorine-containing silicon compound represented by the following formula (1)

wherein Z is a linear or branched divalent polyorganosiloxane residue having 1 to 40 siloxane units, R is an alkyl group having 1 to 4 carbon atoms or a phenyl group, X is a hydrolyzable group, Q is a C 2-12 divalent connecting group, a is an integer of 2 or 3, b is an integer of from 1 to 10, y is an integer of 1 to 5, and Rf is a group represented by the following formula (2)

-Rf 1 -(Q-W-Q-Rf 1 ) q - (2)

wherein Rf 1 is a perfluoropolyether residue, W is an organopolysiloxane residue having 1 to 40 siloxane units and Q is as defined above and may be the same with or different from each other, and q is an integer of from 0 to 3, and
at least one solvent selected from the group consisting of alcohols, esters, ethers, ketones, and perfluoroethers. The coating prepared from the composition is oil-repellent, water-repellent and has water sliding property.
摘要翻译：一种涂料组合物，其包含由下式（1）表示的含氟硅化合物，其中Z为具有1至40个硅氧烷单元的直链或支链二价聚有机硅氧烷残基，R为具有1至4个碳原子的烷基或苯基 X为水解性基团，Q为C 2-12二价连接基团，a为2或3的整数，b为1〜10的整数，y为1〜5的整数，Rf为由以下公式（2）代表的群体：（1）ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ-Rf 1 - （QWQ-Rf 1）q - €ƒ€ƒ€ƒ€ƒ（2）其中Rf 1是全氟聚醚残基，W是具有1至40个硅氧烷单元的有机聚硅氧烷残基，Q如上所定义并且可以彼此相同或不同，q是0-3的整数，并且在至少一种选自醇，酯，醚，酮和全氟醚的溶剂。由组合物制备的涂料具有防油，防水，具有水滑动性。

24. 发明公开

EP0573283A1 Fluorine-containing organopolysiloxane composition 失效
标题翻译： Fluorenthaltende Organopolysiloxanzusammensetzung。
公开(公告)号：EP0573283A1
公开(公告)日：1993-12-08
申请号：EP93304283.0
申请日：1993-06-02
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Kishita, Hirofumi , Sato, Shinichi , Koike, Noriyuki , Matsuda, Takashi
IPC分类号： C08L83/08 , C08L83/12 , C08L83/14
CPC分类号： C08L83/14 , C08L83/00
摘要： A room temperature curable fluorine-containing organopolysiloxane composition comprising:

(A) a fluorine-containing organosilicon compound having the general formula (1):

R²-NHCO-[Rf-CONH-R¹-Q-R¹-NHCO] a -Rf-CONH-R² (1)

wherein a is an integer of 0 or more, Rf is a divalent perfluoroalkylene group or a divalent perfluoropolyether group, R¹ is a divalent hydrocarbon group, R² is a monovalent aliphatic unsaturated group-containing hydrocarbon group, and Q is a divalent siloxane group
(B) a hydrogenorganopolysiloxane containing at least two Si-H groups in its molecule, and
(C) a platinum family metal catalyst. The cured product of this composition exhibits good solvent resistance against non-polar solvents as well as polar solvents, in addition to good chemical resistance, heat resistance, release properties and water repellency.
摘要翻译：一种室温固化型含氟有机聚硅氧烷组合物，其包含：（A）具有通式（1）的含氟有机硅化合物：R 2 -NHCO- [Rf-CONH-R 1 -QR 1 - NHCO] a-Rf-CONH-R 2（1）其中a为0以上的整数，Rf为二价全氟亚烷基或二价全氟聚醚基，R 1为二价烃基，R 2为 >为一价脂肪族不饱和基团的烃基，Q为二价硅氧烷基（B）分子中含有至少两个Si-H基的氢有机聚硅氧烷，（C）铂族金属催化剂。除了良好的耐化学性，耐热性，脱模性和防水性之外，该组合物的固化产物对非极性溶剂以及极性溶剂表现出良好的耐溶剂性。

25. 发明公开

EP0562830A1 Fluorine-containing silicone rubber composition 失效
标题翻译：荧光光刻胶Silikonkautschukzusammensetzung。
公开(公告)号：EP0562830A1
公开(公告)日：1993-09-29
申请号：EP93302211.3
申请日：1993-03-23
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： Inomata, Hiroshi , Kishita, Hirofumi , Sato, Shinichi , Koike, Noriyuki , Matsuda, Takashi
IPC分类号： C08L83/12 , C08L83/14 , C08K5/14
CPC分类号： C08K5/14 , C08L83/14 , C08L83/12
摘要： A fluorine-containing silicone rubber composition comprising (A) a fluorocarbonsiloxane having the following general formula (1):

wherein a to d is a positive integer, R¹ and R² are a monovalent hydrocarbon group free of aliphatic unsaturated groups, R³ is a monovalent hydrocarbon group containing an aliphatic unsaturated bond, Rf¹ is a fluorine-containing alkylene polyether group, and (B) an organic peroxide. The composition is excellent in solvent resistance, chemical resistance and water and oil repellency, and can be molded by press molding and has been improved in respect of insufficient curing.
摘要翻译：一种含氟硅橡胶组合物，其包含（A）具有以下通式（1）的氟代硅氧烷：其中a至d为正整数，R 1和R 2为不含脂族不饱和基团，R 3是含有脂族不饱和键的一价烃基，Rf 1是含氟亚烷基聚醚基团，（B）有机过氧化物。该组合物的耐溶剂性，耐化学性和拒水拒油性优异，可以通过模压成型，并且在固化不足方面得到改善。

26. 发明公开

EP0549214A3 Silicone rubber compositions and cured products 失效
标题翻译：硅橡胶组合物和固化产品
公开(公告)号：EP0549214A3
公开(公告)日：1993-08-25
申请号：EP92311342.7
申请日：1992-12-11
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Takago, Toshio , Sato, Shinichi , Koike, Noriyuki , Matsuda, Takashi
IPC分类号： C08L83/14
CPC分类号： C08L83/14 , Y10S528/901 , C08L83/00
摘要： A RTV silicone rubber composition comprising (A) an organopolysiloxane composed predominantly of a silalkylenesiloxane unit and containing an aliphatic unsaturated group in a molecule, (B) an organohydrogenpolysiloxane having at least two SiH groups in a molecule, and (C) a platinum group compound cures into a transparent elastomer which is increased in rubbery strength without adding a filler.

27. 发明授权

EP2589615B1 Fluorooxyalkylene group-containing polymer composition, surface treatment agent containing the composition, and article and optical article treated with the surface treatment agent 有权转让
标题翻译： Fluoroxyalkylengruppenhaltige聚合物组合物中，表面处理剂与所述组合物和制品，以及与光学制品的表面处理剂处理
公开(公告)号：EP2589615B1
公开(公告)日：2017-01-04
申请号：EP12007419.0
申请日：2012-10-30
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Komori, Hisatoshi , Yamane, Yuji , Koike, Noriyuki
IPC分类号： C08G65/336 , C08G65/337 , C08L71/02 , C03C17/30
CPC分类号： C03C17/30 , C03C2217/76 , C08G65/007 , C08G65/336 , C08G2650/48 , C08L71/02 , C08L2205/02 , Y10T428/3154

28. 发明公开

EP2930201A1 METHOD FOR PREPARING A COMPOSITION COMPRISING PERFLUOROPOLYETHER HAVING A HYDROXYL GROUP AT ONE TERMINAL 有权转让
标题翻译：制造方法的全氟聚醚构成在一端具有羟基
公开(公告)号：EP2930201A1
公开(公告)日：2015-10-14
申请号：EP15162845.0
申请日：2015-04-08
申请人： SHIN-ETSU CHEMICAL CO., LTD
发明人： Yamane, Yuji , Matsuda, Takashi , Koike, Noriyuki
IPC分类号： C08G65/00 , C08G65/30 , C08G65/46
CPC分类号： C08L71/00 , B01D15/12 , C08G65/007 , C08G65/30 , C08G65/46 , Y02P20/544
摘要： An object of the present invention is to provide a method for efficiently and highly selectively preparing a composition comprising perfluoropolyether having a hydroxyl group at one terminal at a higher ratio. The present invention provides a method for increasing a ratio of perfluoropolyether having a hydroxyl group at one terminal, relative to a total amount of the perfluoropolyether having a hydroxyl group at one terminal and perfluoropolyether having hydroxyl groups at both terminals in a composition comprising these perfluoropolyethers, wherein the method comprises a step of subjecting the composition to chromatography in which a moving phase is supercritical or subcritical state carbon dioxide of the specific temperature and the specific pressure, and a stationary phase is silica gel to thereby collect a fraction containing the perfluoropolyether having a hydroxyl group at one terminal at a higher ratio. Further, present invention provides for increasing a ratio of perfluoropolyether having a hydroxyl group at one terminal, relative to a total amount of the perfluoropolyether having a hydroxyl group at one terminal, perfluoropolyether having hydroxyl groups at both terminals and perfluoropolyether having no hydroxyl group at any terminal perfluoropolyether, in a composition comprising these perfluoropolyethers, wherein the method comprises a step of subjecting the composition to chromatography in which a moving phase is supercritical or subcritical state carbon dioxide of the specific temperature and the specific pressure, and a stationary phase is silica gel to thereby collect a fraction containing the perfluoropolyether having a hydroxyl group at one terminal at a higher ratio.
摘要翻译：本发明的一个目的是提供一种有效地和高选择性地制备组合物，其包括全氟聚醚具有羟基在一个末端以更高的比率的方法。本发明提供了用于在一个终端增加具有羟基的全氟聚醚的比例，相对于具有在一个末端具有羟基的全氟聚醚的总量和全氟聚醚具有在组合物中的两末端具有羟基，其包括合成的全氟聚醚的方法， worin所述方法包括使所述组合物，其中流动相为特定温度和特定压力的超临界或亚临界状态的二氧化碳层析的步骤，和一个固定相是硅胶，从而收集包含具有全氟聚醚的馏分在以较高的比率一个端羟基。另外，本发明提供了用于在一个终端在一个末端增加具有羟基的全氟聚醚的比例，相对于具有羟基的全氟聚醚的总量，全氟聚醚两末端具有羟基和全氟聚醚具有在任何没有羟基终端的全氟聚醚，在包括合成的全氟聚醚的组合物，worin所述方法包括使所述组合物，其中流动相为特定温度和特定压力的超临界或亚临界状态的二氧化碳层析的步骤，和一个固定相是硅胶从而收集含有具有羟基全氟聚醚的一小部分在一个末端以更高的比率。

29. 发明授权

EP2383318B1 Adhesive composition 有权
标题翻译：粘合剂组合物
公开(公告)号：EP2383318B1
公开(公告)日：2014-04-02
申请号：EP11003017.8
申请日：2011-04-11
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Shiono, Mikio , Koike, Noriyuki
IPC分类号： C09D183/08 , C08G77/24
CPC分类号： C09D183/08 , C08G77/24 , C08L71/02

30. 发明公开

EP2479611A3 Chemically amplified positive resist composition and patterning process 有权
标题翻译：化学放大的正型抗蚀剂组合物和图案化工艺
公开(公告)号：EP2479611A3
公开(公告)日：2013-01-09
申请号：EP12151375.8
申请日：2012-01-17
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Yasudo, Hiroyuki , Takemura, Katsuya , Koike, Noriyuki
IPC分类号： G03F7/004 , G03F7/075 , H05K1/00 , H05K3/00 , G03F7/039
CPC分类号： G03F7/0048 , G03F7/0046 , G03F7/0392 , G03F7/0755 , G03F7/0757
摘要： A chemically amplified positive resist composition comprising (A) a substantially alkali insoluble polymer having an acidic functional group protected with an acid labile group, (B) an acid generator, and (C) a perfluoroalkyl ethylene oxide adduct or a nonionic fluorinated organosiloxane compound is coated, exposed to UV radiation having a wavelength of at least 150 nm, and developed. The composition has advantages of uniformity and minimized edge crown upon coating, and no scum formation after development.
摘要翻译：（A）具有用酸不稳定基团保护的酸性官能团的基本上不溶于碱的聚合物，（B）酸产生剂和（C）全氟烷基环氧乙烷加合物或非离子氟化有机硅氧烷化合物的化学放大型正光刻胶组合物是暴露于具有至少150nm波长的UV辐射并显影。该组合物具有均匀性和涂布后边缘冠部最小化的优点，并且显影后不会形成浮渣。

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